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By Wm Petruk

"The tungsten-bismuth-molybdenum deposit in southwestern New Brunswick occurs in greisenized and silicified tuffite * and feldspar porphyry in and adjacent to volcanic necks. The ore minerals occur as veins and veinlets and as disseminated grains in gangue. These minerals can be grouped into three assemblages. Assemblage 1 consists of oxides and phosphates of W, Ti, Fe, Nb, Sn, Ta and rare-earth elements, with the main minerals being deposited in the sequence wolframite, rutile, cassiterite. Assemblage 2 consists of arsenopyrite, molybdenite and bismuth, and assemblage 3 of sulphides with minor cassiterite and arsenopyrite. Sphalerite is the main sulphide mineral, but it contains minute inclusions of copper-tin- and indium-bearing minerals. Textural relations suggest that most of the elements can be recovered from this ore by conventional mineral beneficiation and extraction methods, but a variety of techniques must be employed. It is expected that the wolframite and molybdenite can be recovered satisfactorily, but poor recoveries are expected for bismuth and cassiterite. A sphalerite concentrate can be readily obtained by flotation, but it would contain a wide variety of elements. It is suggested that leaching be used to recover the bismuth and the elements in the sphalerite concentrate."

Jan 1, 1973

By Joan C. Biordi

A molecular beam-mass spectrometer-low pressure flat flame apparatus has been constructed for the purpose of examining the chemical microstructure of normal methane-oxygen-argon flames and those inhibited with Halon extinguishants. Details of construction and performance of this apparatus and of related flame temperature measurements are given. Particular attention is paid to the empirical characterization of the perturbation to the flame caused by the sampling probes. The composition profiles obtained for normal flames are compared to those of flames inhibited by CF3Br. In addition to the usual stable species (CH4, O2, CO, CO2, H2O, H2, and H2CO), the inhibitor, its products and intermediates associated with its reactions could be followed. In particular, hydrogen bromide, bromine atoms, hydrogen fluoride, and carbonyl fluoride were observed. The relatively rapid disappearance of inhibitor and early appearance of fluorinated reaction products suggest a short lifetime for the CF3 radical in this system. Observation of COF2 suggests that CF3Br is effective as an inhibitor, at least in part, by virtue of its interference with the oxygen containing species of the normal chain reaction. Profiles of the 17+ peak at low electron energy suggests that the hydroxyl radical may also be sampled, but the profiles obtained are not yet sufficiently accurate to determine the effect of inhibitor on this important flame radical.

Jan 1, 1973

By Robert E. Barieau

General expressions for evaluating various thermodynamic properties applicable to the van der Waals equation of state have been derived. These formulas were subsequently used to evaluate various thermodynamic functions in the two-phase region. The results indicate that, for a van der Waals fluid, there is a finite discontinuity in the second derivative of the vapor pressure curve, in the second derivative of the chemical potential or Gibbs free energy at the critical point, and in the heat capacity at constant volume measured at the critical density. Numerical values are tabulated and graphs are presented for all functions calculated.

Jan 1, 1967

By R. F. Stewart

A key step in changing coals to fluid fuels and chemicals is the conversion of coal to synthesis gas by gasification with steam and oxygen. As oxygen represents one of the largest single expenses in gasification, its cost is a vital factor in the economy of the process. At present, the most economical method for producing tonnage oxygen is by the conventional rectification of liquefied air. Several alternate methods have been proposed for producing oxygen from air: (1) methods based on physical or chemical sorption of oxygen from air by liquids or solids or (2) the oxidation of certain inorganic com-pounds to higher oxides unstable at higher temperature levels. Economic limitations are discussed by which these methods may be evaluated. Chelated metals of the salcomine type are promising chemical sorbents of oxygen from air. This report covers a study of the reversible sorption of oxygen by salcomine and other chelates. The presence of water in the salcomine structure was verified; it is the loss of this water that causes slow deterioration of salcomine during cycling.

Jan 1, 1959

By C. R. Tinsley

Investment activity in the Pacific Rim of Fire has seen a phenomenal surge from epithermal gold exploration. Individual countries are attractive because of lower up-front minerals lease costs (US, Canada), better geological prospectivity (Chile, Indonesia), or cheaper equities (Australia). Since the October 1987 stock-market crash, large companies are shedding minority joint venture interests to focus on core businesses. Some vertical integration is evident in Japanese coal investments in the Pacific Rim. This paper does not cover the aluminum industry oligopoly which is multi-national in character nor does it cover the many Canada to US minerals investments. It will be interesting to see if the new US-Canadian free-trade treaty will reverse that investment flow.

Jan 1, 1990

By Gerhard Bischoff

El presente trabajo compara las contribuciones potenciales de las diferentes fuentes de energía primaria, es decir; petróleo, gas natural, carbón de piedra, lignito, fuerza hidráulica y minerales susceptibles a fisión nuclear, con el total de las existencias disponibles en el futuro.

Jul 1, 1970

By E. LaRocque

Denison Mines Limited has been processing uranium ore in the Elliot Lake area for the past 20 years. As the original concept of uranium processing has been modified somewhat over this period, the present paper will describe the current recovery practices at the Denison mill from crushing through concentrate drying and packing . Special emphasis will be placed on the leaching, ion exchange and precipitation sections of the process, with consideration being given to the entire circuit. Descriptions will be given of equipment now being used and control strategies will be discussed.

Jan 1, 1979

By Zhan-fang Cao, Hong Zhong, Li-feng Li, Shuai Wang, Xiao-yu Cao, Guang-yi Liu, Ming-ming Wang

"In recent years, there has been an increasing focus on the hydrometallurgical processing of molybdenite, with the decline of high-grade and easily handled molybdenum minerals. In this work, a novel method of selective extraction of complex molybdenite concentrate, which is characteristic of high-grade copper ore, has been investigated. The results show that the leaching of chalcopyrite was impacted by the pH of the electrolyte when sodium carbonate and ammonium acid carbonate were added to the electrolyte. The leaching rate of molybdenum reached 99.39%, but chalcopyrite could not be leached at all in 240 min under experimental conditions of liquid-to-solid ratio 25:1, concentration of NaCl 4 mol/L, pH=9, room temperature and agitation speed 400 rpm. The grade of copper in the residue was 21.84%, with a recovery 99.93%. The technology of selective electro-oxidation leaching of molybdenum and recovery of copper from complex molybdenite concentrate is an effective separation method. The diffusion control model can be used to describe the process of leaching of molybdenum. The activation energy of the leaching reaction was found to be approximately 9.21 kJ/mol.IntroductionWorldwide, high-grade and easy-to-handle ore is decreasing, while the proportion of low-grade and complex ore is increasing. Porphyry copper ores with associated low-grade molybdenite are very abundant in China. Molybdenum is a valuable byproduct in the processing of porphyry copper deposits where the molybdenum is present in low quantities in the form of molybdenite (MoS2). In the conventional processing of copper sulfide ores by froth flotation, most of the molybdenite in the ore floats along with the copper sulfides. In this way, a bulk copper-molybdenum concentrate is produced. Afterward, the bulk coppermolybdenum concentrate is treated by differential flotation to obtain a rougher molybdenum concentrate, which requires several successive cleaning steps to produce a final molybdenum concentrate. However, it is widely recognized that flotation alone cannot economically produce a high-grade molybdenite concentrate, i.e., with less than 0.5% Cu. Therefore, in most cases, it is necessary to use a final step of chemical purification of the molybdenite concentrate to reduce the copper content to a level suitable for the market (Antonijevic and Pacovic,1992; Gerhardt et al., 2001; Fu and Zhong, 2003; Reza et al., 2006, Rafael et al., 2013)."

Jan 1, 2015

By R. M. Corn

The Non-Time Critical Forest service CERCLA Action at Mansfield Canyon, Santa Cruz County, Arizona designated previous locators of unpatented mining claims as owners/operators of the Hazardous Waste Facility, retroactively liable for all reclamation costs including reclamation of mines acquired by the Forest Service. The CERCLA Action is based on non-existent tailings, a non-existent permanent resident, inaccurate and unreliable data and did not review or consider prior USGS and USBM data. The consequences of the Forest Service action include(1) reduced exploration, (2) loss of credibility, (3)public disillusionment and distrust.

Jan 1, 2000

Terminology. The term potash originated in "pot ashes" produced by burning wood to ashes in iron pots and then leaching out the soluble salts, chiefly potassium carbonate, from the residue. In modern usage potash is a generic term for various potassium salts used in agriculture and industry. More specifically, it denotes the oxide of potassium, K2O, and the content of potassium in ores and products is stated as weight percent of K2O present. Its salts are commonly referred to as muriate of potash, sulfate of potash, etc. The presence of an adequate supply of available potassium in the soil promotes the health and improves the quality of the plant. insures greater efficiency in photosynthesis, increases resistance to certain diseases, offsets the effect of an oversupply of nitrogen, and helps the plant to utilize soil moisture more advantageously. ("Soils and Men," U.S. Dept. of Agriculture Yearbook 1938.) Occurrence. Potassium ranks seventh among the elements in abundance. It is estimated to constitute some 2.6% of the lithosphere and is found in soluble forms in the oceans, lakes, rivers, and subsurface waters. It is also an important constituent of plant and animal life. Commercially significant accumulations of potassium salts occur in underground deposits formed in past geologic times by evaporation of ancient bodies of saltwater, inland drainage basins, and shallow sea lagoons. The potash content of such waters was the end result of weathering and leaching of insoluble potash-bearing aluminosilicates, such as feldspars, micas, leucitcs, and others. The concentrations of potassium salts in the natural brines of some lakes in the arid and semiarid regions of the continents are also important as sources of potash; the brines of the Dead Sea in Asia Minor, the Great Salt Lake in Utah, and Searles Lake in California typify such concentrations. Every continent has major potash deposits as listed in Table 1 adopted from Cawley.1

Jan 1, 1985

Idaho Bureau of Mines and Geology, University of Idaho, Moscow, Ida. John W. Finch, Director. A list of publications will be sent upon application. A series of Bulletins and Pamphlets have been issued by the Bureau to date since 1920 Of the Bulletins, six are out of print, and a charge is made for eight. Each of the Bulletins, in the main, treats of the geology and resources of a particular district in Idaho, as follows (only available Bulletins listed): Bulletin 1, South central Idaho (1920), 15 cents, 7, North central Idaho (1924), 50 cents, 8, Bonneville, Bingham and Caribou counties (1924), 50 cents, 9, Boise Basin (1924), 50 cents; 10, Boundary County (1926), 50 cents; 11, Region about Silver City (1926), 50 cents; 12, Clark Fork district (1930), 50 cents, 14, Eastern Cassia County (1931), 50 cents, Press Bulletin 15, Teton County (1927), Bulletin 16, Melon Valley near Buhl (1927); 17, Concerning land slips near Whitebird, Idaho (1928) The 37 Pamphlets are issued free of cost, and each treats, also, in the main of the geology and resources of a particular district in Idaho Nos 1, 2, 3, 4, 5, 7, 8, 10, 17, 18, 20, 22, 25, 26, 30 and 35 are out of print Of those available, attention may be called to Pamphlet 6, Reported platinum occurrences near Coeur d' Alene (1925), 11, Bruneau River Basin, 12, Power and Oneida

Jan 1, 1933

By W. J. Birch, M. Kirke

Despite increasing competition from mechanical methods of tunnelling, the drill and blast method is often still the most viable method of excavating tunnels in strong and abrasive rock. To advance a tunnel using drill and blast, explosives are loaded into boreholes in the rock and detonated according to a prearranged sequence. On detonation of the explosive, the rock is fractured and displaced from its original position, leaving behind the desired void. Among the secondary effects of a tunnel blast are ground vibrations caused by elastic disturbances that propagate away from the blasted tunnel face. The possibility that such ground vibrations may cause permanent damage to property and substantial nuisance has generated significant opposition to the use of drill and blast, particularly in urban areas. It is therefore essential that the blasting engineer is able to predict Peak Particle Velocity (PPV) vibration levels at locations in the vicinity of the blast site. Such predictive capability enables the engineer to design blasts so as to ensure that ground vibrations can be kept within acceptable levels. The objective of this project was to analyse data obtained from the ground vibration monitoring program undertaken during the drill and blast excavation of a hard rock tunnel in Central England. Seismograph recordings of tunnel blasts contain a vast amount of information that cannot possibly be expressed using a single PPV value. The main focus of the study was to investigate whether predictive capability could be improved by using scaled distance models derived for selected PPV components relating to specific detonator timings in a given tunnel round. This study has established a method of analysis that can unlock this information for predictive purposes. By permitting the extraction of sub-event Peak Particle Velocity (PPV) values and allowing Scaled Distance (SD) models to be derived for individual period numbers or groups of period numbers, the method has the potential to vastly improve PPV prediction from tunnel blasting. The method established could also help diagnose blasting problems and help target blast design modifications, resulting in improved efficiency and excavation rates.

Jan 1, 2005

By D. J. Barratt

The application of autogenous and semi-autogenous grinding circuits in recent years has contributed toward substantial savings in capital and operating costs compared to conventional circuits, particularly for large scale copper and molybdenum operations. Such savings have been realized from the deletion of operating, maintenance, equipment purchase and substantial civil/structural costs associated with secondary-/tertiary crushing and screening, fine ore storage and conveying. In spite of the downturn in the copper- moly industry in North America, there is still an interest in autogenous and semi-autogenous grincting for copper-zinc, gold and silver ores and in the overseas market. Both single-stage and two-stage circuits are in operation. Primary circuits operate autogenously or semi-autogenously in either open or closed-circuit. Critical sizes are extracted and crushed for recycle in some cases (e.g. ABC circuit). Secondary grinding is conducted using ball mills or pebble mills.

Jan 1, 1985

By Wilford S. Wright, Harold E. Heide, Robert S. Sanford

"INTRODUCTION The United States production of tin has always been negligible, and domestic requirements have been met almost entirely by imports. The advent of war in Europe in 1939 brought a threat to our foreign source of supply, and steps were taken by Congress to forestall shortages of tin and other metals. By authority of the Strategic Minerals Act, passed by Congress in 1939, the Bureau of Mines and Geological Survey conducted investigations of domestic tin deposits.An examination of Alaska deposits was undertaken in 1940 and 1941 by J. B. Mertie, Jr., and Robert R. Coats of the Geological Survey.H. B. Heide conducted a preliminary examination of lode and placer-tin deposits at Cape Mountain in 1942, which was followed in 1943 and 1944 by a program of exploration by churn drilling in the placer area and trenching and sampling the lode deposits.Placer tin, found at the head of Goodwin Gulch, Cape Creek, First Chance Creek, and Boulder Creek, indicates that the mineral was derived from the vicinity of lode cassiterite occurrences on Cape Mountain. Placer tin led to the discovery of at least one, cassiterite vein by the Geological Survey and the Bureau of Mines."

Dec 1, 1946

By M. W. Davies, P. N. Smith

The activity of MnO has been measured in the system CaF2-MnO at 1773 and 1873 K and in the system CaF2-CaO-MnO at 1773 K by the method of equilibration with platinum. Large positive deviations from ideal solution laws have been found, but these became less as the lime content rose. The loss of a volatile component made activity measurements impossible in the CaF2-AI203-MnO system, but the boundaries of a two-liquid region have been measured at 1773 K.

Dec 1, 1971

Improved roof control in high deformation tailgate environments has been achieved over the last decade through development of stiffer and increased capacity standing support products. æThe CanÆ is one such development, being a steel cylinder containing a weak cementitious fill, designed to essentially fold in upon itself whilst maintaining strength. A laboratory study to better define the relative load contributions of the steel cylinder and fill, the confining interaction between these components and most importantly, the potential impact of varying the steel and/or fill properties is described. This would enable the support engineer to ædial-upÆ the desired strength and stiffness properties and optimise the standing support design with respect to load capacity, stiffness, weight (handling) and cost. Design curves to optimise strength based on steel casing thickness, fill strength (confined and unconfined) and æCanÆ geometry were established. Scaled-down (one-third) samples were used in the test program and found to adequately reflect the loading behaviour of full-scale versions, thereby providing significantly greater scope for further product development at less expense compared with testing full-scale products.

Jan 1, 2005

Jan 1, 1966

By E. T. Bowers

Pneumatic conveying of coal underground is not widely used in the United States, although it is becoming increasingly popular in Great Britain, the Federal Republic of Germany, and South Africa. The question of safety has been raised repeatedly: Will the system be prone to dust or gas explosions, and, if so, can it withstand such occurrences safely? The work reported here was done under a Bureau of Mines contract and deals with the safety aspects of pneumatic transport of underground coal, as well as the hazards inherent in more conventional haulage systems. Included are three designs for different applications of pneumatic haulage: off-loading a continuous-mining machine on a room- and-pillar section, vertical hoisting through a 1,200-ft shaft, and off-loading a tunnel-boring machine driving a 2,000-ft tunnel.

Jan 1, 1985

By N. E. Idenyi

The effects of compositions and firing temperatures on the physico-mechanical properties of blended Nsu fireclay and Nkalaha redbrick clay have been investigated. The clay samples were compounded according to the following ratios: 10:90, 20:80, 30:70, 40:60 50:50, 60:40, 70:30, 80:20 and 90:10 in the order Nsu: Nkalaha respectively, and test samples made and fired at 9000C, 10000C 11000C and 12000C. The properties tested for were the modulus of rupture, porosity, shrinkage, apparent density, water absorption and bulk density. From the results obtained, it is inferred that the blends have a maximum service temperature of 11000C, with the 30: 70 blend presenting the best characteristics. A conclusion is drawn to the effect that the blend could be adapted for the production of ceramic earthenware, electrical porcelain pin insulators, cement manufacture and for refractory linings where temperature requirements are less severe.

Jan 1, 2006

Jan 1, 1967