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By F. Doxey

Introduction Numerous papers have been written dealing with the construction and functions of, and the environmental conditions created by, Diesel locomotives. Therefore, it is not my intention to attempt to deal with these phases of Diesel transportation other than to make reference to them in ?relation to and in connection with actual operation. The rapid expansion of industry during recent years and the necessity of products being made available at competitive prices in home and world markets has made the demand for cheaper coal a very serious factor for the coal industry. This condition has meant each coal producing country looking into ways and means whereby greater productivity and reduction in cost could he achieved. Surveys made show that, in addition to face mechanization, savings, in some cases substantial, can be made in transportation. Ventilation The most efficient mines are in-variably the well ventilated ones, for it is true that, where there is good ventilation, there are usually good roads. These combined factors are very essential where Diesel locomotives are used. Good roadways and track allow speed, and good ventilation dilutes rapidly any disagreeable exhaust gases. Locomotive Development In the older types of auxiliary rope haulage, coal hauled per haul-age hand is usually very low.

Jan 1, 1951

By Michael J. Rosko

Methods have been developed for processing and analyzing reflected solar radiation data obtained by Landsat 5 Thematic Mapper multispectral scanner. Spatial resolution for the Landsat series satellites is 30 meters per side per pixel. Materials on the Earth?s surface absorb or reflect different parts of the electromagnetic spectrum depending on their physical and chemical properties and, therefore, typically have characteristic spectral ?signatures?. Using these signatures, environmental parameters such as surface water and vegetation may be identified and analyzed. Principal advantages of the satellite image method for environmental monitoring include: a relatively long historic period beginning in 1985 for which information is available, the reliable numerical basis for the results, and the ability to assemble a historic environmental baseline and provide on-going monitoring for large or remote areas where standard monitoring methods may not be practical. However, because the long-term continued operation of Landsat 5 is problematic due to the age of the equipment, QuickBird and IKONOS satellite images were processed to determine if the two systems are sufficiently similar in their results to allow continuing monitoring using QuickBird data. The QuickBird satellite was launched in 2001 and collects the same visible and near infrared spectral bandwidths as Landsat 5, allowing for equivalent process algorithms for QuickBird, IKONOS, and Landsat 5 data. Spatial resolution for the QuickBird images is 2.4 meter per side, allowing for more detailed characterization of the land surface; spatial resolution for the IKONOS images is 4 meter per side. Because of several differences between the satellite systems, including degradation of the Landsat 5 sensor, it is necessary to calibrate QuickBird and IKONOS results to the Landsat results to verify similarity. Recent images from the satellite systems have been processed and results have been compared to determine the validity of comparing Landsat 5 and QuickBird/IKONOS images so that these newer data can be used reliably in the future instead of Landsat 5 data. Results from this comparison are presented in this paper and suggest that analyses for vegetation using the two satellite systems are comparable, and that little calibration is required. Results from comparison of surface water results from the two systems are less comparable and is currently being investigated by the authors.

Oct 1, 2009

By K. S. Raja, B. Pesic, S. Kshetri

"We investigated the electrochemical corrosion behavior of commercial permanent magnetic material (NdFeB alloy) in 0.1 M NaH2PO4 solution (pH:4.75) containing 0 – 1000 ppm of chloride at room temperature (298 K). The material was evaluated in magnetized and demagnetized condition with different surface preparations such as: Ni-Cu-Ni coated, uncoated (bare), and anodized (in fluoride containing ethylene glycol at 60 V for 15 minutes to form a thick nanoporous oxide surface). The nickel coated magnetic sample showed reasonable pitting corrosion resistance up to 100 ppm chloride addition. The uncoated samples showed passivity in chloride free phosphate solution. Chloride additions caused pitting and the pitting protection potential was equal to the corrosion potential with 100 ppm chloride addition. Demagnetization did not alter the electrochemical polarization. However, the passive film formed on the magnetic sample showed higher charge carrier density than the film formed on the demagnetized sample. INTRODUCTIONSintered NdFeB permanent magnets exhibit excellent magnetic properties such as large energy product [(BH)max > 450 kJ/m3], high saturation magnetization (1.6 Tesla), and high coercivity (1.2 – 2.08 x 106 A/m) (Sugimoto, 2011). However, the NdFeB magnets are prone to corrosion attack because of the presence of Nd-rich intermetallic phases, such as Nd4Fe (Jurczyk & Jakubowicz, 2000). Nd-rich and B-rich intermetallic phases are distributed in a matrix of Nd2Fe14B tetragonal ferromagnetic compound in a permanent magnet. Generally, several types of Nd-rich phases are present in the magnet with Fe:Nd ratios ranging from 1:1.2 to 1:7. The volume fractions of Nd-rich and B-rich (Nd1+xFe4B4 type) phases are about 10% and 7% respectively (Li, Ma, Li, & Wang, 2011) . Among these intermetallic phases, Nd-rich phase has the most active electrochemical potential. Therefore, dissolution of this phase occurs in preference to other phases by galvanic corrosion when exposed to moisture. Since Nd-rich phases are present at the grain boundaries of the Nd2Fe14B matrix, corrosion leads to disintegration of the magnet."

Jan 1, 2012

By K. Soldenhoff, M. Fainerman-Melnikova

The use of strong base resins for uranium recovery is severely affected by the presence of chloride ions in solution. In areas where high-quality process water is not readily available, the use of saline water would extend the potential application for ion exchange in uranium processing. This study presents measurements of uranium uptake, using a wide range of commercially available weak base anionic exchangers, from solutions with chloride concentrations ranging from 2.5 to 22 g/L Cl. Out of 14 weak base anionic resins tested, 3 were identified that were not severely impacted by the presence of chloride and significantly outperformed a gel strong base resin typically used for uranium recovery in high-chloride environments. The uranium loading was sufficiently high for the consideration of development of the application of uranium recovery from uranium ores leached with seawater.

Jan 1, 2012

By M. Reda

Because of the adverse environmental effect of Chromate, Molybdate ions had been investigated as replacement for Chromate and the results had shown not to be encouraging. Film deposited from peroxopolymolybdate (from reaction of Molybdenum meta, with excess Hydrogen Peroxide), are more robust than that deposited from molybdate solutions. This was shown to be due to higher fraction of Mo (IV) and Mo (V) that form from Mo (VI) in the peroxopolymolybdate deposited film than the film deposited from Molybdate solutions. The peroxopolymolybdate film contains 40% un-hydrated molybdic acid, tetraperoxodimolybdate and tetra peroxo tetra molybdate. The protective properties of peroxopolymolybdate were shown to be due to the effectiveness of the un-hydrated molybdic acid.

Jan 1, 2010

By G. T. Lapidus, R. Zárate-Gutiérrez

Selective leaching of lead from a Pb-Ag-Zn concentrate with hydrogen peroxide in citrate solutions was studied at room temperature. Leaching tests were performed, varying the H2O2 concentration and the solid-liquid ratio, holding the solution pH constant at 7, and the citrate concentration at 1 M. Lead extractions of 100 % were achieved with 4 and 5 times the stoichiometric quantity needed to form elemental sulfur, with only a small amount of metal impurities dissolved (Ag, Zn and Fe). The lead solubility limit at those conditions was found to be ~21 g L-1. X-ray diffraction analyses of the leach residues were free of galena (PbS), while other metal sulfides, such as sphalerite (ZnS), chalcopyrite (CuFeS2) and pyrite (FeS2), were basically unaffected.

Jan 1, 2014

By G. O. Prickett, P. Somasundaran

An application of the statistical and computer techniques in basic mineral processing research is illustrated by means of a case history involving the study of starch adsorption on calcite. Multi-factorial experimental designs and computer techniques were used for determining the effect of different system variables, such as solution pH, sodium oleate concentration and starch concentration, and to obtain a mathematical model of the response. Response maps enabled the investigators to see the effects clearly and to predict the results of changes in factor levels within the design region. Use of time-shared computers and plotters made data processing and analysis efficient and relatively inexpensive.

Jan 1, 1973

By O. Rabeau, M. Legault, F. Fallara

"Abstract - The development of robust 3-D geological models involves the integration of large amounts of public geological data, as well as additional accessible proprietary lithological, structural, geochemical, geophysical, and diamond drill hole data. 3-D models and maps have been available, particularly in the petroleum industry, for more than 10 years. Here, we demonstrate how robust 3-D maps can be used as interactive tools for mineral deposits exploration. In particular, we show how the interrogation of 3-D data sets can constrain exploration targets at depth. The main advantages of this technique for the mining industry are the homogeneity of data treatment and the validation of geological interpretations, taking into account geophysical and geochemical data. Data integration and cross-correlation of geology and geophysics can be achieved in two dimensions in any good GIS package. However, the added strength of 3-D analysis is the integration of separate data sets in three dimensions to build more complete, more realistic models, and in delineating areas of high economic potential at depth. Furthermore, these models can be modified and improved at any time by adding new data from ongoing drilling and geoscientific surveys. This paper presents two examples of 3-D models used for mineral exploration: the Joutel VMS mining camp and the Duparquet gold camp, Quebec. In both examples, the creation of the model is discussed and queries specific to the relevant exploration model are introduced. Eight potential exploration targets are generated at Joutel and seven at Duparquet. Although the targets defined are dependent on the details of the chosen queries, it is apparent that this technique has the potential to generate promising exploration activity that can engender new targets. Sommaire - Le développement de modèles 3-D géo-intégrés fiables implique l’intégration de grandes quantités de données géologiques publiques ainsi que des données lithologiques, structurales, géochimiques, géophysiques et de forages en provenance du secteur privé. L’industrie pétrolière dispose de modèles et de cartes 3-D depuis plus de 10 ans. Ce manuscrit présente un exemple d’utilisation de modèles et de cartes tridimensionnels détaillés comme outils interactifs dans l’exploration de dépôts métallifères. L’emphase est mise sur le processus d’interrogation des données en 3-D pour la définition de cibles d’exploration en profondeur. Les avantages principaux de cette technique sont l’uniformité du traitement des données et de la validation des interprétations géologiques, tout en tenant compte des données géophysiques et géochimiques. L’intégration de données et la corrélation de la géologie et de la géophysique peuvent être accomplies en deux dimensions dans n’importe quel logiciel SIG. La plus grande force de l’analyse 3-D demeure cependant la possibilité de construire des modèles complets et réalistes permettant de cibler des secteurs à haut potentiel économique en profondeur. De plus, ces modèles peuvent être modifiés et améliorés de manière interactive en ajoutant de nouvelles données provenant de forages et de levés géoscientifiques en cours. Ce manuscrit présente deux exemples de modèle 3-D géo-intégrés développés pour l’exploration minérale : le camp de SMV de Joutel et le camp aurifère de Duparquet, Québec. Dans les deux cas, la construction du modèle est décrite et les requêtes spécifiques à chaque type de gisement sont présentées. L’exercice a permis de définir huit cibles d’exploration potentielles à Joutel et sept à Duparquet. Bien que les cibles identifiées dépendent des contraintes utilisées pour les requêtes choisies, cette technique permet de générer de nouvelles cibles qui pourraient relancer l’activité d’exploration dans les camps miniers " matures " ou dans des secteurs moins explorés."

Jan 1, 2006

By Roger M. Jones

This paper comments on developments in bulk shipping which will be of direct interest to those who are considering the shipment of dry bulk minerals out of Nova Scotia by water. Various conveying systems, and the slurry system of loading, are considered, and the role of deep water ports as a catalyst to other industries is stressed.

Jan 1, 1971

By V Dolmage

Copper Mountain is the third largest copper mine in British Columbia, and is now producing close to 20 million pounds of copper per year, with which is recovered also 4,000 ounces of gold and. 13,800 ounces of silver. After a long and checkered career, during which the ownership and management changed several times, this deposit finally came into the possession of the Granby Consolidated Mining, Smelting and Power Company in 1923. It was not, however, until the end of 1925 that the mine, under the management of Charles Bocking and C. H. Smith, was successfully placed on a basis of profitable production. It is a low-grade deposit of the contact-metamorphic type, with refractory ores consisting of chalcopyrite and bornite in a gangue of altered andesitic and basaltic breccia. The ore is concentrated to a product carrying over 30 percent copper, which is smelted in Tacoma. The deposit is 12 miles south of the town of Princeton, which is on the Kettle Valley railway, 150 miles east of Vancouver and 40 miles north of the International Boundary line. Princeton is served also by a branch of the Great Northern railway, which leads clown the Similkameen, Okanagan, and Columbia valleys. Copper Mountain mine and camp are connected to Princeton by a good mo tor road extending up Wolf Creek valley, while the haulage level of the mine, which emerges on the steep side of the Similkameen valley 1,000 feet below the camp, is connected with Princeton by a spur of the Kettle Valley railway leading up the Similkameen canyon and passing en route through Allenby, where the concentrator is situated.

Jan 1, 1929

By M. Jackson, R. McDonald, T. Osken, D. Robinson

"The addition of sulphidic materials in the leaching of nickel laterites has several potential benefits that include improvements in the rheological behaviour of the blends, reductions in the sulphuric acid and steam requirements, sweetening of the nickel grade of the combined feed material, and the option of using a range of sulphidic materials. The current study examines the oxidative processing of 30% w/w blends of nickel concentrate and nickel laterite ore at 250oC. In particular, the viability of using low oxygen overpressures was examined for significant amounts of nickel flotation concentrate, up to 12% w/w. Further to this the impact of process water quality, in particular the presence of chloride, upon the kinetics of extraction and the mineralogy of the residue were also investigated. This paper will present the results of preliminary work in this area.INTRODUCTIONThe use of sulphidic ore as a source of sulphuric acid during oxidative hydrometallurgical processing is not a novel idea and can be traced back over forty years (Seidel & Fitzhugh, 1968). A series of patents pertaining to application of this approach for laterite ores can be subsequently found (O’Neill, 1973; Opratko et al., 1974; Rodriguez, 2008a, 2008b; O’Callaghan, 2010; Liu et al., 2011) and a few of articles containing published data (Ferron & Fleming, 2004; Quinn et al., 2009). The use of pyrrhotite tailings as a source of sulphuric acid has also been employed for the leaching of converter slags (Perederiy et al., 2011).It is known that hydrometallurgical operations such as the HPAL plant at Murrin Murrin have added small amounts of sulphides as either transitional (mixed sulphide/oxide) ore or non-smeltable concentrate. This can improve the rheology (Rodriguez, 2009) and provide heat credits. However these plants are generally limited in their ability to add such materials due to their reducing nature and given under highly acidic conditions that the breakdown potential of the titanium used for the autoclave lining is significantly reduced. A suitable oxidant must therefore be present to ensure the potential remains sufficiently high."

Jan 1, 2012

By R. C. Carne, R. J. Cathro

"Most of the recent large discoveries of zinc, lead and silver in Western Canada are Paleozoic-aged stratiform deposits that occur within the limits of the tectonic sub-province of the Canadian Cordillera known as Selwyn Basin. Bounded on either side by coeval carbonate platforms. Selwyn Basin trends northwest for 1300 km from northeast British Columbia to Alaska. Paleozoic rocks of Selwyn Basin consist primarily of chert, shale and coarser-grained clastic sedimentary rocks with minor volcanic rocks.The Selwyn Basin deposits have few counterparts elsewhere in Canada, but have a close similarity in geological setting, mineralogy and morphology to well-known deposits such as McArthur (HYC) in Australia, Meggen and Rammelsberg in West Germany, and Sullivan in British Columbia. Recent studies of these deposits have led to an emerging, but now generally accepted, model of ore deposition in which stratabound zinc-lead-silver shale-hosted or ""sedimentary-exhalative"" (sedex) deposits are precipitated in active tectonic environments from metalliferous geothermal brines that rise to the sea floor along deep-seated fault zones. Although their mineralogy and ore metal zoning can be similar to that of volcanogenic massive sulphide deposits, most sedex deposits have only a weak genetic link with volcanism.Sedex mineralization in Selwyn Basin has been identified within three separate ages of shale or its metamorphosed equivalent. The lower Cambrian-age Anvil Camp in central Yukon Territory contains the only producing mine (Faro). Important lower Silurian-age zinc-lead mineralization is at Howards Pass along the Yukon - Northwest Territories border. Barite and zinc-lead-barite mineralization of upper Devonian age occurs across Selwyn Basin. Potentially economic deposits have been found at Macmillan Pass, along the Yukon - Northwest Territories border and in the Gataga District of northeastern British Columbia."

Jan 1, 1982

By M. P. Tixier

Abstract In a review of the application of electrical logging in Canada, examples are .given of long and short distance correlations by means of the electrical logs. The use of MicroLogging for the determination of permeable and porous formations is explained. The question of log analysis for the quantitative determination of fluid saturation and porosity is .discussed. An example is provided to illustrate the significance of the resistivity gradient. The advantages of the new method of the Laterolog are shown, chiefly for the case of wells filled with high-salinity mud. Introduction Electrical logging techniques developed rapidly in Canada at the time an intensive drilling activity started for the exploitation of the Devonian series in Alberta, namely, at the beginning of 1947. The conventional service was soon thereafter supplemented with the latest technica1 improvements. Canada has been among the first regions to take advantage of MicroLogging*, which has proved a most powerful .tool for the investigation of permeable and porous formations; also, the more recent development known as the Laterolog has ?been introduced in Canada. The Laterolog provides a better determination of .the formations, particularly in the case of salty mud where the conventional logging is greatly handicapped. The various methods of electrical logging are now commonly known in oil industry and have been described in numerous publications ( 1) ( 2) (3).

Jan 1, 1951

By L. Drisdelle, S. Gendron

"Survival in today's business climate requires participation of all employees in a Total Quality Management Program encompassing everything - ""safety, quality of products, quality ofet1ch and every job done, and of course production "". We all know what needs to be accomplished, but struggle with how to do it, especially in an industry which has not always experienced management/union cooperation, and mistrust is still present.This paper describes a process to improve team work and employee involvement in Inco's nickel carbonyl refinery at Copper Cliff The process involves facilitatorship training for all employees, and a system for reinforcing and accomplishing the required behavioural change. The system is described in detail and a number of examples are presented. At the refinery, the staff is starting to understand as Max DePree recently wrote ""Without Quality Behaviour, you cannot have Quality Product"". IntroductionThe Copper Cliff Nickel Refinery (CCNR) is Inco's largest and most modern nickel refinery, which celebrated its twentieth year of successful operation in April 1993.The heart of the refinery is the Inco pressure carbonyl (IPq plant which produces high purity nickel pellets and specialty powders by refining an approximate 80% nickel granule feed. The carbonyl plant is a modem chemical plant with very special and demanding requirements for safety and environmental protection due to the toxic nature of the refining gas.Since 1987, there has been an emphasis at CCNR on a comprehensive Total Quality Improvement (TQI) Program which was designed based on recognizing customers' needs for improved systems for quality management. This program is customer oriented and comprises such elements as team organizational concepts, customer audits, process assessment and internal quality auditing.A detailed review of progress was made in early 1991 and it became apparent that the ""ownership"" of the TQI program was not broad based. In fact, the program was very much a staff driven effort and fell far short of total employee involvement and relentless continuous improvement that are now considered essential to remain competitive and stay in business.Inco staff has now come to regard that early phase of our TQI program as ""the technical aspects of total quality improvement"".The safety experience was also puzzling. Even though the safety statistics were good with an average lost time frequency of 1.6 for the last five years, the perfonnance improvement had plateaued and remained pretty much the same. Clearly a new approach was required if significant progress and continuous improvement was to be made."

Jan 1, 1994

By N. W. Hendry

ABSTRACT Exploration by geophysical methods and diamond drilling of an occurrence of chrysotile asbestos, located ten miles east of Matheson, Ontario, was commenced on March 25th, 1949, by the Canadian Johns-Manville Company, Limited. The asbestos is associated with a narrow sill-like body of basic and ultrabasic rocks which strikes northwesterly across portions of Munro and Beatty townships. To date, asbestos zones of commercial interest, many hundreds of feet in length, width, and depth, have been outlined by diamond drilling along a 2-mile length of serpentine. The fractures occupied by the asbestos veins are closely associated with the regional faulting in the area. The mining of the first occurrence, or A orebody, will be by open-pit methods. Milling will commence at a rate of 50 tons an hour. INTRODUCTION OCCURRENCES of chrysotile asbestos in Munro township have been known at least since 1914 and references to them appear in reports published by the Ontario Department of Mines in 1915 (1) and 1919 (2). J. G. Ross (3) in his excellent publication on Chrysotile Asbestos in Canada, mentions an occurrence in Munro township. The area was first mapped in detail by J. Satterly, of the Ontario Department of Mines, in 1944, and brief mention is made of chrysotile asbestos in Satterly's preliminary report (4), which was published the following year.

Jan 1, 1951

By J. M. Newell, G. R. Peatfield

"The Red-Chris porphyry Cu-Au deposit is located between Ealue and Kluea lakes, southeast of the village of Iskut on the Stewart Cassiar highway in northwestern British Columbia. It was explored by Texasgulf Inc., in a joint venture with Great Plains Development Company of Canada, Ltd. and Silver Standard Mines Ltd., during the period 1973 to 1980. Exploration resumed in 1994, following acquisition of the interests originally held by Texasgulf and Great Plains Development by American Bullion Minerals Ltd.Prospectors were first drawn to the area by prominent limonitic stain zones exposed in creek gullies in the western part of the property. These zones are developed on the alteration halo at the western periphery of the deposit. The potential ore zones do not crop out and were first exposed in a bulldozer trench excavated in 1971. Subsequent exploration was by percussion and diamond drilling, guided to some extent by induced polarization surveys. In 1976, estimated resources contained within two crudely designed open pits were 41 million tonnes with an average grade of 0.56% Cu and 0.34 g/t Au, with a cutoff grade of0.25% Cu. New resource estimates based on a major drilling program completed by American Bullion in 1994 were released as this paper goes to press. These estimates were calculated using various copper cutoff grades; at the 0.4% Cu cutoff, the ""in-situ geological reserve"" is given as 100 million tonnes grading 0.58% Cu and 0.46 g! t Au (American Bullion Minerals Ltd., 1995).The deposit consists mainly of pyrite, chalcopyrite and increasing bornite at depth, in zones of quartz-vein stockwork hosted by an elongate body of altered monzonite porphyry of latest Triassic or earliest Jurassic age. The stock intruded volcanic and sedimentary rocks of probable Stuhini Group affinity and is in faulted contact with sedimentary rocks of the Jurassic Bowser Lake Group. Gypsum stockworks are developed in the higher levels of the subvolcanic porphyry system. Late-stage quartz-carbonate veins carry small amounts of galena and sphalerite. Complex faulting within the deposit makes drill-hole correlations difficult. Alteration assemblages include an early potassic phase, almost completely destroyed by later phyllic alteration, and surrounded by a propylitic assemblage dominated by ankeritic carbonates in altered sedimentary rocks.The deposit has characteristics of bath the alkalic and calc-alkalic classes of porphyry copper deposits. The development of quartzvein stockwork suggests a calc-alkalic affinity, but the hostrocks contain little or no free quartz, molybdenum is present in trace amounts only and gold values are significant. Copper grades vary between wide extremes with unusually high grades in some sections of the deposit. The weight of evidence available in the 1970s led us to place the Red-Chris deposit firmly in the alkalic family. The quartz-sericite alteration assemblage was attributed to breakdown of potassium feldspar in a near-surface alteration environment in which seawater may have had a significant role. These interpretalions are retained here, but preliminary conclusions from the most recent work suggest that they may require some modification."

Jan 1, 1995

By M. Drozd, A. Ibrado, P. Butcher

While effective in treating refractory sulfide ores, pressure oxidation leaves carbonaceous matter unscathed and able to adsorb gold from cyanide solutions. Barrick Goldstrike's strategy to mitigate this problem is to minimize contact between dissolved gold and native carbon in advance of the carbon-in-leach (CIL) process. Measures currently in use include limiting carbonaceous matter in the plant feed by meticulous blending of ore, controlling the degree of oxidation in the autoclaves and blinding native carbon surfaces with lauryl sulfate. The presence of residual cyanide and thiocyanate in the process water remains to be a cause of premature gold dissolution and loss of gold by adsorption on carbonaceous matter. This cyanide is introduced by water that is recycled from the tailing pond. Of several treatment options considered, oxidation by peroxymonosulfuric acid, also known as Caro's acid, is deemed to be the most effective. Laboratory and pilot plant tests show that Caro's acid can oxidize free cyanide, weak¬acid-dissociable (WAD) cyanide and thiocyanate, resulting in significant improvements in gold recovery downstream. The process requires Caro's acid at 125 % of the stoichiometric requirement and pH in the range of 9.5 to 10 to accomplish the desired destruction in about twenty minutes. A cyanide destruction plant is currently being designed and construction should be completed by the end of 2005.

Jan 1, 2005

By M. Tanaka, H. Narita, K. Morisaku

"The selective separation of palladium (Pd), platinum (Pt), and rhodium (Rh) from a hydrochloric acid solution by solvent extraction was investigated using amide-type extractants, i.e., N,N,N’,N’-tetra-n-octyl-thiodiglycolamide (TDGA) and N-n-hexyl-bis(N-methyl-N-n-octyl-ethylamide) amine (BisAA). The separation experiments employed two separation schemes: (1) extraction of Pd with TDGA and that of Rh and Pt with BisAA; and (2) extraction of Rh, Pd, and Pt with BisAA. Separation scheme 1 achieved the highly selective separation of each metal. For separation scheme 2, Rh can be recovered prior to Pd and Pt, despite having a lower selectivity for Pd/Pt than separation scheme 1. INTRODUCTIONThe recent increase in the use of platinum group metals (PGMs) in industry (especially auto catalysts containing palladium (Pd), platinum (Pt), and rhodium (Rh)) has lead to their increasing waste; therefore, improvements in the recovery techniques for PGM have received significant attention. In metal refineries, PGMs are mainly separated and purified by solvent extraction (Cox, 2004). The extraction process used in INCO’s Acton precious metal refinery is one of the most famous commercial processes and is utilized worldwide. In this process, silver is first removed as a residue (AgCl), and then gold, Pd and Pt are extracted from hydrochloric acid (HCl) solutions using dibutylcarbitol (DBC), dialkylsulfide (DAS), and tri-n-butylphosphate (TBP), respectively. Finally, Rh remains in the raffinate (Barns & Edwards, 1982).The development of a successful solvent extraction process depends on the choice of the appropriate extractants. We have studied the extraction of PGM using N,N-disubstituted amide compounds (Narita, Tanaka, Morisaku, & Abe, 2004; Narita, Tanaka, Morisaku, & Tamura, 2006; Narita, Tanaka, & Morisaku, 2008a, 2008b). They are relatively stable against acids, and their metal extractability can be improved by changing the side chain length and/or introducing additional donor atoms like sulfur and nitrogen. We have recently found that thiodiglycolamide and an amide-containing tertiary amine have good extractabilities for Pd and Rh, respectively."

Jan 1, 2012

By B. Grinbaum

The solvent extraction of Cu from acidic leach solutions is carried out using oxime extractants. The mechanism can be described as liquid ion exchange, where a labile H+ in the oxime replaces Cu++ ion from the pregnant leach solution. The process is reversible and, at high acidity, the copper is stripped back to the aqueous phase. As the extraction proceeds, the acidity of the aqueous phase increases and the equilibrium may shift against the extraction reaction. This phenomenon may become significant in leach solutions with high copper concentration, where large amounts of acid are transferred from the solvent into the aqueous phase. An efficient way to increase the recovery of copper consists of splitting the extraction into two circuits, and either neutralizing with lime or extracting the excess acid of the intermediate raffinate. In the second case, the acid can extracted using a solvent, which can be stripped with a base, e.g., NaOH or ammonia. A third option is direct neutralization with soluble basic salt, e.g., Na2CO3, within a single extraction battery. The choice of the preferred process depends on the specific process demands and on the relative availability and price of the raw materials and by-products price.

Jan 1, 2007

By P. Bonadia, A. Tabereaux

Nearly all aluminium smelters are increasing the potline amperage to achieve higher aluminium production. In some instances the higher amperage operation has a significant negative impact on shortening the lifetime of aluminum electrolysis cell cathodes due to loss of the protective sidewall cryolite ledge freeze and too rapid penetration of the cell bottom refractory lining by cryolitic bath components due to the higher temperature isotherms. Thus Cathodes require careful thermal modeling of the cathode relining designs and improved refractory materials to allow greater heat loss from the sidewall to preserve a stable sidewall ledge freeze at higher amperages, and the selection of optimum refractory barrier materials to control the penetration and reaction of bath into the cathode bottom refractory and insulation lining. This requires an understanding of the reaction mechanisms and product formation for molten NaF enriched bath and alumino-silicate refractories. It is desirable to use dense, low porosity refractory fireclay firebricks, or similar materials with a sufficiently high silica content to promote the formation the mineralogical phase albite, NaAlSi3O8, that significantly increases the viscosity of the melt which slows the diffusion of reactive species in the melt and thereby retards further bath penetration.

Jan 1, 2004