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By W. Zhang

"The adsorption of collector on bornite has been studied in situ in aqueous solutions by applying an atomic force microscopy (AFM). The AFM images show that xanthate, such as potassium ethyl xanthate (KEX) and potassium amyl xanthate (PAX), adsorbs strongly on bornite mainly in the form of insoluble metal xanthate, which binds strongly with the mineral surface without being removed by flushing with ethanol alcohol. This adsorption mechanism is very similar to the one obtained with chalcocite/xanthate system. However, the result also clearly shows that the adsorption of xanthate on bornite is totally different from its adsorption on chalcopyrite, during which oily dixanthogen is the main adsorption product on chalcopyrite surface. The obtained AFM images also showed that the adsorption increases with increasing the collector’s concentration. When Cytec Aerofloat 238, a dialkyl dithiophosphate collector, is used, it adsorb on bornite mainly in the form of an oily substance, which can be rinsed off mineral surface by flushing with ethanol alcohol. AFM images also show that the adsorption of Cytec Aerofloat 238 increases with increasing the adsorption time. INTRODUCTION The adsorption of collector on mineral surface is vital for a successful flotation process to achieve a satisfying recovery. Historically, many works have been carried out to clarify the adsorption mechanism of collectors on sulfides. (Gaudin and Schuhmann, 1936, Poling and Leja, 1963; Allison et al., 1972, Fuerstenau, 1982; Leja, 1982; Woods, 1984) Compared to other copper minerals such as chalcopyrite and chalcocite, much less work has been done to study the adsorption collector on bornite. Allison et al. (1972) studied the reaction products of various sulfide minerals with xanthate solutions and reported that the measured rest potential of bornite in 6.25×10-4 M KEX solution at pH 7 was +60 mV and the reaction product of PAX on bornite was cuprous alkyl xanthate. Mielczarski and Suoninen (1984a, 1984b) applied the XPS and studied the adsorption of potassium ethyl xanthate on cuprous sulfide. It was reported that there was a relatively rapid formation of a well-oriented monolayer of xanthate ions followed by a slow growth of disordered cuprous xanthate molecules on top of this layer. Buckley et al. (1984) investigated the surface oxidation of bornite by linear potential sweep voltammetry and X-ray Photoelectron Spectroscopy and proposed the adsorption products on bornite depended on the solution potential. Zachwieja et al. (1987) studied the electrochemical flotation of the bornite-ethylxanthate system and reported that KEX reacted with bornite through an electrochemical oxidation reaction forming cuprous xanthate between -0.4 and -0.2v (SCE). Hangone et al. (2005) studied the flotation of a bornite-rich copper sulfide ore using thio collectors and their mixtures and reported that the highest copper recoveries were obtained with the diethyl dithiophosphate (di C2-DTP)."

Jan 1, 2016

By Fumio Wada

Kuroko deposit is a stratabound massive sulphide and sulphate deposit associated with Miocene submarine volcanics and has been considered to be a prototype of meta- morphosed Palaeozoic and Precambrian equivalents. Since the discovery of Uchinotai deposit of the Kosaka mine in 1959, Dowa and other mining companies have conducted intensive exploration work in the Hokuroku district of northeastern Japan. Dowa has been placing its first priority on the exploration of Kuroko deposits and made a series of remarkable successes in finding the Kuroko deposits, i.e. Uchinotai, 1959; Matsumine, 1963; Uwamiki, 1966; Fukazawa, 1969 and Ezuri, 1975. It is emphasized that our successes have resulted from the proper application of exploration technologies accumulated through our experiences. Firstly we defined the Kuroko horizon and favourable felsic volcanism based on the detailed structural and volczno-stratigraphic study of the Hokuroku district, and then delineated the promising areas by means of the quantitative evaluation of geophysical, geochemical and mineralogical parameters such as the magnetic susceptibility and contents of alkaline and alkaline earth metals in the foot wall dacites and clay mineral assemblages of both hanging and foot wall pyroclastics and dacites. Practical application of these techniques is essential to our routine Kuroko exploration.

Jan 1, 1982

By K. L. Lamb

At the Sierrita mine, 40 km (25 miles) south of Tucson, Arizona, Duval Corporation is rapidly gaining operating experience with its new Portable Crushing and Conveying System, (PCCS). As of November 23, 1983, over 4.5 million tons (5.0 million st) of ore have passed through the system. Mining cost per ton for the months of July, August and September was 83% below the average for the first five months of 1983. Although all the cost reductions experienced cannot be attributed to the Portable Crusher, it was a major contributing factor. The Sierrita ore deposit has several natural topographic and geologic conditions which are not favorable to mining. It is not a sidehill deposit and therefore no low-level exit points exist to facilitate truck haulage. The ore is very hard. Quartz diorite, hardest of the three major rock types, averages 172-207 MPa (25-30 000 psi) unconfined compressive strength and may run as high as 345 MPa (50 000 psi). Blasting in this rock produces oversize material which runs approximately 20% 51 centimeters (20 inches). The ore is low grade, averaging slightly better than .30% contained copper and .035% contained molybdenum, with small amounts of silver. These conditions, plus high design production tonnages, make the Portable Crushing and Conveying System (PCCS) practical for Sierrita. Without crushing and conveying, truck haulage would be prohibitively expensive. A typical, October, 1983, ore haul from the bottom of the pit would involve a vertical lift of 260 meters (850 ft) and a horizontal distance of 3 860 meters (12 200 ft) were not in-pit crushing and conveying available. The corresponding cycle time would be nearly 32 minutes.

Jan 1, 1984

By R. W. Waytulonis

New exhaust control techniques and devices may be necessary to meet future diesel particulate matter emission standards in underground coal mines. This paper reviews conventional work practices and devices used to control diesel exhaust emissions, and new techniques being tested by the Bureau of Mines. Discussions will center on important work practices and on the function and efficiency of exhaust after-treatment devices. An industry/government cooperative research project to develop and test an exhaust after-treatment system for part 36 equipment is also discussed.

Jan 1, 1990

By J. J. Sammarco

Computer-aided control of a mining machine pl aces its operator in a safe, remote location, thus reducing health and safety risks, Sensing systems that provide machine position (xy coordinate) and heading (yaw), are extremely useful in aiding remote positioning of mining machines. The U. S. Bureau of Mines has developed two sensing systems for position and heading information: A scanning laser system based on the Lasernet sensor and a mechanical position and heading system based on linear-position transducers. The Bureau is also investigating a system from Honeywell, the modular azimuth and positioning system that employs ring-laser gyroscopes. This paper presents a brief background and status of these sensing systems as applied to the remote positioning tasks of a continuous mining machine. Included are field test results of each system operating in a room-and-pillar research section at a cooperating mine in West Virginia.

Jan 1, 1992

By C. E. Larson

Man's use of 'glass predates recorded history. Although early man had no knowledge of how to form glass, artifacts have been found near naturally occurring glass formations where molten rock had been rapidly cooled. In areas where volcanic activity is evident, primitive people fortunate enough to have lived in that area used the naturally formed glass to make arrow heads, knife blades, tools and ornaments. These glass artifacts have been found all over the world. In fact in todays modern society there are recorded cases of aboriginal tribesmen in Australia fabricating arrowheads from glass bottles. 2. A Brief History of Glass The first evidence of man made glass were beads made around 2500 BC by the Egyptians. The Mesopotamians also made glass beads at about the same time.

Jan 1, 1986

By Jerry W. Owens

Current steel consumption for grinding media, mill liners and rods in North America runs in excess of 400,000 tpy in the mineral processing industries. Steel consumption ranks as one of the major consumables along with energy in most operations with total annual industry expenditures in excess of $275 million. It is generally agreed that there are 3 main categories of wear responsible for this metal loss. These three main types can be loosely defined as follows; 1) Abrasion. The cutting, rubbing, scrapping and gouging of the metal surface by the ore with which it is in contact; 2) Impact. Spalling on both micro and macro scale, breakage, and deformation due to metal to metal contact; 3) Corrosion. The oxidation losses of the metal due to electrochemical interaction between the grinding media and the slurry

Jan 1, 1984

The future phosphate rock deposits in South Florida contain a significant fraction of dolomite. The high MgO content of the rock is undesirable in the production of phosphoric acid. Several flotation schemes have been attempted to separate dolomite from phosphate rock. Alternately, Selective Flocculation process has been suggested to separate dolomite from apatite. A high MgO content rock was simulated by a 30:10:60 synthetic mixture of apatite, dolomite and silica. Single mineral selectivity was observed in the mixed mineral systems apatite-silica and dolomite-silica with Polyacrylic acid (PM) and Poly(ethylene oxide) (PEO) flocculants respectively but not realized in apatite-dolomite system with PEO flocculant. Heteroflocculation, suspected to be the major reason for loss in selectivity, was minimized by addition of a Site Blocking Agent (lower molecular weight fraction of PEO). Process parameters such as size reduction schemes, flocculant/SBA dosage, and pH were investigated to achieve the desired separation. The selectivity obtained in binary mixed mineral tests was translated into the ternary mixed mineral system, viz. apatite-dolomite-silica. In this presentation surface chemical characterization of the samples and their flocculation behavior will be discussed.

Jan 1, 1994

By M. Guzman, S. B. Thais, M. F. Obispo, M. R. Arribasplata

The impact generated by old abandoned mines in Peru have produced mining environmental liabilities, which can generate an impact on the environment. In the search for long-term sustainable solutions, Phytoremediation is presented as an interesting alternative, since it allows the use of Peruvian native plant species for the accumulation of heavy metals. In this paper, we present the results of native high Andean species: Stipa Ichu and Cortaderia Nitida. The final metal concentration in the aerial parts and in the roots of each plant show that Stipa Ichu is more efficient to recover Fe, reaching almost 278 times its initial value. In the same way, this plant is efficient to remove Zn, Cu and Cd, reaching maximum values of 64, 39 and 12 times its initial concentration respectively. Cortaderia Nitida turned out to be more efficient to recover Fe, Zn, Cu and Cr, with highest recovery of 250, 117, 39 and 13 times its initial value respectively. Finally, based on translocation factor, Stipa Ichu has better capacities of hyperaccumulation of Fe, Cu, Zn, Pb and Cr. Cortaderia Nitida only shows hyperaccumulation of Cr.

Mar 2, 2022

By S. Upadhyay, A. M. Afrapoli

"Fluctuation in market price of mineral products has enforced mining companies to cut down their operating costs. One useful way of reducing operating costs in mining operations is to make optimal operational decisions, incorporating efficient mining fleet management systems (FMS). Over the last 50 years, several types of FMS have been developed and introduced in the mining systems around the world. However, there are two major shortcomings in existing systems. Firstly, none of the existing systems consider effects of the short-term plan on dynamic truck assignment. Secondly, most of the existing FMSs make decisions in a way that optimize a specific objective while ignoring others. Herein, we propose a multi stage and multi objective FMS that deals with aforementioned shortcomings of the currently available systems. The developed FMS, in its upper stage, links semi-dynamic operational decision making process to the short-term production plan by simultaneously assigning shovels to mining faces and allocating trucks to the shovels by implementing its first multi objective decision making model. Then in its second stage, in a real time dynamic decision making process, it assigns trucks to shovels and corresponding destinations by optimizing its second multi objective decision making model. The developed fleet management system has been verified using an Iron ore case study and the results are presented in this paper. INTRODUCTION Open pit mining method is the most common method to mine mineral from the earth. Based on Wetherelt and van der Wielen (2011) there exist 2500 open pit metal mines that are categorized as industrial scale mines. Over all of those, the amount of material handled using truck and shovel material handling system is more than the amount handled by all other systems together (Humphrey & Wagner, 2011).It has been proven by several studies that more than 50 percent of operating cost in a truck and shovel based open pit mining operation is accounted for material handling (Moradi Afrapoli & Askari-Nasab, 2017, Alarie & Gamache, 2002, Ahangaran et al., 2012). Thus, introducing even 1 to 2 percent cut in its material handling cost saves huge amount of money for the stakeholders. Over the last 50 years, two major areas have been identified to cut this cost. On one hand mining industries have been implementing equipment with higher production capacities, and on the other hand, researchers have been developing operations research techniques to make dynamic decisions as close to optimal as possible to deduct operational costs in truck and shovel based mining operations."

Jan 1, 2018

By W. Zhang

"The adsorption of collector on chalcocite has been studied in situ in aqueous solutions by applying an atomic force microscopy (AFM). The AFM images show that xanthate, such as potassium ethyl xanthate (KEX) and potassium amyl xanthate (PAX), adsorbs strongly on chalcocite mainly in the form of insoluble metal xanthate, which binds strongly with the mineral surface without being removed by flushing with ethanol alcohol. The result clearly shows that the adsorption of xanthate on chalcocite is totally different from its adsorption on chalcopyrite, during which oily dixanthogen is the main adsorption product on chalcopyrite surface. AFM images also showed that increasing solution pH to 10 doesn’t prevent the adsorption of xanthate on chalcocite much and the result confirms with the fact that chalcocite floats well in a wide pH range up to 12 with xanthate being used as a collector. INTRODUCTION In flotation, the adsorption of collector on mineral surface is vital for a successful flotation process to achieve a satisfying metal recovery. Historically, many works have been carried out to clarify the adsorption mechanism of collectors on sulfides. (Gaudin and Schuhmann, 1936, Poling and Leja, 1963; Allison et al., 1972, Fuerstenau, 1982; Leja, 1982; Woods, 1984) The adsorption of xanthate on chalcocite surface in aqueous solution also attracted the interest of many researches. Gaudin and his colleagues (Gaudin et al., 1934; Gaudin and Schuhmann, 1936) studied the solubility of potassium ethyl xanthate and its reaction products in organic solvents and firstly proposed there was initially chemisorbed xanthate (X-) on chalcocite surface followed by insoluble cuprous xanthate (CuX). Allison et al. (1972) studied the reaction products of various sulfide minerals with xanthate solutions and reported that the measured rest potential of chalcocite in 6.25×10-4 M KEX solution at pH 7 was +60 mV and the reaction product of PAX on chalcocite was cuprous xanthate. Mielczarski and Suoninen (1984a, 1984b) applied the XPS and studied the adsorption of potassium ethyl xanthate on cuprous sulfide. It was reported that there was a relatively rapid formation of a well-oriented monolayer of xanthate ions followed by a slow growth of disordered cuprous xanthate molecules on top of this layer. Richardson et al. (1984) carried out an electrochemical study of chalcocite flotation with the addition of ethyl xanthate. It was proposed that cuprous xanthate and possibly cupric xanthate were adsorbed hydrophobic species on chalcocite surface due to the exchange and charge transfer oxidation reactions. Leppinen et al. (1989) applied an in-situ FTIR study of ethyl xanthate adsorption on sulfide minerals under conditions of controlled potential and they concluded that, for chalcocite, there were three different potential regions of xanthate adsorption, including chemisorption, copper ethyl xanthate formation on the surface and multilayer formation."

Jan 1, 2015

By David A. Zegeer

It's a pleasure to be here, and an honor to be invited to address this distinguished group of professionals. Today, I'd like to begin with an overview of progress in coal mine safety and health. I'll discuss some current areas of concern. And I'll make some suggestions as to where we may be headed in the future. This year marks the coal industry's 15th anniversary under the Coal Mine Safety and Health Act, which took effect in 1970. We have come a long way in those 15 years. As a coal mining man from way back, I remember the era when the Coal Mine Safety and Health Act first was passed. Some of you may remember it, too. At that time, the safety and health of coal miners was in the public eye even more than it is at present. One reason was a mine explosion that killed 78 miners when it occurred in a large underground coal mine in November 1968. That disaster raised tremendous public concern about protecting the safety of miners.

Jan 1, 1985

By Michael J. Friedel

The permeability and flow capacity in unsaturated media is investigated by the Bureau of Mines for application to in situ copper leach mining at the Cyprus Casa Grande mine site. Moisture retention properties are derived and combined with scanning electron microprobe data to characterize the mineralogy, texture, pore size, distribution, and permeability of the host rock. Finite element modeling is used to derive a saturated permeability, ambient degree of saturation, and assess various injection-recovery schemes. Recommended design modifications for optimization of solution distribution and maximum recovery from the rock matrix requires either (1) the injection pressures on the order of 1500 psi and recovery wells operating in a suction mode, or (2) performing permeability enhancement, through rubblization. By producing a maximum block diameter of 4 m, injection pressures can be reduced to 500 psi with improved recovery and containment of solutions.

Jan 1, 1991

By Paul A. Rittenhouse

Its a pleasure to be with you this afternoon and to talk briefly on one of my favorite subjects -- the U.S. sulphur industry. As our Chairman mentioned, I have been associated with the sulphur industry either directly or indirectly for the last twenty years, both on the production side and as a consumer. Sulphur, while unseen and relatively unknown to most people, is like margarine ... that ubiquitous spread ... that is yellow and nearly omnipresent in the industrial world. It is because sulphur, in some form, is required in nearly all aspects of our economy that makes its study so interesting to me as a researcher. An analysis of the sulphur outlook requires examination of such industries as fertilizer, paints and pigments, copper and zinc, uranium, petroleum, chemicals, pulp and paper and textiles - just to name a few. Of course, because its use is so widespread and ever-changing it is difficult to develop and maintain a good understanding of the sulphur industry. It is also a problem to cover the industry in a short discussion and to project its really dynamic nature. Hut, if you will bear with me, I will attempt the task. First of all, let me say that sulphur today is a world commodity and to a large extent moves freely in world trade; nearly a third of the world's sulphur or something over 15 million tons in 1974 entered international trade. However, today our interest is in the current changing sulphur picture in the U.S., with particular emphasis on the western part of the country.

Jan 1, 1975

By Ronald Ludchak

Since coal has been designated as the short-term answer to the threatening world energy crisis, improved surface mining techniques, along with improved extraction and handling equipment, are needed to increase the amounts that can economically be mined by open pit methods. A dwindling supply of low cost oil and gas have dictated a major rethinking of our energy sources and their use. New methods for open pit coal mining have to be found to increase coal production and to meet more stringent reclamation laws. Modern twin-engine elevating scrapers can play a vital role in meeting these needs. They are readily available, with short delivery times, from several experienced manufacturers of earthmoving equipment. Recent developments of the elevator system have extended its working range to include many of the materials commonly encountered in open pit mining. The paper deals with the advantages of using twin-engine elevating scrapers in the performance of various mining tasks. These tasks range from utility work to the major task of using the scrapers as a primary stripping toot and, of even more importance, a stripping- reclamation tool for, with scrapers, the overburden can be moved and redeposited in the same strata sequence or soil horizon as in its natural state. A recap of current applications of the elevating scraper will be presented, along with proposed uses.

Jan 1, 1975

By Z. Rogovin

In order to develop more accurate procedures for scale-up and design of semi-autogenous-grinding mills through detailed mathematical models, a better understanding of the charge motion and rock/ball segregation is needed. To achieve this a 0.61 m (2.0 ft) diameter x 0.305 m (1.0 ft) length plexiglas mill was constructed as a scale model of a commercial SAG mill. Rock motion in the rotating mill was simulated using various sizes of ceramic balls. Quantitative measurements of dynamic angle of repose, water and slurry motion, holdup and size segregation of the charge were taken. In addition, a video-presentaiton (available to the public) was prepared to elucidate charge and water motion at various mill speeds, charge volumes, rock size distribution and flow rates.

Jan 1, 1985

Integrated mining information and process control systems can reduce information delays, enhance decision making and improve the responsiveness of mining operations to, for example, variations in market conditions, mineral grades and ground conditions. This paper examines developments in the areas of: monitoring, data analysis and diagnosis,' communications systems; integrated mining support system;, and process and machine control. It concludes that the development of a comprehensive information technology plan is fundamental to the phased implementation of these technologies. In addition, hardware and software standards and concurrent digital design and simulation practices in selected manufacturing industries are examined and concluded to have relevance to the mining industry. Integrated information and process control systems will lead to emergence of the "digital mine". Such advances in mining information infrastructure as well as mining equipment will enable mining operations to shift from mass production methods to leaner production techniques. "Lean mining" aims to enhance and accelerate cash flow over the life of a mine by focusing on reduction of' throughput times; stockpiles for volume and quality control; and wastage and rework.

Jan 1, 1995

By A. Taghavi, I. Hassan, A. Solecki

"The Eglinton Crosstown Light Rail (LRT) Project is part of an $8.4 billion investment to expand transit in the Toronto, Canada area and is the largest transit project initiated in Province’s history. Settlement control and impact to over 1400 adjacent structures due to tunnelling was identified early as a critical project risk. The ground conditions along the 10km tunnel alignment consist of water bearing soft ground deposits (clays, sands, silts) which required careful analysis and control during design and construction. This paper will describe the process used to analyze settlements along the numerous of adjacent structures and evaluate achieved settlement results to those used during design. The paper will demonstrate that with the appropriate design specifications, selection of modernized EPB machines, and contractor performance, settlement can be maintained well below typical industry (volume loss) standards, expanding the application and suitability of soft ground tunnelling in sensitive settlement areas. INTRODUCTION The Eglinton Crosstown Light Rail Transit (LRT) Project is part of an $8.4 billion (2010$ CND) investment from the Ontario provincial government to expand transit in the Toronto, Canada area. The project is being developed by Metrolinx, an agency of the Government of Ontario to provide 19 kilometers of dedicated LRT service connecting the City of Toronto from the west to east along Eglinton Avenue. Upon completion in the year 2020, the Crosstown will be the first LRT constructed in Toronto. It will link regional and local transit, cut travel time along the route by half and provide over a thousand jobs during construction."

Jan 1, 2016

By S. K. Kawatra, V. Claremboux, S. Valluri

Carbon dioxide capture from coal-fired power plant flue gas and subsequent sequestration is expected to play a vital role in mitigating global climate change. To meet the growing need for CO2 capture Technology, Michigan Technological University is researching CO2 capture and Utilization. We have successfully converted CO2 into oxalic acid using an electrochemical approach. If oxalic acid can be produced in bulk from CO2, it can be used to leach rare earth minerals at low cost. Electrochemical reduction of CO2 to hydrocarbons and other chemicals is a complex multistep reaction with adsorbed intermediates. The exact reaction mechanisms leading to various products are not clear from the literature to date and will likely change over the range of conditions like pH, electrode potential, electrolyte medium, catalyst, etc. In this paper, we will present an idea of how the factors mentioned above will effect the electrochemical reduction of CO2 to Oxalic acid. INTRODUCTION. CO2 is thermodynamically quite stable, as shown by its highly negative heat of formation. Thus, it is expected that the formation of any useful chemical from CO2 will require the input of at least as much energy as geological sequestration. However, to be more effective the resulting economic value of the chemical need only pass the cost of the additional energy required beyond geological sequestration. This lends itself to two extremes: one where the quantity of energy required is low and one where the economic value of the additional energy is low. It is expected that CO2 can be reduced via electrolysis to several compounds. Of particular interest are formic acid, oxalic acid, methanol, ethanol, formaldehyde, and carbon monoxide (as a component to syn-gas). These chemicals have been reported as electrolytic products previously in literature and have considerable potential for application. EXPERIMENTAL Electrocatalytic Production of Oxalate from CO2 We are using membrane electrolysis cell to produce oxalate from CO2. A membrane electrolysis cell is a 2-chamber electrolysis cell where the chambers are separated by a selectively permeable membrane. To produce oxalate, a cation exchange membrane (which selectively exchanges cations) was used. Previous literature suggests that in the cathode chamber an organic electrolyte, such as tetraethylammonium perchlorate or tetraethylammonium bromide in dimethylformamide, are preferred3. In the anode chamber, a sodium hydroxide solution water is used. Carbon dioxide is then bubbled into the cathode chamber as a current is applied.

Jan 1, 2019

By William P. Blacutt

This paper describes the strategy, the struggles, and the obstacles encountered during the last two years in the ongoing process to capitalize Vinto. The effort involves the offering of a vertically integrated business package composed of the tin and antimony smelters along with the two principal tin mines of the country. Capitalization: Bolivia's Innovative Approach for Privatization, the Vinto Case provides a summary of hard-earned lessons. These experiences can be success- fully implemented in other nations committed to transforming their state natural resource sector.

Jan 1, 1998