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Minerals similar to the indicator minerals used in kimberlite exploration are widespread in the Cainozoic alkali basalts of north Queensland. Magnesian ilmenite, pyrope garnet, chrome diopside, chrome spinel, phlogopite and zircon were recovered from most of the localities examined. The occurrence of these minerals creates significant problems when indicator minerals are used for diamond exploration. Basaltic ilmenite is visually similar to kimberlitic ilmenite. Untransported grains are rounded and have pitted surfaces. Basaltic ilmenite grains often have exsolution lamellae and reaction rims of titanomagnetite. Although kimberlitic and basaltic ilmenite are chemically similar, basaltic ilmenite grains are usually less magnesian than their kimberlitic counterparts. Basaltic ilmenite contains very little Cr203. Pyrope garnet occurs as megacrysts and in a variety of xenolith lithologies in north Queensland basalts. Most basaltic garnet is Cr-poor and comparable with kimberlitic garnet from Groups 3 and 5 of Dawson and Stephens (1975). Wine-purple, chrome-bearing garnet is common in kimberlite but rare in basalt.

Jan 1, 1984

By M Grinceri

The New MetroRail City Project was completed in 2007 in Perth, Western Australia. The project included construction of two underground stations, twin bored rail tunnels of 1.4 km combined length and cut-and- cover tunnels and dive structures of about 1 km total length. It is the first major underground construction project within the Perth central business district (CBD). This paper provides an introduction to the project and describes the geology and hydrogeology of the area. Ground conditions varied significantly along the alignment from soft estuarine muds in an area of reclamation to very dense cemented sands and very stiff to hard clays. Deep foundations for the project extend down into the bedrock below the CBD, a Tertiary siltstone/sandstone. Key geotechnical hazards encountered during the project are discussed. The building protection methodology on the project is described, including damage assessment, condition surveys, monitoring and protection of key structures.

Jan 1, 2008

By Robins R. G

The dissolution of metallic copper powder in aqueous solutions of cupric sulphate under the influence of ethylene gas was investigated. The dissolution reaction stoichiometry obtained was: Cue+(aq) + Cu(s) + 2C2H4(g) = 2(CuC2H4)+(aq) The rate of formation of the copper (I)-ethylene complex in the above reaction was studied in a laboratory autoclave and the effect pH, temperature, ethylene partial pressure and initial concentration on the dissolution rate was measured experimentally and expressed theoretically in terms of several simple conceptual kinetic models. The results led to the selection of optimum conditions for the reaction and the suggestion of an "ion-molecule reaction" mechanism to explain the very low activation energies for the reaction system. The area of application of this reaction lies in the direction of refining impure copper such as cement copper. Several experiments were performed in which an acidified solution of cupric sulphate under ethylene pressure was used to dissolve copper from the cement copper powder in the form of the copper (I)-ethylene complex, followed by the release of gas pressure to disproportionate the complex and precipitate a purer metallic copper.

Jan 1, 1987

By M Binks

This paper presents a case study that describes the selection, development, engineering and construction of a process plant for the biological oxidative pre-treatment of a refractory pyrite-arsenopyrite gold ore flotation concentrate. Prefeasibility and feasibility study resource modeling, metallurgical testwork, and environmental and engineering studies are outlined. Options considered for oxidation of the ore, which examine cost, risk, operability, recovery, engineering and environmental aspects are compared, with particular reference to pressure and biological oxidation. The BIOX« biological oxidation process was selected as the preferred oxidation process and the flow sheet for this process is presented. Selection of the BOIX« process resulted in special requirements for the feed preparation circuit, residue treatment and disposal, materials of construction and engineering. Use of a biological process in ore treatment also introduces particular process and engineering risks the management of which are discussed.

Jan 1, 2004

A standard practice of auditing mill designs has developed in the mining industry. The purported aim of this task is to ensure that the mill being offered conforms to the design specification, thus reducing the purchaserÆs risk. However, careful examination of the auditing methods used in the past shows that this is not the case. In some cases, what auditors have been providing is effectively a quality assurance check of the input data, not a full independent audit of the vendorÆs design. It will be shown that these past auditing methods have contributed to the stagnation of mill specification development. This lack of specification improvement combined with the current trend towards increased allowable fatigue stress ranges can result in an increase in risk for the purchaser.

Jan 1, 2002

By Fabjanczyk M. W

Artificial ground support has developed into a refined science over the past 20 years. From reactive support systems such as timber props and steel supports, to active systems such as roof bolts and cable anchors, ground support technology has now developed efficient systems that work well in many instances. However this paper demonstrates that there is still a long way to go to develop optimum ground support systems. Some conventional rock bolts and cable anchors emphasise their tensile capacity only, without considering other factors such as their shear strength or shear modulus, or if the support member can transfer all of its support capacity to the surrounding rock. Examples are given of the use of ground anchors with high tensile and shear capacity in underground coal mining as well as examples of slope failures in open pits where the cable bolts have remained intact because they have been unable to transfer their full capacity to the surrounding weak rock mass. For underground coal mines, speed of installation is also of primary concern, but it must also have high tensile and shear capacity both in terms of strength and stiffness. Ground support systems of the future must therefore address these problems. An innovative new rock bolt is discussed which goes some way towards solving these problems. This new rock bolt is screwed into the rock and thus has a direct mechanical interlock with the rock. Initial field results show that it has an extremely high anchor capacity and can be fully installed in approximately 30 seconds. It has considerable capacity to improve the productivity of the coal mining industry.

Jan 1, 1992

An empirical kinetic model is discussed that enables the number of stages in a carbon-in-pulp plant and the amount of carbon in each stage to be calculated for any desired metallurgical performance. It is shown that a knowledge of the kinetics of gold extraction by activated carbon in each stage assists plant operators in the important' areas of process control and optimization. Factors such as mixing efficiency, concentration and distribution of carbon through the plant, bypassing of pulp through a stage, and carbon poisoning are examined. The resin-in-pulp process for the extraction of gold cyanide is also discussed, and the chemistry of absorption and elution on strong- and weak-base resins is examined. In addition, operating results from a small-scale resin-in-pulp pilot plant are presented, and various applications in which resin-in-pulp may be preferable to carbon-in-pulp are discussed.

Jan 1, 1982

By Maxwell HW

Pacific Coal Pty Limited (a wholly owned subsidiary of CRA Limited) managed the interests of six members of a joint venture formed to mine and export eight million tonnes of export quality steaming coal from a mine developed at Blair Athol in the Bowen Basin of the Central Queensland coal fields. The mine is now operated by Blair Athol Coal Pty Ltd. Crooks Michell Peacock Stewart Pty Limited (CMPS) was awarded a project management and engineering contract for the total mine portion. Following a feasibility study, CMPS carried out an Optimisation Study which produced changes to the design of the project, thus resulting in the project budget being reduced by some A$13 million. In spite of a number of late additions to the scope of work, the project was completed at a final cost of A$148 million, many millions below the reduced project budget. The project was also completed several months ahead of schedule. Total services were provided to take the project from feasibility stage through to the establishment of an operational facility and included project management, planning and control, accounting and financial control, as well as the organisation of engineering, procurement, construction, industrial plant commissioning, and technical training matters.

Jan 1, 1986

By Woodcock JT

This paper reviews the chemistry of flotation pulps with the aim of gaining a better understanding of the effect of chemical environment in flotation and ap- plying the knowledge to improving the con- trol of reagent additions. Theories of flotation are considered briefly, but they are only of limited help in specifying an appropriate chemical environment and in establishing control techniques. The chemical nature of flotation pulps is reviewed. Four distinct phases are present - solids, an aqueous liquor con- taining many dissolved reactive sub- stances, organic liquids, and gases. All of these vary in many ways and interact with each other. It has now been estab- lished that there are many previously- unsuspected materials present in plant pulps that can or might affect flotation. Concentration profiles of selected para- meters in operating plants are given to show some typical changes that occur. Recent advances in collector chemistry, especially that of xanthate and related species, are reviewed. Modes of decompo- sition and/or formation in pulps of xan- thate, dixanthogen, perxanthate, xanthyl thiosulphate, and monothiocarbonate are reviewed, and their W absorption spectra are compared. Some relevant information on dithiophosphates, mercaptobenzothia- zole, and thionocarbamate is summarized, and some speculative comments are made about reactions of these collectors.

Jan 1, 1984

UNLIKE coal mines, in which some form of artificial ventilation is rendered necessary by gases given off by the material mined and is also enforced by the mining laws of all countries, metalliferous mines have almost entirely relied on natural ventilation, viz., that due to the difference in temperature between the outside atmosphere and the mine air. In small mines natural ventilation has proved sufficient, but as mining proceeds at a greater depth, and where large ore bodies arebeing attacked the writer is of opinion that some means of artificial ventilation will be rendered necessary if only from an economic standpoint.The Broken Hill Proprietary Mine was one of the first metal mines to introduce a scheme of artificial ventilation on a large scale. In order to render the working conditions of the semi-friable stopes of Block 12 and the lower levels of Block 11 morecomfortable for the men at work in these places, in 1903 it was decided to install a fan to thoroughly ventilate these stopes. The fan chosen was a Capell double-inlet fan beltdriven from a steam engine: this engine was later on replacedby an electric motor. The fan was put in commission at the latter end of 1904; its principal dimensions are as follows: Length 6 ft. 6 in., diam. 7 ft., diam. of inlet 4 ft. 7i in. The fan is reversible, though this is a rather misleading term, asthe direction in which the fan blades revolve is not reversed...

Jan 1, 1921

By Howard G. L

The gold treatment plant of Great Western Consolidated N.L. is at Bullfinch, Western Australia, 22 miles north of Southern Cross, which is 100 miles west of Kalgoorlie. A railway to Southern Cross connects the mine with the main Perth-Kalgoorlie line.The plant, which commenced operations on the 31st October, 1952, was, designed by Messrs. Alex: Stewart & Co. in consultation with the technical staff of Western Mining Corporation Ltd. to treat 1,000 long tons a day, made up of approximately equal parts of quarry oxidized ore and underground sulphide ore, by moderately coarse grinding (2-3 per cent plus 65 mesh Tyler) and straight cyanidation without straking. The design had to allow for future treatment of all sulphide ore at the rate of 40,000 tons per 28-day periodand to make provision for the possible later inclusion of preaeration treatment.The test work on .which design was based was done on representative development samples, the mine being divided into zones for this purpose, to check possible local variations from average treatment behaviour. Proposed mill feed mixtures were made up from time to time for complete ore dressing tests, which were conducted in the Western Mining Corporation laboratory at Kalgoorlie.The chief feature of the design was that the plant had to handle the extremes of very soft, poor settling and filtering oxidized ore and very hard, good settling and filtering sulphide ore. On one hand, crushers and mills had to be large enough to handle the sulphide ore and on the other, thickeners and filters had to be large enough to handle the oxidized ores.The design is marked by simplicity, the use of large units of equipment, and flexibility to cope with a variety of ores.

Jan 1, 1956

By C V. Putnis, T Geisler, A Putnis

In nature, ilmenite (FeTiO3) undergoes weathering through oxidation and removal of Fe to form an apparently continuous series of compositions from ilmenite to pseudorutile (ideally Fe2Ti3O9), and with further weathering, to leucoxene. To determine the mechanism of acid-leaching of ilmenite to ultimately form rutile, we have carried out an experimental study of ilmenite alteration in autoclaves at 150¦C in HCl solutions. Resulting products were studied by X-ray diffraction, scanning electron microscopy, electron microprobe and Raman spectroscopy. In some experiments the solution was initially enriched in 18O and the distribution of the isotope in the alteration products mapped from the peak shift in the Raman spectra. The results indicate that the alteration may proceed in two stages, each with a sharp interface between the parent phase and the product. The alteration begins at the original ilmenite crystal surface and along cracks through which the fluid can migrate. The first alteration product is pseudorutile û no phases intermediate between ilmenite and pseudorutile were detected. The textural relationship between ilmenite and pseudorutile suggests a coupled dissolution-reprecipitation mechanism rather than a solid state continuous oxidation and Fe diffusion mechanism. The second stage involves a further dissolution-reprecipitation step to form rutile. Raman spectroscopy shows that the 18O is incorporated in the rutile during the recrystallisation. Throughout the alteration process the original morphology of the ilmenite is preserved although the product is highly porous. The rutile inherits crystallographic information from the parent ilmenite, resulting in a triply-twinned rutile microstructure.

Jan 1, 2008

By Y Yang

Despite the importance and usefulness of basicity in metallurgical slags, the optimum quantitative expression of it has remained elusive, partly due to the fact that the precise concept of basicity has not been properly clarified. The two basic approaches to the concept of basicity are the Lux-Flood, which perceives basicity in terms of the activity of the free oxide ion, aO2-, and the Lewis, which perceives basicity in terms of the ability to donate negative charge. The former has been almost universally adopted in the area of metallurgical slags, while the latter has been increasingly accepted in the field of glass chemistry. In this paper, some difficulties of the Lux-Flood approach are pointed out, including the need for indirect measures of aO2-, which have proliferated in recent years. Accordingly, it is suggested that the Lewis approach has a good deal to commend it, and that the quantification of it in terms of optical basicity is the best measure of basicity available, which should therefore be more widely applied in metallurgical slags than it currently is. The fact that there are intrinsic problems in evaluating the optical basicities for the transition metal oxides is acknowledged, and a new scale is recommended. The patterns of iso-optical basicity lines in ternary systems are shown to agree well with the pattern of iso-activity and iso-capacity lines under appropriate conditions.

Jan 1, 2000

Many parameters are important when considering the performance of a concentrator. These include metallurgical performance, such as throughput, metal recovery and final concentrate grade and operating costs, such as power consumption, water usage, reagents and spare parts. In most operations the objective is to maximise metallurgical performance and minimise operating costs, ideally without a large investment in new capital items. A number of projects have been carried out at Newcrest MiningÆs Cadia Valley Operations (CVO) with the aim of improving metallurgical performance and minimising operating costs. This paper focuses on the installation of newly designed flotation mechanisms in various cells in the Cadia flotation circuit and describes the effect these changes had on performance and operating costs.

Jan 1, 2009

By D Craw

Interactions between structure and lithology in the Hyde-Macraes Shear Zone controlled the style of gold mineralisation at the Macraes mine. Large volumes of rock in some mine pits have most gold disseminated in hydrothermally altered schist, rather than in quartz veins. Mineralisation was initiated in the latter stages of metamorphism. Pods of massive schist rich in quartz and feldspar are surrounded by more fissile schist consisting of interlayered micaceous and quartzofeldspathic schist. Later shears have been partly controlled by the micaceous schist, and anastomose around pods of more massive schist. Micaceous schist was replaced by pyrite and arsenopyrite, accompanied by recrystallisation of phengitic muscovite under lower greenschist facies conditions. Gold occurs in sulfides and with microcrystalline quartz formed during minor silicification. Massive schist is locally mineralised along sulfidic microshears which have phengitic muscovite largely illitised under sub-greenschist facies conditions. Mineralised massive and micaceous schists were overprinted by cataclastic shears, with addition of graphite and more sulfides. Mineralisation occurred during a transition from ductile to brittle deformation regimes as the schist was uplifted in the late Jurassic.

Jan 1, 2004

By Sandenbergh RF

The debate on the mechanism of adsorption of gold and silver di-cyanide onto activated carbon could be divided into two schools of thought. On the one hand, it has been proposed that the combined effects of electrostatic and chemical interaction between the activated carbon surface and adsorbing gold di-cyanide anion results in the adsorption of the latter. On the other hand the `ion-pair' adsorption reaction mechanism has been vigorously advocated as the dominant mechanism responsible for the adsorption of gold di-cyanide onto activated carbon. It is maintained that gold is adsorbed onto the carbon surface as the neutral ion-pair [M"+][Au(CN)z ]". Adsorption is viewed as the result of mainly the chemical interaction while electrostatic interactions are neglected. The validity of the `ion-pair' adsorption mechanism may be challenged on a number of counts. However, the alternative mechanism (based on aqueous surface chemistry principles) has not gained general acceptance yet, because it has not been applied widely enough to explain the different adsorption phenomena associated with gold di-cyanide on activated carbon. In the present study the case in favour of an adsorption mechanism based on general aqueous surface chemistry principles is presented. A model framework is developed for the adsorption reaction mechanism of gold di-cyanide onto activated carbon which incorporates the effects of chemical and electrostatic interactions between the dissolved species, the aqueous solution and the carbon surface. This model is then employed to explain a wide variety of reported adsorption phenomena for gold di-cyanide on activated carbon, such as the effects of pH, the adsorption of different metal cyano complexes, ionic strength, and type and concentration of cations in solution. In addition the effects of cyanide and dissolved oxygen concentration were investigated. No ready explanation, in terms of aqueous surface chemistry principles, is yet available for the switch in adsorption behaviour that agrees with ion exchange to ion-pair adsorption with increasing ionic strength.

Jan 1, 1997

By C Mroczek, B Mitchell

Perilya Broken Hill, from its inception, has budgeted for more than 2.0 million tonnes per year from the Southern Operations. This tonnage was planned to come from in excess of 100 stopes per year in a remnant mining environment with numerous mined voids and consequent mining challenges. To mine an average of two stopes per week requires patience, flexibility and detailed knowledge to best manage the potential risks and hazards. The evolution of the Perilya Broken Hill Mine Planning Process has necessitated the establishment of a process to identify and manage these risks during the planning stage in a reliable but efficient manner. This process is to ensure that vital steps for each stope are not missed, and that each personÆs work can be tracked by other members of the team. This paper outlines the planning process from resource to stope closure.

Jan 1, 2005

The Beruang Copper-Gold Deposit is located very near the centre of Kalimantan in Indonesia. It is a dacitic tuff hosted deposit currently being explored by Kalimantan Gold Inc of Canada. Exploration activity to date at Beruang has been focused on the Main Zone, which is defined by a north-south elongate, 1 + 1.5 km zone of anomalous copper and gold, and intense phyllic alteration. The disseminated sulfides responsible for the anomalous copper values produce a moderate to high chargeability signature. Phyllic alteration is overlain at high levels, and on the western edge of the Main Zone, by advanced argillic alteration. The dacite tuffs hosting the mineralisation are cut by post-mineralisation dacite dykes that are delineated by ground magnetics and geological mapping. Base metals, principally zinc and lead, form broad halos around the Main Zone. These metals are incorporated in massive NE-trending, polymetallic mineralisation that outcrops to the north and south of the Main Zone. IP survey results highlight the highly pyritic NNE-trending shear zone, which hosts most of the copper mineralisation in the Main Zone. A high chargeability anomaly at depth in the central-east part of the Main Zone is interpreted to be the source for mineralising hydrothermal fluids. This is suggested by zonations in alteration and mineralisation. A deep chargeability anomaly can be correlated with the downward plunge of a pyritic breccia, encountered at shallow levels in drillholes, and is a potential breccia pipe target. Compilation and inversion modelling of the IP results has yielded some interesting drill targets.

Jan 1, 2004

By Langham B. M

A chemical study of the petrographic components of Greta (Maitland) coal, carried out by the Metropolitan Gas Co. (Melbourne), has revealed an anomaly in the composition of the durain which was thought to warrant petrological investigation.The original study, by the Metropolitan Gas Co., extended over eight shipments of coal received during the winter of 1943.The percentages of the several petrographic components were eslimated by careful handpicking of large samples of each shipment, and analyses were made of the handpicked components, which were also tested as to their gas-making and coking properties.The results are summarised in Tables 1 and 2. At first sight the components of the Greta coal bear a general resemblance in composition to those of other bituminous coals of similar rank, apart from a notable richness in volatiles, which is a distinctive feature of Greta coal. The durain has a typically higher ash content, and lower volatile content than the clarain (Table 1); and the coking behaviour of the four components is typical (Fig. 4).When, however, the analyses of Table 1 are re-calculated on a dry, ash-free basis, an anomaly appears: the clarain and the durain, on this 'pure coal' basis, have practically identical compositions, with the durain containing a slightly higher proportion of volatiles than the clarain (cf. Table 3); but the tar yield of these two components is very different (Table 1). Re-calculated on a dry, ash-free basis, the yield from the clarain is 18.9 gallons of tar per ton, while, that of the durain is 29.0 gallons per ton. The gas derived from the durain is correspondingly richer in illuminants (CH etc) and poorer in hydrogen than that from the clarain (Table 2), and is also notably richer in nitrogen.That the composition of the Greta durain is consistent is proved by the analyses of Table 3, in which the compositions of the respective durains and clarains of eight separate shipments of coal are compared. In most bituminous coals, the durain contains several per cent less volatile matter than the associated clarain, and high volatile content in a durain usually indicates a durain rich in spores.

Jan 1, 1947

The working of alluvial deposits has from all times been a popular form of mining, not only from the simplieity of its operations, but also, in its more primitive stages, from the possibility of carrying it on without large capital, without skilled lahour, expensive plant, long terms of preparatory work, or, in fact, any other requisite than a shovel, a dish, and a stout pair of arms. It is possibly one of the oldest industries, and probably, also, it has been one of the most profitable.In tbe Australian States the happy days of rid alluvial deposits, when gold was to be hltd for the shovelling, are now almost over. The lust for gold has caused almost every corner of the world to be ransacked, and the more easily earned wealth to he exhausted: for the most part there remain now those deposits only which are too poor to be profitably worked by means of the implements and methods of old times. But, though the deposits have become poorer, the keen inventiveness of man has devised means whereby such large quantIties can be treated at a cost so low that he can still make a profit out of them. In this article, out of the many means devised, three only will be referred to-viz., hydraulic sluicing, bucket dredging, and hydraulic dredging. All mining may be divided into three principal operations-1st, the breaking down and conveying of the ground to where it is to be treated for the recovery of the metallic values, 2nd, the treatment of the material for the recovery of those values; and, 3rd) the removal of the worthless material or tailings. In all mining the object is to effect these three processes for the least expenditure of money commensurate with the highest degree of efficiency.

Jan 1, 1907