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By P. Kawulka

An integrated pilot plant for the development of the S-C Copper Process was constructed at Fort Saskatchewan in 1975 and operated in 1976. The pilot plant was designed to treat 9 tonnes per day of a pyritic copper concentrate. A demonstration run conducted during the last quarter of 1976 averaged 90% on-stream time, and confirmed that the process is operable as a stable and integrated unit. The paper describes the parameters and equipment developed for thermal activation of chalcopyrite copper concentrates to make them amenable for the dissolution of iron and zinc, and their subsequent separation and recovery. The resulting high-grade copper sulphide was leached with return electrolyte and oxygen to extract 98.5% of the copper into solution. The copper was electrowon at 650 amps per square metre from purified solution, to produce cathodes analyzing 0.1 ppm Se, 0.1 ppm Bi, 4 ppm Pb and 10 ppm S. The electrical conductivity was >101% lACS and the spring elongation value [ ]350 mm. Elemental sulphur and gangue are removed from leach residues to make a concentrate containing over 95% of the silver and gold and most of the unleached copper. Conventional construction materials such as stainless steel, titanium, Hastelloy, acid brick, rubber and plastics performed well. The containment inherent in hydrometallurgy provided high standards of hygiene and safety.

Jan 1, 1978

By S. P. Lowe

Flotation testing of Flin Flon ore was started in the Denver laboratory of Complex Ores Recoveries Co. in March, 1926. There had been a considerable amount of flotation testing previously which had shown possibilities of success, and it was felt that, with the increased knowledge of flotation and the comparatively new reagents then available, flotation held out the best prospects for a successful commercial treatment of this ore. There remained available for this experimental work a small amount of the rejects from a thorough sampling of the mine and some ore from the mine dump.

Jan 1, 1930

By W. W. Rudolph, L. N. Trevani, P. R. Tremaine

UV-visible spectroscopy, Raman spectroscopy, and vibrating tube densimetry have been used in our laboratory to determine equilibrium constants of aqueous species at temperatures as high as 325 °C. The UV-visible and Raman spectra of solutions containing metal complexes and ionized acids or bases can be used to yield formation constants by applying curve fitting methods to resolve the contribution of each species. Colorimetric pH indicators identified by Johnston and coworkers at the University of Texas (Austin) provide an alternative means of determining ionization constants and the pH of complex mixtures. High precision density measurements over the same range yield standard partial molar volumes, which are key parameters for "equations of state" for aqueous species. Examples are given for the copper-ammonia system, simple carboxylic acids, and the iron-sulphate system.

Jan 1, 2004

By Victor Azbe

Introduction Lime enters our daily life in many ways. Our building, chemical, agricultural, sanitary, and industrial endeavours depend on it to such a great extent that it could probably be called the most important inorganic chemical, and the extent to which it is used might be considered an index of industrial development. Industrial limes vary greatly in quality, due to internal structure and other characteristics. They may be good or bad, sensitive or slow to react. While improper manufacture may not greatly alter the appearance of the lime, it may affect its properties considerably and thus its suitability in the many processes in which lime is used. In some of the processes, one kind of lime is wanted, in others another. While the nature of the stone from which it is made has much to do with whether a lime is suitable or not, its burning and hydration are the crux of the matter. Up to not so many years ago, the knowledge of lime burning was rather imperfect and it is only relatively recently that its manufacture is approaching the state of a higher industrial art. This slow development was in part due to lime manufacture being scattered among many small concerns who, independently, either lacked the inclination or could not afford to strive for a higher technical development.

Jan 1, 1946

By John H. Nicholls

In this paper, Imperial Oil Limited reports briefly on the drilling by contract rigs of twenty-nine slim holes in the Virden, Smiley, and Souris Valley areas. The investigations showed that slim-hole penetration rates, as a result of careful control of drilling variables, can approach those achieved with 7 7/8-inch bits. It is concluded that slim-hole drilling is acceptable for development or exploratory work. Imperial also reports on the completion techniques and equipment that have been developed on twenty-seven tubingless 2 1/2-inch casing completions. Indications are that the method is economically desirable where excessive gas or water production is not anticipated.

Jan 1, 1958

By Zhibao Li, Lanmu Zeng

The behavior of dicalcium silicate in NaOH-NaAl(OH)4-Na2CO3 solution is of significance for controlling the silica level in the production of alumina via the sintering process. Dicalcium silicate samples were obtained through a twostep approach: coprecipitation of calcium and silicate from CaCl2-Na2SiO3-NaOH solutions; and calcination of the hydrated precursor at 1200°C for 4 hours. The optimization of the synthesis parameters including temperature, solution concentrations and aging time was also investigated. Xray diffraction (XRD) and chemical analysis show that the calcined solids include dicalcium silicate with trace amounts of wollastonite. The solubility of the synthesized dicalcium silicate in HCl, NaOH, mixed NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was determined. It was found that the solubility increases with increasing HCl and NaOH concentration. The effect of temperature on the solubility in HCl solutions is limited, but the solubility decreases with increasing temperature in NaOH solutions. The solubility of dicalcium silicate in NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was shown to increase with increased temperature, Al(OH)3 and Na2CO3 concentration. The BromleyZemaitis model for the aqueous electrolyte system was selected to predict the solubility of dicalcium silicate. The model’s predictions yielded certain success compared with experimental solubility data.

Jan 1, 2014

An optimized long-term mine planning determines the best order of material extraction, so that the Net Present Value (NPV) becomes maximum. In the case of oil sands surface mining, one of the key constraints in NPV maximization is the volume of tailings slurry that will be generated downstream. Specifications of tailings slurry are also important from environmental perspective. Moreover, most of the material that will be used for the reclamation of tailings ponds in later periods is generated in extraction and processing of oil sands. In this paper, an integrated optimization framework is proposed to maximize the NPV of the produced oil sands, with respect to tailings capacity constraints and reclamation material requirements. A mixed integer linear programming (MILP) model is developed to find the optimal solution for long-term mine planning problem. The proposed model is coded in Matlab and has been run using CPLEX for verification. The results for real-case oil sands dataset show that the optimal production schedule meets material requirements for reclamation, tailings volume is within tailings capacity range in all periods and the production schedule follows the predetermined horizontal direction.

Aug 1, 2013

By A. Koster, V. Maurel, S. Dezecot, Szmytka. F.

The aim of this work is to clarify the role of microstructure heterogeneity in the initiation and growth of cracks in a lost foam cast A319 for low cycle fatigue (LCF) loading condition. Because 2D analysis fail to establish the scenario of damage events, this study is based on 3D in situ analysis using synchrotron X-ray tomography during LCF test performed at 200°C. If X-ray tomography is now an established technique to study damage development in 3D, its application for relatively high temperature cyclic tests has never been done so far. Initial 3D observations of damage show that the cracks that lead to fracture initiate near large pores and propagate into the hard particles 3D network of the eutectic regions.

Jan 1, 2015

By W. Tse, D. Wong

Dense medium separation (DMS) is one of several preconcentration methods used for early waste rejection from run of mine ores at relatively coarse particle sizes prior to additional milling and beneficiation. DMS has been used extensively in the coal, diamond and iron ore industries but lab scale and pilot test work has demonstrated successful separation and upgrading of other minerals such as lead, zinc, copper and lithium based ores using DMS. This paper reviews historical dense media systems, results from the pilot scale Condor DMS system as well as associated laboratory heavy liquid separation (HLS) test work.

Jan 1, 2014

By Jr. Jones

This paper is derived from a document that compiles autogenous and semi-autogenous mill installations worldwide, through the end of 2010. Updates have been solicited from all major mill manufacturers and most have responded. A review of AG/SAG mills sold to date and in the last five years indicates that the AG/SAG mill market is very healthy and the trend is larger diameter mills with high diameter-to-length ratios. Ring motors (gearless) are the preferred drives for large mills even though the power transmitted through a gear drive is expected to near 11,000 kW per pinion in the near future.

Jan 1, 2012

By M. A. Creaney

"The Construction Group is responsible for the construction of all of Placer Dome’s major projects and contributes to the development of most major feasibility studies. This group includes an international collection of Placer Dome people who have built mines in Papua New Guinea, Australia, Chile, the United States and Canada. This paper outlines the changing role of the Construction Group from the early days of single projects to today, when several projects are in various phases from feasibility to construction. The projects’ total annual budgets have from time to time exceeded one billion dollars. IntroductionAs the competition increases globally between the major gold mining companies, the impetus continues to build mines at the lowest cost with the shortest construction schedule. Placer Dome has more than met that challenge by building mines around the world at a pace that was not contemplated 15 or 20 years ago. Since 1960, Placer Dome has built 30 mines and expansions at a cost of nearly 4.5 billion dollars.In the last six years alone, Placer Dome has built 14 mines and expansions, worth 2.6 billion dollars. The company’s success is due primarily to Experience, Innovation, People and Standards.The diversity between projects, let alone the pace, has been a challenge. Placer Dome has built mines around the world in a variety of extreme climates and distinctive cultures. The construction experience gained from these projects has allowed Placer Dome to develop an extensive knowledge and data base making it easier to “fast track” projects.Through the years Placer Dome has developed a human resource base. It now has an experienced and adaptable core team of people able to set up construction projects and build mines anywhere in the world. By developing standards and systems to support the projects they can act as soon as a new project is approved, and complete the projects quickly and effectively. The result is that Placer Dome now has the construction expertise to build its own mines, giving them the competitive advantage that allows them to design and construct a mine in the least time at the lowest capital cost. This was demonstrated in March 1997 with the completion of the construction of two new mines in 12 months."

Jan 1, 1998

By Donald E. Archibald, Gerald A. Allcott

"Noranda's Heath Steele Mine is located 35 miles north of Newcastle in northern New Brunswick. Blasthole open stoping with partial delayed filling is the major mining method in use. The selection of stope and pillar dimensions to ensure mine stability was originally subjective. This paper describes the progress made in attempting to rationalize design.One major feature is the fracture pattern. The main orebody now being mined, the B zone, has undergone five periods of folding and each period of folding developed a family of fracture planes which are axial planar to that particular fold pattern.The other major features considered are the calculated increase in stress due to mining and depth and its relationship to measured strain. Experience has shown that ground problems affecting production have usually originated in rib pillars. Field observations of ground deterioration and multi-wire extensometer measurements of strain are tabulated together chronologically for each pillar.A factor representing stress and a common plane of weakness are identified. Graphical analysis is used to determine the effect of the plane of weakness on a typical stress/strain curve and provides a base for the design of pillars."

Jan 1, 1981

By A. J. Miller

Estimates of interstitial water saturation derived from capillary pres-sure data are compared with residual water saturations found by the analysis of cores out in oil-base drilling fluid. A theoretical explanation for the high-rate of water production from the Bellshill Lake Field is proposed, based on the interpretation of the capillary pressure data.

Jan 1, 1960

By Charles W. Villiers

AS is well known, there are large and valuable deposits of coal in British Columbia, both on the mainland and on Vancouver island. These deposits are widely distributed over the Province. The chief sources of supply on the mainland are found in the Fernie and Princeton-Nicola districts and on Vancouver island in the Comox and Nanaimo districts. The coals range from a very high quality bituminous coal to lignite. On the Upper Skeena river there is said to be a very large deposit of anthracite or semi-anthracite, but this field has not been developed. Coal was first discovered in British Columbia on the north end of Vancouver island in the year 1835, but it was not until 1852 that coal mining was seriously undertaken by the Hudson's Bay Company at Nanaimo, where mining has been carried on continuously ever since that date. The production of coal in the Province continued to increase until the year 1910, when the annual output reached its peak at 3,100,000 tons and a total of 7,800 men were employed in the industry. Since 1910, the production has dropped steadily until, in 1934, only 1,347,000 tons of coal were produced and less than 3,000 men were employed. This continued decrease in production has in no way been caused by lack of coal reserves. It has been due entirely to curtailment of markets. I do not propose to discuss coal mining practice in British Columbia, where we have all sorts of mining conditions, including submarine mining. There is no lack of coal supplies for either industrial or domestic purposes, nor is there likely to be any shortage of coal in the Province for many generations. We have our mining troubles, which increase the cost of production, but there are no insuperable difficulties to prevent the extraction of a large and increasing supply of coal. Our main difficulty-in fact our only serious difficulty-is to find a market for our output, and we must consider means which can be evolved not only to conserve our existing markets but also to expand them, at any rate within the boundaries of Canada. I will therefore confine my remarks chiefly to the all-important factor of Markets for our coal.

Jan 1, 1936

By S. Kursunoglu

The aim of this study was to investigate the effectiveness of Ascorbic (C6H8O6) Acid (AA), Activated Carbon (AC) and Guar Meal (C6H12O6) (GM) as a reductant for the simultaneous complete dissolution of zinc (Zn) and manganese (Mn) from a spent and mixed Zinc-Carbon (Zn-C) and alkaline battery powders in sulphuric acid (H2SO4) leaching. AA was tested previously as a reductant by other researchers while AC and GM were tested as a reductant for the first time in battery recycling. The effects of H2SO4 concentration, AA/AC/GM dosages, reaction temperature and leaching time on the Zn and Mn dissolutions were investigated according to 2k full factorial experimental design and Central Composite Design (CCD) technique; then, a simple optimization study was carried out for comparing the reductants. The optimum reductive acid leaching conditions for AA were determined at 3 hours leaching time, 70°C leaching temperature, 0.5M H2SO4 concentration, 13 g/L AA dosage, 1/20 g/mL solid/liquid (S/L) ratio and 200 rpm stirring speed. Under these conditions, the dissolution efficiencies were 99.9% for Zn and 99.3% for Mn. The best reductive acid leaching conditions for AC were determined at 3h leaching time, 80oC leaching temperature, 1M H2SO4 concentration, 3 g/L AC dosage and 400 rpm mixing speed. Under above conditions, Zn and Mn dissolutions were not complete. At 2M H2SO4 concentration, 10 g GM dosage, 700C leaching temperature, 200 rpm stirring speed, 1/20 g/mL solid/liquid (S/L) ratio and 3 hours leaching time, full dissolution of both Zn and Mn was achieved. As a result, three different reductants were evaluated in this study for complete simultaneous Zn and Mn dissolutions. This paper also compared present test results with previous spent battery recycling studies for Zn and Mn dissolutions. Full valuable metals dissolutions from spent batteries were achieved at low H2SO4 concentrations with AA and high concentrations with GM. Selective precipitations of Zn and Mn from acid solutions were carried out using NaOH and KOH. Using 3M NaOH as precipitating agent at room temperature and at pH 8; 95.4% of Zn and at pH 10; 93.7% of Mn were precipitated from the leach solution. Under the same conditions, using 3 M KOH at pH 8; 91.6% of Zn and at pH 10, 96.4% of Mn were precipitated. Based on the experimental results obtained, an appropriate flow sheet was proposed to recover both Zn and Mn.

Aug 1, 2013

By K. A. Clark

"The repacked mineral aggregates of good grade oil sands have permeabilities ranging between 15 darcys to 350 millidarcys. The variation is due to the silt contents of the aggregates. Few good grade oil sands contain as much as 30 per cent •silt, most of them contain less than 20 per cent, and a large proportion have less than 10 per cent.The permeabilities of repacked good grade oil sands (oil included) depend on the degree of liquid saturation. When saturation with oil plus water reaches between 80-90 per cent, permeability is reduced to zero. As total saturation decreases below 80 per cent, permeability increases ranidly. Permeabilities of between one and two darcys were observed for total saturations between 60-70 per cent.The mean value for 18 measurements of the permeabilities of ""undisturbed"" core samples of good grade oil sands was 50 millidarcys. This value is •probably too high. The mean value for 20 measurements on core samples of interbedded oil sand and shale was 100 millidarcys. The mean value for 11 measurements on shale was 10 millidarcys."

Jan 1, 1960

By P. Mageau-Béland, È. -M. Proulx, M. -C. Patoine

Over the past six decades, Hatch has helped several industrial processing facilities in debottlenecking their operations, allowing them to produce more with the same equipment, to reduce and even eliminate expenditure investments, or to increase the return value of their expansion projects. These successes result from the application of a proven analysis approach that can be applied to any industrial facility. A five-stage methodology is discussed and demonstrated with a specific example of a nickel concentrator optimization study. The first stage is an observation stage which allows to meet key actors at the plant, develop mutual understanding of problems, understand operating philosophy, and efficiently collect large amounts of operating and maintenance data. Following is a data compilation stage during which data is analyzed over a representative time period to identify parameters that significantly affect the production, to evaluate data reliability and to define the focus of the upcoming analysis. Quantitative metrics are defined using statistical tools such as pivot tables, histograms, percentiles and MDR (Maximum demonstrated production rate during 3 to 7 consecutive days). Then, the production bottlenecks are identified by a thorough analysis of the facility’s control philosophy, process throughput, equipment capacity, availability, downtime causes, and interaction between components of each circuit. Understanding the maintenance practices and frequency of planned shutdown is also critical to this analysis. Opportunities for improvement are identified in collaboration with the operation, maintenance and engineering teams, ranked as a function of their impact on the bottlenecks and prioritized. The final and most critical stage involves engagement with the plant stakeholders, namely the operators and the maintenance staff members, to present the results of the analysis and obtain their participation in the implementation of the solutions. The benefits of the case study translated into: 10% production capacity gain, improved maintenance planning and avoidance of several million dollars of investment.

Jan 1, 2016

By F. Baczek, S. S. Rocks, D. Chaiko, C. Eyzaguirre, S. Asihene, T. Walters

The majority of efforts to improve primary copper sulfide leaching have focused on solution chemistry, temperature, O2 pressure, ultra-fine grinding, the use of catalysts, etc. Historically, very few studies have focused on the solid/solution interface. A new, patent pending approach to catalyzed, copper sulfide leaching has been discovered by FLSmidth that enables manipulation of the 2-D semi-conductor properties of chalcopyrite surfaces to the benefit of higher electrochemical reactivity. Copper dissolution rates are then further accelerated by incorporating a Stirred Media Reactor (SMRt) into the process. By using minute amounts of Cu2+ to "pre-activate" chalcopyrite, leach times have been reduced from >20 hours with incomplete Cu dissolution to <2 hours with 98+% Cu dissolution at 80°C. The pre-activation process takes only minutes to complete at temperatures of 80°C or less. The total atmospheric leaching process, incorporating the pre-activation and Stirred Media Reactor is compatible with existing SX/EW processes. Results of batch leach testing are presented and possible mechanisms are discussed.

Jan 1, 2015

By X. -G. Chen, K. Liu

Nowadays, great interests are rising on aluminum alloys for the applications at elevated temperature, driven by the automotive and aerospace industries requiring high strength, light weight and low cost engineering materials. As one of the most promising candidates, Al-Mn-Mg 3004 alloys is found to possess considerably high mechanical properties and creep resistance at elevated temperature resulted from the precipitation of a large number of thermally stable dispersoids during heat treatment. In present work, the effect of Fe contents on the evolution of microstructure as well as high temperature properties of Al-Mn-Mg 3004 alloys has been investigated. Results show that the dominant intermetallic changes from a-Al(MnFe)Si at 0.1 wt.% Fe to Al6(MnFe) at both 0.3 wt. % and 0.6 wt. % Fe. In the Fe range of 0.1 to 0.6 wt.% studied, a significant improvement on mechanical properties at elevated temperature has been observed due to the precipitation of dispersoids, and the best combination of compression strength and creep resistance at 300°C is obtained in the alloy with an intermediate Fe content (0.3 wt.%) with finest size and highest volume fraction of a-Al(MnFe)Si dispersoids. The superior properties obtained at 300°C makes 3004 alloys more promising for high temperature applications. The relationship between the Fe content and the precipitation of stable dispersoids as well as the materials properties has been discussed.

Jan 1, 2015

By J. R. Morris

"A hoisting plant design should satisfy two basic requirements:1. to provide the necessary materials handling capacity, including ventilation where applicable, while meeting the requirements of good practice and, as a minimum, government regulation; and2. to optimize the economics of the project. Selection of hoisting equipment to meet the first objective is a complex but logical engineering process. The necessary calculations of payloads, accelerations, speeds, rope strength, hoist size, and power requirements are very readily carried out on computers or programmable calculators. A variety of hoist options can be quickly examined to assess the effects of changes in design parameters.Meeting the second requirement involves balancing the costs of various hoist arrangements and shaft designs, together with the time cost effects of differing shaft sinking rates and potential advances to be gained by concurrent level development. The proposed mine layout is significant here, as is the possibility of future shaft deepening and/or production increase. The availability of used equipment may be significant, both as regards first cost and delivery time. The factors are interactive, with their relative effects .varying from project to project. This paper sets out the primary factors to be considered."

Jan 1, 1990