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By R. E. Eyre, L. P. Landucci

C URRENT practice in the zinc concentrate roasting plant of The Consolidated Mining arid Smelting Company of Canada Limited, at Trail, B.C., involves passing the furnace effluent gases through an electrostatic precipitator for the recovery of dust. After removal of the dust the gas is treated for recovery of sulphur dioxide by conversion into sulphuric acid ( 1). However. as roasting techniques improved, and furnace productivity in-creased, the rated capacity of the precipitator was exceeded and it was necessary to consider various means of improving the dust recovery. A study of methods indicated that a baghouse using silicone-treated glass fabric, might be suitable for this particular application. Glass fabric was chosen because the temperature of the roaster effluent gases would range from 450°F to 500°F and tempering air was undesirable to avoid dilution of the sulphur dioxide gas.

Jan 1, 1962

By Shichang Liu, Hongli Jia, Zhaolian Wang, Maotang Liu, Ltd. Shandong Huate Magnet Technology Co., Fengliang Liu

"Introduce and promote a latest technology and equipment for magnetite. It’s featured of purifying concentrate, lowering tailing grade, high concentrate recovery rate and stable operation. HUATE® New Style Elutriation Electromagnetic Separator is an equipment to obviously upgrade magnetite. The slurry is fed into separation area through feeder. Generated by excitation coil, the working magnetic field distributes specially in separation area. Under the combined effect of the background field, excitation and demagnetic field and gravity, the mineral particles float downwards in the form of magnetic chains, and interact with the rising water. The gangue, non-magnetic particles, lean intergrowth,etc will be discarded as tailing via overflow tank and pipe. While the magnetic will be discharged from concentrate pipe. Its grade is 2%-10% higher than that of traditional magnetic separation equipment. It adopts the technologies of transformer oil cooling, alternative and uniform pulsation magnetic field controlling the tailing grade, larger drum feed-in device, more uniform umbrella scattering discharge and stabler output current, and realizes lower coil temperature raise, stabler magnetic field, more uniform discharge, effective isolation of weak-magnetic area from non-magnetic area, more obvious upgradation and recovery rate and lowering tailing mFe%. It’s more suitable to purify and thicken the high grade and ultrafine iron powder. Compared with traditional elutriation equipment, it adopts new technologies in removing impurities, operation, large-scale, process simplification, water-saving, remote control, etc. It optimizes the comprehensive beneficiation index, expands its application scope, reduces resource wastes and increases economic benefits.INTRODUCTIONMagnetite accounts for a comparatively great proportion in various iron resources. As it’s a kind of strong magnetic mineral, we must adopt the weak magnetic separation equipment in magnetic separation process to realize removing Si and lowering impurities. While it cannot do very well to use the common weak magnetic separation equipment in the final cleaning to remove Si and lower impurities. At present, the plants, adopting single magnetic separation process to realize cleaning and removing Si and lowering impurities, are in the minority. Most magnetite plants adopt the flotation separation process to remove Si, lower impurities and purify the concentrate. Though with stable indexes and high Fe recovery rate, the flotation process is very complicated, high-cost and with lots of environmental pollution. If adopting the weak magnetic separation equipment can realize removing Si, lowering impurities and the final cleaning, the magnetic separation process should be the primary choice."

Jan 1, 2016

By A. K. Chetin, W. W. Fitkin

"The reservoirs of Mississippian Mi-dale beds and Frobisher beds found in the Weyburn field lie at the north-western termination of a broad productive belt extending 120 miles along the northeastern rim of the Williston basin. These carbonates, and inter-bedded evaporites, originated during cycles of marine transgression and regression, and were deposited as rock types characteristic of shoal, lagoon, and basinward shelf environments. The Frobisher-Alida Beds, which form a secondary reservoir to the main Midale Beds of producing zone are composed of oolit1c, fragmental-bioclastic, vugular limestone capped by an impervious dolomitic mudstone. Production is controlled by localized structural features resulting from de-positional build-up. Excellent reservoir conditions are accompanied by an active water drive. The Frobisher Evaporite, consisting of massive primary anhydrite with dolomitic veinlets, forms the floor seal for the Midale beds oil accumulation. A significant facies transition into an oolitic, bioclastic, vugular limestone characterizes this unit. Beyond the depositional margin of the evaporitic facies, marked increases in porosity and permeability of the en-tire reservoir are noted. Carbonate units overlying the areal extent of the Frobisher Evaporite exhibit a greater degree of metasomatism, dolomitization, and more abundant secondary anhydrite.Porous carbonates comprising the producing zone of the Midale beds are divided into an oolitic, fragmental bioclastic, vugular limestone, and an overlying granular marly lime-stone unit, capped, by the Midale Evaporite. Oil is accumulated in a stratigraphic trap bounded above and be-low by primary anhydrite and truncated by the post-Mississippian erosional surface. Mississippian strata dip basinward from this erosional surface in a broad homocline exhibiting only minor irregularities. Rapid lateral and vertical porosity and permeability variations are common. Localized, separated, porous lenticles contain interstitial water in areas where the Midale beds are underlain by the Frobisher Evaporite. The major portion of the field, however, is capable of water-free production. Bottom and edge waters are found in certain portions of the field. Productive limits are tentatively defined around most of the present field perimeter. A large area along foe southern edge of the field remains open to future development. Probable ultimate remaining recoverable crude oil reserves, as of September 30th, 1958, were estimated by Mc-Daniel Consultants Ltd. to be in excess of 330 million barrels."

Jan 1, 1959

By Zygmunt Kowalczyk

"A theory permitting the determination of expected surface deformations for planned underground exploitation is proposed and discussed in this paper. The relations between surface subsidence and various methods of mining are analyzed, and allowable horizontal .deformations for protected objects, according to the degree of their significance, are reviewed."

Jan 1, 1966

By J. A. Drozdiak

In this paper we examine, through pilot-scale testing, the possibility of operating a circuit comprised of two stages of HPGR comminution, followed by grinding through a horizontal stirred mill. In order to assess whether the novel circuit design could achieve the reduced energy requirements indicated in the literature, two more-established circuits, a cone crusher / ball mill and an HPGR / ball mill, were examined using a combination of testing and flowsheet simulation. The results showed that, based solely on the specific energy requirements for comminution, the HPGR / stirred mill circuit achieved a reduction of 9.2% and 16.7% over the HPGR / ball mill and cone crusher / ball mill circuits, respectively.

Jan 1, 2012

By F. Siciliano, D. Bai, S. Yue, A. M. Elwazri

The influence of niobium addition and very low temperature (`cool') deformation on the microstructure and properties of low carbon microalloyed steels was investigated. In this work, the specimens were heated at 1200°C and held at this temperature for 20 minutes. Some specimens were aged at 400°C for times ranging from 10 minutes to 10 hours followed by air-cooling. Others were subjected to deformation at 400°C (`cool deformation') prior to aging. It was observed that the proportion of acicular ferrite was increased as the amount of Nb was increased. It was found that cool deformation increased both yield and tensile strengths significantly compared to that of the aged only specimens.

Jan 1, 2005

By A. Deneys

This paper reviews industrial gases used in primary copper production. Copper smelting industrial gas demand has steadily increased since the first commercial oxygenconcentrate smelting in 1952 [1]. In copper production oxygen for smelting is the dominant industrial gas use followed by oxygen for converting. Nitrogen is finding increased use in copper smelters. Nitrogen is used for porous plugs for copper converting and anode refining [2-5]. Nitrogen can be used for concentrate drying [6,7] and is also used in some Ni-Cu smelters as a coolant in Peirce-Smith converting [8,9]. Industrial gas supply options of cryogenic or adsorbent based on-site plant or cryogenic liquid delivery are detailed.

Jan 1, 2007

By Hajime Miki, Gde Pandhe Wisnu Suyantara, Shigeto Kuroiwa, Eri Takida, Tsuyoshi Hirajima, Masashi Yamane, Yuji Imaizumi, Mitsuru Sawada, Keiko Sasaki

Selective flotation of molybdenite and chalcopyrite using various oxidation treatments (i.e., ozone treatment, hydrogen peroxide, and Fenton-like reagent) was studied in this work. It was found that ozone treatment produced a depressing effect on both minerals, resulting in a lower separation of both minerals. On the other hand, oxidation treatment using hydrogen peroxide (H2O2) and Fenton-like reagent could deliver selective oxidation on chalcopyrite surface and depress its floatability. However, bench-scale copper- molybdenum (Cu-Mo) flotation tests show that oxidation treatment using H2O2 required a higher dosage of H2O2 and a longer treatment time in order to deliver comparable flotation results to that of conventional Cu- Mo flotation using NaHS treatment. On the contrary, Fenton-like reagent could deliver selective Cu-Mo flotation results comparable to that of NaHS treatment at a lower dosage of H2O2 and a shorter conditioning time. Contact angle measurements and X-ray photoelectron spectroscopy (XPS) analysis were employed to understand the depressing mechanism of these oxidation treatments. It was found that the chalcopyrite surface covered by various oxidation products that render the surface hydrophilic. Meanwhile, the surface of molybdenite was slightly oxidized, making the surface remained hydrophobic. INTRODUCTION Molybdenite (MoS2), the main source of molybdenum, is associated with copper sulfide minerals, mainly chalcopyrite (CuFeS2), as a trace mineral. Molybdenite is a valuable mineral and plays an important role in making the copper-molybdenum (Cu-Mo) processing plant economically viable (Laskowski, Castro, & Ramos, 2013). Therefore, it is important to recover molybdenite efficiently and effectively and separate it from copper minerals. Conventional separation of copper and molybdenum minerals is usually carried out in selective Cu- Mo flotation process using a copper depressant (i.e., sodium hydrosulfide (NaHS), Noke’s reagent, or cyanides) (Ansari & Pawlik, 2007; Bulatovic, 2007). However, this process still suffers due to imperfect molybdenum recovery. Moreover, the copper depressants use in this process are toxic and harmful to the environment. As alternative, various methods have been developed to replace these toxic and hazardous depressants, for example, by synthesizing new non-toxic or low-toxic depressants or by using various oxidation methods such as sodium hypochlorite in an alkaline medium, manganese dioxide, oxygen, and plasma pre-treatment (United States Patent Office Patent No. US 2559104 A, 1951; Patent No. US2238250 A, 1941; Barzyk, Malysa, & Pomianowski, 1981; Hirajima et al., 2014). However, the oxidation phenomenon and mechanisms are still not clear since detailed surface analyses have not done and the plasma pre-treatment method is facing technical issues for industrial scale application.

Jan 1, 2019

By J. P. Norrie

The presence of copper-bearing rocks in the Coppermine River area of Arctic Canada has long been known. Word of this was probably circulated along the Arctic and Hudson Bay coasts by the Eskimo, who no doubt traded articles made from native copper among themselves. It is not known whether any of these ever reached the southern shores of Hudson bay. The Indians, also, knew of the occurrence of copper here, as they served as guides to Hearne when he made a successful trip over land from Hudson bay to the Coppermine river. The possible commercial importance of these copper deposits was early appreciated by the Hudson's Bay Company, who on December 7th, 1770, despatched Samuel Hearne from Fort Prince of Wales, now Fort Churchill, to investigate them. He reached the then unnamed river at a point forty miles from its mouth on July 14th, 1771, and after surveying the river to its mouth and naming it the Coppermine, he retraced his steps to Fort Churchill by an overland route. Hearne's expedition was probably the most remarkable and arduous ever attempted in Arctic exploration, but the actual value derived from the trip was entirely out of proportion with the hardships he must have suffered. He verified the occurrence of native copper, but his astronomical and other observations were of little value. Until 1912 no concerted effort was made to obtain any definite information as to the geology and economic value of the Copper-mine deposits.

Jan 1, 1931

By R. W. Culley

"In many areas of Saskatchewan, known gravel deposits have been depleted or are diminishing rapidly; in other areas, particularly in the north, demands for all-weather highways and access roads are far exceeding the supply of gravel sources with which to surface them. These two problems have made conventional methods of air-photo and ground surveys insufficient for gravel location. In the first case, hauling costs on construction now warrant searching for buried deposits and for smaller, less obvious surficial deposits that may be closer to the project. In the second case, search and access conditions are so difficult and costly that the ratio of successes to failures must be kept very high. The Department of Highways has long been aware of the oncoming scarcity of quality gravel deposits and is continually investigating ways of forestalling it. One of these ways is the use of airborne geophysical methods that permit rapid coverage of large areas and that sense and discriminate between earth properties to a significant depth below ground surface. In 1967, the Department began an investigation of an airborne conductivity survey method called INPUT*, or ""Induced Pulse Transient'', leading to a trial in 1968 and data analysis in 1969. The results of this trial initiated• modifications to the technique to improve its sensitivity for mapping shallow deposits. Part way through this modification in 1970, a decision was made to change to an airborne resistivity survey method called EPHASE*. Trials with this technique were conducted and analysed in 1971. This paper is an explanation of the E-PHASE system and a summary of the results from one of three areas mapped in 1971."

Jan 1, 1973

By Liu Liu

In the recent 10 years the rapid development of Chinese steel industry has attracted the attention of the world. The technological progress of converter steelmaking has played an important role in this process. First of all, slag splashing has been extensively adopted by Chinese steel companies in various sizes of converters from largest to smallest ones, and even including those using special hot metal containing V and Ti. Remarkable metallurgical results have been achieved. Up to now the average converter campaign life has reached nearly 10,000 heats, and the longest exceeds 30,000 heats in three melt shops. Based on this process, the long-life combined-blowing converter steelmaking technology has been developed. Slag splashing has been used to form a gas permeable "slag mushroom" on the top of bottom nozzles to protect the nozzles. In order to keep the effective bottom blowing, furnace bottom thickness control technique has been developed to prevent the furnace bottom growth. It makes the service life of bottom nozzle the same as the converter campaign life (average 10,000 heats and longest > 30,000 heats). The complete combined blowing was ensured through out the furnace campaign. Concentration product [C][0] is in the range of 0.0023 ~ 0.0030%, the T.Fe in the slag is lowered by 4 ~ 6%, and the [0] in steel is decreased by 100 ~ 250 ppm.

Jan 1, 2004

By L. Juteau

"""The north coast of the St. Lawrence River will be the scene of an industrial development during the coming decades"". The facts which underlie this statement are the occurrences of iron and titanium ore, the abundance of hydro-power and the availability of deep-water ports in this region. Havre St-Pierre, Sept-Iles, Port Cartier and Baie Corneau already exist as major ports and urban centers. The huge quartz deposit at Baie Comeau will be a decisive contributing factor in the development of a metallurgical plant in this area. Due to its purity, it lends itself, first of all, to the manufacture of glass of different kinds, being comparable to the quartz sands now used by the plate glass and glass container industries in the Montreal area, Moncton, N.B., Trois-Rivieres and - in the future - at Bécancour, Quebec. However, its high quality will also make it possible to use it as one of the main basic materials for the production of silicon carbide and ferrosilicon, and as a flux in metallurgical processes. It is intended, in this report, to offer conclusive proof of the economical importance of this large quartz deposit by presenting the results of the studies made to date."

Jan 1, 1971

By S. Mohammadnejad, M. Olizadeh, B. Mehrabi

A new method using a combination of comprehensive mineralogical and analytical approach which includes optical and electrical microscopy and several analytical techniques with diagnostic leaching has been used to characterize the associations and distribution of gold in a variety of minerals from the Zarshuran refractory gold ore, NW Iran. Zarshuran ore with an average of 7.9 g/t Au-grade and about 8% arsenic with gold recovery less than 20% in direct cyanidation is considered as high arsenic, high au-grade refractory gold ore. In most of the refractory ores, gold is associated with arsenopyrite and co-para genetic ore minerals, while in Zarshuran ore; gold is associated with orpiment, realgar and arsenian-pyrite. Considering its mineralogy and As content, it can be considered as the most difficult refractory ore for characterization and processing. Results from the mineralogical examination and diagnostic leaches indicate that there is only a small amount of free gold (17-19%) that is present in cyanide-soluble sulfo-arsenides compounds, predominantly orpiment and realgar. Diagnostic leaches also indicate that little gold is occluded within the silicate structure (14%). Overall, the gold is mostly included in sulfides, arsenic sulfides and sulfo-arsenides (50%). The results also have shown how the technique can be used to gain a good initial understanding of potential metallurgical problems for a refractory gold ore.

Jan 1, 2005

By G. K. Quainoo

In the automotive industry, the awareness to meet Corporate Average Fuel Efficiency (CAFE) standards has evolved the need to reduce vehicular weight in new automobile designs, with the overall goal of reducing gas emissions into the atmosphere (Kyoto protocol), One efficient method has been to use lighter materials such as aluminum in outer body panels, Heat treatable AA6111 is one of the materials employed due to its unique combination of formability, paint bake strengthening and superior corrosion resistance characteristics, Researchers have applied various thermo-mechanical processes on 6000 series aluminum alloys and have found an improvement in the mechanical properties of these alloys, For a formed and painted automobile panel, the final mechanical properties involve a combination of strength components arising from cold work, strain aging and precipitation minus recovery. In this study, the evolution of microstructure resulting from the interaction of cold work and precipitation in AA6111 has been studied by means of transmission electron microscopy (TEM) after subjecting samples to various heat treatments, tensile testing and differential scanning calorimetry (DSC), This has been done to understand the evolution of microstructure and its influence on the properties of the alloy, The results show a considerable improvement in strength with a corresponding increase in strengthening precipitates with increasing level of cold work in the alloy. DSC results following the application of various levels of cold work also show acceleration in the precipitate phase formation, as precipitates are observed to form at lower temperatures, with increasing level of cold work/

Jan 1, 2005

By M. Krasowska, K. Malysa, M. Krzan

The paper presents fascinating, in our opinion, observations on mechanism and course of processes occurring during bubble collision with hydrophobic and hydrophilic solid surface. Hydrophobicity of particle surface is a necessary condition for the particle attachment to bubble. We have observed that even in the case of such hydrophobic solid surface as Teflon, the bubble attachment didn't occur at first collision. In distilled water the bubble bounced a few times without attachment. Influence of a-terpineol and n¬pentanol on bubble local and terminal velocity and the phenomena occurring during bubble collisions with hydrophobic and hydrophilic solid surfaces was studied. Bubble collisions with the solid surfaces were monitored and recorded using the high-speed (1182 frames per second) camera. It was found that in distilled water the velocity variations of the "approach-bounce" cycles were identical for Teflon and glass. Four distinct "approach-bounce" cycles were detected both at Teflon and glass surfaces. Moreover, the amplitude and frequency of the velocity variations were identical on collisions with the hydrophobic (polished) and hydrophilic surface. There was no immediate three phase contact formation, with the hydrophobic Teflon surface, what we found really astonishing. Roughness of Teflon surface seems to be important parameter, which affects probability of the bubble attachment as a result of a presence of micro-and/or nano-bubbles at the surface. It was detected that the presence of the micro-bubble affected attachment of the colliding bubble even in distilled water. Presence of a small amount of a-terpineol or n-pentanol affects dramatically the bubble velocity, but their role in mechanism of the bubble attachment needs further study.

Jan 1, 2004

By J. C. Gibson, C. H. Stockwell

"The San Antonio gold mine is at Bissett, Manitoba, on the north shore of Rice lake, 100 miles northeast of Winnipeg. Gold was discovered on the property in 1911, but intensive exploration was not undertaken until 1926. Milling commenced on May 1st, 1932. Total amount of ore milled from that time until the end of 1946 was 1,766,670 tons, having a value of $18,378,317.GENERAL GEOLOGYThe rocks in the vicinity of the mine are Precambrian and include three groups, namely, the Rice Lake series of volcanic and sedimentary rocks, basic and acidic intrusions, and a younger formation of sediments known as the San Antonio formation (Fig. 1). The lower part of the Rice Lake series, consisting of flows of rhyolite, trachyte, and andesite with interstratified beds of agglomerate, occupies an area extending southward from Rice lake. The lake itself and the country to both east and west of its northern end is underlain by the next succeeding beds of the series, which are chiefly tuffs, arkose, and conglomerate, but include a thin band of basalt. Northward from the lake, these are succeeded by the upper beds of the series, first a thin band of basalt and, overlying this, porphyritic andesite flows interlayered with beds of volcanic breccia or agglomerate.The Rice Lake series has been invaded on the east side of the lake by a body of basic rock ranging in composition from gabbro to diorite and quartz diorite, now much altered. This is cut by younger sills and dykes of basic rock, probably diabase, the original texture of which is largely destroyed by alteration. Numerous dykes of feldspar porphyry, quartzfeldspar porphyry, and a few of a rhyolite-like rock, occur south of the lake, but are uncommon to the north. They cut the diabase and older rocks.Extending westward from Rice lake and lying with marked angular unconformity against all of these rocks is the San Antonio formation, consisting of cross-bedded, arkosic quartzite."

Jan 1, 1954

By Carlos Rebolledo, Nelson Parra

Arsenic is an unresolved problem in the mining industry considering the fact that most of the new copper deposits have high arsenic contents; stricter environmental restrictions for handling, transporting and processing complex materials are expected and stable abatement of arsenic is not extensively applied. In 2018 Chile produced 24.5% of the total copper from concentrates and in the future copper production in Chile is expected to increase, mainly associated with production of concentrates that will also contain more arsenic. China has set an import benchmark of maximum 0.5% for arsenic content in copper concentrates and this value is expected to be more restrictive in the future. On the first day of 2018 China banned the importation of scrap. Blending practice has been a business option, but it is not sustainable in the future, as “normal” copper concentrates become less and less clean. By the end of 2018, Chile formulated new regulations, increasing the capture of SO2 and arsenic to 95%. In order to comply with these regulations Chilean smelters had to make large invest large amounts of money. Disposing of arsenic as a stable residue is a pending issue. EcoMetales is a 100% subsidiary of Codelco and provides the mining industry with environmental solutions. It has a plant near Calama in Chile that treats flue dust from smelters, refinery effluents and acid solutions from acid plants. EcoMetales is fully committed to contributing to the solution to the arsenic problem. Currently we are developing four main projects: 1) Concentrates treatment. A PLCC project considering the treatment of 200 ktpy of copper concentrates with arsenic from the northern district of Codelco; 2) EPAS DET project considering the treatment of 700 m3/d of weak acid solution with arsenic from the of El Teniente devision of the Codelco acid plant; 3) Borras project, considering the recovery of valuable metals (Cu, Ag, Ge, Pb) from the flue dust leaching plant; 4) Tailings project, considering the recovery of metal values from tailings. The purpose of this work is to present the trends and treatment processes for arsenic handling in the copper mining industry with a focus on the scorodite process. INTRODUCTION Between 2000 and 2015 the global copper concentrates production has grown from approximately eleven to fifteen million metric tons per year. Chile produced 26.5% of the total copper from concentrates and in the future copper production in Chile is expected to increase, mainly as a result of the production of concentrates (Figure 1)

Jan 1, 2019

By J. Dubinski

Underground mining of copper ore in the Legnicko-Glogowski Copper District basin generates a number of seismic events, whose energy often exceeds 108 J (Butra, 2010). The number of tremors and their location shows that the area of rock mass involved in the deformation and failure processes significantly exceeds the area of mining operations. Locations of seismic foci of high energy tremors, as well as the aftershocks that accompany them, extend hundreds of metres, confirming that processes to restore the energy balance of rock mass occur in a short amount of time and over a wide area. Thus, an area of similar size should be considered in predictive analyses of the tremor?s position. It should be emphasized that a large portion of the rock mass still has a level of freedom resulting from the way the rock mass is held together and its geometric continuity. This level of freedom is dependent on the scale and duration of mining, the number and size of natural structures, and rock mass pressure, including gravitational pressure constricting individual fragments of rock mass in the area (Burtan, 2012). It can therefore be assumed that in real conditions, areas where mechanical strength of the layers has been exceeded may be located a considerable distance from each other and do not necessarily need to coincide with the working area location. In this sense, a rock mass influenced by mining exploitation is essentially a rock mass in which numerous fragments with concentrated energy exist simultaneously. Energy will be released within these rock mass areas each time rock mass strengths are exceeded by the induced stress changes related to mining operations. This paper presents a discussion on how to predict the location of seismic activity areas based on a change of position of seismic energy equivalents. This parameter is calculated for a given set of seismic tremors with defined foci coordinates. For a given set of seismic tremors, the location of seismic energy equivalents may be used for predicting the location of high-energy seismic events.

Aug 1, 2013

By G. J. Kipouros, W. Judge

"The prevalent metal extraction processes for most reactive metals are fused salt electrolysis and metallothermic reduction. The feed material for both of these processes is the anhydrous chloride of the metal under consideration. Dehydration of the feed material is then a critical step in the production of most reactive metals and requires rigorous thermodynamic analysis. Thermodynamic data for most of the reactive metal chloride hydrates have not been measured. Improper dehydration of the metal chloride may lead to a prohibitive amount of hydroxychloride, oxychloride, and oxide. To prevent hydrolysis a certain pressure of hydrogen chloride is required. An estimation and prediction model is presented for the vapour pressures of reactive metal chloride hydrates in an attempt to deduce the conditions necessary for dehydration to proceed without hydrolysis. Thermodynamic data including heat capacities, standard entropies, and standard enthalpies are estimated/predicted for all conceivable intermediate hydrate compounds. Estimations are based on published data as well as trends proven in similar systems. The thermodynamic estimations and predictions are presented for the magnesium, neodymium, praseodymium, and dysprosium chloride hydrates. INTRODUCTIONThe high reactivity of metals such as the alkalis, alkaline earths, and lanthanides prevents their reduction by traditional pyro- or hydrometallurgy. In their elemental form, these metals are raw materials in the manufacture of intermediate products such as alloys and electronic components. Currently the only two viable metal production methods are fused salt electrolysis and metallothermic reduction. Various feed materials have been proposed for these processes. Using the chloride of the metal as a feed material offers advantages in separation and purity of the final product, as well as lower energy input. Chlorides, however, are hygroscopic and must be dehydrated before use. Improper dehydration will lead to a prohibitive amount of oxychloride which will lower efficiencies and contaminate the final product.Optimum conditions for proper dehydration of MgCl2•6H2O to produce pure MgCl2 without hydrolysis have been calculated from existent thermodynamic data and have been reported previously (Kipouros, 1987; 2001). Calculations were also performed for the case of production of pure anhydrous NdCl3 from NdCl3•6H2O (Roy, 1997)] and the mechanism of dehydration was elucidated. Some thermodynamic studies on the dehydration of chlorides of the rare earths have also been conducted (Sundstrom, 1997; Hong, 1997; Aschcroft, 1968; Haeseler, 1965; Ukraintseya, 1989)."

Jan 1, 2012

By Stéphane Robert

This document presents estimates of future "total cash cost per ounce" and "minesite cost per tonne" that are not recognized measures under United States generally accepted accounting principles ("US GAAP"). This data may not be comparable to data presented by other gold producers. These future estimates are based upon the total cash costs per ounce and minesite costs per tonne that the Company expects to incur to mine gold at the applicable projects and do not include production costs attributable to accretion expense and other asset retirement costs, which will vary over time as each project is developed and mined. It is therefore not practicable to reconcile these forward-looking non-GAAP financial measures to the most comparable GAAP measure. A reconciliation of the Company's total cash cost per ounce and minesite cost per tonne to the most comparable financial measures calculated and presented in accordance with US GAAP for the Company's historical results of operations is set forth in the notes to the financial statements included in the Company's Annual Information Form and Annual Report on Form 20-F, for the year ended December 31, 2009, as well as the Company's other filings with the Canadian Securities Administrators and the SEC.

May 1, 2011