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By R. G. L. McCready, Marco Zentilli

"Brogan coal containing mean averages of 6,93% w/w total sulphur (1.1% sulphate sulphur, 1.6% organic sulphur and 4.24% pyritic sulphur) and 16.34% mineral ash was used as the test coal in these studies.Shake-culture leaching studies on seven size fractions of the coal, ranging in size from 0.045 mm to 1.7 mm, showed that the rate of pyrite leaching was inversely proportional to the particle size. As the use of continuous stirred tank reactors would be uneconomical for the reclamation of waste coal, column leaching studies were initiated on coal sieved to >6.35 mm to < 12.7 mm, The leachate was monitored for all metal ions and the release of iron was used to monitor the rate of pyrite oxidation . Measurable amounts of Zn, Co, Ni, Mn, and V, all of which can replace iron in the pyrite crystal structure, were released during the initial stages of leaching. Further, high concentrations of AI, Ca and Sr and trace amounts of Sn, As. Se, B, Ca, Cr, Si, and Ti were detected in the column effluents.These studies suggest that bacterial leaching will remove the pyrite and qualitative amounts of environmentally undesirable trace metals from the coal if such a process is developed for waste coal reclamation.IntroductionIn 1947, Colmer and Hinkle showed that acid mine drainage was the result of an oxidative attack of the iron-mineral sulphides by Thiobacillus ferrooxidans to produce sulphuric acid . Ashmead (1955) proposed the use of these organisms to desulphurize coal , but the subsequent research effort was concentrated on the metabolism and physiology of these extreme acidophiles.A limited number of studies have been reported on the bacterial leaching of pyrite from coal (Silverman et al., 1963; Dugan, 1977). However, the bacterial oxidation of pyrite is a self-limiting first-order reaction, probably due to the precipitation of Fe(OH)J and elemental sulphur , which progressively inhibits intimate contact between the bacterial cells and the sulphide-mineral surface. Consequently, the best pyrite oxidation experiments with coal reported to date required five days to remove 97070 of the pyrite (Dugan &Apel , 1978) using mixed cultures of T. ferrooxidans and T. thiooxidans."

Jan 1, 1985

By Christian Brits, Bob Blain, Lloyd Buckingham, Juliu Stieger, Jean-Francoi Dupont

Barrick Gold Corporation (Barrick) has undertaken innovative methods of evaluating and improving the performance of grinding mills in several of its operations around the world. The results have been positive with some of the mines showing more than 20% net energy improvement leading to more than 43,000 tonnes per year reduction in CO2 emissions in four of the operations reviewed.

Jan 1, 2012

By J. Basi, J. A. Finch

ABSTRACT Testing the effects of bubble size (Db) in a Mo cleaning ?otation column at Highland Valley Copper mine indicated that increasing the proportion of small (< 1 mm) bubbles signi?cantly improved column metallurgical response, compared to typical operation. The results were a three- to four-fold Mo recovery increase and a 1 to 2% Mo (absolute) concentrate grade increase. The improvedcolumn operation produced a 4% Mo plant recovery increase. This study also showed that modelling the ?otation rate constant (k) as an inverse square function of Db was more accurate than considering k to be inversely proportional to Db.

Jan 1, 2010

By A. R. Sheik, A. A. Baba, M. K. Ghosh, K. Sanjay, R. B. Bale, A. G. F. Alabi, F. A. Adekola, L. Ibrahim

"This paper studies the characterization and dissolution of a Nigerian pyrolusite ore, reporting the results of ore physicochemical analyses and detailed ore characterization before and after leaching at optimal conditions. Ore dissolution rate increased proportional to acid concentration and temperature, but decreased with ore particle size. In a 4 M H2SO4 solution at 80°C with a particle size of –90+75 µm and moderate agitation, ore dissolution rate reached 78.7%. Unleached residue produced under optimal leaching conditions consisted of silica with admixtures of cristobalite and stishovite. The calculated activation energy supported the proposed diffusion control mechanism for the process.RÉSUMÉ Le présent article étudie la caractérisation et la dissolution d’un minerai de pyrolusite du Nigeria, il donne les résultats des analyses physicochimiques du minerai et de la caractérisation détaillée du minerai avant et après la lixiviation sous des conditions optimales. Le taux de dissolution du minerai augmentait proportionnellement à la concentration de l’acide mais décroissait avec la taille des particules. Dans une solution 4 M H2SO4 à 80 °C, avec une granulométrie de –90+75 µm et une agitation modérée, le taux de dissolution du minerai a atteint 78,7 %. Les résidus produits sous des conditions optimales de lixiviation étaient constitués de silice avec un mélange de cristobalite et de stishovite. L’énergie calculée d’activation supportait le mécanisme de contrôle de la diffusion proposé pour le procédé."

Jan 1, 2016

By M. B. Kime

"Discrete-element method (DEM) modelling is a powerful tool for studying particulate systems within the mineral processing industry. DEM simulations were conducted to investigate the power draw, load behaviour, and impact energy profile of an experimental ball mill under different milling conditions. The variables considered were mill rotational speed (percent critical speed), ball size, and lifter face angle. The simulation results indicated that the grinding efficiency would be enhanced by using 80% critical speed, 30 mm ball diameter, and 45° lifter face angle. These findings can be useful in guiding actual ball milling tests involving an ore sample.RÉSUMÉ La modélisation par méthode des éléments distincts (MED) est un outil puissant qui permet d’étudier les systèmes particulaires au sein de l’industrie de traitement des minerais. Des simulations par MED ont été menées de façon à étudier le profil de la consommation énergétique, du comportement de la charge et de l’énergie de rupture d’un broyeur à boulets expérimental dans diverses conditions de broyage. Parmi les variables prises en compte figuraient la vitesse de rotation du broyeur (vitesse critique en pourcentage), la taille des boulets et l’angle de coupe de la cornière élévatrice. D’après les résultats de la simulation, on pourrait améliorer l’efficacité de broyage en utilisant une vitesse critique de 80 %, un diamètre de boulet de 30 mm et un angle de coupe de 45 ° de la cornière élévatrice. Ces résultats peuvent se révéler utiles pour les essais concrets de broyage à boulets impliquant un échantillon de minerai."

Jan 1, 2017

By G. D. Mcdowell, L. B. Cochrane, B. D. Thompson

"Abstract - Exploration for deep underground copper and nickel sulfide deposits in the Sudbury mining camp is carried out with surface drilling. More detailed drilling, with an advanced underground exploration program, may be necessary to establish an accurate interpretation of the deposit geology and upgrade the resource estimate to the measured category for reserve estimation and feasibility assessment. Resource evaluation is a lengthy and costly process that could result in a decision not to proceed with the project. For projects that proceed to production, significant reductions in the operating and capital costs could be achieved with a more accurate interpretative model of the deposit geology and mineralization. Quality control procedures to ensure the integrity of the drilling data and interpretation guidelines are essential steps in the development of a deposit model. The use of block modeling techniques and the application of geostatistics for resource estimation further improve the quality of the resource model.Significant improvements to the interpretive models can also be achieved by incorporating additional information from geophysical measurements to validate and constrain the geological interpretation. The geophysical models must be consistent with known geological environments and oreforming processes, which has required the concurrent development of comparative models from exploited deposits. These geophysical techniques can also provide key geotechnical information required for the optimum design of the mining method and mining sequence. The objective of this program is to improve the accuracy of the deposit model and the quality of the resource and reserve estimates in order to optimize capital investments and reduce the development and operating costs of underground mining projects. Several of these techniques are currently being tested at INCO Limited’s Sudbury operations. The results from those tests are presented and their applications are discussed within the framework of resource/reserve classification systems and project evaluation objectives."

Jan 1, 1998

By Doris Stüben, Geoffrey P. Glasby, Akira Usui, Jörg-Detlef Eckhardt, Bruce W. Mountain, Zsolt Berner

"Abstract - Twenty-seven marine Mn and Fe deposits chosen for their diverse origins have been analyzed for five platinum-group elements (PGE). The PGE display their highest concentrations in hydrogenous Mn crusts and nodules, lesser concentrations in diagenetic nodules and two to three orders of magnitude lower concentrations in hydrothermal Mn and Fe crusts. This difference of behavior reflects the well-known fractionation of Mn and Fe from the other transition elements, rare earth elements (REE) and PGE in hydrothermal Mn and Fe crusts. Pt, Ru, Rh, and Ir show a close geochemical coherence in these deposits and are differentiated from Pd which shows a negative anomaly with respect to the other PGE in hydrogenous and diagenetic Mn deposits. Pd is less depleted than the other PGE and the Pd anomaly much less pronounced in the hydrothermal Mn and Fe crusts relative to the hydrogenous and diagenetic Mn deposits.Stability field diagrams show no evidence for the oxidation of Pt to the tetravalent state in seawater as suggested by some authors. Rather, Pt appears to be present in seawater as Pt(OH)2 0. Adsorption of Pt(OH)2 0 onto the surface of Mn and Fe oxyhydroxide minerals may explain the enrichment of Pt in marine Mn deposits. However, Pt metal is the thermodynamically stable solid phase of Pt under seawater conditions and reduction of Pt(OH)2 0 to Pt metal, particularly in the vicinity of the oxygen minimum zone, is possible, although the high Ce/La ratios of the Co-rich Mn crusts do not support this hypothesis. Pt, Ru, Rh, and Ir display their maximum concentrations in the Corich Mn crusts. This may reflect, among other things, the low growth rates of these deposits. The stability field diagram of Pd shows that Pd is undersaturated in seawater and occurs in seawater dominantly as PdCl4 2- and anionic mixed-hydroxide-chloride complexes. This would explain the anomalous position of Pd among the PGE with respect to its uptake into marine Mn deposits. A study of inter-element associations indicates that the incorporation of the PGE from meteoritic dust plays only a minor role in the uptake of these elements into marine Mn deposits. The PGE remain the most poorly studied group of elements in marine Mn deposits. The data presented here emphasize the need for the establishment of a more comprehensive database of the PGE in marine Mn deposits in order to understand more fully their uptake into marine Mn deposits and their pathways through the oceans."

Jan 1, 1999

By E. Fiset, T. Hennebel, F. Verbruggen, A. Prévoteau, K. Rabaey

Arsenic (As), bismuth (Bi) and antimony (Sb) are known to affect the quality of copper deposits in copper electrowinning operations. The codeposition of As was previously believed to occur only at current densities far exceeding the range of typical current densities for copper electrowinning. In this study, we investigate the copper electrodeposition on different pretreated stainless steel (SS) substrates from bleed electrolyte in galvanostatic mode at –45 mA/cm². Scanning electron microscopy (SEM) micrographs illustrate that during the initial phases of copper nucleation and growth, the current density was locally increased due to the pretreatments. It was reasoned that the codepostion of As could possibly occur in normal electrowinning conditions, but the risk can be substantially reduced by good SS substrate handling and maintenance practices. INTRODUCTION The presence of As, Bi and Sb is known to have a deleterious effect on the copper cathode quality in copper electrowinnings (Hiskey & Maeda, 2003; Hoffmann, 2004; Xiao, Cao, Shen, & Volinsky, 2012; Xiao, Cao, Mao, Shen, & Ren, 2014; Jafari et al., 2017). They are known to influence both the chemical and physical quality of the copper as they can contaminate the copper (Jafari et al., 2017) and affect the copper deposit structure (Hiskey & Maeda, 2003; Kim, Kim, & Chung, 2009), which contributes to a degraded market value of the copper (Tuddenham, 1984). The incorporation mechanisms of these impurities are believed to occur mainly through slime inclusion (F. Xiao et al, 2012) and electrolyte inclusion (Hiskey & Maeda, 2003). Other studies suggested that codeposition of these impurities is possible by their standard reduction potential being close to the one of copper (Xiao et al, 2014). Hiskey and Maeda (2003) investigated the copper electrodeposition on a copper electrode substrate in Cu electrolytes with a Cu, H2SO4, As, Bi, Sb composition representative for commercial copper tankhouses. The combination of voltammographic techniques and Auger electron spectroscopy showed that As was the first impurity to be electrodeposited from this electrolyte, yet at potentials where the limiting current density of the copper electrodeposition reaction is exceeded. The copper tankhouses usually operate at a current density ratio of 0.3 to the limiting current density in order to achieve tolerable copper quality deposits. The codeposition of As could be considered impossible in this current density condition. However, it is known that during the initial phases of electrodeposition on foreign substrates, a substantial part of the reaction proceeds by growth of individual nuclei where the current density is locally high and diffusion limited (Radisic, Ross, & Searson, 2006). Furthermore, it was observed that copper nucleation on TiO substrates occurred preferentially in the scratched oxide free areas which could serve as parts with high localized current densities (Chang, Choe, & Lee, 2005).

Jan 1, 2019

By André Chagnon, Michel Malo, Benoît Dubé, Chantal Pelchat

"Abstract- In the southern Gaspé Appalachians, gold mineralization is spatially associated with the Acadian dextral strike-slip Grand Pabos-Restigouche fault system. Two different structurally-controlled gold prospects, the Lac Arsenault and the Saint-André-de-Ristigouche, are described to unravel the genesis of gold mineralization in this part of the Canadian Appalachians.At the Lac Arsenault gold prospect, gold mineralization consists of Au-As-Pb-Zn-Cu-(Ag) polymetallic fault-filled quartz veins with laminated textures emplaced in brittle-ductile sinistral X shear fractures. Mineralized veins are hosted by Middle Ordovician graywacke of the Arsenault Formation, belonging to the Dunnage Zone, the Early Paleozoic oceanic domain of the Appalachians. Terrigeneous rocks of the Arsenault are regionally metamorphosed at the lower greenshist facies and the mineralized veins are included in a zone of Fe-carbonate alteration.The Sb-Au-As mineralization of the Saint-André-de-Ristigouche gold prospect, in the southwestern Gaspé area, comprises extension veins in the extension direction emplaced in brittle conditions. Mineralized veins are hosted by calcilutite and laminated silty and argillaceous limestone of the Early Silurian part of the White Head Formation, which belongs to the Gaspé Belt, the Middle Paleozoic successor basin in the Gaspé Appalachians. Metamorphic grade of the White Head Formation in the southwestern Gaspé area is very low, but the gold mineralization is included in a zone of hydrothermal propylitic alteration which includes two Cu-skarn mineral occurrences. The Lac Arsenault gold prospect has many characteristics of "greenstone-hosted quartz-carbonate vein" deposits whereas the southwestern Gaspé area, which includes the Saint-André-de- Ristigouche gold prospect, shows affinities with the geological setting of sediment-hosted gold deposits (Carlin-like deposits). The two gold prospects are controlled by the Grand Pabos- Restigouche fault system but they were not emplaced at the same level in the crust. Acadian strikeslip fauting played a major role in their respective genesis in providing channelways for ore-bearing fluids. The recognition of the analogy of the geological setting of the southwestern Gaspé area with that of Carlin-like mineralization gives new ideas for exploration in the area and elsewhere in the Appalachians.Résumé - Dans le sud des Appalaches de la Gaspésie, on trouve des minéralisations aurifères spatialement associées au système de failles de coulissage dextre acadien de Grand Pabos-Restigouche. Deux indices très différents, Lac Arsenault et Saint-André-de-Ristigouche, sont décrits pour évaluer la genèse des minéralisations aurifères à contrôle structural de cette partie des Appalaches canadiennes. Au Lac Arsenault, la minéralisation aurifère comprend des veines polymétalliques à Au-As-Pb- Zn-Cu-(Ag) en remplissage de failles. Ces veines à texture laminaire se retrouvent dans des zones de cisaillement fragiles-ductiles senestres de type X. Les veines minéralisées sont encaissées dans les grauwackes d’âge Ordovicien moyen de la Formation d’Arsenault appartenant à la zone de Dunnage, le domaine océanique du Paléozoïque précoce des Appalaches canadiennes. Les roches terrigènes de l’Arsenault sont métamorphisées régionalement au faciès inférieur des schistes verts et les veines aurifères sont dans de larges zones d’altération dolomitique (Fe-carbonate).Dans le sud-ouest de la Gaspésie, la minéralisation à Sb-Au-As de Saint-André-de-Ristigouche est dans des veines d’extension comprises dans la direction d’extension et mises en place dans des conditions de déformation fragile. Les veines minéralisées sont encaissées dans les calcaires argileux et les calcilutites de la partie silurienne de la Formation de White Head qui appartient à la ceinture de Gaspé, le bassin successeur du Paléozoïque moyen des Appalaches de la Gaspésie. Le degré métamorphique des roches du White Head est très bas, mais"

Jan 1, 1998

By X. Cao, M. Xiao, M. Jahazi

Magnesium alloys have low hardness, wear, erosion and corrosion resistance. The repair of service-damaged aerospace components made of magnesium alloys is an attractive solution in terms of time and cost saving. The feasibility of applying laser beam technology to repair ZE41A-T5 magnesium alloy sand castings in the machined surface conditions was studied using a continuous wave 4 kW Nd:YAG laser system. The influence of process parameters such as laser power, cladding speed, wire feed rate and defocusing distance on the shape, size and area of single cladding beads is discussed using a process optimization software. Sound single clad beads with good geometric characteristics were obtained using strictly controlled laser process parameters. The overall results indicate that laser surface cladding using filler wire has the potential for repairing aerospace components made of cast magnesium alloys.

Jan 1, 2006

By R. D. Studer

"The Snow Lake massive sulphide deposits are hosted by Aphebian volcanic rocks of the Flin Flon - Snow Lake greenstone belt, which in this area were deformed and metamorphosed to the amphibolite facies during the Hudsonian orogeny. All the known deposits occur in felsic rocks a short distance below the contact with an overlying mafic rock unit.The Stall Lake copper deposit occurs close to the top of an explosive felsic volcanic sequence. Rocks stratigraphically underlying the deposit have been hydrothermally altered by the mineralizing fluids. The sulphides were probably deposited from submarine volcanic vent(s) on the flanks of a felsic dome. The ore has been tightly folded, flattened and elongated parallel to the northerly trending lineation of the surrounding rocks during the several periods of deformation. Strike lengths of the lenses range from 60 to 300 feet and plunge-to-strike ratios are as much as 15:1.Ore lenses I to 4 typically consist of massive coarse-grained pyrrhotite, chalcopyrite and pyrite. A stratigraphically higher lens differs in that it contains fine-grained pyrite and chalcopyrite, with an increase in sphalerite toward its hanging wall. The No.4 orebody has a distinct footwall alteration zone characterized by brecciation and abundant chlorite-staurolite- garnet schist, with minor kyanite, anthophyllite, cordierite and anhydrite, as well as sulphide minerals. Chemically, the alteration zone is distinguished from the unaltered felsic rocks by Na20 depletion and Mg-Fe enrichment"

Jan 1, 1982

By P. B. Demarsh

"Location: - On highway 59, 17 miles east of Val d 10r near junction of Montreal highway in Northwestern Quebec.Life; - Started production 1952, ceased 1965.Ore: - Pyrite, chalcopyrite and small amounts of free gold and goldsilver tellurides in narrow quartz-carbonate-tourmaline veins in granodiorite. Specific gravity 2, 70.Capacity: - 700 tons daily Bevcon ore supply, l 000 tons daily when custom ore available.Assay: - Heads 0 .140 oz. per ton; tails 0. 009 per ton; extraction 92.5%.Grind: - 75% minus 200 mesh at 700 tons; 68% minus 200 mesh at 1000 tons. Detention time 28 hours and 21 hours respectively.Treatment: - Cyanidation process.Reagents: - Per ton. Aero Cyanide (NaCn) 0, 50; crushed unslaked lime 1. 75; zinc 0. 03; litharge 0. 10; steel consumption 2. 25.Water: - Pumped from land-lock spring fed lake l 1/2 miles distant.Cost: - Per ton. Crushing 0. 13; grinding 0 .32; filtration 0. 07; cyanidation 0.14; miscellaneous 0.29; total 0.95.Power: - Hydro-electric, 25 cycle, 12, 000 volts reduced to 550 volts.Labour: - Predominantly French Canadian, nucleus English Canadians.Tailings: - Impounded low lying pond.Personnel: - 15 including supervision.Flow sheet: - Canadian Mining Manual l 9 5 6 .Building: - Wood truss construction: 3/ 4 in. siding, ten test and 1/ 4 in. transite outside. Corrugated galvanized iron roof. Ground level foundations. Internal self induced heating. Wood stave tank equipment."

Jan 1, 1966

By E. W. Johnson

"The current increase in gold price may presage a resurgence of gold milling plants in Canada similar to that of the thirties. Because the industry has been at a low ebb for almost two decades, future operating responsibilities will likely devolve upon personnel with limited cyanidation experience. My comments, which may seem elementary to experienced operators, are directed towards these industry newcomers to highlight operational features in cyanidation which forty years' experience has shown me to 0e of importance. A brief review of what actually takes place in a cyanide circuit may help give a better understanding of the topics to be discussed.These will include: (1) expose the gold (2) dissolve the gold(3) make solid/liquid separation(4) recover the gold from solution.1. Expose the GoldThe chemical key to gold recovery by cyanidation lies in the ready solubility of the metal in a relatively weak solution (0.04%-0.075% NaCN equivalent by weight) of calcium or sodium cyanide. Obviously, dissolution cannot start unless the cya1ide is in contact with the gold. As an analogy, the yolk of a hard-boiled egg can oe taken to represent the gold particle and the egg white and shell, the surrounding gangue or sulphide host. As the sl1ell and white must be fractured to expose the yolk, similarly the surrounding gorngue or sulphide host must be broken or fractured to enable the cyanide solution to contact the gold."

Jan 1, 1979

By Jerry Handford

Investing in the Development of our Future Workforce ?Collaborative partnerships with educational institutions, industry associations, governments and other businesses. ?Programs: »Co-op / Discipline Student Program »Trades Development Initiatives »Operator Training Programs »General Student Program »Careers Next Generation / Community Careers Co-operative

May 1, 2006

By G. Kordosky

The experience of one plant regarding degradation of copper solvent extraction reagents in the presence of 20 to 30 g/1 nitrate in the leach solution was described at Cobre 2003. However, little information is available about the degradation of copper solvent extraction reagents where the nitrate concentration of leach solution is much lower. Analysis of plant organic samples taken from an operating copper SX plant over a long period of time shows that small amounts of nitrate in the leach liquor can be a significant contributor to reagent degradation provided certain other conditions are present. These conditions are discussed and cautionary suggestions on copper SX plant operations in the presence of even low levels of nitrate in the pregnant leach are made based on industry experience with copper solvent extraction plants and copper solvent extraction reagents.

Jan 1, 2007

By Dwayne D. Tannant

This paper presents a summary of results from a questionnaire sent to surface mines in western Canada seeking information on haul road design, construction, and maintenance. There has been a marked increase in the size of the trucks used over the last decade with some mines now using trucks with a payload capacity of 360mt. Consequentially, geometrical elements of haul roads, such as width, have been enlarged to accommodate larger trucks. Most haul roads are constructed on the basis of past experience without use of formal design procedures. With the introduction of larger haul trucks, problems related to rolling resistance, deterioration, and maintenance of the haul roads have become more important. This has lead to adoption of more rigorous design methods for roads at some mines, most notably for the oil sand mines operated by Syncrude Canada Ltd. A summary of the evolution of haul road designs implemented at Syncrude Canada Ltd. is presented.

May 1, 2001

By D. Zagidulin

Short term electrodeposition experiments (up to 80 min.) at two current densities 220 and 275 A/m2 with varying concentrations of thiourea and glue were performed to determine the optimum levels of glue, thiourea and current density for industrial copper electrorefining. White Light Interference Microscopy was used to acquire digital images of the morphology of the electrodeposited copper. Scaling analysis was employed to pa-rameterize the morphological information encoded in the images. The limiting rough¬ness, *, the critical scaling length, Lc, and the aspect ratio, 4*/ Lc, were determined as a function of the deposition time and the amount of organic additives. These parameters were used to calculate the dynamic exponent, B, the roughness exponent, 1/z, and the as¬pect ratio exponent, y, plotted as a function of glue and thiourea concentrations. These 3D plots allowed us to find conditions corresponding to the minimum of B and y, at which the deposited copper is characterized by a small roughness and a dense structure.

Jan 1, 2007

By G. B. Harris

A new process for the recovery of copper and associated base metals from a polymetallic massive sulphide ore is described. The massive sulphide contains copper and especially nickel sulphide in a mineralogical form which negates both good recovery and high grades in concentrates using conventional flotation methods. Flotation concentrate processing and smelting from this ore is therefore probably not an economically viable option. Utilising the properties of high concentration chloride brines, a flow sheet has been developed and tested whereby the recovery of all of the metals and some of the power requirements for the plant itself can be derived from the ore. The new process overcomes the less-amenable-to-flotation ore characteristics, and provides the opportunity of economic processing in remote locations where the dependency on fossil fuels is both a logistical and an economic concern. The Ferguson Lake deposit of Starfield Resources in Nunavut, Canada, is the subject of this paper, which focuses on the leaching and copper recovery unit operations of the proposed flow sheet.

Jan 1, 2007

By Shoma Sinha, Nirmal K. Sinha

Deformation in a material at any temperature is known to consist of two major components - a reversible (elastic) part and an irreversible part (often called plastic). What is not universally known is the fact that at high temperatures greater than about 0.4Tm, where Tm, is the melting point in Kelvin, the reversible part includes not only elastic but also a delayed elastic (recoverable but time dependent) component. A very simple computational model is presented here for a constant-strain stress relaxation test (SRT) on the basis of a three-component constant-stress rheological equation derived from strain relaxation and recovery test (SRRT) data. It is shown that the rapid stress reduction during the early periods of relaxation when the stresses are high is governed primarily by delayed elasticity irrespective of the imposed strain level. This is in contradiction to the popular concept prevailing today. The asymptotic approach to a quasi-stable stress rate at longer times and lower stresses is, however, controlled by viscous flow (power-law creep). The validity of the theory is examined by comparing the predictions with experimental results obtained for a titanium-base alloy Ti-6246 at 0.45Tm.

Jan 1, 2004

By Michio Okada

Dissociative adsorption of hydrogen (deuterium) on thin gold films grown on Ir{111} surface has been studied with temperature-programmed desorption using a quadrupole mass spectrometer and nuclear reaction analysis. Thin Au{111} films are epitaxially grown on Ir{111}. Surprisingly, H2 (D2) can dissociatively adsorb on these Au{111} films, although it is well known that Au surfaces are noble enough not to dissociate hydrogen molecules [B. Hammer and J.K. Nørskov, Nature 376, (1995) 238]. We attribute this to the sensitivity of hydrogen to changes in the local surface properties, e.g., electron localization (the narrowing of the s-band, the s-band center model), which could explain the upto now unexpected high for the reactivity of a thin Au{111} surface. Moreover, we found that H (D) atoms can be confined into a Au thin film and/or the interface between an Ir surface and the thin Au film. We demonstrate how anomalously reactive thin Au films grown on an Ir surface are, and also compare the Au films with Ag films grown on Ir to test the validity/generality of our proposed s-band center model.

Oct 1, 2003