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By D. G. Klaren, E. F. de Boer

Self-cleaning fluidized bed heat exchangers have demonstrated unparalleled performance internationally for the implementation of indirect heat transfer in severely fouling fluid environments. The ingenious configuration of recirculated cleaning particles through the tubes of vertical shell and tube heat exchangers provides the ability to solve any problems that arise as a consequence of tube-side fouling during indirect heat transfer to process fluids or slurries. In most cases, the cleaning particles consist of chopped metal wire, however other process-specific materials have been used. In addition to the mitigation of fouling effects, a number of other significant benefits for slurry heating are afforded by the mode of operation of the self-cleaning fluidized bed heat exchangers. Increased turbulence at the slurry/tube interface is imparted by the action of the fluidised particles, resulting in very high heat transfers at relatively low liquid velocities. Furthermore, given the thixotropic nature of most process slurries, the action of the fluidised particles imparts additional shear to the process slurry, resulting in shear thinning effects with a consequent reduction in pressure drop and enhancement of heat transfer across the heat exchanger. The benefits provided by the self-cleaning fluidized bed heat exchanger make it the ideal option for the indirect heating of laterite nickel slurry for High-Pressure-Acid-Leach (HPAL) plants. This article explains the principle and application of the self-cleaning fluidized bed heat exchanger technology for the processing of laterite nickel and cobalt slurries in HPAL plants. It also presents an elegant method to revamp existing direct heated laterite nickel and cobalt processing plants into an indirect heated configuration employing self-cleaning fluidized bed heat exchangers.

Jan 1, 2004

By Jack G. Hazan

The Critical Path Method is the modern scientific answer for solving the planning and scheduling problems inherent in today's complex projects. With this method, nothing is left to chance. All resources are controlled and kept to the minimum. The various phases are properly planned and strategically determined. Optimum conditions are evaluated for the most economical and fastest way to complete a definite project. The method must be fully understood and implemented with positive data and continuous feedback to obtain the best results. This paper covers the various aspects of the Critical Path Method and mentions some of its applications in the mining and metallurgical fields. T 0 progress to a higher state of human welfare necessarily involves sacrifices. The greatest sacrifice is to relinquish social freedom in favour of economic freedom. In the old days, for example, a cobbler was free to work at whatever time of the day he chose; today, he can't. He is now forced to adapt himself to environment and to work at stand-

Jan 1, 1965

By Hajime Miki, Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, A. M. Elmahdy, Keiko Sasaki

"Seawater has been reported to depress molybdenite in a copper-molybdenum (Cu-Mo) flotation process at high pH due to the precipitation of Mg(OH)2. Meanwhile, to improve mineral recoveries, collectors are usually added into the flotation cells, thus adding the complexity to the mechanism of bubble-particle interactions involved in Cu-Mo flotation. Therefore, understanding the interaction mechanism in seawater flotation and in the presence of collectors is important to explain the minerals depression. The present work investigated the effect of kerosene on the bubble collision and attachment to pure chalcopyrite and molybdenite surfaces in MgCl2 solution as one of the seawater major components at pH 6 and 11. Mineral surfaces were characterized using atomic force microscopy (AFM). In addition, minerals floatability in the same system were tested in a column flotation. The study of bubble-particle interactions shows that following several collisions, bubble could displace the intervening liquid layer on the mineral surfaces, forming a three-phase contact (TPC). A TPC formed more rapidly in the presence of emulsified kerosene in a 0.01 M MgCl2 solution at pH 6 for both minerals. The reason is kerosene increased the surfaces hydrophobicity and destabilized the intervening liquid layer on the surfaces. Moreover, the average time required to form a TPC was shorter on molybdenite surface. This can be attributed to the effect of adsorbed kerosene on molybdenite surface and molybdenite surface roughness.INTRODUCTIONIn froth flotation, bubbles are used to separate hydrophobic mineral particles from hydrophilic particles. In this process, bubble-particle interactions (i.e., collisions, attachment, and detachment) are crucial with regard to mineral recoveries. The effectiveness of froth flotation depends on the formation of stable aggregates between the hydrophobic particles and the bubbles, allowing the bubble to carry the particles to the froth layer. To form such aggregates, the bubbles and particles must collide, and the intervening liquid layer must be drained below the liquid layer critical thickness, forming a stable threephase contact (TPC) (Ralston & Dukhin, 1999). Particles detachment may take place if the particles still have sufficient kinetic energy and the TPC is not formed. Previous studies of bubble-particle interaction in electrolyte solutions have been conducted using atomic force microscopy (AFM) (Assemi, Nguyen, & Miller, 2008), and by approaching the bubble using mica plate (Pushkarova & Horn, 2008), however, these studies did not focus on the bubble-particle collisions. Bubble collisions and attachment to hydrophobic (Teflon) and hydrophilic (glass) surfaces in a a-terpineol solution have been investigated by Krasowka et al. (2003)."

Jan 1, 2016

By H. Salomon-de-Friedberg

The amount of pyrite in copper concentrates fed to the CESL Process can vary appreciably. The fraction of pyrite that oxidizes influences both capital and operating costs and is therefore an important variable. The present paper explores operating conditions that influence the extent of pyrite oxidation and the probable overall reaction chemistry under CESL conditions.

Jan 1, 2014

By F. Baczek, S. S. Rocks, D. Chaiko, T. Walters

The atmospheric leaching of chalcopyrite concentrates using acidic ferric sulfate lixiviants is well known to suffer from slow leach kinetics and poor copper recoveries. A number of approaches have been proposed for improving both leach kinetics and recoveries in this system. Many of these, while effective, suffer from high CAPEX and/or OPEX. As many mine sites begin transitioning from heap leaching of copper oxides to processing of primary copper sulfides, cost-efficient leach processes that are compatible with existing SX/EW processes will be needed to maintain existing cathode production. To this end, FLSmidth is exploring process options and reactor technology for the hydrometallurgical processing of primary sulfides. One approach that appears to be highly effective at increasing copper recoveries takes advantage of the enhanced reactivity of transitory, surface-defect structures generated during particle fracture. Significant process efficiencies are gained by matching the rate of grinding to the rate of electrochemical leaching in Mechano-Chemical leach processes. The patent-pending FLSmidth® ROL process uses a Stirred Media Reactor (SMRt reactor) to achieve copper recoveries of 97+% in 6 hours or less. This approach overcomes many of the surface passivation problems that have hindered other atmospheric leach processes. New insights to leach mechanisms are presented.

Jan 1, 2015

By H. Tsuruta, A. Fujibayashi, I. Sumi, A. Murao, R. Murai

Injection of biomass into blast furnace as alternative reducing agent is so effective for the purpose of mitigation of carbon dioxide emissions from steel industries, because biomass is considered to be carbon neutral raw materials. Certain amount of Palm Kernel Shell (PKS) is abandoned after Palm oil extraction process. To use as a reducing agent of blast furnace, PKS was carbonized and classified by 100 mesh sieve. To examine the gasification behavior of PKS carbide under the blast furnace conditions, several combustion experiments were conducted using hot model experimental furnace. The experimental results showed that the gasification efficiency of PKS carbide increased as the quantity of volatile matter increased. This tendency is the almost the same for the pulverized coal, so carbide of PKS can be used at blast furnace at appropriate amount of volatile matter that can be controlled by carbonization condition. In addition, the pressure drop of the furnace tends to decrease because the amount of ash in PKS carbide may be smaller than that of pulverized coal. PKS carbide is a suitable reducing agent in that respect.

Jan 1, 2015

By G. W. Norval, V. G. Papangelakis, G. A. Moldoveanu

Smelting has been the primary method of treatment for refractory copper sulfide concentrates such as enargite (Cu3AsS4), but the pyrometallurgical processing generates elevated levels of volatile arsenic. The present research investigates a novel hydrometallurgical process of oxidative dissolution of enargite at ambient conditions in the presence of chlorine dioxide (ClO2), a very powerful oxidant generated in solution by the reaction between a strong acid (HCl or H2SO4) and sodium chlorite (NaClO2). The effects of initial oxidant concentration, particle size, agitation speed and temperature on dissolution kinetics and copper extraction were investigated. It was found that a stoichiometric ratio of ClO2:Cu3AsS4 = 9:1 were needed to completely and congruently dissolve the mineral with fast kinetics (<15 minutes) under ambient temperature. The dissolution extent (metal extraction) increases with increasing ClO2 concentration and decreasing particle size of solids, but is not influenced by temperature or agitation speed.

Jan 1, 2014

By T. Orser

In 2010 Newmont made the decision to purchase a 42 foot (ft) Semi-Autogenous Grinding (SAG) mill from Metso and a 28 Mega-Watt (MW) Gearless Mill Drive (GMD) from ABB for the Conga Project in Peru. The test and study work showed that a single line 42 ft SAG mill circuit gave the most favorable project economics in comparison to an equivalently powered single line 40 ft SAG mill circuit. This paper does not address the process design or the project economics, but instead focuses on the key aspects of the SAG mill design, GMD design and the associated component manufacturing. This paper also addresses, where applicable, the potential reliability differences between the initially proposed 40 ft SAG mill and the finally accepted 42 ft SAG mill.

Jan 1, 2012

By R. S. Bigelow

Part 1.- Metal Mines Early experiments with mechanical loaders in metal mines were confined largely to machines of the shovelling type and generally air-operated. Although the first application of the scraper to metal mines dates back to 1910, it was not until about twelve years ago that it came to be used extensively. Generally, the scraper gives better results in metal mines than in coal mines, as degradation due to soft bottom and breakage are not factors, but it has a wide range of application and is successfully used in the mining of salt, potash, gypsum, zinc, copper, and a variety of ores, from soft material to hard chunky ore which settles compactly. Today, the scraper has replaced to a large extent the shovelling type of machine in metal mines. Scrapers have offered an inexpensive solution for the mucking problem and are now employed in most mining districts throughout the world. They are operated by labourers of all colours and degrees of skill. Each installation, however, requires individual study on the part of the mine mechanical department to determine the type of scraper, horsepower of hoist, and most economical speed of rope, as well as method of rope rigging. Unfortunately, the scraper has no power to select pay ore from waste and its suitability for use under circumstances which might require sorting of the ore can only be decided by a weighing of the economic factors involved

Jan 1, 1931

By B. Tonn, F. Kröger

"The continued development in engine technology is leading to an augmentation in power density which steadily elevates the requirements for thermally and thermo-mechanically highly loaded components such as cylinder heads and pistons. Due to these high performance requirements conventionally applied Al-Si alloys have reached their application limits, since their mechanical properties deteriorate quickly under the influence of heat. Improved applicability is given by Al-Cu-based casting alloys which have a superior high-temperature strength than Al-Si alloys. Since Al-Cu alloys exhibit insufficient casting characteristics, especially regarding hot tearing susceptibility and increased tendency for porosity, it is currently not possible to cast geometrically complex components in robust permanent mold casting processes. The further development of Al-Cu alloys is aimed at finding an optimum between improved castability while high-temperature strength and thermal conductivity are not deteriorated. It is known that a high amount of eutectic reduces the hot tearing susceptibility of an alloy, but it reduces thermal conductivity at the same time. In this paper it will be presented how the conflicting objectives – improved high-temperature strength, good thermal conductivity and reduced hot tearing susceptibility – can be brought together to develop an optimized Al-Cu alloy for application in permanent mold casting.INTRODUCTION At the beginning of the 21st century car, engine blocks were primarily made of gray cast iron (GJL). Less than half a decade later, the choice of material had shifted towards lightweight materials. Ever since, the car engine manufacturing is dominated by aluminum-based alloys. The weight of car engine blocks could thus be reduced by around 50% due to the lower specific weight of aluminum alloys compared to gray cast iron. Furthermore, the high thermal conductivity of aluminum alloys allowed a reduction of complex cooling channel systems and thereby promoted the advancement of this material group. The further development in engine technology leads to an augmentation in power density which elevates the requirements for thermally and thermo-mechanically highly loaded components. For example, in diesel-powered car engines the upper required limits can reach an ignition pressure as high as 230 bar and gas temperatures of up to 1000°C. Thereby, thermal loads can cause high alternating thermal stresses (Grzincic, 2003) which can effectively be reduced by providing high thermal conductivity."

Jan 1, 2017

By S. C. Ellis

THE bituminous sand of northern Alberta has already an extensive literature, and most of the reports dealing with the subject are still available (see Selected Bibliography at end of paper). A phenomenon so striking and, as regards its extent, so unique, as the deposit in the vicinity of McMurray settlement could not fail to attract the notice of the early explorers, and we find references to it as far back as the latter part of the eighteenth century. However, scarcely a thought had been bestowed upon the possible economic value of minerals in the the remote northern parts of Canada before the second decade of the present century, and practically no detailed mapping had been done north of the town of Athabaska. The late Wm. Ogilvie made a track survey of Athabaska river in 1884, and surveys of certain lines-including the 23rd base line-had been completed by 1911. Between this base line and lake Athabaska, nothing had been attempted. Actually, no definite information at all was available regarding the character and extent of the bituminous sand when, in the earl y summer of 1913, a reconnaissance party set out from Athabaska for McMurray. At that period, the journey was made in summer by scow or canoe. No telegraph line had been laid, and a casual mail service by canoe or dog team once in three months formed the only means of communication with the outside world. The investigation has begun by the Mines Branch was continued during several subsequent years. The sand deposits were studied and sampled, the bi rumen was extracted from the sand and studied chemically and physically, and the economic significance of the deposit was given exhaustive study.

Jan 1, 1937

By A. V. Corlett

THE use of the diamond-drill hole as a means of breaking clown ore and waste is not new. Years ago, the method was adopted in mines in northern Ontario and in the western United States to reach out to bad pillars, or to remnants of ore left on walls, the winning of which by any other method might be dangerous or too expensive. The practice is still in vogue and has generally proved a success. Of the known mineral deposits in Canada and elsewhere, many are of very low grade. Some are marginal and not even worthy of being classed as &apos;ore&apos; until some means is found and proved of exploiting them economically. Other conditions being favourable, if a mining method could be found that would give a large &apos;bulk break&apos; with a sufficiently low cost of development and a low cast of mining per ton, mineral deposits of this latter type might be brought into the classification of ore. We know that any block-craving system whereby the ore may be undercut and allowed to crush and cave will give a very high breakage and low costs. In some cases, however, the physical characteristics of the ore do not lend themselves to this method. In such ore-bodies, the alternative system of &apos;bulk-breaking&apos; might be aided by long diamond-drill blast holes. We could obtain this &apos;bulk breaking&apos; by the use of long diamond-drill holes in conjunction with a sub-level system using extremely thick benches, or possibly by the adaption of modified open-pit methods to underground mining. ln fact, if conditions are favourable, the idea would be simply ta open up a slot or free face and break into it on a larger scale with longer holes. The use of deeper benches-that is, using each level as a sub-level and thereby eliminating much development footage, slashing, setting up, and mucking time-would naturally be expected to lead to cheaper mining.

Jan 1, 1940

By D. C. Treilhard

After a brief history of the mining and smelting operations of Kilembe Mines Limited, this paper outlines the smelter layout and describes . the. daily operations at the Jinja plant. Particular attention 1s paid to the details of the furnace and converter operation. A subsequent section of the paper deals with the significant developments in plant metallurgical practice, covering both smelting and converting.

Jan 1, 1966

By P. S. Arthur, G. R. F. Alvear

Development of a new smelting process is risky. Many novel processes in the metals industry failed to fulfil the initial expectations of their inventors. Large sums of capital have been invested in technologies that either didn&apos;t provide a satisfactory return on investment, or didn&apos;t perform at all, and had to be replaced. One of the keys to success in process development is incremental scale up of the technology, with potential problems being identified and rectified as early as possible. In this way the cost of any rectification that is required can be minimized. The ISASMELTTM process was developed to maturity by Mount Isa Mines through the 1980&apos;s and 1990&apos;s using incremental scale up. Commercialization only occurred once the process had been proven on laboratory, pilot and demonstration scale over many years. As a result ISASMELTTM technology now operates successfully at numerous plants around the world. The methodical approach to development of the technology has allowed owners to modernise their existing operations or create new businesses with significantly reduced technical risk.

Jan 1, 2011

By R. Elliott, C. A. Pickles, J. Peacey

As the nickel sulfide ore deposits become decreasingly viable as a source of nickel metal, increasing attention is being paid to the exploitation of the nickeliferous laterite ores. Attempts to produce a high grade ferronickel concentrate from these ores by pyrometallurgical methods face several challenges, in particular the selective recovery of the highly disseminated nickel from the reduced ore. The current work explores strategies for maximizing the size of ferronickel particles formed in order to improve the selective recovery of the ferronickel by magnetic separation. The effect of various coal, elemental sulphur, pyrite and sodium sulphate additions on ferronickel particle formation and size at 1000°C have been investigated. It has been observed that increased coal additions leads to a moderate improvement in the size of the ferronickel particles, while the presence of any sulphur bearing reagent leads to a significant increase in particle size. The retention of sulphur in the reduced material has also been studied, showing sodium sulphate has the highest retention, followed by pyrite and then elemental sulphur. An inverse trend was observed in the efficiency of sulphur retention on the basis of residual mass of sulphur per unit mass of reagent added.

Jan 1, 2015

By J. G. Debanne

MOST company-employed petroleum engineers have in their accounting departments punch-card computers that can perform engineering calculations thirty to three hundred times faster than desk calculators, or they can rent such machines from Computing Service centres. These machines not only eliminate the drudgery of desk calculation but also the risks of human errors. The I.B.M. t 604 punch-card computer of Texaco&apos;s accounting department in Calgary has been used for oil and gas property evaluations, curve fitting by least squares, statistical core analysis studies, unsteady-state water in-flux studies, phase equilibrium performance prediction of oil reservoirs, gravity segregation calculations, etc.

Jan 1, 1958

By Lars A. Bergstrom

High-voltage direct -current transmission is a relatively new technology. The successful development and operation of AC/DC converters, capable of handling large power blocks, have made HVDC transmission generally accepted by utility engineer s and planners around the world. HVDC technology still has significant development potential and, as a result, it is expected that equipment costs will escalate at a substantially slower rate than those of conventional AC equipment. This development will also result in still more compact terminal stations. This paper reviews two modern HVDC installations. In Zaire in Africa. a 1700-km overhead DC line rated at 500 kv, will supply power to the copper mining district in the Shaba region. Another HVDC link connects Norway and Denmark through a submarine cable rated at 250 kv. This is the longest HVDC cable in the world, 127 km, and the water depth , maximum 530 m, is also much greater than for any previous similar cable. The reasons for selecting HVDC are discussed, and the design and layouts are presented.

Jan 1, 1978

By D. G. Eskin

"It is well known that it takes some time for the solid phase to completely dissolve upon melting, especially inside the defects of insoluble particles, e.g. oxides. Until then the oxides remain active solidification substrates in the case of subsequent solidification. It is also known that ultrasonic melt treatment causes grain refinement through activation and dispersion of solidification substrates (one of the mechanisms) and also accelerates the dissolution of solid metal in the melt. In this study we combine these effects and demonstrate that the introduction of an alloy rod into the matrix melt of the same composition results in significant grain refinement, this effect being increased by the ultrasonic vibration of the rod. The achieved grain size is comparable to that obtained by a standard Al–Ti–B grain refiner. All samples were cast using a standard TP-1 mould to enable correct comparison. The effect of the temperature range of the rod introduction, as well as the effect of ultrasonic vibrations are discussed.INTRODUCTION The fact that by introducing solid metal into the melt one can achieve structure refinement is rather well known. As early as in the 1930s–1950s a series of papers and patents have been published, showing the benefits for grain refinement when dissolving solid metal in the melt before solidification (Danilov and Neimark, 1938; Scheil, 1956). Later on this way of structure refinement was developed further and dubbed “suspension casting” or introduction of “internal chills” (Madyanov, 1969; Zatulovsky, 1981). The solid metal was added in a form of cut wire, cut sheet, or powder, with the resulting grain refining, elimination of columnar grain structure in ingots and castings of steel, copper and aluminium alloys. The underlying mechanisms have been suggested as (1) rapid cooling of the melt due to the latent heat consumption upon melting of the solid metal with the resultant melt undercooling and (2) introduction of many solidification substrates in the form of crystal fragments and active non-metallic inclusions (Danilov & Neimark, 1938; Balandin, 1973). A number of patents have been filed where either the same solid alloy or a master alloy with additions (e.g. Ti for Al alloy) is introduced in the amounts up to 50% (typically less than 10%) into the melt close to the liquidus temperature (Schmidt, 1966; Talbot & Soller, 1973, Krupp, 1974; Bondarev, 1979). The main reason that this technique is not widely used in industry is the possible incomplete dissolution of the solid parts introduced into the melt with ensuing inhomogeneous as-cast structure and potential defects. Also the selection of the temperature range where the technology works the best is not clear."

Jan 1, 2018

By R. J. Traill

Introduction Following the discovery of high-grade deposits of pitchblende in the Great Bear Lake area of the Northwest Territories by Mr. Gilbert LaBine in May, 1930, samples were submitted to the Mines Branch for examination and investigation as to suitable methods of treatment (1). The purpose of this paper is to present, briefly, the results of the investigative work conducted on the ores and an outline of the methods developed for the extraction of the radium content and recovery of the by-products. The paper is presented in two parts. Part I gives a review of the history of radium production and of the principal processes used in other countries. Part II describes the work and gives the results of the Mines Branch investigation. Part 1-Radium Production In Other Countries Historical Outline Uranium was discovered in 1789, and more than a century later Madame Curie, while studying the physical properties of this element, observed that the ore of uranium exhibited greater activity than the pure uranium com-pounds she had prepared and traced the cause to the presence of a new element which she named radium. Eventually, research proved radium to be a disintegration product of uranium, and always present in uranium ores.

Jan 1, 1933

By M. Barati

A collaborative research between University of Toronto and Hatch was conducted to understand and optimize the process conditions pertaining to a novel steelmaking technology. In this technology, known as CRISP, direct reduced iron is continuously melted and refined in a stationary electric arc furnace. The major challenge against continuous operation of the electric furnace was identified to be minimizing the corrosion of the refractory in order to achieve uninterrupted operation for a minimum of one year. Theoretical analysis and bench scale experiments together with two pilot runs resulted in defining an operating window for slag chemistry that would minimize chemical attack to the refractory while satisfying the oxidizing conditions required for sufficient decarburization. An analysis of the process in terms of energy consumption and emission of greenhouse gases revealed that it is superior to the current batch DRI-based steelmaking technologies.

Jan 1, 2011