Search Documents

By Y. Bai, J. J. Liu, D. Q. Li, S. Z. Liu, X. T. Wang

"This paper presents the results of an industrial test using 8 t/d of Baotou concentrate (50% REO) of a clean metallurgical process, which includes: 1. Roasting with H2SO4 at low temperature (220~260 0C) in a batch roasting furnace followed by water leaching to obtain a leach liquor as feed with a yield of >95% RE and Th, recovering F as fluoride, producing a leach residue amounting to 1/3 of an equivalent high temperature residue and containing <0.03% Th and radioactivity < 3×104 Bq/kg compared to the normal high temperature residue containing 0.2-0.3% Th and 1×105 Bq/kg. 2. Separating Th with N1923 and extracting RE by P507 has been completed in mixer-settlers. Test results indicate that the ThO2 product has a purity of > 95% with a yield of 99%, and the RE has a yield of >95%, in which ThO2/REO <5×10-6, and that P507 loaded RE connect straight with separating RE using P507-HCl system. 3. Treatment and multipurpose use of "three wastes" (water, gas and solids) are discussed in some detail."

Jan 1, 2014

By T. Iwasaki

This paper points out two key elements in resource trade in general and the Canada-Japan relationship in particular. The first is that the advanced countries have a more important role than one would expect in the supply of resources in world trade. Canada &apos;s dual role as a major resource supplier in conjunction with an advanced economy will continue to increase. The second point is the heavy reliance on foreign resource supplies in some advanced economies, particularly in Japan. Finally, as regard the future of the Canada-Japan economic relationship, particularly .in resource development, it is suggested that trade could be enhanced by an accelerated exchange of various types of resources between the two countries. These include natural resource commodities as well as the more abstract capital, technological and human resources.

Jan 1, 1978

In order to maintain a production rate of 6,000 tonnes per day from underground at the Williams Operating Corporation, two independent mining areas were required which created a long narrow sill pillar between them. During initial mining of the sill pillar there were a number of significant ground falls [LeBlanc and Murdoch, 2000] and in March 1999, with no active mining ongoing in the sill pillar area, a rockburst of magnitude 3.0 Nuttli occurred. Extensive ground support was designed and installed to withstand events of similar magnitude [Bawden and Jones, 2002]. A mine wide microseismic system was installed to monitor mine induced seismic behaviour over the entire mine. The area most directly affected by the 1999 rockburst was rehabilitated using a highly ductile support design. Along with microseismic instrumentation, the areas were instrumented using conventional SMART Cables and SMART MPBX?s. Subsequent to this, the area was impacted by a large number of high magnitude seismic events [magnitudes between 1.7 and 3.5 Nuttli]. The ground support performed very well during these events, providing confidence in the mine?s ability to control the ground under severe rockburst conditions. Analyses of microseismic and conventional instrumentation, combined with numerical analyses of sequence alternatives, were used to develop an optimal mining strategy for the sill pillar area. The selected strategy involved utilization of instrumentation data and calibrated model results to analyze yield zones in the sill. The analyzed ?yielded? zones were assessed to be low seismic risk. Initial mining in the sill was then concentrated in these low risk areas, with the objective of further concentrating stress into the remaining seismically active area, in order to induce ultimate failure of the sill. Continuing large magnitude seismicity and resulting damage in the remaining ?high seismic risk? area, led to abandoning a second portion of the footwall access and the strategic decision to extract a stope near the centre of this zone in order to force final failure of the sill pillar. During execution of this plan two large magnitude seismic events occurred resulting in destressing and final failure of the remaining sill pillar. The paper provides a detailed description of this ?strategic mine sequence driven self-destressing process? and the implications to final extraction planning in this area of the mine.

Apr 1, 2005

By T. Holmes

Investigations reveal that the throughput difference between a perfect production day and the average is often on the order of 40%, and that bulk solids handling system deficiencies are the largest (>50%) class of lost opportunities. Root causes for underperformance of elements in material handling systems can often be traced back to the detailed design and even study-stage oversights. To reduce or eliminate bulk solids handling problems in an existing system requires an analysis of troublesome handling equipment – for example, a concentrate transfer chute that experiences plugging, poor flow to the furnace, unacceptable dust generation, and spillage. These problems often lead to significant maintenance costs related to downtime and personnel time. Understanding the cause and cost of flow issues is the first step in troubleshooting the problem. Next, measuring the material’s flow properties is critical to providing design data required to develop a comprehensive scientific solution. In the case of a new installation, the design data is required to properly design the system right first time and prevent flow problems from occurring so that the new equipment works correctly from start-up. This paper highlights the cost of material handling problems and discusses the best approach to evaluate material handling system deficiencies. A case study is given of how Anglo American's operation in Barro Alto Brazil enjoyed a 5-month payback from a bulk solid transfer chute debottleneck project. INTRODUCTION When operating a plant or designing a greenfield or brownfield operation, the intent is to have perfect production days (PPD) each and every day. Money is made by moving material through the plant in a controlled manner to produce the desired product. Mining operations and copper concentration processes are at the most basic level a practice in bulk solids handling (BSH). Unfortunately, many of the project planning steps are overlooked, particularly related to BSH. Investigations reveal that the throughput difference between a PPD and the actual average is often on the order of 40%, and that BSH system deficiencies are the largest (>50%) class of lost opportunities (Wellwood, 2017). Root causes for underperformance of elements in material handling systems can often be traced back to the detailed design and even study-stage oversights. BSH issues are essentially baked into the fabricated plant and left to operations to accept the deficiencies and deal with them for the life of the mine. These deficiencies then become part of the normal operation of the mine and plant.

Jan 1, 2019

By James F. Archibald

Research has been conducted for the Workplace Safety and Insurance Board of Ontario (WSIB) to characterize thin, spray-on lining materials (TSLs), as well as combinations of TSLs and conventional spray supports, and to assess their capacity for inhibiting damage created by mining-induced rockbursts. This study has been performed to assess the capabilities of such support systems for preventing rock and support material damage that often results due to rockbursting. A variety of TSLs and other spray support media were subjected to the effects of simulated rockbursting, through use of explosive detonation trials, to evaluate their damage mitigation capacity. Results have validated that TSLs and variant layer combinations may be as effective as or better than conventional support materials for mitigating rockburst or like damage in highly stressed mine environments. In civil engineering construction, and typically in underground tunneling operations where concrete linings are applied, liner deterioration is a continuing and pervasive problem that often requires expensive and time-consuming rehabilitation effort. The ability of TSLs to provide effective concrete structural reinforcement while providing sustainable resistance against underground or restricted environmental hazards, as with fires or dynamic failure events, may permit wider use of TSLs than is currently foreseen by the mining industry. Significant benefits for use of TSL materials in concrete liner rehabilitation and for concrete material protection have been assessed.

May 1, 2006

Plan de l?exposé ?? Présentation du site de la mine Restigouche et du mandat confié à Genivar ??Dénoyage de la mine ??Processus d?enlèvement des boues au fond de la fosse ??Utilisation de Géotubes dans le procédé à l?usine de traitement des eaux.

Feb 1, 2008

By Jeffiey B. Austin, Maurice Tagami

"The ores of the Iberian Pynte Belt are typically massive sulphide ores with very fine grained mineral textures. EuroZinc Mining Corporation is currently evaluating one of the massive sulphide deposits located near the town of Aljustrel, in South Central Portugal. The deposit contains significant grades of lead, zinc and silver. The ores are comprised solely of sulphide mineralization consisting of pyrite, sphalerite, galena and some secondary copper minerals. Liberation requirements for these ores are typically 22 to 25 microns. A selective flotation process has been utilized to produce separate lead and zinc concentrates for sale to off-site contract smelters.This paper outlines the process test results and describes the process parameters required to optimize the process parameters. Ths test program has been conducted in support of the re-opening of the facilities in Aljustrel. The 3500 tpd mining and milling facility was commissioned in 1990 and operated for 18 months before closing. The previous facility was designed to produce three products using a selective copper-lead-zinc flotation process. EuroZinc Mining Corporation is proposing to re-open the operation, selectively mining from a lead-zinc phase of the massive sulphide deposit and produce only lead and zinc concentrates.Results are presented and discussed.PROJECT HISTORY AND CURRENT PROJECT OBJECTIVESThe EuroZinc Aljustrel Project is a potential major producer of lead, zinc and silver located in the Iberian Pyrite belt of south-central Portugal. The town of Aljustrel is historically associated with mining dating to the time of the Romans. The area is rich in pyrite deposits, and sections of the pyrite deposits contain significant zones of copper, lead, zinc and silver. Mining in Aljustrel during the last century (1900’s) included a major pyrite mining operation, which produced feed for sulphuric acid production. Pynte mining operated from the 1930’s to the early 1970’s and a short-lived base metal operation from 1989 to 199 1."

Jan 1, 2000

By P. N. Saavedra, E. A. Salamanca

"The maintenance strategies in the mining industry are changing from operative and periodic inspection strategies to a condition-based, predictive maintenance strategy centred in vibration analysis plus complementary techniques. Condition monitoring can also help to improve availability by being able to pinpoint and diagnose problems on operating machinery at an early stage. This reduces unscheduled downtime and production losses.However, in mining, for shovels operating in transient modes, with variable load and/or speed, the FFT (Fast Fourier Transform) standard approach is not directly applicable for analysis. This work illustrates how spectral order analysis and new transforms, called time-frequency transforms (TFT), allow us to monitor the shovel when it is working. Some practical examples showing the application of these analysis techniques to occasional vibrations measured on hoist and crowd transmission of a shovel are also presented. It is shown that at present, it is possible to carry out the vibration monitoring in the mining shovel while it is working, therefore avoiding the high cost of a loss of production which can occurr in traditional monitoring, where the measurement is taken while the shovel is out of production."

Jan 1, 2002

By H. Soto, J. Jara, F. Nava

"A combination of oxidation and precipitation was used to eliminate cyanide from gold milling effluents. Preliminary laboratory work developed with both synthetic cyanide solutions and with industrial effluents indicated that ozone can easily destroy free cyanide and weakly complexed cyanide (i.e. copper and zinc cyanide). In this case the reaction is quite fast and seems to be controlled by the mass transfer of ozone to the solution. Experimental results indicate that free cyanide and weak-acid dissociable cyanide in mill effluents can be reduced to less than 1 ppm. However, the iron-cyanide complexes proved to be quite resilient to destruction with ozone and they remained in the solution even after most of the free and weakly complexed cyanide was destroyed with ozone. These results were confirmed in a pilot trial developed at the Sphinx plant in northern Quebec.To deal with the problem presented by the presence of the iron complexes two different approaches were studied: use of a combination ozone-ultraviolet light oxidation, and the precipitation of iron-ferrocyanide complexes in the residual solution after ozonation. This last method proved quite promising since reduced the total cyanide levels of industrial solutions assaying as much as 250 ppm to less than 1 ppm of total cyanide. Control of the · pH of the solution was the key to obtain the precipitation of the iron complexes. The use of iron to precipitate cyanide complexes has the advantage of being less expensive and less toxic than copper (used by the Inco process)."

Jan 1, 1992

By Norman A. Jull

"IntroductionThe scope of this paper is intended to deal mainly with cyclones in grinding circuits. However, the section on Cyclone Equipment, contains more general descriptions, to cover most of the cyclones used in mineral separation plants.Cyclones as heavy media separation vessels are discussed by Mark Freberg (this volume). Their use in tailings deslirning is discussed by P.C. Lighthall, eta/. (this volume).Cyclone EquipmentCyclone TerminologyApexObviously, the apex of a cone is the smallest end. However, with cyclones the term is usually used for the fitting which is attached there to control discharge of the underflow stream.Note that the cyclone need not be so mounted that the apex is the lowest point, although that is the most common method. Keeping the apex below the rest of the cyclone helps avoid plugging when the underflow contains very large particles and the tonnage of underflow solids can fluctuate.Various devices for adjusting apex diameter or otherwise controlling the underflow are discussed later under ""Cyclone Construction"".BypassingThe transport of a portion of feed slurry directly to underflow so that classification is bypassed by that portion of feed.This action is fundamental in any hydraulic classification, whether gravity or centrifugal, because the large particles going to underflow have some void volume between them, which remains filled with feed slurry.D50By definition, D50 is that particle size which has an equal probability of going to overflow or to underflow.It is calculated by drawing a curve of recovery vs particle size and noting the size at which 500Jo recovery occurs.This may be done equally with corrected or with gross recovery (see below) and the resulting value should therefore be identified as d50c (corrected d50) or as d500 (gross d50).Note also that it is common in industry practice to plot size analysis data on the retained size rather than on the average of passing and retained (the middle of the size band). To portray sizing alone it makes no difference, but to read a D50 value off a curve of corrected or gross recoveries, it is essential to plot those values on the average size of each band."

Jan 1, 1989

By Turgut Yalcin

"High-grade concentrates are achieved in flotation columns primarily due to the use of thick froth layers and wash water, both of which facilitate the drainage of hydrophilic minerals from the froth. However, conventional columns employ tall, non-agitated recovery sections for bubble-particle attachment that require high headroom and special gas spargers as well as imposing particle size limitations. These disadvantages can be all alleviated by carrying out the recovery part of the process in a mechanical or pneumatic cell which generate froth more conveniently and efficiently.This paper describes the combining of mechanical and column flotation in a single unit and discusses the influence of various parameters on the performance of the system.INTRODUCTIONIn a flotation process, some of the minerals lifted up to the froth phase may drain back to the pulp due to various reasons such as weak attachment of particles to air bubbles, bursting of air bubbles, agitation of froth, etc. Weakly floating and entrained hydrophilic minerals drain at a faster rate than the strongly floating minerals, and effective exploitation of such differential drainage can lead to cleaner concentrates.For a given mineral, if the rate of flotation from pulp to froth is k1 (min·1) and the rate of drainage from froth to pulp is k2 (min""1), then the net (overall) flotation rate of the mineral, k (min-1 ), will be [Lynch et al., 1981 ]:"

Jan 1, 1997

By S. Mostaghel, S. Nicol, M. Y. Solar

Once upon a time, the process engineer developing the design criteria for a new saprolite ferronickel smelter had it easy: most ores were around 2.5% Ni, with a Fe/Ni ratio of 4 to 5 and a SiO2/MgO ratio of about 1.6; to use the French word: garnierites. The ferronickel grade selected was the conventional 20 to 25% Ni and the impurity levels could be predicted from well established [C], [Cr] and [Si] vs (FeO) graphs. However the process engineer can no longer depend on statistics to design smelters: Ni grades are decreasing while the goethite contents are increasing; SiO2/MgO ratios vary from 1 to 3; and Al2O3 concentrations are reaching levels that cannot be ignored. Mechanistic models must be developed to select or predict essential parameters such as kiln and furnace reductions, ferronickel grade, slag losses, metal and slag liquidus, operating temperatures, etc. But these models must be simplified so that they can be used on a routine basis; and they must be calibrated against a wide range of commercial operations in order to yield the most realistic predictions possible. The present paper proposes one possible approach, using FactSage as a basic source of thermodynamic data. The predictions thus obtained are compared to actual performance for two well documented operations, as well as to the predictions made with other tools that might be more accessible.

Jan 1, 2014

By K. Duckworth

"Comparative tests of the conventional Turam survey configuration and an alternative configuration called the Tx-parallel configuration were conducted at the McClean uranium deposit in northern Saskatchewan. Both configurations detected the known conductors at the site but the alternative configuration demonstrated its particular effectiveness in the reconnaissance role. This effectiveness results from the fact that the length of Tx-parallel traversesis controlled only by the length ofthe transmitter and not by its power. In addition, the field strength along a Tx-parallel traverse is uniform unless the traverse approaches the end of the transmitter. This freedom from a strong gradient of the primary field along a Tx-parallel traverse eliminates the gradient-induced anomaly shifts which are common in conventional Turam operations. The locations of each of the McClean conductors, that were obtained from the Tx-parallel profiles, werein better agreement with the locations known from drilling than were the locations obtained from the conventional profiles. However, the conventional profiles gave better estimates of the conductance of the targets.The results obtained over the McClean conductors indicate that current gathering has a strong influence on Tx-parallel results with consequent unpredictable influence on depth and conductance estimates. However, the depth estimates obtained from the Tx-parallel data appear to be in good agreement with the known depth of the McClean south conductor. The Txparallel results provide shallow estimates of the depth of the McClean north conductor which suggest that the fracture zone above the graphitic conductor is a significant conductor as was also suggested by earlier VLF surveys.Comparison with the wide range of published geophysical test surveys for the McClean site showed that apart from the work required to lay the transmitter, the Tx-parallel mode of operation of a Turam exploration system is operationally very similar to a moving source Slingram type of survey. At the McClean test site, it provided the same depth of exploration as a conventionally deployed fixed loop transmitter."

Jan 1, 1988

By V. Prostakova, M. Shevchenko

The copper smelting gas / slag / matte / metal / solids system with the Cu-Fe-Ca-Si-O-S major elements has been a long-term focus of the present overall research program using integrated experimental and modelling approach for the phase equilibria characterisation and development of a thermodynamic database. A systematic investigation of phase equilibria of slag systems in equilibrium with Cu metal is providing information for systems where copper coexists in slag with lead, zinc, and aluminium oxides as major components. Experimental studies involve high-temperature equilibration of synthetic samples; rapid quenching; and measurement of the compositions of equilibrium phases using electron probe X-ray microanalysis (EPMA). Particularly important feature of the present study a wide range of temperatures (660-1670°C) being characterised that reveals major inconsistencies in the existing thermodynamic description of the multicomponent system, and allows to establish the thermodynamic properties from phase equilibria in a reliable way. FactSage-based thermodynamic modelling is integrated with experimental research. Initial thermodynamic assessments are used to identify priorities for experiments, planned to provide specific data for thermodynamic optimisation. Significant improvement in the accuracy of the phase equilibria description is achieved, in particular in the PbO-Cu2O-SiO2, ZnO-Cu2O-SiO2, and Cu2O-CaO- Al2O3 systems in equilibrium with metallic Cu. INTRODUCTION Slags high in lead and copper are generated in primary metal production in the smelting of lead sulfide concentrates and in pyrometallurgical metal recycling systems. The compositions of these slags are varied due to increased fraction of recycled materials in the feed as well as introduction of previously unused chemical elements to modern technology. Therefore, their processing becomes chemically more complex; in that way they contain a large number of different metals. These slags form complex non-ideal solutions (with possible formation of several immiscible slags) that can coexist with stoichiometric solids, solid solutions, mattes and molten metal depending on the bulk composition and process conditions. Predicting the outcomes of smelting and refining processes is becoming increasingly difficult. To assist in the optimisation of these metallurgical processing operations, a comprehensive research program is underway to develop accurate thermodynamic databases for these non-ferrous process systems.

Jan 1, 2019

By P. Pyykkö, E. Peuraniemi, J. Järvi, P. V. Latostenmaa, V. Törölä, S. Junnikkala

"Nickel concentrate smelting started in Harjavalta in 1959. First, flash smelting - Peirce-Smith converting route was applied, and the high-grade converter matte was further refined to nickel cathodes. In 1995 the original smelter flow sheet was simplified with the novel DON (Direct Outokumpu Nickel) technology. In Harjavalta with the DON technology, high-grade nickel matte with low iron content is produced in flash smelting furnace directly without subsequent converting stage. The metal values in the smelting slag are recovered in an electric furnace as an iron containing bottom alloy. Main special features in Boliden Harjavalta nickel smelter are smelting of high-magnesia concentrates, the high recoveries of nickel and copper, as well as those of PGM`s and cobalt.Sulfur and dust emissions to air can be seen generally as one main disadvantage of nickel smelting operations. In Harjavalta continuous improvements in environmental performance has been rewarded by minimum sulfur and dust emissions to the environment and working atmosphere. Today Boliden Harjavalta’s nickel smelter is presenting state-of-art-technology at nickel smelting.This paper describes the nickel smelter process and includes recent production and emission data. It describes features required to achieve environmental and occupational hygiene goals and compares environmental performance data to that published on other smelting operations. General description of New Boliden Way is presented and a case example of production stability project is also presented."

Jan 1, 2014

By B. Dubé, R. Friedman, J. Oliver, R. Aubertin, M. Burson, G. Panneton, M. Hamilton, J. Ayer

"The Detour Lake gold deposit is located within the northwestern limit of the Archean Abitibi Subprovince of the Superior Province. Mineralized zones are hosted by a sequence of pillowed and massive flows, hyaloclastite units, and altered ultramafic rocks, and are commonly oriented parallel to a series of high-strain zones that are co-planar to the regional-scale Sunday Lake Deformation Zone. Early in its kinematic history, the Sunday Lake Deformation Zone placed older (2.72 Ga) volcanic rocks of the Detour Lake Formation over younger (2.70 Ga) sedimentary rocks of the Caopatina assemblage. Gold mineralization is also parallel to the position of a laterally persistent siliceous rock unit, the 2.725 Ga ‘Chert Marker Horizon.’ The Chert Marker Horizon coincides with the boundary between the mafic-dominated upper Detour Lake Formation and the ultramafic-dominated lower Detour Lake Formation. Stratigraphic and geochronological data suggest that the Chert Marker Horizon is a deformed felsic volcaniclastic unit. At a cut-off of 0.6 g/t Au, the Detour Lake deposit contains 17.26 million ounces of Au within 445.9 million tonnes of rock grading 1.20 g/t Au. Gold occurs in shear-hosted and extensional vein arrays within rocks of the upper and lower Detour Lake Formation and within the Chert Marker Horizon. The Detour Lake deposit has many of the characteristics of a greenstone-hosted, quartz-carbonate vein deposit; its very large size may be attributed to large-scale rheological controls resulting in the formation of dilatant sites in permissive rock units."

Jan 1, 2012

By H. Zhu, Y. Sato, O. Takeda, K. Nakano

Recycling of rare earth magnet wastes is essential to insure the stable supply of rare earth resources. For the development of a novel recycling process, the removal of rare earth oxide from an off-spec alloy magnet was investigated by melting the alloy magnet at 1503 K together with fluoride flux, LiF-50 mol% NdF3 and LiF-?25 mol% NdF3-25 mol% DyF3. After melting, the separation of magnet alloy from the fluoride flux was achieved, and neither suspension of alloy in the flux nor suspension of flux in the alloy was observed. Oxygen concentration in the alloy decreased from 5000 mass-ppm to 160 mass-ppm by utilizing 1.5 times of equivalent amount of flux needed to completely dissolve the oxide. The investigated process is suitable for mildly contaminated waste such as a used (end-of-life) magnet because of its simplicity, low energy consumption and small limitation on location for operation.

Jan 1, 2014

By D. H. Rubisov, V. G. Papangelakis

Sulphuric acid pressure leaching is the process of choice to recover nickel and cobalt from laterites with variable iron and magnesium contents. The latter influences the acidity levels required for effective leaching of nickel and cobalt, and during leaching, iron is rejected in-situ as hematite. Classical solid/liquid separation is performed via a CCD circuit, the performance of which depends upon the size and shape of precipitated particles. In this paper, precipitates obtained by acid-leaching of various lateritic feeds at 270°C are characterized using SEM/EDX and laser particle size analysis. It is shown that as acidity increases, the shape of the precipitates gradually changes from platelets to spheres, thus improving the S/L separation properties of the residue. The use of hydrogen ion concentration “at temperature,” calculated from a speciation analysis, allows the explanation of this change of morphology independently of the type of the ore feed. The possibility of precipitating magnesium sulphate “at temperature” is also discussed. In order to take advantage of this precipitation for scale reduction (as has been proposed in the past) without compromising the residue quality, [H+] “at temperature” must be controlled within an optimum range.

Jan 1, 2000

By Michael J. Lord, Richard H. O. Wagner

"The technologies used in the mineral processing of ores are being increasingly applied to the identification and remediation of metal contaminated industrial, military and landfill sites. The objective of mineral processing treatment of contaminated site material is to restore the value of the land and to concentrate the contaminants into a very small volume of separated material which, depending upon its nature, can be further processed, marketed, or sent to a landfill. A systematic characterisation of the site material is first undertaken. Bench and pilot testing follows to evaluate criteria for metal separation. The testing may examine one or more physical or physico-chemical reprocessing methods, singly or in combination, for the remediation of the test samples. These mineral processing tests determine the % metal removal fiom the soil and the contaminants concentrated from the medium. The usefulness of mineral processing testing for site remediation flowsheet design and execution is illustrated by the case studies presented. This paper will present the test results of three case studies: an industrial site decontamination, the cleanup of a small arms firing range, and the reclamation of property within a landfill.INTRODUCTIONEnvironmental legislation and our society’s quest for a cleaner environment has led to the application of mineral processing expertise and technology for industrial site decontamination, military site cleanup and landfill reclamation. Although the required level of decontamination varies between jurisdictions, a site becomes a candidate for decontamination once the contaminant concentrations are found to exceed the Canadian Council of Ministers of the Environment (CCME) Interim Remediation Criteria for soil (decommissioning guidelines) or applicable provincial guidelines. The objective of mineral processing treatment of contaminated site material is to restore the value of the land and to concentrate the contaminants into a very small volume of separated material which, depending upon its nature, can be further processed, marketed or disposed of in a landfill"

Jan 1, 1999

By M. Leroux, S. R. Rao, J. A. Finch

"Poor Pb-Zn selectivity during Pb flotation in laboratory tests on a Mississippi Valley-type Pb-Zn ore was traced to apH effect. In the pH range, 9.5 to 11.0 sphalerite floated readily without copper activation. Compared to sphalerite flotation with copper activation this procedure gave equivalent selectivity but reduced flotation rate.Possible mechanisms of this sphalerite flotation without copper activation are discussed. Activation by Fe(OH)2 is suggested, the Fe- + ions being derived from superficial oxidation of pyrite in the ore. IntroductionGalena and sphalerite commonly occur together. A typical procedure, using xanthate collectors, is to float the galena first, at pH - 8, followed by flotation of sphalerite after activation with copper (II) sulphate at pH - 10 (to depress pyrite).Flotation tests following this procedure in an undergraduate laboratory course with a Pb-Zn ore from Polaris failed to achieve consistent selective flotation of galena. Occasionally a considerable amount of sphalerite, even though unactivated with CUSO4, floated. This was traced to accidentally high pH. A systematic study was carried out which revealed that sphalerite floated readily in the pH range 9.5 to 11.0 without activation by CuSO4 This paper describes the results of the study and discusses a possible mechanism of this flotation of sphalerite."

Jan 1, 1987