Search Documents

By C. A. Morais, L. V. Resende

"The technological development observed in recent years has stimulated the application of rare earth (RE) elements. Amongst their various applications it is well worth mentioning their use in electronics, superconductors, nuclear medicine, as well as in special inks - as those used in radar invisible airplanes. TV and computer monitor screens present as coating a powder containing some rare earth elements, mainly Europium and Yttrium. The recovery of the RE elements from electronic scrap is extremely important as the economic and environmental issues are concerned. This paper describes the study of the Eu and Y recovery from e-scraps. The first step of the process was the leaching of the powder obtained by manually scraping the inside surface of the screen. After the optimization of the leaching, the dissolution of Eu and Y was higher than 98 w/t% and a pregnant sulfuric liquor containing 11.9 g L-1 Y and 0.72 g L-1 Eu was obtained. The second step was the separation of the metals found in the liquor by the solvent extraction technique. The separation of Eu and Y was carried out in a counter current circuit compound of 3 extraction stages, 7 scrubbing stages and 15 stripping stages. DEHPA was used as the extractant, whereas a diluted sulfuric acid solution was applied as scrubbing agent and a hydrochloric acid solution at high concentration was used as the stripping agent.INTRODUCTIONThe rare earths (RE) are a moderately abundant group of 17 elements composed of lanthanides, scandium and yttrium. Amongst the RE, promethium (Pm) is extremely rare, however several of the RE elements are not very rare and occur dispersed in a variety of forms (Greenwood & Earnshaw, 1984; Tyler, 2004).The innumerable applications of the RE elements are based on their particular properties, mainly their spectroscopic and magnetic properties (Martins & Isolani, 2005). The technological development observed in recent years has stimulated the application of rare earth (RE) elements. They have been used in agriculture, electronics, superconductors, nuclear medicine, automobile industry, special inks – as those used in radar invisible airplanes, X-ray screens, high intensity mercury vapour light bulbs, neutron scintilators, charged-particle detectors and optical memory reading systems (Maestro & Huguenin, 1995; Nagaosa & Binghua, 1997; Sánchez et al., 1999)."

Jan 1, 2012

By C. O. Swanson

Introduction It is thirty-odd years since I first entered the mining field by working underground at Anyox, which makes 1t clear that I can qualify as one of the older generation and claim the privilege of dealing in generalities and broad impressions. In this position I find it interesting to re~ view the salient changes that have taken place during the past quarter-century and indulge in some speculations concerning the future, with the hope that my comments may be of value to others engaged in the field of mining geology. As indicated by the title, the treatment is a perspective from a single viewpoint rather than an attempt to give a complete and impartial analysis. This plan, while deficient in some respects, has the advantage of being more specific than one based on .a. compilation of opinions. An additional advantage is brevity, which would be difficult to obtain on a subject of this scope if it were viewed from all angles. In conformity with the general plan, specific references to the literature have been avoided as much as possible, although a number of publications of general nature are listed at the end of the paper. This procedure is intended to give credit to the sources used without making them in any way responsible for the interpretation. The starting point for the discussion is the situation as it existed twenty-five years ago, when, as a recent graduate, I first had a fairly complete picture of it. However there is one impression of an earlier; stage that seems worth mentioning. In one of my first courses in geology the statement was made that some of the leading authorities of the previous generation, who guided geological thought at about the beginning of the century, were inclined to question the value of an association with mining. This attitude was no doubt exceptional, and certainly it was not adopted by the students who laid the groundwork for mining geology in North America. But its existence even in a limited circle is significant m showing how far the application of geology has advanced as the result of the investigations started during the first part of this century.

Jan 1, 1949

By J. F. K. Brown

WHEN I first received the kind invitation extended to me by the Mining Society of Nova Scotia, I read over very carefully the suggested title-"The importance of long-distance planning and budgetting in modern methods of mining, and the advisability of working to some definite plan". I came to the conclusion that I might as well confess my inability to handle properly such a vast and intricate subject within the scope of any one paper. More properly, I think a round-table discussion should be indulged in-a sort' of symposium carried on in similar fashion to the World Power and Coal Conferences- you know, a committee for this, a committee for that, and, finally, a committee to see what the committees are doing. Weil, your Secretary's suggestion is just like that- much too comprehensive for any half-hour's presentation. As a paper, also, it either becomes too general and therefore uninteresting, or i.t descends into detail and describes means and methods to the end desired, which have little attraction because they were designed to meet quite different conditions than those my audience would mentally be considering. Of the two evils facing me, I have chosen the one that sticks to the generalities. Your Secretary's query almost automatically divides itself into two distinct phases: First, the importance, and second, the advisability, of planning. Let us dwell for the moment on the second, because, if we can prove advisability, that leads to desirability and, finally, to doing. Proving is the difficult part of the little problem. Here was something I, personally and as a mining engineer, had been battling for all my corporate life without being able to prove it to anybody. Then I saw the way out of that. I perceived I could put that little question of advisability on another basis altogether-:put it in the class of "coming- some day- soon" whether you or l or anybody else liked it or not; call it, if you please, mandatory, certain, necessary, enforceable planning. All of which means that the problem of advisability has rather suddenly become the very practical one of "how to do it". Why?

Jan 1, 1937

By W. H. Zieman

NORMAN WEISS, Milling Engineer, American Smelting• and Refining Company: The subject of the Forum on Rod and Ball Mill Liners is very fascinating, and there is no end of discussion when operators get together on grinding. However, the hypotheses and suppositions easily outrun the facts, especially when we •consider the inaccuracy of many reported observations. Still surprisingly small is the number of concentrators even reasonably well equipped to measure power consumption of each grinding mill, together with running time, so that data on this tangible factor, at least, can be obtained with precision. While the more elaborate devices of this nature, producing for each 24-hour period the total power consumption, average kilowatt hours per hour, short-term demand chart, instantaneous demand, and print-out, may cost in the neighbourhood of $2,500 per mill and may be difficult to justify, the combination of an ammeter, watthour meter, and running-time meter will cost only a few hundred dollars, so there appears to be little reason not to in-stall them in view of their numerous advantages.

Jan 1, 1959

By W M. Cameron

Geophysical studies have extended seaward in recent years, and the important discoveries which have been made have led to a better understanding of geological processes. A present source of certain minerals, the sea will eventually serve as an important source of desalinated water. The continental helves, in particular, represent a potential mineral resource. The expansion of Canadian oceanographic effort that is now underway will eventually lead to the exploitation of the wealth beneath the sea. THE subject of this symposium, which emphasizes the word "geophysics," the specialties of the speakers who are contributing and the nature of the audience at first made me believe that I, a a physical oceanographer, would be out of place. However, I shall undertake to classify myself as a geophysicist, and shall arrange my remarks on my specialty o that they might be of interest to those of you who are predominantly geologists, metallurgists or mining engineers.

Jan 1, 1963

In the present work, the effect of pH, non-ionic polyacrylamide flocculant and anionic polyphosphate on rheology and settling behaviour of colloidal TiO2 suspensions (15 ? 50 wt% solid) is investigated. Maximum particle aggregation, reflecting in the highest suspension settling rate and maximum shear yield stress was achieved at pH 7.2, the isoelectric point (iep), consistent with DLVO expectation. However, the maximum aggregation condition at the iep also resulted in the poorest suspension consolidation behaviour. Significantly enhanced consolidation was achieved for a more dispersed suspension at pH values away from the iep but at reduced settling rate. Thus, when pH alone is used to control conditions which facilitate strong interparticle attraction, a high settling behaviour which is not conducive to compact consolidation results. Improved suspension consolidation may be achieved at the iep via anionic polyphosphate addition which leads to attenuation of the strongly attractive van der Waals forces and emergence of "soft" repulsion due to weak inter-particle electro-steric forces. The weak repulsion act to lubricate particles involved in the hydrodynamic interactions which controls the compressibility of the sediment bed, allowing a compact consolidation of solids to be obtained. Alternatively, non-ionic polyacrylamide homo-polymer (Magnafloc 333) was fairly effective in flocculating titanium dioxide suspensions leading to high settling rate and acceptable pulp consolidation at the iep.

Jan 1, 2006

By S-E. Vandat

The goal of this work was to select an appropriate electrode for dummy load of diesel engine in fully salt-water in the DESA factory. The electrochemical corrosion rate of general structural steel, commercial pure aluminum and cathode copper calculated as weighting, volumetric and commercial in fully salt-water by city power. After several tests and then applying the fuzzy logic method, it was determined that general structural steel is the best selection for this purpose.

Jan 1, 2005

By John G. McCamis

The Maritimes Carboniferous Basin is the largest intermontane basin in the Appalachian Mountain System, occupying a total area of 57,200 square miles and containing up to 30,000 feet of late Devonian through Permian .sediments. Deposition began with continental elastics in late Devonian and early Mississippian. Marine deposition is represented by a limestone-evaporite sequence of late Mississippian age. Pennsylvanian and Permian continental rocks deposited largely in flood-plain and swamp environments complete the succession. Marine seismic data disclose several varieties of structure, both halokinetic and tectonic in origin. Recent exploratory drilling in the offshore part of the Basin encountered good reservoir rocks in the Riversdale sandstones, which also provided encouraging shows. The most likely source rocks of hydro~ arbons in the Maritimes Basin are shales in the Horton and Riversdale groups. Potential recoverable reserves of the Maritimes Basin are estimated to be 400 million barrels of oil or 7.8 trillion cubic feet of gas, based on the volume-of-sediment method of calculation.

Jan 1, 1973

By L. B. Tsymbulov, L. Sh. Tsemekhman, A. N. Golov

Gipronickel Institute, JS is developing a process of continuous converting of Nicontaining copper matte and concentrates resulting in the production of blister copper and fluid NiO-containing slag in a two-zone Vaniukov furnace. The process under development is an alternative for the existing technology of blister copper production in converters, the latter being characterized with insufficient sulphur utilization, low direct copper recovery and the production of inconvenient for further processing solid slag on the basis of NiO and NiFe20 4- The results of pilot testing on processing of copper concentrate obtained from high-grade matte (HGM) separation in the two-zone Vaniukov furnace with the hearth area of 11.4 m2 are presented.

Jan 1, 2007

By John O. Galloway

"The year 1947 was a momentous one in the history of the petroleum industry in Canada. It was in that year that Imperial Oil Limited made its discovery at Leduc, the forerunner of other discoveries, large and small, and the spark wl1ich started a most intensive exploration and development programme there.If, to use boxing parlance, Leduc was the first blow of a one-two combination which left doubting Thomases groggy, then Redwater was the number two blow which achieved the knockout. The oil industry's exploration leaders did about-face without delay and the rush of oil operators of all classifications to western Canada began. It is still continuing, and the influx of capital which the operators have brought in and are bringing in has a bouyant effect upon the over-all economy. The boom is on, but it is a sound one, and it is difficult to conceive that it will have anything but the most beneficial effect on Canada, and particularly western Canada.The petroleum industry is an important segment of the general economy. Its activities call for tremendous amounts of capital; its employees are well paid; it is a large customer for a wide range of products of other industries; its commodities are essential to the citizens and the nation.The industry is carried on by highly aggressive and independent groups and individuals, of which a small minority are integrated while the majority are relatively small operators engaged in only one or two phases of the business. Competition is the rule and, since the nature of the business is mass production, the industry is faced from time to time with serious problems, many of which are peculiar to it."

Jan 1, 1950

By S. S. Yuan, Q. Z. Zhu, J. F. Shao

"This paper aims at enriching a homogenization-based anisotropic damage model for hard rocks under complex loading. A new damage criterion is proposed to capture material strain softening. Within the framework of irreversible thermodynamics, we are particularly concerned with two strongly coupled dissipative mechanisms: frictional sliding and damage by microcracking, which usually take place at cracks within cohesive geomaterials under compression. Focusing on the representative elementary volume containing multiple crack families, the free enthalpy of the matrix-cracks system is obtained. Importantly, a back-stress term is involved in the local stress applied to microcracks. This back stress plays the hardening/softening role in the friction criterion which is formulated at local scale. Strain hardening owns to the accumulation of frictional shearing and dilatancy while strain softening is caused by crack growth. The multiscale damage model is used to simulate laboratory tests on the Westerly granite under true triaxial compressions. INTRODUCTIONWhen subjected to compressive loads, hard rocks present nonlinear mechanical behaviors and induced material anisotropies. In that process, two main dissipative mechanisms have been largely identified: damage by crack growth and frictional sliding along closed crack faces, which are usually strongly coupled to each other on crack scale. Theoretical investigations have shown that the damagefriction coupling analyses allow explaining a large number of experimental phenomena involved in brittle or quasi-brittle materials. Concerning constitutive modeling, the standard Eshelby’s solution-based homogenization procedure for heterogeneous materials was recently applied successfully to describing the mechanical and poromechanical behaviors of cracked frictional solids."

Jan 1, 2015

By W. J. Weymark

"The Gregg River project is located 40 kilometres southwest of Hinton, Alberta, adjacent to and east of Jasper National Park. This metallurgical coal mine has been developed as a joint venture between Gregg River Coal Ltd. (a subsidiary company of Mana/ta Coal Ltd.) and seven Japanese companies. This 200-million dollar project consists of a conventional truckshovel open-pit operation and a coal preparation plant rated at 2.14 million tonnes of clean coal per year. Mining operations started in October 1982 with plant start-up following in April 1983. Introduction This paper is an overview and update of the Gregg River project, a metallurgical coal mine being developed as a joint venture between Gregg River Coal Ltd. (a subsidiary of Manalta Coal Ltd.) and seven Japanese companies. The Gregg River Coal leases cover 3440 hectares and are located 40 kilometres south of Hinton, Alberta, adjacent to and north of Cardinal River Coal Mine (Fig. 1). This 200-million dollar project consists of a conventional truck-shovel operation and a coal preparation plant rated at 2.14 million tonnes of clean coal per year. A total of 31.5 million tonnes of clean metallurgical coal will be sold to the Japanese over a fifteen-year term. At present, mining operations are ahead of schedule and the plant started up on schedule in April 1983. Access and Climate An all-weather road, Highway 40, connects the minesite with Hinton (the nearest commercial centre) and a Canadian National Railway (C.N.R.) spur line connects the minesite with the C.N.R. main line in Edson. Hinton is accessible by road chartered airline and rail. ' ~h~ rug~ed and varied topography in the area creates large vanations m temperature and precipitation over short distances. The region is characterized by precipitation throughout the year long cold winters and short cool summers. The mean temperatur~ of the area range from a low of -14°C in January, the coldest month, to a high of 12°C in July, the warmest month. Long-term precipitation data indicates a mean yearly precipitation of 870 mm of which 620Jo occurs during the summer months."

Jan 1, 1985

By Neil Campbell

"The Pine Point area is on the south shore of Great Slave Lake, 510 air miles north of Edmonton and J JO miles south of Yellowknife, N.W.T. The occurrence there of lead and zinc was reported in J 899 by R. Bell (5) of the Geological Survey of Canada, and in the following years several claims were staked and some prospecting was done. In 1928 Atlas Exploration Co. took over the property containing the discovery occurrences. In 1929 The Consolidated Mining and Smelting Company of Canada Ltd. (""Cominco"") and Ventures Ltd. participated with Atlas in forming the Northern Lead-Zinc Co., which, under the direction of J. M. Bell, carried out 24,499 feet of drilling in the discovery and surrounding areas. Two shafts and many surface pits were also sunk. This work showed that the discovery deposits contain about 500,000 tons of lead-zinc ore, but no new orebody was found.In 1936 D. F. Kidd (11) drew attention to the highly significant space relations between the base-metal discoveries at Pine Point and the projections of certain major Precambrian faults mapped earlier by C. H. Stockwell. Geological work by Cominco in 1940 and subsequent years suggested the presence of mineable deposits within a belt of land including part of the area of earlier field work and extending far beyond it. Between 1946 and 1954 exploration financed by Cominco and Ventures Ltd. included 182,950 feet of diamond drilling, 383 feet of sinking, and 240 feet of drifting, raising, and crosscutting. This work was successful in finding substantial quantities of new ore in places where bedrock is completely concealed.The topography is one of low relief, characterized in many places by swampy muskeg and shallow, marl-bottomed ponds. The area where ore has been found is generally higher ground which, though not well drained, is comparatively dry. It is also marked by raised beaches and a few sand dunes overgrown by small spruce and pine. Bedrock is generally overlain by a variable thickness of hard, glacial boulder clay. This in turn is covered by silt, sand, and gravel, probably deposited from the waters of Great Slave Lake, which formerly extended many miles beyond its present southern shore."

Jan 1, 1949

By A. Boehm

"For recycling LD slag into the steel making process, the phosphorous containing calcium silcate phases have to be removed from iron oxide phases. One possible technical solution could be magnetic separation in a wide range of susceptibilities from ferromagnetic to paramagnetic. To check the feasibility of magnetic separation the distribution of the magnetic susceptibility in size classes as well as the liberation of the phosphorous containing phase were evaluated by a new method combining two dimensional physical property analysis with QEMSCAN analysis. The particle size classes of energy controlled comminution products were subdivided into fractions of defined magnetic susceptibility using a hand magnet of well known field properties (pick up method). On the one hand the susceptibility classes were wet assayed on the other hand analyzed by QEMSCAN followed by data evaluation using iDiscover 5.3.1(FEI), which was adapted to the data structure of two physical properties (size and magnetic mass susceptibility). The results allow the comparison of mass based (3D) cumulative distribution of grades from the wet assays with the area based (2D) distribution from QEMSCAN analysis, in order to control a systematic (size dependent) stereological error for this special type of material. As the physical separation property forms a crucial parameter the results from the liberation analysis by QEMSCAN can be interpreted more profound with respect to an expectable separation result. Once the various mineral compositions of the particles are assigned to the physical properties the Henry Reinhardt chart serves to predict the best possible separation result and thus the feasibility of a separation technique.INTRODUCTIONThe two Austrian steel plants operated by voestalpine AG produce about 650,000 t (voestalpine 2014) of LD slag in the course of steel production from pig iron according to the basic oxygen process blowing oxygen in the converter by an oxygen lance. The process is also known as the Linz Donawitz (LD) steelmaking process. By the addition of lime (CaO), carbon, phosphorus, silica, manganese and sulfur, which are present in the molten pig iron, shall be oxidized and bound in the slag either as oxide or silicate phases, or leave the slag in the gaseous phase (CO). The average chemical composition of the investigated LD slag is given in table 1."

Jan 1, 2016

By D. R. Reeves

This paper describes the geophysical Jogging of coal that is being carried out for the National Coal Board in the United Kingdom. An explanation of the technique is given and results are presented showing estimations of seam thickness to within ±0.5 in. and ash content to accuracies of ±2.5 per cent. The basic method of interpretation is outlined and some conclusions regarding the conditions of roof and floor material which may be deduced from the logs are explained. An indication of future developments in this field, including the identification of coal type and moisture content, is given.

Jan 1, 1971

By C. A. Y. Shephard, H. L. Brusset

Pressure maintenance by water flooding in the Pembina Field made consideration of wet crude dehydration and disposal of the produced water mandatory. Crude dehydration, the treatment and disposal of produced water, as well as the sale of gas and crude oil were expected to be handled more efficiently at one central point than at several conventional batteries. This plan was effected by routing the produced fluids to the central station by way of several well testing batteries referred to as satellites. To realize the full efficiency inherent in such consolidation the entire system was made self-regulating. Programming ensures the testing and proper routing of all products to their destination. Forty producing wells have been self-operated during the winter 1959 -1960 with gratifying results.

Jan 1, 1960

By M. E. Holuszko

Although there is no widely accepted rigorous definition of handleability, the handling coal characteristics often referred to as handleability define whether a coal has the ability to flow unhindered through the processing and transportation systems. The handleability may be severely affected if fine coal particles tend to aggregate. In the pelletization process, the rolling action of the drum is applied to bring the individual particles into proximity with each other so that they can aggregate and form pellets. Because of apparent similarities between these two processes, the pelletization tests are carried out in parallel to the handleability tests in this project, and the pelletization results are used to explain coal handleability properties.

Jan 1, 2004

By A. G. Scobie

THE research laboratory of this Company was recently faced with the problem of determining trace amounts of tungsten in a series of classifier sands. A spectrographie survey revealed the feasibility of using this instrument in the final evaluation, but a check of the common methods in use for the isolation of tungsten (3, 4) showed these methods to give incomplete separation for trace amounts. An investigation into the possibility of modifying these procedures, or developing others, was thus indicated. ASSAY PROCEDURE Weigh 10 grams of 200-mesh ore or concentrate into a 400-ml. beaker, wet the sample well with about 20 ml. of water, and add 100 ml. of hydrochloric acid. Cover, digest at 60° to 70° C. for about 1 hour, and then boil down to approximately 25 ml. Cool, add 25 ml. of hydrochloric acid and 10 ml. of nitric acid, and again boil to former volume. Add 20-ml. portions of nitric acid with successive boiling clown until chemical action is complete. Then add 20-ml. portions of hydrochloric acid until all nitric acid is removed. Take nearly to dryness on a law-temperature hot plate, but do not bake. Take up in 10 ml. of hydrochloric acid and 20 ml. of water and heat on a law-temperature hot plate until all iron goes into solution. Dilute to 200 ml. and heat to just below boiling. Stir in pulp of about half of a No. 41 Whatman filter paper (12.5-cm.) and continue digestion on plate with occasional stirring for 15 to 20 minutes.

Jan 1, 1943

By M. Aushouri, S. H. Mansouri, N. Aminizadeh

A thermo-chemical model of the Peirce-Smith copper converter in blowing the copper stage has been developed to predict the molten temperature. The key assumption of the model was that white metal and gas phases in the converter were in thermal and chemical equilibrium. In this model, the chemical reaction of white metal and oxygen was accomplished completely. So long as sulfur existed in the bath, the generation of Cu2O was frozen. The reaction rate was considered to be constant and controlled by the reacted sulfur. The converter temperature was calculated by heat balances over time. The model was validated by a detailed comparison with measured industrial data. A good agreement was obtained. The converter temperature depended on process parameters such as oxygen efficiency, molten emissivity and oxygen enrichment.

Jan 1, 2007

By K. Sawamukai, S. Ogasawara, D. Umenai, T. Tsuruta

"Removal of cobalt, strontium or cesium ion from the aqueous solution containing each metal ion only using microorganism was examined. Arthrobacter nicotianae which had a high ability to remove cationic metal ion was used for the removal of each metal. The removal of cobalt, strontium or cesium using A. nicotianae cells was affected by the solution pH, concentration of metal ion, and cell amount. The effects of above mentioned factors on the removal of each metal and time course of strontium from the solution containing each metal only using A. nicotianae cells were reported in this paper. INTRODUCTIONRadioactive elements, such as cesium, iodine, strontium, plutonium, barium, cobalt, lanthanum, yttrium, and tellurium, were detected around Fukushima Daiichi nuclear power plant, which was damaged by the magnitude 9.0 earthquake and the tsunami followed.The removal of radioactive elements from contaminated sources is a worthwhile subject to investigatein terms of environmental control. Research efforts have been especially concentrated on studying microorganisms that remove uranium including bacteria (Andres et al, 1993, Hu et al, 1996, Marques et al, 1991, Strandberg et al, 1981), actinomycetes (Byerley et al, 1987, Friiss and Myers-Keith, 1986, Golab et al, 1991), fungi (Byerley et al, 1987, Galun et al, 1983a, Galun et al, 1983b,Tsezos and Volesky, 1981, White and Gadds, 1990) and yeasts (Strandberg et al, 1981, Schmate II et al, 1978).We have investigated removal and recovery of uranium from aqueous systems using microorganisms isolated from uranium mines. We identified some strains of bacteria with extremely high uranium removing abilities (Sakaguchi et al, 1996), and thus, the microbial biomass may be considered as an adsorbing agent for the removal and recovery of uranium and heavy metals present in aqueous systems around Fukushima Daiichi nuclear power plant.In the present study, we screened various species and strains of bacteria, actinomycetes, fungi, and yeasts for their ability to adsorb uranium (Tsuruta, 2002). Basic features affecting uranium adsorption?co-existing cations and anions, cell amounts, pH, and the adsorption time course?by Arthrobacter nicotianae cells, which adsorbed the largest amount of uranium, were also investigated. In addition, we examined the removal of an other actinoid element, thorium ion, which may be present with uranium in refining effluents.In this paper, the removal of cobalt, strontium, or cesium from the solution containing each metal ion using A. nicotianae cells is discussed."

Jan 1, 2012