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By C. D. Shackelford, J. F. Muñoz, M. Vauclin, P. Rengifo, A. Suazo

The results of a field-scale study involving in situ leaching of copper ore tailings using sulphuric acid as the leaching agent, injection wells to introduce the leaching solution and extraction wells to recover the copper-enriched pregnant leaching solution are presented. The study was performed at an abandoned tailings disposal site using a battery of injection and extraction wells. The medium was characterized through the determinations of physical, chemical, mineralogical, and hydro-dispersive properties based on laboratory and field tests, including a tritium tracer test, a pumping test, particle size analyses, and hydraulic conductivity tests. Numerous horizontal strata with different hydraulic conductivities were identified. A previously developed model was used to simulate the leaching of copper ore tailings. Although the study confirms the feasibility of using in situ leaching for recovery of residual copper from tailings deposits, the efficiency of the technology depends significantly on the medium stratigraphy and hydraulic conductivity.

Jan 1, 2001

By James A. Finch, Jason S. Doucet, Cesar O. Gomez

"Exercising control over the physical environment of flotation as a step towards process optimization is the driving force for characterizing gas dispersion in flotation cells, a subject of considerable research and still not fully understood. From an operational standpoint, however, there are just a few variables that can be manipulated to manage gas dispersion on a cell-to-cell basis, the most important being gas rate (superficial gas velocity Jg). Measurements in eight plants demonstrate there is often no strategy for distribution of gas to cells in a bank, i.e., there is no particular Jg profile. Two exercises where Jg profiles were set allowed metallurgical performance to be manipulated and an optimum Jg profile to be selected. To facilitate setting Jg profiles, a multi-unit device based on McGill Jg sensor technology is introduced. Possible directions for gas dispersion management are discussed.INTRODUCTIONThe earliest patents regarding the flotation process ignored the importance of air and in certain cases, steps were taken to eliminate bubbles from the system (Nelson and Smit, 2005). Rickard (1916) described a keen metallurgist who observed better than expected performance and hypothesized that entrained air was enhancing the process. Within a few years of this observation, the basic concept of modern froth flotation was developed whereby air is dispersed into slurry to induce bubble particle contact.As research into flotation advanced, the link between performance and the flow-rate of air entering the cell was established. In the first volume of the International Journal of Mineral Processing, Harris (1974) described the importance of airflow-rate and derived parameters such as the superficial gas velocity (then called the superficial airflow velocity) as being important parameters for cell design and scale-up. Mehrotra and Kapur (1974) presented research suggesting that the rate of flotation was strongly correlated to the aeration rate. McKee et al. (1976) continued to demonstrate the importance of airflow-rate linking it to the entrainment rate of hydrophilic gangue material."

Jan 1, 2006

By Gregg S. Hill, Bert J. Huls

"This paper on coarse particle recovery (CPR) summarizes a process to capture coarse particles that are not recoverable by regular flotation. Several porphyry copper operations in the world operate analogous circuits that recover non-floated copper from tailings; however, the case presented here is unique in that extensive underlying test work has allowed us to elucidate some fundamental principles behind recovery enhancement. This paper discusses an overview of the flow sheet that is proposed to Minera Escondida Ltda., the nature of copper in the feed to the CPR circuit, and the various unit operations within the recovery circuit. Details of the technology behind each unit operation will be presented in later publications.INTRODUCTIONSince 1996 BHPBilliton and MEL (Minera Escondida Ltda.) have developed a process to recover copper from coarse particles in the rougher tailings. Copper recovery from fresh tailings is not new. Several operations in Chile, such as Chuquicamata, El Teniente (AMEC, 2003), Mantos Blancos and others have operated various forms of tailings circuits. Both Chuquicamata and El Teniente practice cascade flotation scalping off froth containing fine copper particles after allowing sufficient retention time, air inducement and, sometimes, additional reagent addition. Chuquicamata tailings are not segregated but floated in sequential cascade and conventional large cell arrangements. At the Valle Central operation of El Teniente a coarse fraction of mill tailings is ground and floated, with the rejects recombined with fine tailings and subjected to cascade flotation through a sequence of concrete launders as the tailings flow towards their final deposition area. Mantos Blancos cyclone the rougher tailings and blend the underflow with scavenger concentrate from elsewhere in the principal circuit prior to flotation in Wemco Cells. Kemess in BC, Canada operates a 160 m3 Outokumpu cell to reduce the tailings sulfur content (Rasmussen, et.al, 2004)."

Jan 1, 2005

By Norman O. Lotter, Dominic Fragomeni, Lori J. Kormos, Guy Comeau, Antonio Di Feo

"A performance opportunity was identified for the Raglan concentrator operation by changing the selection of xanthate from Potassium Amyl Xanthate (PAX) to Potassium Isobutyl Xanthate (PIBX). This opportunity was identified by a Statistical Benchmark Survey of the operation and QEMSCAN measurement of these survey samples, in which fine liberated pentlandite was found in the final tailings. This was confirmed by some laboratory scale flotation testwork using High- Confidence Flotation Testing. A statistically designed plant trial was implemented in 2007 to measure and confirm the performance gain. This trial design used on-off switching following a three-month reference distribution of normal operations using PAX. This layout provided both external and internal reference distributions on PAX to be established. These were used to evaluate the internal reference distributions on PIBX. This trial format was deliberately designed so as to block out the effects of autocorrelation in the operations data. In this way, small but significant metal recovery gains may be measured and proven in a plant trial. The paper describes the case study to show that this approach successfully blocks out autocorrelation in time, which is an obstacle in analysing concentrator operations data. The results showed that the PIBX had produced clear and statistically significant recovery gains for Ni, Cu, Pt and Pd. Adjusted for feed and concentrate grades, these recovery gains were: Ni: 1.00, Cu: 0.96, Pt: 5.07 and Pd: 1.90%.INTRODUCTIONConcentrator OperationsMilling and flotation, sometimes accompanied by gravity separation, are well-established unit processes. These have traditionally been used to treat ore that has been mined, producing a lowbulk concentrate containing a high percentage of the paymetal(s) in the ore mined. These concentrates are more economically treated in subsequent beneficiation processes than the ore from which they were produced.This choice of a concentration process results in a significant and variable paymetal loss to the concentrator tailing. This tailing is discarded and disposed of in an impoundment area, and has no immediate business use. This paymetal loss forms the largest loss of paymetal in the entire flowsheet by which refined, or saleable, metal(s) are produced [Cramer, 2001]. The question arises as to whether any particular concentrator is performing at its full potential, and how this answer may be determined. In a concentrator operation, there is always an ongoing performance improvement programme for this reason."

Jan 1, 2009

By Buse Florian

This paper presents the specific features of the large-scale production and transportation systems (LSPTS), describing the main notions and characteristics of the LSPTS elements. A methodologically unitary approach of the formulation, formalization and solution of the problems regarding the planning of the LSPTS structure development is offered, based on the system description by the aggregation-decomposition method, as weil as on the complex of interreloted models for the planning optimization. The paper describes the characteristics of the complex of dynamic models for investments, utilized in solving the planning problems of the LSPTS structure development.

Oct 1, 2009

By Klaus Tietz, Hamish Adam, John Selby, Ian Glazier, Brian Sinfield

"Room-temperature tunable diode laser (TDL) analyzers are gaining in acceptance for highly critical safety monitoring applications in a variety of industries. This paper describes the testing, evaluation and deployment of a laser-based hydrogen cyanide monitoring system at the Campbell Complex of Goldcorp’s Red Lake Gold Mines in Balmertown, Ontario, Canada.A trial, single channel installation was followed by a staged multi-channel installation. Unexpected technical issues with the multi-channel installation were addressed and resolved.INTRODUCTIONLaser-based gas detection has several advantages over existing gas detection techniques (Ballangrud, 1993; Silver, 1992; Bomse, 1995; Table 1). For practical purposes, lasers generate light at a single wavelength. Room temperature tunable diode lasers (TDL) emit light in the near infrared (NIR) part of the electro-magnetic spectrum. Many gases of interest, including HCN, NH3 and others, absorb energy in the near infrared (NIR). Each gas has a unique absorption signature, or spectrum, made up of a large number of individual “absorption lines”. A TDL can be tuned to select a single absorption line of a target gas, which does not overlap with absorption lines from any other gases. Therefore, laser gas sensing is selective and does not suffer from interference from other gases. The single-wavelength nature of laser light also means that laser gas analysers have a linear response over a wide dynamic range.Tunable Diode Lasers (TDL) generate only a few mW of power. However, all this power is concentrated at one wavelength, the wavelength where gas absorption occurs, resulting in high signal-to-noise ratios and short response times, typically of about 1 or 2 seconds (Ballangrud, 1993). This also means that long path lengths can be used, enabling accurate measurements of very low concentrations, even with weakly absorbing gases. Tunable Diode Lasers provide all the advantages of other semiconductor devices: they are small, solid-state devices, operate at room temperature, and have long-term reliability (over 15 years). Currently, they can be obtained for any wavelength throughout the NIR (700nm to 2000nm). Because many gases absorb in the NIR, the technique is widely applicable."

Jan 1, 2011

By J. M. Menacho, J. M. Reyes

"Batch and continuous regrind tests were conducted in 3 kW and 15 kW tower mill units, respectively. Single particle size classes of a chilean copper sulphide concentrate were employed in the batch tests, while a fraction of the plant stream was deviated to the continuous unit operated under different conditions.Results are interpreted in terms of the simplified grinding kinetic model energy-based and conveniently adapted to this application. Based on the above figures plus some industrial data supplied by MPSI Inc., a scale-up relationship was developed for the apparent specific rate of breakage siE, as a function of the net power draw P, i.e.siE = siE text (P/P test) 0.089This equation fit very well the available data at the three scales and its application to regrind 4400 t/day of rougher copper concentrate from 70% below 325 Tyler mesh to 95% below same mesh, involves around 30% energy-saving compared to standard ball mill for same grinding task.INTRODUCTIONImpact and abrasion-attrition breakage are two extreme mechanisms present in any grinding system in a proportion defined by specific design and operating conditions. Impact breakage is generally efficient for coarse grinding, while abrasion-attrition is adequate to produce fine particles. Efficiency of conventional tumbling mills decreases as fineness of the product increases, even though distribution of applied stresses is always much stronger than internal force distribution in the particles. On the other hand.in a vertically stirred ball mill like the tower mill, distribution of applied stresses and particle strengths are in the same order of magnitude, making possible nearly ideal abrasion conditions (1).Tower mill configuration includes a cylindrical body vertically mounted and provided with a central screw with flights to produce circulation of balls moved up through the inner region to return down by the external space. Fresh material can be fed into the top , center or bottom in order to assure appropriate agitation of suspended particles. Size reduction and evacuation rates should compensate settling of coarse particles to avoid sanding of the screw. Detailed description of the tower mill and its operation have been given elsewhere (2),(3)."

Jan 1, 1989

By John R. Hawley

"This paper is intended as a review of the progress that has been made in the Province of Ontario in the field of acid drainage waste treatment technology.Three years ago, at the Third Annual Meeting of the Canadian Mineral Processors, we presented a paper entitled ""The Problem of Acid Mine Drainage in Ontario"". At that time I was working for the Ontario Water Resources Commission. The paper turned out to be the very beginning of the Commission's acid mine drainage control program. In the intervening three years, the Ontario Water Resources Commission has been amalgamated with other government groups and has evolved into the present Ontario Ministry of the Environment. Today the Ministry is involved in running one of the most advanced acid mine waste control programs in the world.As a part of its mining program, the Ontario Ministry of the Environment has published three major reports which deal directly and specifically with the industrial waste disposal problems that may arise at a mining operation. In order of publication, these reports are as follows:(1) ""The Problem of Acid Mine Drainage in the Province of Ontario"".This 338-page report covers all aspects of the problem of acid mine drainage and includes detailed sections on acid flow detection, acid flow chemistry and acid flow treatment.(2) ""The Use, Characteristics and Toxicity of Mine-Mill Reagents in the Province of Ontario"".This report, 244 pages in length, gives the chemistry and toxicity of nearly all of the chemicals that find common use in the Canadian mining industry. Most of the toxicity figures quoted are the result of a comprehensive bioassay program that was initiated by the Ministry."

Jan 1, 1974

By S. McAlister

"Falcon Concentrators Inc. has developed a high capacity centrifuge for the recovery of fine, free gold as well as other metals and minerals which were previously thought to be unrecoverable by gravity means. Development started in the early 1980's and the first commercial operation was commissioned in 1986. Gold applications include scavenging conventional gravity and cyanidation circuit tailings, cleaning gravity concentrates, cleaning flotation concentrates to melting grade, scavenging flotation tailings, and placer mining. Recent development work by Falcon has expanded the applications scope of the centrifugal concentrator to include many minerals amenable to gravity concentration including iron, tin, industrial minerals, and hazardous wastes. This paper discusses this technology including its history, present applications, and future potential. OVERVIEW OF CENTRIFIJGAL CONCENTRATIONUsing centrifugal force to enhance the separation of materials by differential specific gravity has been researched for over a century. Many attempts have been made to concentrate minerals in high gravity fields. Patents were granted on this subject as early as 1891 (see Figure 1). Patenting activity continued into the 1920's and has been relatively quiet since. It is significant that no centrifugal system of gravity concentration has been broadly accepted by the mineral processing community until recently. Much of the world's reserve of mineral deposits which are amenable to conventional gravity concentration technology (coarse-grained) have been mined and therefore there is an increasing demand for technology which can economically recover the fine-grained gravity recoverable minerals in the remaining deposits. In addition, centrifugal concentration can play an increasing role in solving environmental problems by offering an inexpensive method of concentrating hazardous materials such as uranium, plutonium, mercury, lead, and other heavy metals. The overall cost of disposing of these substances safely can be drastically reduced if they are recovered into a concentrated form prior to disposal."

Jan 1, 1992

By Arun Verma

Thermal energy storage offers a means of effecting significant costs savings and conservation of premium fuels. Na2SO4 has been found to be a good material for storing thermal energy in the medium-temperature range, mainly because of its dimorphic nature and high heat of transition. Basic data and development of the salt to a practically usable block are discussed.

Jan 1, 1978

By M. Tarvainen, J. Kallioinen

"Depressed metal prices coupled with increasing production costs have presented a great challenge for operators to control and reduce the costs of production to maintain profitability. Depleting ore reserves, added to the above has forced Outokumpu to take a hard look at its operations, to develop new methods to profitably extend the life of its mines. One of the areas investigated and approved for further development has been the use of larger and more energy efficient equipment. As a result, large flotation machines were developed and today 38 and 60m3 flotation machines are in use.Secondly, ore preconcentration has been developed to avoid processing the part of the ore that has little or no mineral values.Another quite recent development and the topic of this paper, has been the use of coarse flotation before conventional flotation. The main idea is that part of the valuable mineral is separated as early as practical by floating it with specially designed flotation equipment, installed in the grinding classification circuit. The new flotation cell is specially designed for this application and differs from the conventional cells in the tank design, feed arrangement and modified mechanisms in some cases."

Jan 1, 1984

By Eugen Gluck, Gus Van Weert, Peter Kondos

"Microwaves have the capability to heat up sulphides, especially clusters of particles of approx. 1 mm. Some sulphides absorb microwaves more readily than others. Molybdenite is especially effective in this regard, possibly due to its flaky nature and/or electrical conductivity. Even where it occurs in low concentrations in a deposit, individual rocks may be ore grade due to the high monetary value of MoS2. Such rocks often result from crushing mined veinlets or stockwork, or are contained in the cutoff grade fraction of ROM. Machine segregation of rocks high in MoS2 by infrared sensors after microwaving could therefore advantageously be used to upgrade lower grade ore between Mine and Mill. This would reduce the size of the latter, and thus its CAPEX and OPEX. Such upgrading could also yield shipping ore for a distant Mill, or extend ore reserves.Barrick Gold Corp. has been supporting the development of MW/IR sulphide sorting for the past three years. The results of MW/IR sorting work on molybdenite and other (pyritic) ore samples from a variety of sources are being presented here.INTRODUCTIONThis paper looks at mechanized, i.e. machine ore sorting technologies currently available and under development, and what conditions would be needed for the potential application of such ore sorting to sulphide mining and milling. Current machine sorting involves no-contact sensing technology for rocks, and signal processing after sensing to activate airblast segregation of certain rocks, normally the smallest mass to keep compressed air costs down.The forerunner of modern sorting is probably magnetic separation, which utilizes an inherent property of certain ores to divert it into mag and non-mags fractions. Radiometric ore sorters, which have been applied successfully for decades in the pre-concentration of uranium ores (Wotruba and Riedel, 2006) initiated modern sorting. In the 90’s, sensor-based machine sorting became a viable means of increasing the overall economic recovery of a resource. This technology became driven by the availability of low cost computing equipment and the concurrent development of algorithms, and by the availability of extremely fast response sensors and air actuators, allowing the sorting equipment to run faster, dropping the cost per tonne. It has been in industrial minerals processing that rock sorting has been most widely adopted, not really surprising. Liberation occurs on a different scale than in the base metal industry. Most industrial minerals are mined from massive deposits, requiring (in the past) no upgrading. Many of these operations now run into product contamination problems, which ore sorting can solve. One illustration: in Finland, a quarry is separating limestone from dolomite at 500 tonnes / hour, with individual rocks weighing up to 15 kg. Many of these industrial minerals operations have stockpiles of earlier discarded below-quality rocks, now being reprocessed with the help of ore sorting. The economics of this are very favourable, going from zero or negative value (stockpiles can not be left when closing the mine) to full product value for at least a portion of the stockpile. This suggests that in the future the economics of overburden sorting could become attractive under the right circumstances and such treatment could well become an integral part of open pit mine development."

Jan 1, 2009

A key point in the manufacture of cemented backfill is the dewatering and settlement of the total tailings product. A new technology characterized by rapid non-mechanical settlement of total tailings has been developed based on a large number of laboratory and field tests, where dynamic settlement and continual slurry preparation of total tailings in a vertical sand silo are realized by the addition of an effective flocculating agent named NPA. It has been shown that the sedimentation velocity of the interface between total tailings and water after NPA was added is 10 to 20 times higher than that without any flocculating agent, that the mass fraction of sand slurry deposited at the bottom of the vertical sand silo reaches 70%, and that the solid particle content in effluent waste water meets national water quality standards. The simple devices used to add flocculants have little deleterious effects on the current preparation tank and have been tested in an industrial environment. The processing cost of total tailings by the new technology is only 10% to 20% of that required for mechanical settlement.

May 1, 2007

By W. J. Witte, M. K. Witte

"The purpose of this report is to present a generalized preliminary design and cost estimates for a typical heap leach operation such as might be undertaken in Northern Ontario. This report should be of value to anyone in the mining industry planning, or contemplating, a heap leaching operation in Ontario, either on a large or small scale. While more detailed costing and design work will obviously be required for each specific project being contemplated, the data provided in this report should enable parties to make preliminary estimates of the costs of proposed projects and should identify most of the planning and design parameters that will need to be considered.Although heap leaching has been used extensively as a low cost gold recovery method in other parts of the world for many years, it has only recently become of interest to the Canadian mining industry.In order to investigate and demonstrate the feasibility of using heap leaching in Ontario, the Ontario Ministry of Natural Resources in 1982, undertook to locate a private sector proponent willing to undertake a 10,000 ton demonstration project. This project was to have been carried out at a production scale under normal northern Ontario field conditions. The Ministry was to have provided technical management and design for the designated project."

Jan 1, 1985

By Lloyd W. Trevoy

Syncrude Canada Limited is presently studying commercial production of heavy minerals from plant tailings of the openpit A lhabasca tar sands operation. When tar sands are processed and upgraded to synthetic crude oil, heavy minerals can be removed f rom the extraction circuit and beneficiated to provide concentrates of zircon and titanium minerals. Calculated recovery rates indicate that crude oil production capabilities of 105,000 barrels per day would provide 26,000 tonnes of zircon and 114,000 tonnes of titanium minerals annually. The titanium minerals concentrate is a mixture of ilmenite, leucoxene and rutile; it could be used as recovered or upgraded to synthetic rutile. With the consrruction of further synthetic crude oil plants in Western Canada, a large reserve of heavy minerals will become available.

Jan 1, 1984

By J. E. Sepulveda, R. Morrow

"The Linear Wear Theory provides a reliable framework for the assessment of grinding media performance at full scale. This theory can be applied for analyzing grinding media consumption rates in any given grinding operation as well as the evaluation of alternative grinding media products, based on actual operational data, correcting for conditions like ore hardness, feed and product sizes, mill power and circuit throughput; all of them unrelated to the grinding media intrinsic quality attributes. A series of Moly-Cop Tools 3.0 applications have been developed to facilitate the calculations involved. Moly-Cop Tools 3.0 is available, free of charge, to all interested parties through the corresponding author.INTRODUCTION Mineral grinding circuit operators recognize the significance of grinding media (balls) consumption on the cost structure of any full scale grinding facility. The effective cost associated with this essential consumable depends on two factors: delivered price and durability (quality) of the grinding media. When evaluating alternative grinding media varieties, there is a well accepted evaluation criterion by which a given media type is considered to be “cost-effective” when its unit application cost – normally expressed in $/ton of ore ground – is shown to be lower than that of a nominal reference condition: Grinding Media Cost = Ball Price x Ball Consumption (1) ($ /ton ground) ($/ton balls) (ton balls/ton ground) Under this criterion, an alternative, higher-price grinding media product could be “cost-effective” if its associated consumption rate is sufficiently lower than the reference media, enough to yield a lower grinding cost, as dictated by Equation 1. For the proper application of the above criterion, evaluators must rely on representative indicators of grinding media quality, ideally independent of most mill operating conditions. In each particular case, ball price is always a known component; however, it is not so evident how media performance (quality) differences amongst alternative product types could be assessed with a reasonable degree of accuracy and precision."

Jan 1, 2014

By Valentin Choquenaha Bombilla, Oscar Alvarez Muiloz

"Tintaya’s basic production line is copper concentrate, which has an important gold content. The process used is flotation; the objective of the metallurgical department is to obtain the best results in the copper recovery without neglecting the gold, using very specific reagents. Copper recoveries are considered high, nevertheless every day emphasis is placed upon increasing those recoveries. Regarding gold, optimum recoveries could not be achieved with flotation; and implementation of a gravity circuit was considered.According to microscopy studies, the coarse and very fine grains of gold in native form are lost to tails. The native gold due to its high specific gravity is concentrated at the underflow of the cyclone, remaining in the circulating load of the circuit. It reaches three times the concentration compared to the head grade entering the ball mills. This re-circulation generates very fine and laminated gold particles inside the ball mill, passing to the classification stage making a short circuit to the overflow of the cyclone.The very coarse gold particles as well as the thick flakes of gold do not react favorably to the conventional flotation process; thus studies that have included gravity separation have been conducted to increase the gold recovery. Part of the research included concentrating tables, jigs, and Knelson Concentrators. The Knelson Concentrator proved to be the best selection in terms of metallurgical performance and recoveries considering the throughput and operation conditions of the Tintaya Plant.The gravity concentration circuit with the Knelson Concentrator was commissioned in BHP Tintaya in October 1998, as per the flowsheet shown later on. Presently the global gold production surpasses any estimated expectations.Present efforts are directed towards showing the evaluation and optimization of the different parameters that govern the performance of the Knelson concentrator, as well as illustrating the difficulties and successes throughout the operating period.In the first year of operation 200 tons of gold concentrate have been produced with an average concentrate grade of 320 gramdton, having paid back in full the cost of the automated KC-XD- 48 Knelson Concentrator, the peripheral equipment, and the cost of the installation."

Jan 1, 2002

By Jesse L. Duke

Outline ?Understanding the context ?The Business, political, social and legal environment ?Recipes for Success (three Ps) ?Develop effective Partnerships/relationships ?Plan carefully ?Actively Manage the ?Process? Business Environment ?Nunavut?Impressive mineral potential ?Emerging diamond industry ?Dominated by Juniors ?NWT ?Maturing Diamond industry ?Emerging oil and gas industry ?Yukon ?Alaska Highway Pipeline ?Junior-dominated exploration and development ?Growing acknowledgement in Canada of the importance of northern resources ?Shift of thinking: north-south infrastructure (vs. East-west)

May 1, 2006

Background Chronology 2008 Positions May 8, 2010 Summit Going Forward Say one thing and do another ??Genuine passion to see our customers succeed?, ?A passion for exceeding our customer?s expectations? Self serving actions to gain competitive advantage at the expense of the customer No single supplier or technology can manage the overall mine and its integrated operation - April 2005: Informal meeting at Toronto CIM 2004 -Unanimous interest - July 2005: Formal Calgary Meeting, developed: - Scope and vision statement , - OEM/OTM communication plan, - industry communication plan - Aug?Nov 2005: Aligned with SMART - Nov 2005?May 2006: Direct OEM, OTM communication - May ?Sept 2006: Developed baseline standards - Sept -April 2007: Developed SMART document - Sept 2007: Document distribution and request OEM OTM response - Jan ?May 2008: Acquired OEM OTM feedback and positions May 2008: Results presented to SMART and discussions on next steps

May 1, 2010

By Samantha Beeson, Collin Poole

"This paper examines the development of two new selective flocculation techniques for recovering KCI values from low grade carnallite potash ore.Direct recovery of KCI was achieved using one of two mid-range molecular weight polymers, one non-ionic and the other strongly cationic, in conjunction with the same selective anionic dispersant. From initial response studies on pure minerals and selective flocculation tests on synthetic mixtures, investigations were extended to recover KCI values from a natural carnallite potash ore. A single-stage process achieved products grading up to 61.3% KCI at recoveries up to 85.4% for the cationic flocculant suite and up to 64.8% KCI with recoveries as high as 90.3% for the non-ionic flocculant suite, with dispersant and flocculant dosages of 150-250gr1 and 10-75gr1, respectively. These results clearly demonstrate not only the feasibility of treating such problematic ores at low reagent dosages, but also the potential elimination of desliming prior to froth flotation.The experimental results presented are considered in terms of the reagent adsorption phenomena present in the system and various aspects of floe formation and cleaning.IntroductionAs high-grade sylvinite potash ores become scarce, lower grade sylvinite and carnallite potash ores are becoming more attractive. However, these ores often contain large amounts (up to 15% by weight) of water-insoluble slimes which must be removed prior to KC! flotation, owing to their high adsorptive capacity for the amine collectors used. The slimes are generally removed by scrubbing followed by hydroclassification and any residual material not eliminated is blinded with reagents such as guar gum or starch to inhibit interference in subsequent KC1 flotation.An alternative approach used commercially in Canada by Agrium Inc. involves water-insoluble slimes flotation prior to KC! flotation. In this process, the slimes are selectively flocculated and then separated by froth flotation. Losses of KC! to the slimes product and associated brine requirements are both reported to be less than those encountered in conventional desliming, but the technique is somewhat limited in its application at present."

Jan 1, 1997