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By Elma van der Lingen

Gold is considered the most inert of all metallic elements, but the metal can show catalytic activity when prepared by specific techniques. Preparation techniques being used to prepare gold catalysts systems mainly involve precipitation methods incorporating gold compounds or complexes. This paper introduces a totally different method for the preparation of gold-based heterogeneous catalysts that can be used for oxidation and reduction reactions, as well as electrocatalysts. The method involves alloying of gold with a less noble metal, such as aluminium, to form a gold-containing intermetallic precursor. AuAl2 was produced by melting gold and aluminium together in a vacuum arc furnace under a protective atmosphere. The aluminium is then dissolved from the AuAl2 precursor by means of NaOH to produce a highly porous gold structure. The paper also reports on a method of incorporating transition metal oxide(s) with the porous gold to form an active heterogeneous catalyst. Promoter elements can also be melted with AuAl2 to improve catalytic activity. Alloying has the advantage that the promoter element can be in contact on atomic level with the gold. In-situ xray photoelectron spectroscopy (XPS) studies have also been done on the porous gold catalysts to further clarify the CO oxidation mechanism on gold-based catalysts.

Oct 1, 2003

By Z. F. Zhou, X. Y. Zhou, V. G. Papangelakis, Z. D. Jankovic, S. M. Ulyanov, S. N. Lvov

Recently developed flow-through electrochemical techniques (1,2) were employed for measuring pH in high concentration aqueous solutions and geothermal brines. The pH values of (1) 5.0 mol kg-1 NaCl + x mol kg-1 HCl, (2) 3.0 mol kg-1 of NaCl + 0.5 mol kg -1 of KCl + 1.0 mol kg-1 of CaCl2 + x mol kg-1 HCl (x < 0.1 mol kg-1), and (3) mixtures of Al2(SO4)3-H2SO4-H2O, MgSO4-H2SO4-H2O, and NiSO4-H2SO4-H2O solutions have been measured at temperatures from 100 to 280°C. The obtained experimental data and their thermodynamic analysis demonstrated that the electrochemical system can be used for on-line pH monitoring of high concentration aqueous solutions with an accuracy of ±0.1-0.3 pH units over a wide range of temperatures. Greater deviation exists in real laterite leach solution measurements due to in situ precipitation of Na-alunite. The system is excellent for research and process development work. Further work is needed to ensure robust operation under pressure leach conditions of laterites.

Jan 1, 2004

By James K. B. Booth

The natural crustal abundances of the principle metals of commerce are examined in relation to production and prices for each metal. Two factors, the abundance x price ratio (BP factor) and abundance/production (B/T factor) are listed for each metal. Ideally, for these desirable commercial metals, each factor should be a constant and the same for all metals; comparing the divergences for the full list of metals allows conclusions to be drawn on the relative degree of natural availability of each metal and the ease or difficulty of winning the metal from the earth's crust. Plotting the two factors for each metal over the past decade of steady industrial usage illustrates the anomalous position of copper and, to a lesser degree, molybdenum and it is concluded that over the long term the price of copper will continue to rise steeply. Possible future prices for copper are examined and a suggested preferred order of ranking of the metals as exploration targets would be copper, nickel, tin, zinc, silver, molybdenum and lead, for the near term, with molybdenum possibly increasing its ranking in the list within the next decade.

Jan 1, 1971

By T. Skinner, M. Sahebkar

"In recent years, the mining industry has been inundated with new technologies and software systems to aid in productivity improvement. Accompanying this increased level of technology and computer systems has been the exponential growth in data sources and sinks for all aspects of a mining operation. This rapid growth in data and technology has evolved through vendor “push” approaches and user “pull” scenarios, the result of which has been that currently, no standards exist defining how data from new technology should be accessed and transferred from surface mining equipment and systems. Consequently, many incremental benefits of the systems have not been realized. This paper will present a discussion of this important issue and introduce a new committee formed to address standards to assist the industry in making effective use of current and future technology. Potential benefits accruing from the development of these standards will be illustrated through the use of a case study at Fording Coal Limited. IntroductionThe mining industry is currently faced with a rapid evolution in the computing-based systems capabilities of mobile production equipment. At the same time, there is a trend toward the introduction of even larger machines, with novel designs or incorporation of new technologies within existing designs. Computing and control technology will be required to operate and acquire knowledge about equipment operation, utilization, and performance. Such knowledge has the potential to lead to enhanced equipment design, more appropriate equipment selection, and optimized equipment performance. The equipment systems will be required to be integrated with mine production monitoring systems, maintenance management software, and a wealth of other information systems to provide a complete understanding of the effects of various factors such as maintenance, equipment design and production on economics (Roman and Daneshmend, 2001). This will lead to a better understanding and implementation of the opportunities to enhance the performance of the mine through interaction of the mine operations."

Jan 1, 2003

By Matthew D. Meyer

SMART, an association of surface mining companies formed in 1995 to develop a coordinated approach to technology development for the mining industry, has recognized the need for the establishment of a worldwide database that continuously collects mining equipment data and provides metrics related to productivity and cost. Under the auspices of SMART, Syncrude Canada, Suncor Energy and Albian Sands Energy (three oil sands mining operations located in northern Alberta) have established a pilot project for mine benchmarking. This presentation will include a review of the pilot progress including: ???Data gathering techniques: means of collection and storage, proposed practice for data control and normalization, access to data/reports and format for data. ???Reports/analyses for individuals, across groups, within the total industry pool and publicly. ???Security and confidentiality of information belonging to identified parties. ???Sharing of best practices among members. SMART has identified two key deliverables to ensure success of the project. First, data supplied from surface mines must be validated and normalized to common definitions and then analyzed to provide participating companies with regular reports that allow them to understand their position and resultant opportunities to achieve world-class performance. This model maintains granularity of the data for each operation that can then be recombined into standard comparisons or specific indices as required. The general categories of: operating delays, maintenance downtime, standby, and scheduled downtime, have been used to frame comparisons. Second, participating companies are looking to go behind the indices to identify and share best practices that distinguish particular operations. The spirit of cooperation between the companies involved in the pilot project is meant to be a model for future expansion of the benchmarking project.

Apr 1, 2005

By L. Haavanlammi

Iron is a significant component of all copper concentrates leached in the HydroCopperTM process. The metals in the concentrate are leached in a chloride solution by oxidation with cupric ions. Copper enters into the solution as a cuprous chloro¬complex. Iron dissolves at the same time in the ferrous form, but it is immediately oxidized to the ferric state. Oxidation is effected by sparging air or oxygen into the leaching reactors. Because the pH is 1 - 2.5, ferric ion precipitates as akaganeite (T<90°C) or hematite (T> 90°C). Arsenic, antimony and the main part of the bismuth co-precipitate with iron and report to the leach residue. Cupric leaching is faster than iron oxidation; thus, leaching of low-iron concentrates (secondary copper minerals) is quicker than leaching high iron concentrates (chalcopyrite). Pyrite does not dissolve during copper leaching, but is oxidized slowly at higher redox-potentials after the copper has been leached.

Jan 1, 2006

By L. Lariviere, M. Grenier, R. Khalili, D. Shook

A mineral processing facility near Montreal, CEZinc, Noranda Inc., has recently implemented a leading-edge intranet solution for monitoring the performance of plant operations, and providing condition-based maintenance. This innovative multi-faceted software implementation incorporates: web-delivered plant information systems; area-wide control loop performance assessment (using sophisticated algorithms to evaluate poorly performing controllers); and integrated alarm management functions.The system has enabled a project to improve plant operations through better process control. Maintenance technicians, engineers, supervisors and managers all can see the performance of the controllers, and the performance of the plant itself, through webdelivered graphics and reports. Information is combined from many sources, real-time, historical, relational and analytical, to provide a complete picture of plant operation.The web-based solution centralizes the administration of user access, and simplifies the deployment of several different kinds of information to many desktops. It is an extensible system that allows users to create and share their own web pages and data views.The paper will discuss the solution architecture and the improvements the IT, operations, maintenance, and engineering groups have experienced, and overall benefits to the facility.

Jan 1, 2003

By Edith Lafontaine

Modern underground mines operate fleets of mobile production equipment including drill jumbos, long-hole drills, load-haul-dump machines, trucks and bolters. Their availability has a substantial impact onto production cost and thus onto mine profitability. Through appropriate collection of pertinent data and information, use of adequate performance measures and their analyses, mine operators can identify the most promising and cost effective opportunities to get more from their equipment and to reduce the overall cost. This paper presents results of the study aimed to review and analyse means and measures used to quantify equipment availability and its contributing factors (reliability, maintainability and maintenance support) in several Canadian underground mines. It overviews current reporting procedures, sources, quality and quantity of the data and information collected as well as examines performance measures and their definitions used by the surveyed mines. Problems concerning data acquisition as well as meaningfulness and usefulness of the above mentioned metrics are also discussed. The paper concludes with some suggestions and recommendations concerning several aspects of equipment availability assessment. It is believed that the latter may become a more useful tool for mine operators in their efforts to reduce production cost than it seems to be the case at present.

May 1, 2007

By P. Talonen

Since the last Iron Control in Hydrometallurgy Symposium in Montreal in 1996, the Kokkola zinc plant has increased its capacity from 175,000 t/y to 280,000 t/y by installing an atmospheric concentrate leaching process, which has also affected iron control in the leaching circuit. Major changes have been made at the jarosite residue pond; a subterranean plastic wall reinforced with bentonite and cement has been built around the pond. A new water collecting system that is used for groundwater level control in the pond area was installed. With these two investments in the pond area, it is now possible to prevent any seepage flow from the pond into the surrounding environment. Water pumped from the residue pond is treated in the water treatment plant. This paper describes the behavior of iron in Kokkola&apos;s current leaching processes. The treatment of the jarosite, the improvements to the residue pond and the water treatment process are also described.

Jan 1, 2006

By Lawrence D. Meinert

Most large skarn deposits are zoned in both space and time relative to associated intrusions. Zonation occurs on scales from kilometers to micrometers, and re?ects in?ltrative ?uid ?ow, wall rock reaction, temperature variations, and ?uid mixing. The most spectacular examples of skarn zonationusually occur at the skarn-marble contact, where transitions between monomineralic bands can be knifesharp. Other small-scale examples occur in zoned veins and individual mineral crystals. Although,visually striking and scienti?cally interesting, in mineral exploration these small-scale variations areless useful than deposit- or district-scale zonation. In most skarn systems there is a general zonationpattern of proximal garnet, distal pyroxene, and vesuvianite (or a pyroxenoid such as wollastonite, bustamite, or rhodonite) at the marble front. As well, individual skarn minerals may display systematic color or compositional variations within the larger zonation pattern. Such patterns are reviewed for 14well-studied examples of Cu, W, Sn, Au, and Zn-Pb skarns. In addition, many deposits have endoskarnor other alteration of the associated intrusion, and recrystallization or other subtle changes have occurred in the surrounding wall rocks. Copper skarns, such as Mines Gaspé in Quebec and Big Gos-san in Irian Jaya, have high ratios of garnet:pyroxene and are zoned outward from the intrusion, to gar-net, to pyroxene, to massive-sul?de replacement and vein deposits. Garnets in Cu skarn are Fe-rich and change from dark red-brown near the intrusive contact to paler brown, green, or yellow in distal loca-tions. Pyroxenes in Cu skarns are pale and diopsidic near the intrusion, and become darker and more Fe- and Mn-rich away from the intrusion. Tungsten skarns, such as Salau and Costabonne in France and Pine Creek and Garnet Dike in California, have intermediate ratios of garnet: pyroxene, are more extensive vertically and along strike than perpendicular to the intrusive contact, and have zonation pat-terns commonly complicated by overprinting of metamorphic lithologies. In W skarns, garnet is com-monly subcalcic and the pyroxene is Fe-rich, re?ecting particularly reducing wall rocks or great depth of formation. Tin skarns, such as Dachang in China and Moina in Australia, also can have subcalcicgarnet and Fe-rich pyroxene, but this reduced mineral assemblage typically is due to an association with reduced S-type granites. Tin skarns differ from most other skarn types in having a late greisens stage that may replace earlier Sn-bearing calc-silicate minerals, thus liberating Sn to form cassiterite.Many high-grade Au skarns, such as Hedley in British Columbia and Fortitude in Nevada, have low ratios of garnet: pyroxene and are associated both with reduced plutons and reduced wall rocks. Gold-rich zones occur in Fe-rich, pyroxene-dominant, distal skarn. Zn-Pb skarns, such as the Yeonhwa-Ulchin district in Korea and Groundhog in New Mexico, have low ratios of garnet: pyroxene and generally form distal to associated intrusions. These skarns also are zoned from proximal garnet to distal pyroxene and pyroxenoid (bustamite-rhodonite), with signi?cant zones of massive sul?des within and beyond skarn. Manganese enrichment of most mineral phases, particularly pyroxene, is characteristic of distal zones. Fundamental controls on skarn zonation include temperature, depth of formation, composition and oxidation state of associated plutons and wall rocks, and tectonic setting. Most W skarns form at relatively great depth, 5 km to 20 km, with extensive high-temperature metamorphic and meta-somatic mineral assemblages. In contrast, most other skarn types are relatively shallow, <10 km and mostly <5 km, with limited, lower temperature metamorphic aureoles. Differences in oxidation state correlate well with different skarn zonation patterns, particularly garnet: pyroxene ratios and compositions, and can be used in both classi?cation of and exploration for skarn deposits

Jan 1, 1997

By C. Harold Riches

This article is directed co a commentary on the patent system in its relation to the public interest. As man gained supremacy over his environment, he could devote progressively increasing portions o his time to improving his standards of living. In the history of the human race, we have advanced from the hollowed floating log to the modern steamship of the present age; from the sickle and flail to the reaper and combine; from the trumpet and drum as a means of communication co the telegraph, telephone, and radio; from the horse and ox cart to the automobile, truck, aeroplane, and train; and so on ad infinitum through the list of inventions on which are based the industrial and political economies and standards of living we enjoy today. It has also been a long road from the day of the alchemist and his closely guarded secrets to the era of the patent system and its storehouses of knowledge open to the world. The alchemist and the craft and merchant guilds closely guarded their secrets. In fact, they largely opposed innovations on the grounds that they might injure profits and restrict employment. In these days of unrest, with great clamour out of doors for radical changes in our political and industrial economies, it may not be untimely to examine one of the keystones which support the economic structure we know as the free enterprise system, the system which is predicated upon the right of the individual to own property. Many, through impractical idealism, ignorance, confused thinking, or blind political prejudice, advocate the substitution of ownership by the State ? for the right of ownership by the individual. As civilization has advanced to the high standards of living we enjoy today through the efforts of a comparatively few inventors, the patent system which has provided the incentive that created the inventions on which our industries and our employment are based is fully understood and appreciated by a comparatively small percentage of our people. As a result, the patent system, as a keystone in our free enterprise economy, is an apt target for destructive criticism, with the thought, possibly, that by eliminating or drastically restricting the several rights to individual ownership one by one, ownership by the State will progressively replace ownership by the individual.

Jan 1, 1949

By J. P. Dick

THIS paper is a description of the milling practice and metallurgy at the Moneta Porcupine mine, Timmins, Ontario. The results obtained with an all-cyanide circuit and later with flotation followed by cyanidation are described. The ?investigation which prompted the various changes in milling practice have also been dealt with. Moneta ore is possibly the most refractory now being milled in the Porcupine district. This is due to the ultra fine state in which the gold occurs and to its intimate association with pyrite. No doubt there is ore of similar characteristics on the neighbouring properties but it probably forms only a small portion of the tonnage being mined, whereas at Moneta the bulk of the ore requires an extremely fine grind to liberate the gold. The fineness to which an ore can be ground economically has gone far beyond what was thought to be the limit only a few years ago. Formerly, a set of standard screens was all that was required to measure the fineness to which an ore was ground. At present, the Haultain infrasizer is practically indispensable, and the nominal micron has become a familiar unit of measurement to all those dealing with the problems of fine grinding.

Jan 1, 1941

By D. T. White

Pressure acid leaching of nickel laterite ores typically involves the production of an intermediate product that is releached and refined to pure nickel and cobalt products. BHP Billiton is developing the Ravensthorpe Nickel Project to produce up to 50,000 t/y of nickel via a mixed hydroxide intermediate, which will be refined at its Queensland Nickel (QNI) Yabulu Refinery near Townsville, Queensland. The hydroxide precipitation flowsheet has been adapted to process high magnesium ores through an atmospheric leach stage, eliminate iron(III) as jarosite and oxidise iron(II) during neutralisation. The neutralisation conditions are controlled to precipitate aluminium, chromium and silicon, and to ensure good solid-liquid separation. Soluble impurities such as magnesium are purged with the tailings stream and will be managed over the long term by crystallisation in evaporation ponds.

Jan 1, 2006

Surfaces forces have been measured between gold sphere and gold-coated glass plate in xanthate solutions using an atomic force microscope (AFM). The measurements conducted in potassium amyl xanthate (PAX) and potassium ethyl xanthate (KEX) solutions showed long-range hydrophobic forces, with the force curves showing no evidence for nanonubbles on the surface. The strongest hydrophobic force was measured at contact angle of 94° with a decay length of 23 nm. The hydrophobic force became weaker at higher concentrations and after a long immersion time, which may be attributed to the xanthate species adsorbed on top of the first mono layer. The hydrophobic force became stronger when the residual xanthate solution is displaced by pure water, indicating that hydrophobic force becomes the strongest in pure water.

Jan 1, 2009

By Al Goodier

"This paper discusses the experience of Noranda Mines Limited, Matagami Division, with the vertical crater retreat (VCR) method in the mining of narrow-vein stopes. Although limited to only one stope, the viability of this method at the Radiore No.2 Mine has proven that further use of VCR in narrow-vein mining will be made.IntroductionThe Radiore No.2 property is located east of the Bell River in the southeast quadrant of Isle-Dieu Township, approximately 4.5 km east of the town of Matagami. The new James Bay Highway is 2.5 km north of the property and access to the mine is by a 2.5-km logging road.The property was staked by Radiore Uranium Mines in March 1961 and the sulphide body was first indicated by an E.M. survey. Diamond drilling commenced in the fall of 1961 and was completed by the end of 1962. As per an agreement in 1970, the claims were sold and assigned to Orchan Mines Limited. Subsequently, the property was transferred to Bell Allard Mines Limited, a wholly owned subsidiary of Orchan Mines. Early in 1979, Noranda Mines Limited acquired the property and it is now part of Noranda&apos;s Matagami Division.Geology and MineralizationThe deposit is in a band of volcanic rocks north of the Bell River complex. The lens of massive sulphides dips almost vertically and strikes almost east-west. The north contact is essentially sharp against andesite material; the south contact is less well defined, as the massive sulphides tend to grade into more disseminated material.The orebody varies from 5 to 20 feet in width, by 350 feet long and 200 feet in height. The overburden is composed of sand, gravel and clay, varying from 0 to 26 feet in depth. The ore reserves were 153,340 tons grading 1.97% copper and 1.01% zinc including 10% of dilution at zero grade."

Jan 1, 1982

By I. E. Wahn, E. A. Boutin

"The Manibridge Mill is unique in its treatment of relatively high grade nickel-copper ore because in the mill design are included one 10' diam. x 10' Maxwell cell, and three 12' diam. x 12' tank cells. These large cells are used as rougher-scavenger cells. Three 8' diam. x 8' tank cells as well are used for cleaning and recleaning of the tank cell concentrate.Flexibility of flow is the main criterion in the tank cell circuit. Targets from these cells are a high grade nickel-copper product with a minimum of talcose gangue.The operation of the tank cells has been encouraging and they have performed well with both low and high grade heads, yielding a high grade concentrate product.Manibridge Tank CellsDescription:The tank cells at Manibridge consist of one 10' x 10' Maxwell cell, three 12' x 12' tank cells, and three 8' x 8' tank cells. The four large cells are currently being used as rougher scavenger cells. The three small cells are used as cleaner cells.Both sets of tank cells consist of Denver steel tank and Super Agitator Mechanisms with steel beam super-structures. The agitator mechanism has a totally enclosed ball bearing spindle housing with a cold rolled steel shaft, and a stanclard standpipe with adjustable collar.The air rings for the tanks were fabricated by Nelson Machinery. Both large and small cells have injection rings with equally spaced air holes in the bottom centre line of the ring.Air is supplied to the tank cells by a Dresser Clark low pressure air blower.The following is a table of pertinent data on the tank cells:"

Jan 1, 1974

By D. E. Macdonald

"Approximately 2.0 million tonnes of phosphate rock is imported from the U.S. to Alberta annually and is used in the production of agricultural fertilizers. No phosphate rock is presently mined in Canada, although sources of igneous phosphate have been mined in the past. Sedimentary phosphate rock is found in nine geological units within the Cordilleran Foothills and Front Ranges region of Alberta. The Devonian-Mississippian Exshaw Formation, Permo-Pennsylvanian Rocky Mountain Supergroup, and the Jurassic Fernie Formation have the best potential f or future development. Most of the phosphate rock in Alberta is of low grade and lies within restricted land use areas. The best over-all resource potential lies in the Fernie basin area of southeastern British Columbia, in the Fernie Formation. The possibility of deep phosphate rock deposits in the plains region should be examined.Phosphate rock is mined in Idaho, Utah, Montana and Florida, and is shipped to Canadian fertilizer plants for processing. Raw phosphate rock is acidified, usually with sulphuric acid, by a wet process. Varying amounts of ammonia are added, and the fertilizer is pelletized. Future research, in western Canada, is needed in the beneficiating of low-grade ores and in the area of in situ mining. At the present time, phosphate rock sells for around US$50Itonne, and Alberta fertilizer companies probably pay in the range of C$7D-$85Itonne for U.S. phosphate rock delivered to the plant. Environmental concerns about phosphate rock processing are centred around gypsum tailing ponds, and radioactive wastes.U.S. supplies of phosphate rock are secure until the year 2000; however, by this time, the richer deposits in the U.S. may be exhausted. Alternate deposits, such as the ones in Alberta and British Columbia, might then be considered. Phosphate byproducts, such as uranium, vanadium, fluorine and rare earth elements, may help in making the processing of low-grade Canadian phosphates economically feasible."

Jan 1, 1988

By K. C. Hendrick

The paper will review the significant developments in world copper over the past ten years and their impact on the Canadian industry. It will also examine the outlook for the future.

Jan 1, 1971

By Robert B. Parsons

"Finance Minister Paul Martin&apos;s second budget might be good for Canada&apos;s mining industry in the long run, but the budget raises a number of concerns for the industry in the near term. The budget papers suggest that the 25% resource allowance is not working as intended, and report that the Department of Finance will be reviewing this valuable allowance. The so-called ""large corporations tax"" rate will be increased. This annual tax, which is imposed on a corporation&apos;s capital even when the corporation is not in production, is particularly harmful to the mining sector.IntroductionThe Honourable Paul Martin, in his second federal budget, emphasized spending cuts and made only modest tax changes. However, two of these tax changes could have a serious impact on the Canadian mining industry: the proposed review of the 25% resource allowance; and, the increase in the large corporations tax rate.Personal Tax Measures Personal Tax Rates UnchangedThe government has been under political pressure not to increase personal tax rates. Mr. Martin&apos;s announcement that rates would not change will be popular."

Jan 1, 1995

By B. Arlyuk

On the basis of research of relations among the market participants the analytical model has been created which connects the price of industrial good at stock exchange with volume of sales and the stock of the sellers and buyers, Also a model was developed for assessment of these parameters of the market status by the actually fixed stock exchange and general market indicators. The composition of these models made it possible to create reliable system of short-term price forecasting for commodities or base metals up to one quarter ahead. Imperfectability of creation a model for reliable price forecasting by purely statistic methods (by the "black box" principle) was shown. A model of price behavior qualitative forecasting till one quarter ahead has been developed, which determines the probability of reaching in future of the given level as well as of the price maximums and minimums, Optimal values of threshold probability were determined for forecasting the future price maximums and minimums securing the maximum profit from the forecasting system application for commercial activity. The developed system of forecasting was identified for primary aluminium at the period of 1990-2003. The system was tested daily during 20 months period for speculations on 3M primary aluminium forwards at London Metal Exchange with high commercial result.

Jan 1, 2004