Search Documents

By R. M. Murray

Although blister copper has been produced at the Mount Lyell Mining and Railway Company's works since 1896, it is only during the past five years that electrolytic refining has been undertaken locally, this having been done previously at customs refineries, at first in the United States, and afterwards at Port Kembla, New South Wales. Left to right: smelter building, converter building, blower building (in which converter-generators are housed), tank house and anode dock. Wire-bar furnace building in background at center. Possessing a hydroelectric power plant capable of generating power considerably in excess of the requirements of its mines and works at the time, the company was in a favorable position to undertake its own refining work, provided this advantage was not offset by the high cost of coal, which would have to be imported from the mainland, and provided also that the capital cost of the plant would not be unduly large in regard to the relatively small amount of copper to be treated. A study of these several conditions led to the adoption of a high-density plant using blister-copper anodes and equipped with an electric boiler to provide any

Jan 1, 1934

By Henry M. Howe

in Cast-Iron. It has been generally accepted that the presence of silicon in cast-iron leads to the formation of graphite; and this has been explained by saying that the silicon lowers the solvent power of iron for carbon at and somewhat below the freezing-point, so that, in the presence of silicon, the iron is unable to retain in solution or combination the whole of the carbon with which it has united while molten, and therefore expels the excess of carbon in the form of graphite, during and immediately after solidification. Probably the best way to study this question would be to examine pure cast-irons, i.e., those containing nothing but iron, carbon and silicon, which at the same time should have been saturated with carbon when molten. But the data for such a study are not at hand; so we must turn to commercial pig-irons as they are made in the blast-furnace, and before their composition has been changed by remelting. Much evidence has been offered of late, tending to oppose the theory of the action of silicon above set forth. Some of this evidence will be examined here. 1. Mr. Bachman's Results. In particular, Mr. F. E. Bachman† has published a collection of analyses of cast-iron, in which the proportion of graphite at first appears to be nearly independent of the proportion of silicon present. Thus, in his Table LI., we find that with pro-

Jan 1, 1901

By C. McLean, Erickson, S. G. Kolb, S. C. Moore

The Grossschloppen vein-uranium deposit, Bavaria, West Germany, was examined with underground workings during 1980-82 by Esso Erz GmbH, an affiliate of Exxon Minerals Company (EMC). Geologic evaluation entailed dense drilling of a portion of the deposit from workings constructed specifically for the program. Discovered in 1977, the deposit was initially explored by surface diamond drillholes which allowed definition of a 30-60 m wide vein system discontinuously mineralized along a 1000 m strike length and to at least a 450 m depth. The underground program was conceives as a cost-effective procedure to answer quest ions on vein correlation, grade continuity and variability. A 1200 m decline allowed access for detailed sampling of approximately 10% of the known area of mineralization. Fanned drillholes, logged by gamma probe, were spaced to provide intersections of veins at 10 to 20 m intervals. Six cross-cuts also penetrate the pitchblende and uranophane mineralization which occurs in 0.1 to 2.5 m thick quartz veins. Detailed cross-sections and level plans were constructed for resource estimates of the intensively studied portion of the vein system. The program resulted in the discovery of local, high grade areas and an average grade in the evaluated area nearly double that expected from surface drilling.

Jan 1, 1984

By Robert W. Bartlett

A computer model for predicting the rate of oxidative leaching of copper from fragmented low grade sulfide ores is presented. The model involves the kinetics of the dissolution of chalcopyrite grains and solution diffusion of oxygen within rock pores. Adjustable curve fitting parameters are not used. The model was tested by comparing computed extraction curves with experimental results for a -11 inch ore obtained by block caving and leached at 90°C and 400 psi oxygen for one year at the Lawrence Livermore Laboratories.

Jan 1, 1973

By R. M. Brick

A PREVIOUS publication 1§ has described the effect of quenching stresses on the lattice parameter values of high-purity aluminum-copper alloys particularly with reference to the solution and precipitation of CuAl2. A similar study has been made of the aluminum-rich aluminum-mag-nesium alloys. Attention has been directed in the present investigation to the magnitude of the quenching stresses as affected by the specimen size and shape, the number of solute atoms and the quenching rate. The effect of cooling stresses in causing plastic deformation or cracking has been considered in relation to the physical properties of the alloy. On reheating alloys in the two-phase field, the time required for pre-cipitation to occur has been observed in connection with the degree of supersaturation, the rate of diffusion of the solute atoms as a function of the comparative atomic radii, degree of strain, temperature of reheating and grain size. A few qualitative comparisons on the relative effect of these factors have been drawn between the aluminum-copper alloys and the aluminum-magnesium alloys.

Jan 1, 1935

THROUGH the courtesy of the Southern Appala-chian Coal Operators' Association, a joint meeting of the Southern Appalachian Efficiency Associa-tion and local members of the A. I. M. E. and A. S. M. E. was held at Knoxville, Tenn., on Nov. 12. In introduc-ing the subject and stating the object of the meeting, H. Foster Bain, speaking for the. Institute members, said "Shoveling coal is the largest job of hand labor re-maining in this country, with the exception of the mis-cellaneous work on the farms, and even there nearly all the big jobs are now performed with the help of machines. The men in the coal mines, by hand labor, dig, each year, more cubic yards than were taken out of the Panama Canal. It has been a natural ambition of engineers, operators and men alike to follow here the characteristic lead of American industry and to substi-tute as far as possible the work of machines for the work of men; to promote the latter to the position of con-trolling and directing mechanical power rather than being themselves the machines that lift the coal from the floor of the room into the mine car. "Handling materials is one of the regular jobs of mechanical engineers, and the American Society of Me-chanical Engineers maintains a Materials Handling Division for discussion of the technical problems con-cerned. Having in mind the excellent results that had flowed from application of mechanical power and de-vices to these problems in factories, port terminals, warehouses, and other above-ground plants, the Me-chanical Engineers began to consider the possibility of introducing similar methods underground. Individual-ly, many were called upon to design, erect and operate machines for such use and at once they found them-selves faced by many novel conditions and difficulties. The Division thereupon planned a general meeting in New York in March, 1926, for consideration of problems and progress in this field. The Mining Engineers. and representative coal operators were invited to attend and

Jan 12, 1927

By U. C. Tainton

FOR the last 15 years lead has been the standard material for anodes in electrolytic zinc production and it has been generally accepted that this lead should be as free as possible from impurities. Laist1 says, "Next in importance to the purity of solution is the purity of the electrodes and tank lining material. The purest lead obtainable should be used for anodes." The same conclusion is expressed by Ingalls2 and by two German investigators who say that experiments have demonstrated that the purer the lead, the greater is its resistance to corrosion during electrolysis.3 Pure lead, however, while the best material hitherto available for anodes, is not entirely free from objection. The plain lead anode gradually disintegrates under electrolysis, so that the life of an anode, say ¼ in. thick, is frequently not more than two years. Part of the lead from the anode finds its way to the cathode, lowering the purity of the deposited zinc and decreasing the hydrogen overvoltage. The rest of the lead that comes from the disintegration of the anode goes into the manganese dioxide which is precipitated in the cells, rendering unsaleable what might otherwise be a valuable by-product. Yet a further disadvantage of plain lead anodes comes from their tendency to bend or buckle during electrolysis, as a result of intercrystalline oxidation. This makes it necessary to use a fairly wide spacing between anode and cathode to avoid short circuits, and thus leads to a higher power consumption than would otherwise be necessary. The power consumption is also affected by the high decomposition voltage at a lead peroxide surface.

Jan 1, 1929

By Beverley S. Randolph

While our coal-mining practice, in regard to hauling on main roads, has advanced very rapidly in recent years by means of compressed air, electricity and ropes, that of gathering from rooms or working-places has remained almost stationary. Few large mines are without some method of mechanical haulage on main roads, but the gathering from working-places is still done almost entirely by means of animals or men. An effort to improve this has been made recently by the Consolidation Coal Company, under the direction of the writer, at its mines in the Georges Creek region. The seam worked is the Pittsburg bed, known locally as the " Big Vein." It is from 8 to 12 feet thick. Immediately overlying the coal there is from 5 to 6 feet of " rashings," consisting of thin alternating beds of shale and coal, which disintegrate rapidly on exposure to the air, and making a very treacherous roof. Rooms are driven from 12 to 15 ft. wide, with a single track close to one side. A line of posts is placed just far enough from this side to leave a clear space for the mine-car with a driver at the brake. This brings the post not far from the middle of the cross-bar, and provides more effectual support than if placed at the end. The tracks in these rooms are usually of 4 in. x 4 in. oak scantling, though of late years, owing to the advance in the price of lumber and the reduction in steel rails, more of the latter are being used. This track is laid by the miner. His pay for the work is included in the price per ton for mining. It is therefore, as a rule, unskillfully and often carelessly laid, and cannot be relied upon to carry safely any weight materially greater than the loaded mine-car. Compressed air was already in use on the main roads, driving motors weighing 30,000 pounds each, which were used to. bring the mine-cars that had been assembled from the rooms

Jan 1, 1904

By L. A. Weakly

The Viburnum ore trend is the largest, single known ore body of lead in the world. Four well-known mining companies operate in the trend, which is approximately 64 km (40 miles) long and up to 610 m (2,000 ft) wide, located some 121 km (75 miles) southwest of St. Louis, MO. Total production from the mines for 1979 was 33 kt/d (36,000 tons) of ore or 472 kt/a (520,350 tons) of lead and coproduct metal. The district is the number one producer of lead, providing 90% of the United States' output with its coproducts, zinc ranking second, and copper and silver both ranking sixth in total US output. Mining is done in a stratiform deposit approximately 305 m (1,000 ft) in depth with the host rock principally dolomite. Ore is mined in large open stopes by the method commonly referred to as room-and-pillar mining. Mining methods and equipment are fairly similar, with the mines classified as trackless, all mining equipment operates on rubber tires. This paper will present a description of the different methods and equipment used to move ore from the active heading underground to the ore shaft for hoisting to the surface. Basically, three methods are incorporated: front-end loader and truck haulage combination; front-end loader and truck, with main line track haulage combination; and front-end loader and truck, with conveyor haulage combination. The logistics of each system, such as method of use, equipment specifications, ore handling rate, and those cost figures that could be made public, will be included.

Jan 1, 1983

By F. J. Arriagada

A conventional technique used to process auriferous sulfidic concentrates involves a pre-leach oxidative-roast step. The structural characteristics of the calcine have a strong influence on the eventual recovery of gold by cyanidation. Surface analytical techniques such as scanning electron microscopy and BET gas adsorption have been utilized to determine quantitatively the structural morphology of calcined pyrite and arsenopyrite samples in the range of 450 to 750 °C under an oxidizing atmosphere. In the case of. pyrite calcines a highly porous hematite product was found below 500 °C; at higher temperatures, a coarser oxide network , was observed. The surface area of these calcines was found to decrease sharply with increase in temperature. In contrast, the surface area of arsenopyrite calcines was found to follow a bimodal-type behavior with roasting temperature with maxima at 500 and 625 °C. In the case of pyritelarsenopyrite mixtures, the surface area was observed to increase dramatically as the content of pyrite increased. The appearance of pyrrhotite as an intermediate phase in the oxidation reactions is postulated to have important structural implications.

Jan 1, 1984

By Raymond Mancha

TO determine the optimum inside dimension of an airshaft, it is necessary to strike the proper balance between the cost of power for air friction and turbulence losses within the airshaft, on the one hand, and the cost of sinking the airshaft, on the other. An airshaft larger than necessary is extravagant because the increased amortization rate exceeds the reduction in power cost. Conversely, an airshaft smaller than is needed wastes more power than can be justified by the corresponding reduction in amortization rate. The airshaft power is a function of the air volume Q cu. ft. per min. and the air- pressure drop p in. water gauge across the airshaft The airshaft pressure drop is calculated by the formula: [ ] wherein R is the air-friction coefficient for the portion of the airshaft 1 ft. deep, 0 ft. in perimeter and A sq. ft. in area, when passing an air volume of Q cu. ft. per minute. The airpower w kw. dissipated within the airshaft is computed by the formula: [ ] With a combined over-all unit efficiency of the fan and drive of E per cent, the air- shaft power requirements become [ ] There are 8760 hours per year, so with energy at I cent per kilowatt-hour the annual cost per kilowatt for continuous operation is $87.60; therefore, with energy at C$ per kw-hr. the annual airshaft power cost MI dollars per year becomes: [ ] which, expressed by the component parts, becomes : [] The amortization rate a dollars per year per dollar invested includes both depreciation and interest on the investment. These in turn involve the expected useful life of the airshaft and available monetary interest rate. For the purpose of this discussion the cost of airshaft sinking is assumed to comprise a fixed move-in charge Y dollars, which covers the cost of transporting, erecting and removing the shaft-sinking equipment and is independent of the air- shaft size. Also, it is assumed that the cost of shaft lining, if any, is fixed at $X per cu. yd. of lining material and that excava-

Jan 1, 1946

By Herbert Ives

THE incandescent gas mantle is of considerable interest from the standpoint of temperature measurement because it presents a series of apparent contradictions to the established laws of radiation on which are based some of our best methods of temperature determination. One of these contradictions is that the mantle of least brightness (of the commercial thoria-ceria group) is the one having the highest temperature; this, though explicable without any violation of radiation laws, was long a stumbling block to the understanding of the performance of the mantle. Another anomaly is that the energy radiated by the mantle decreases with the rise of temperature, thus apparently invalidating total radiation methods of pyrometry, based on the fourth-power law. The discussion of methods of measuring mantle temperature which follows, is largely taken from an extensive study of the physics of the Welsbach mantle. 1 The incandescent gas mantle consists of a skeleton of refractory oxide of very light weight and open structure, formed by the ignition of a cotton or silk "stocking" previously thoroughly impregnated with salts of certain rare earths. The mantle of commerce is a mixture of approximately 99 parts of thorium oxide with 1 part of cerium oxide. This mixture, discovered largely by accident, gives luminous radiation many times greater than that from either of the constituents taken alone. It is customary to speak of the thoria as the "base" and the ceria as the "colorant," and the commercial mantle represents one of a family in which an oxide of low emissive power is employed as a base, which will assume a high temperature, while a small amount of some other oxide of high visible emissive power is added, which will reduce the temperature of the mantle but little. This is, in general, the most efficient- way, from the standpoint of visible emission, to utilize a substance of high emissive power in the visible spectrum. But it is not necessary. that two substances should be employed to produce a radiator

Jan 9, 1919

By William Reynolds

This paper deals with the results of a study of the application and development of mining machines for cutting out and removing dirt bands in bituminous coal beds. Face Preparation When one or more dirt bands1 occur in a seam of coal, the problem of elimination of impurities becomes manifest. The degree of completeness to which these impurities arc removed at the face has an important bearing upon labor costs, haulage costs and outside cleaning costs, and often the ash content of the product is markedly affected. Yet, because the present-day miller is paid for the number of tons he loads he often lacks interest in the quality of the coal. To insure a clean product, a system of penalties for dirty coal is enforced, but control of extraneous impurity content in the loaded coal is often inadequate and ineffectual when coal and banded impurity are shot as one. It seems only logical that to reduce the amount of impurities by proper face preparation before the men are permitted to load the coal is the most efficient method of preparation. Many mines with one or more bands of impurities in their seams are able to mine a desirable product with a comparatively small amount of surface preparation. In fact, three companies in West Virginia have recently changed their methods of fact* preparation, with most gratifying results. The first company (in the Kanawha field) after changing its cutting practice with the hope of relieving a sales problem, was rewarded by an approximate 3 per cent drop in ash in the product. Another company, operating in the same field, reduced its ash approximately 4 per cent by a change in cutting practice. The third company (in the Pocahontas field) found the wet washer inadequate in producing a marketable coal, and installed new cutting machines. Three cuts are now being made in each working place, and the results arc so satisfactory that the cleaning plant has been abandoned.

Jan 1, 1938

By R. A. Foos

During the radium boom in the early part of the twentieth century, the basic chemistry of uranium was fairly well defined. Uranium production has progressed from the status of a radium by-product to a very important industry. With the ever increasing need for more efficient and cheaper methods of processing uranium ores, new techniques are being developed. Since uranium and vanadium often occur together in nature, the latter element will also be considered. As production rates, costs, and certain aspects of uranium chemistry are still classified by the Atomic Energy Commission, these will not be discussed. Domestic uranium deposits, in general, are composed of the minerals carnotite, which contains hexavalent uranium, and to a lesser extent, pitchblende and uraninite, which contain tetravalent uranium. Carnotite also usually contains vanadium. The uranium and vanadium contents of these ores vary considerably. The ores currently processed on the Colorado Plateau assay from 0.2 to 0.4 pct U and from trace amounts to 5.0 pct V. On the other hand, the phosphate rock deposits of the southeastern U. S., from which uranium is also recovered, contain only about 0.01 to 0.02 pct; processing of the

Sep 1, 1956

By Sir Lowthian Bell

WITH the exception of air and water, it is open to question whether there is any form of matter which the human race could less easily spare than iron. Short of going the length of asserting that, without this metal for an anchor or steel for the compass, the adventurous navigator could never have crossed the wide Atlantic, we may credit the locomotive' and the steamer, and hence iron, for that sequence of events which has peopled North America with the

Jan 1, 1891

By A. L. Bollens, R. H. Johnson

The appraisal of oil wells, now that we have the age-size method of making composite decline curves, and the present worth of successive time units method of valuation, has its greatest remaining uncertainty in the difficulty of extending into the future the price curve and the composite production curve. The point of attack in this paper is the carrying on (or extrapolation) of the production curve. Led by the valuable discovery of Lewis and Beal that the decline curve is nearer the hyperbolic class, y = (x + a)-", than any other form, the current practice is the graphic method. The data are plotted on logarithmic paper and shifted with successive trials until the line becomes straight. This straight line can then be extended into the future. The method was a great help during the period when, for tax purposes, there was need for a quick method even though the errors were large. Now that we seek greater validity in our methods we find the following faults with the current method. 1. Where the shift is great (it exceeds 10 in some cases) the scale cannot be read with the necessary precision so that the resulting data would give a very irregular and inaccurate curve. 2. Where the curve cannot be straightened on logarithmic paper because of sigmoid shape the method has a serious systematic error. We believe the sigmoid curves to be more common than usually supposed, indeed when one considers the number of variable causative factors this is to be expected. We have therefore been seeking a method that is free from these difficulties and yet not so laborious as fitting a curve to the data and the calculation from the formula which, since it involves looking up logarithms, is unduly time-consuming. The method here described has been developed on the basis suggested by Earl Oliver, that the amount of oil produced per month or year for each reduction of production of a barrel of oil per day could be plotted to advantage. A step forward was made by Earl Carpenter in this laboratory, and some of the

Jan 1, 1928

By William P. Blake

In addition to uintaite, the Uintah Mountains contain a deposit, or vein, of the peculiar hydrocarbon mineral, to which I have given the name wurtzilite, * in honor of the chemist, Henry Wurtz, Ph.D., of New York, who, in 1865, described grahamite, and who has added to our knowledge of the composition of the hydrocarbon minerals. Wurtzilite and uintaite are very similar in appearance, but are very different in their physical and chemical properties. Both are black, splendent and shining in fresh fracture; but the wurtzilite has a decided toughness, and a degree of elasticity, especially when warmed, which suggests to some persons a resemblance to caoutchouc. It was at first, at Salt Lake, believed and reported to be a mineral form of India-rubber, and great expectations of its value as a substitute for crude rubber were indulged in. It was, however, found that it would not act like rubber with sulphur; it would not incorporate with it and become "volcanized," and it was very refractory and insoluble in the ordinary solvents of rubber and of uintaite. The elasticity, though unlike the elasticity of rubber, led to the reference of the mineral to the species elaterite, the only name under which an elastic bitumen is described in the mineralogies; and it is so called in the list of the mineral products of Utah, given in the last message of the Governor of the Territory. The name elaterite, as used by Dana, covers at least three differing substances, ranging in specific gravity from 0.905 to 1.223. Two of the varieties are soft and elastic, much like India-rubber, and one is occasionally hard and brittle, imbedded in the softer kinds. All are rare, and comparatively unknown, and not generally represented in mineral collections. One of the varieties referred to here is the subterranean fungus from Derbyshire, described by Lister as early as 1673.

Jan 1, 1890

By J. B. Hiskey

The hydrometallurgical application of thiourea in processing precious metal ores and concentrates has reached the development stage. This paper reviews recent technical literature covering the process development of thiourea leaching. In addition, recent fundamental contributions are discussed. Most of the interest in thiourea leaching has involved treating high grade concentrates that have sufficient value to just the use of thiourea as a reagent. An important development in thiourea technology is the addition of SO2 to the leaching solution. This procedure effectively reduces the decomposition of thiourea and eliminates the problems of passive surface layers that limit the leaching efficiency. Results for the thiourea leaching of a bulk sulfide concentrate and a residue from the autoclave leaching of a smelter flue dust are also reported. As determined by a standard bottle roll cyanidation test, the bulk concentrate was extremely resistive to cyanide leaching yielding only 16% gold and 2% silver extraction in 24 hours. Leaching with a relatively concentrated thiourea solution (1MCS (NH2)2) resulted in 83% gold and 75% silver extraction in four hours. With the treated flue dust residue, gold extraction was about 60%. Gold and silver extraction with cyanide was sensitive to both cyanide concentration and oxidizing conditions. Cyanidation resulted in 59% gold extraction and 77% silver extraction in 24 hours.

Jan 1, 1985

By David R. Mitchell, R. B. Hewes

MANY processes for cleaning coal that are in use depend primarily on physical properties of coal and refuse other than specific gravity and surface conditions relating to froth flotation. These properties are' shape, coefficient of sliding friction, resilience, friability, magnetic susceptibility, and electrical conductivity. In many of these processes specific gravity does have some effect and many separators are designed to utilize more than one of the physical properties cited. Although the processes described herein do not have a widespread application, yet for specific coals and specific conditions, they are economically important. A problem confronting many coal-mining districts is the marketing of the slacks or screenings and dust passing the final sizing screens. Proc¬esses in commercial use installed primarily to increase the form value, and hence the market value, of these slacks and dusts include briquetting, packaging, and low-temperature carborization. MECHANICAL PICKERS Machines utilizing shape, frictional resistance, and differences in resilience of coal and impurities are usually called mechanical pickers. They require a closely sized feed, therefore their use is confined to the pea, nut, and egg sizes. Various types of these devices are described by Berrisford, 1. 2 Taggart, and Yeele.

Jan 1, 1943

By H. R. Hanley, Charles Y. Clayton

ONE of the most important contributions to the art of electrolytic zinc production has been the aluminum cathode. This has been used in all major production since its commercial development in 1916. The literature is replete with important contributions, some of which may have been replaced by better ones, but thus far there appears no other metal to take the place of aluminum as cathode material. Credit for this innovation goes to Sherard Cowper Coles, of England. When experi¬menting on the extraction of zinc from Broken Hill ore at Hayle, Cornwall, in 1893, he introduced the aluminum cathode, and in 1895 obtained British Patent No. 20073. The reason for this dominant position of aluminum as cathode material in zinc sulphate electrolytes is its unique surface, to which electrodeposited metals usually do not tightly adhere. The metal must be of high purity for best results. It is possible to develop a starting-sheet method by which thin electrodeposited sheets of cathode zinc are made and stripped from a smooth aluminum plate. Such thin sheets of cathode zinc may be used as are the copper sheets in standard electrolytic copper-refinery practice. However, complications arise because of extreme warping of the zinc starting sheet after a few hours of deposition, and thus special arrangements must be made to compensate for this abnormality. Reasons advanced for the ease with which deposits may be stripped from the aluminum surface are: (1) presence of a permanent oxide coating on the metal, (2) failure of aluminum to alloy with the deposit, (3) differences in coefficient of expansion, (4) high position of aluminum in the electromotive series of metals. Of these reasons for nonadherence, which may have some application in general deposition, probably the oxide coating has the greatest bearing on the subject of zinc deposition. Adherence of zinc deposits has occasionally had serious effect oil tonnage and production costs. Opinions have differed as to the specific

Jan 1, 1938