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By W. R. Hopkins, J. A. Davis

"This paper presents a discussion of the mechanisms by which aerosols of the process electrolyte are entrained into the breathing environment of copper, Zinc and nickel eIectrowinning tankhouses. Literature outlining the health effects associated with worker & posure to the acidic and metallic contaminants found in the airbome aerosols is summarized and compared with existing North American regulations.A brief review of the existing technologies for the source reduction of these aerosols is presented. This paper outlines the industry experience with use of covers, balls, beads, shapes, fixtures and chemical surfaetants. Each of these devices is ranked according to its effusiveness in the process in which it is used, and rated according to its operator acceptance.The various forms of existing in-plant ventilation systems are reviewed with a discussion of their relative merits and effectiveness. Actual experience is related, detailing the methods of testing for ambient contaminant levels in a variety of tankhouse environments. Guidelines are provided for the site and process specific criteria which govern the selection and ultimate effectiveness of a particular form of ventilation system.Finally, actual project experience is cited in which hydraulic modelling is used a design tool in tankhouse ventilation design. These projects include the upgrading of existing traditional ventilation designs, and the ''grass roots"" design of a more efficient aerosol source control system to be used in high altitude, cold weather sites."

Jan 1, 1994

By Raynald Vézina, Richard Leclerc, Jean Boissonnault, Louis P. Gignac, Gérald Veillette

Since mid-1989, Cambior has increased its producing gold mines from four to six, having acquired the Chima Mine and brought the Silidor Mine onstream. In June 1990, the company announced that the Mouska project would also be put into production. Gold production reached almost 190 000 ounces in 1989 and is expected to exceed 220 000 ounces this year. Cambior has also a non-gold operation with an interest of 50% in the Niobec Mine and has recently signed an option agreement in the development of the Lac Knife graphite deposit in northeastern Quebec. During the past year, the company has extended its exploration activities to the United States and Indonesia, and now has interests in nearly 80 properties. Last May, Cambior signed an option agreement with Golden Star for a gold deposit in Guyana, the OMAI Project, containing at least 2 000 000 ounces of gold in situ.

Jan 1, 1990

By C. J. Li, J. L. Feng

In the present study we focuses on developing the poroelasticity model that deals with adsorptioninduced permeability change mostly occurred in porous media constituted several phases such as coal. The underlying pressure induced by adsorption is obtained by Virial expansion form, which is substantially founded on statistical physics. The corresponding thermodynamic pressure applying on the pore surface is then used to detail the pore pressure and further to evaluate the macroscopic volumetric strain and the porosity. In the process of physical adsorption, the adsorbed phase is in thermodynamic equilibrium with the gas phase regardless of pore size, and the corresponding chemical potentials are all equal. The relationship between surface strain and volumetric strain is derived under infinitesimal deformation conditions to gain an explicit formulation of pore surface area with respect to volumetric strain and porosity. After the formulation of surface stress modified by the Langmuir isothermal adsorption is derived, the differential micromechanical constitutive equations of porous media are obtained. By supposing that the ratio of current permeability to initial is equal to the cubic ratio of current porosity to initial porosity, the differential equations for permeability change is consequently derived. The numerical simulations by the present model for permeability change of coal induced by adsorption of CO2 and CH4, respectively, are presented under confined stress conditions. The predictions from the model are good in agreement with the experimental data of sorption-induced permeability change of coals in the literature.

Jan 1, 2015

By Liu Tao, Wang Wei, Liao Wenjiang, Yang Weiyan, Tang Bin

Side-blown Furnace technology is a developing technology and was developed very quickly in China in recent years, dozens of reference smelters can be found for the treatment of copper concentrate, copper slag, Lead slag, zinc leaching slag and different kinds of slurry. This paper introduces the working principle of the technology, displays the innovations and specifications of China Nerin's SBF technology, gives examples of the typical reference smelters, and looks ahead to future applications. INTRODUCTION Side-blowing furnace smelting process The side-blowing furnace smelting process (SBF process) is one of the bath smelting process with independent intellectual property rights of China Nerin. This process was originally applied to treat copper concentrate and high-lead slag. The SBF process includes two categories, i.e. to treat copper concentrate and to treat industrial solid waste. Up to now, the SBF process has been applied in around 5 million tons of copper concentrate processing capacity and 20+ plants with high-lead slag reduction process. In recent years, SBF process has been gradually used in zinc leaching slag, electroplating sludge, industrial solid waste (e.g., various metallurgical slag), and electronic waste disposal. The basic principle of SBF process is that the material to be treated is directly charged to bath through charging hole with crushed coal and flux, then, enriched oxygen air would be sent to slag level (Vanyukov/Jifeng style furnaces)or matte level (Baiyin style furnaces) via primary tuyere. In this case, the material completes matte/slag metallurgical reaction of gas-liquid-solid interaction under vigorous mixing, and separate matte and slag at the bottom of furnace hearth. With the help of secondary tuyere, the low-pressure air or enriched oxygen would be provided for secondary combustion in the freeboard. The core of SBF process is process parameter control and engineering design of SBF. Presented as a fixed rectangular type, the SBF is a metallurgical furnace consisting of copper water jackets and refractory material. The SBF is consisting of hearth, middle of furnace and furnace top with the sequence from bottom to top. The middle of furnace itself can be further divided into bath area and post-combustion area with primary tuyere and secondary tuyere at both sides. The furnace hearth is made of refractory bricks, which are fused and rebonded Mg-Cr brick, Mg-Cr brick and clay brick from inside to outside. The furnace top adopts a steel water jacket with charging hole and uptake shaft. The water-cooled partition wall is placed at uptake shaft and near charging hole.

Jan 1, 2019

By Gary Walters, Matthew White, Thomas W. Gonzales

The copper smelting industry has transitioned into the 21st century compliant with environmental regulations, new smelter installations and brown field expansions. The industry faces new challenges as copper in concentrate grades have decreased while contained impurities have increased. A new benchmarking survey was undertaken to update the last survey of 2016 for operating copper smelters in the world. The information collected was separated based on primary smelting technology rather than by geographical location and supplemented from published literature. Each smelting technology’s unique use of specialized process equipment, concentrate smelting capacity, and impurity flexibility are discussed INTRODUCTION The 20th century was a remarkable time for the growth of copper smelting. Electric, blast and reverberator furnaces dominated the smelting technology well past WWII. In the 1970s, SO2 regulations and high energy cost drove the development of new primary smelting technology. Technological advancements decreased energy consumption and enriched sulfur dioxide concentrations of the process off-gas to levels where sulfur capture in sulfuric acid plants was economically viable. The new smelting technologies began to replace reverberatory and electric furnaces starting in the late 1940s. A new paradigm in copper smelting was established and the enabler was then Outkumpu’s® flash smelting technology from the 1940s through to today. Now, Outotec had become the dominant primary smelting technology with over 44 copper flash smelting furnace installations world-wide. Figure 1 shows the historical installation statistics of primary smelting technologies over the last 70 years (ICSG 2018). The dominance and acceptance of the Outotec® smelting technology from the 1940s to current can be seen. Isasmelt® technology for copper was introduced in the 1970s and did not see advancement in new installations until the 1990s through today. Isasmelt® has 12 world-wide copper furnace installations to date. Mitsubishi® also introduced continuous smelting and converting technology in the 1970s, but had no new installations until the 1990s with a total of 5 copper smelters. Outotec Ausmelt® smelting technology had 3 installations in the 1990s and totals 10 furnaces. Most recently the Chinese technology of Bottom Blown and Submerged Lance Smelting began commercial operations in 2005 for total installations of 11, mostly in China. Other technologies, such as, El Teniente, Noranda, Inco, and Vanyukov furnaces have contributed to the overall global smelting capacity, but have not penetrated the smelting industry to challenge the existing dominant smelting technologies. The technology distribution in Figure 1 also shows flash smelting technology for sulfide concentrate domination untill 2000, bottom blow technology has become the preference in China. Currently, China is the only country building new smelting capacity. Isasmelt® technology also seen a large increase in installations in the current decade.

Jan 1, 2019

By A. Probst, N. Moores, J. A. Finch

"In 1994 McGill and INCO (Sudbury operation) initiated transfer of technology originally developed to detect level in flotation columns to thickeners. A conductivity probe was installed in a concentrate thickener to monitor the mud-line and solids load. The probe consisted in a vertical tube with 32 equally-spaced electrode rings connected in pairs to give 31 conductivity cells. Conductivity was measured as a function of depth (so-called conductivity profile) from which the mud line and % solids could be inferred. The probe was installed in October 1994 and has been successfully detecting profiles since then. This communication includes a description of incidents and experiences during this technology transfer process including: probe installation and start-up; software modifications to accommodate operating conditions and operators' needs; calibration procedures to adjust to changes in performance as a consequence of long term use; and preliminary observations on the last stage, still in progress, signal interpretation and use to facilitate operation, particularly by providing early reaction to upstream disturbances.IntroductionThickening is one of the basic unit operations in mineral processing and hydrometallurgy used to separate suspended solid particles from a solid-liquid dispersion by gravity settling. As the dispersion enters the thickener, the solids settle and clarified water overflows the top. A thickener, which may be continuous or batch, is basically a large vertical cylindrical tank provided with devices to feed the dispersion and to remove the settled solids. The tank provides residence time for the particles to settle. The dispersion enters the thickener through the feedwell whose function is to dissipate the momentum of the feed stream and to create relatively quiescent conditions around the entering point. Rotating rake arms move the settled solids towards the discharge point located at the bottom centre of the tank.There are normally three distinct zones in a thickener: a top layer of clear water, a middle layer called a sedimenting zone in which particles are settling, and a bottom layer called a compression zone in which particles are pressed together as a consequence of the weight of accumulated particles. Proper operation of a thickener requires two simultaneous conditions: no solids in the water overflowing the top and the target solids content in the underflow pulp. To achieve these conditions is difficult because sensors for detecting the sediment line (interface between clear water and sedimenting zone) and the solids content in the compression zone are not commercially available."

Jan 1, 1998

By R. Siwik, N. K. Davé

"The national reactive tailings (RATS) program is a co-operative industry-government effort to develop practical techniques for closure of reactive tailings areas. This paper summarizes the RATS program objectives and areas of research, and details the Noranda/CANMET project on the Waite Amulet tailings.Geophysical and biohydrogeochemical investigations were carried out at an inactive copper-zinc mine tailings site, Waite Amulet, in Noranda, Quebec. Geophysical investigations consisted of seismic, electromagnetic conductivity and electrical resistivity surveys to determine the thickness of the layers above bedrock and to map conductivity variations within the tailings and the immediate outlying area. Biohydrogeochemical investigations consisted of installing multilevel piezometer nests to determine groundwater flow patterns and porewater chemistry, obtaining solid core samples and characterizing for physical, chemical and mineralogical parameters, and iron oxidizing and sulphate reducing bacterial counts.The geophysical survey indicated a bedrock ridge extending under the tailings from the northeastern outcrop which may act as a porewater boundary layer. The survey also indicated a 2 to 20 m clay layer underlying the main tailings dam. Preliminary results of the saturated zone porewater chemistry have indicated three major zones of high electrical conductivity varying between 1,000 to 12,000 µs and pH between 3.4 to 8. Lower pH and high metal and sulphate concentrations were obtained in a shallow zone near the water table. With depth, the concentration of metal and sulphate ions decreased and pH increased below the water table. The underlying clay layer is relatively impervious -and most of the seepage from the tailings is probably exiting from the sides of the impoundment dam."

Jan 1, 1987

By Ali Bunjaku, Lauri Pesonen, Hannu Johto

It is well known that there are many ways to process copper concentrates into copper anodes using the pyrometallurgical route. All modern copper smelting technologies are fundamentally energy efficient and environmentally safe options, and therefore choosing one depends on the desired capacity range, feed impurity levels, plant location, flexibility needs, overall energy use, and of course smelter economics in both the short and long term. This paper focuses on comparing different solutions which have potentially the lowest variable opex (operational expense), meaning in practice finding out which technology offers the best chances for profit maximization under certain scenarios. For the comparison, we chose to have a closer look at Outotec Flash Smelting (FSF) – Peirce-Smith Converting (PSC), Outotec Flash Smelting (FSF) – Outotec- Kennecott Flash Converting (FCF), Outotec Ausmelt TSL Smelting (ASF) - Peirce-Smith Converting (PSC), Outotec Ausmelt TSL Smelting (ASF) - Outotec Ausmelt TSL Converting (ACF), Mitsubishi Smelting Process (MIT), Bottom Blowing Reactor (BBR) – Bottom Blowing Continuous Converting (BCC), and Side Blowing Furnace (SBF) - Top Blowing Converting (TBC) since these seem to be the main state-of-art technologies now being applied in many recent copper smelter projects around the world. The work was carried out by modelling each smelting route by using the new HSC SIM 9 simulation software and applying operation time, energy, and consumables consumption numbers for each unit process and stream. Combined with cost data, the exercise produced a rich set of information which will be shown in detail for each area per scenario. The authors’ goal here was to provide a fair comparison where each technology can be evaluated from various perspectives such as electricity use or refractory consumption. INTRODUCTION Copper can be produced either pyrometallurgically or hydrometallurgically. The hydrometallurgical route is used only for a limited amount of the world’s copper production (~20%) and is normally only considered in connection with in-situ leaching of copper ores. On the other hand, most of the copper extraction from Cu-Fe-S minerals is pyrometallurgical (~80%) (Schlesinger 2011, ICSG 2017). Thus, several different processes can be applied for copper production, including the following state-of-the-art technologies: Outotec Flash Smelting (FSF) – Outotec-Kennecott Flash Converting (FCF) Outotec Flash Smelting (FSF) – Peirce-Smith Converting (PSC) Outotec Ausmelt TSL Smelting (ASF) - Peirce-Smith Converting (PSC) Outotec Ausmelt TSL Smelting (ASF) - Outotec Ausmelt TSL Converting (ACF) Mitsubishi Smelting Process (MIT) Bottom Blowing Reactor (BBR) – Bottom Blowing Continuous Converting (BCC) Side Blowing Furnace (SBF) - Top Blowing Converting (TBC)

Jan 1, 2019

By J. Brent Hiskey

At present, approximately 80 % of the worlds mine production of copper is achieved by smelting and electrorefining. The principle aim of copper electrorefining is to satisfy the large demand for extremely pure copper. It is remarkable that high quality copper cathodes with the required purity (99.99+% Cu, ASTM B115-10) and structural characteristics (i.e. deposit density and morphological texture) are produced from impure copper anodes dissolved in electrolytes containing a variety of impurities. This is accomplished with the proper control of operating parameters such as: current density; temperature; copper and sulfuric acid concentration; agitation; substrate preparation; and the application of electrolyte additives. The basic elements of the electrolysis of copper have not changed significantly over the past 150 years since the early developments of James Elkington. Importantly, our fundamental understanding of the underlying electrochemistry has advanced considerably. This is especially true regarding our knowledge of the mechanistic role of additives during the electrocrystallization of copper. This is a very complex subject and modern electrochemical techniques and the development of surface characterization and imaging instruments has helped immensely in our ultimate understanding of how additives control the deposit structure and morphology. The purpose of this paper is to review the historical development and application of electrolyte additives in copper electrorefining and to examine our current knowledge regarding their use. INTRODUCTION The first transatlantic telegraph cable was completed in August 1858. Regrettably, this cable failed shortly after the initial connections. After several more failed attempts, improvements in materials and copper quality resulted in successful communication between Europe and America on July 28, 1866. In many ways this hallmark event demonstrated the need for high purity copper. The first copper refinery in the world was commissioned in May 1869 in Pembrey, South Wales by partners Josiah Mason and James Balleney Elkington. (Historical Note). The 1865 and 1868 British patents issued to James Balleney Elkington were the foundation for the first commercial production of high purity electrolytic copper (Elkington, 1865, 1869, 1870). This important achievement was made possible primarily by the invention of the dynamo which was based on the fundamental operating principles advanced by Michael Faraday. A symbiotic relationship between copper refining and the dynamo was henceforth established. The dynamo provided electric current for electrolytic refining of copper and the electrorefining tankhouse provided pure copper which was required for the generation and transmission of electricity.

Jan 1, 2019

By K. Reinharter, J. Schmidl, D. Gregurek, A. Spanring

Copper smelting furnaces are typically lined with magnesia-chromite refractories, which are exposed to multiple and complex stresses. The selection of the processing route, furnace type and slag system will be dictated by the specific ore type available, this will determine the individual refractory wear. This paper evaluates the common refractory wear mechanisms as observed in the copper Peirce-Smith converter and in the copper anode furnace. The chemical factors include corrosion caused by fayalite type slag and sulfur supply, as well as, by Cu-oxide attack. Changes in the temperature during the furnace operation (thermal-shock) create stresses in the brick lining which can only be absorbed in limited extent. Mechanical factors include erosion, caused primarily by the movement of the metal bath, slag and charging material, as well as, stresses in the brickwork due to punching. Finally improper lining procedures can also effect the service life. All these wear parameters lead to severe degeneration of the brick microstructure and a decreased lining life. Therefore, a detailed investigation and understanding of the wear mechanisms through “post mortem studies” together with thermochemical calculations by FactSageTM software is an important prerequisite for the refractory producer. Based on these research results, combined with specific process knowledge, appropriate brick lining solutions for copper processing furnaces can be recommended. INTRODUCTION The refining of copper includes converting of matte or black copper into blister copper for final fire refining process in the anode section. Typically Peirce-Smith (PS) converters are in use. Other technologies include Hoboken Converter, TBRC but also Flash Converting Furnace and bath smelting furnaces (ISA, Ausmelt) (Davenport et al., 2002). For fire refining two types of furnaces are used – the rotary furnace type is dominantly used in the primary production route while secondary smelters tend to use hearth refining furnaces which are more suitable for scrap melting. Installed working linings are based on magnesia-chromite bricks but especially in the anode refining section the application of alumina-chromia bricks have become more popular in the recent years. It comes without saying that, to some extent, large variations in the slag composition can be observed from the data provided to RHI Magnesita during post-mortem studies of used refractory samples and this needs to be addressed properly during the selection process of refractory linings.77

Jan 1, 2019

By T. Moyo

Ammoniacal solutions are attractive and effective lixiviants for the dissolution of chalcopyrite, allowing for the formation of stable ammine complexes with copper while rejecting iron. Chalcopyrite dissolution in ammoniacal solutions is reviewed from literature, and results from a recently completed study evaluating it through electrochemical and controlled leach studies are discussed. Ammoniacal leaching of copper ores dates back to 1916 in the leaching of low grade copper ores in the Kennecott leaching plant and in the Calumet and Hecla mines, followed by the commercialisation of the Sherrit Gordon process for the ammoniacal leaching of sulphide copper ores in 1948. Since then ammoniacal leaching has received intermittent focus from researchers with the development of the Anaconda’s Arbiter process and the unsuccessful Escondida process. In these leaching processes, the formation of surface deposits has historically been reported to result in the passivation of the chalcopyrite surfaces, whereas oxygen mass transfer in solutions has been the focus of process design improvements. Results of studies on high grade chalcopyrite material is presented in this paper which show that although a surface deposit was formed, it did not result in the passivation of chalcopyrite in ammoniacal solutions, and that while oxygen transfer is critical, it is not the direct oxidant in the reaction. INTRODUCTION Ammonia and its salts have been used in the hydrometallurgical treatment of non-ferrous metals such as copper, cobalt and nickel from oxide ores. Its chemistry allows for the selective dissolution of desired metals, leaving behind gangue including iron. Chalcopyrite is a copper sulphide ore known to be very stable and hence recalcitrant to many hydrometallurgical processing methods. Thus, the dissolution of chalcopyrite continues to be an attractive area of research. The dissolution of chalcopyrite in ammoniacal solutions is possible due to the stabilisation of copper(I) and copper (II) ions by ammonia in alkaline media. Ammonia has become more attractive as a lixiviant during the present socio-economic climate due to its low toxicity, relatively low cost and ease of regeneration by evaporation (Meng & Han, 1996). Ammonia processes are ideal when the gangue minerals are acid consuming e.g. with calcareous or dolomitic gangue (Paynter, 1973).

Jan 1, 2019

By K Byrne, W. Hawker

The average grade of copper concentrate is steadily declining, forcing the industry to turn to lower grade and metallurgically challenging orebodies. When faced with a low grade, challenging ore, mining companies are often forced to choose between high recovery at low grade or low recovery at high grade. Hydrometallurgical processing of copper concentrates using metathesis reactions, which replace iron with copper in copper-iron sulphide minerals and increase the copper to sulphur ratio in copper sulphide minerals, provide an opportunity to upgrade copper concentrates and potentially allow high copper recovery for a high grade concentrate. Factors such as concentrate mineralogy, reaction time and temperature, and the concentrations of copper, chloride and acid in solution are reported to affect the reaction extent and mineral phases formed by metathesis. In this paper, a copper concentrate has been studied over a wide range of conditions to investigate the influence of these key parameters on the extent of copper metathesis reactions and product phases formed. Solution and solid phases are assayed with the main mineral phases identified by Quantitative X-Ray Diffraction. INTRODUCTION The minerals present in copper deposits determine the prospective processing options either: pyrometallurgical or hydrometallurgical. For copper oxide ores, copper is typically present as oxides, carbonate, chlorides, silicates and sulphates. These minerals are readily solubilised in acid and are usually treated through hydrometallurgical processes. The typical process route for copper oxides is to leach copper into aqueous solution, purify and upgrade the solution phase through solvent extraction and then recover copper as metal by electrowinning (Davenport, King, Schlesinger, & Biswas, 2002). Copper sulphide deposits may contain a multitude of copper bearing minerals, including chalcopyrite, bornite, enargite, covellite, digenite and chalcocite. The copper ore grade and treatment options are affected by the mineral type and distribution. Sulphide ores are typically treated through comminution and mineral flotation to form concentrates, followed by pyrometallurgical smelting. Hydrometallurgy can also be used to process sulphides depending on the mineralogy and impurity levels (Davenport et al., 2002). The trend of decreasing copper grade with increasing impurity levels are common across the mining industry and pose future challenges to copper processing. This trend has prompted research into hydrometallurgical options for upgrading copper concentrates. One promising hydrometallurgical option is using metathesis reactions. Metathesis reactions, sometimes also called double replacement or displacement reactions, are chemical processes involving the exchange of bonds between two chemical compounds or species. In this case, the metathesis reactions involve copper in solution exchanging with cations in the solid sulphide concentrate. The driving force for copper sulphide metathesis is the relative affinity of the exchanging cation elements for sulphide. Based on sulphide precipitation diagrams, the expected order of affinity for sulphide should be Hg2+ > Ag+ > Cu+ > Cu2+ > Bi3+ > Cd2+ > Pb2+ > Sn2+ > Zn2+ > Co2+ > Ni2+ > Fe2+ > Mn2+ (Monhemius, 1977). Hence, copper metathesis reactions are capable of increasing copper content and removing impurities such as iron, nickel, zinc and lead from copper concentrates.

Jan 1, 2019

The total current inventory of mature fine tailings is estimated to be nearly 850 million m³. Pressure has come to bear on the industry to accelerate its tailings management practices and prevent this inventory from steadily growing. The present paper describes the treatment, management and reclamation of fluid fine tailings. New technologies being evaluated include: i) Thin layered - fines dominated deposits, ii) Deep - fines dominated deposits, iii) Fines enriched sand deposits, and finally iv) water capped disposal in end pit lakes. A brief overview for each of the methods of treatment and disposal for fluid fine tailings is provided.

Aug 1, 2013

By M. B. McClenaghan

"The Ontario Geological Survey completed a regional till sampling project between 1984 and 1988 in the Black River Matheson (BRiM) area of northeastern Ontario. The project was designed to aid mineral exploration in the area by documenting the Quaternary stratigraphy and by providing a database of till geochemistry. This paper summarizes the results from the sonic overburden drilling component of the BRiM project carried out in areas of thick drift (> 5 m). Results from till sampling in areas of thinner drift (<5 m) have been presented in a separate paper. Approximately 1100 till samples were collected from 225 sonic drill holes. For each sample, the non-magnetic heavy mineral (>3.3 S.G.) and fine (-250 mesh) till fractions were analyzed geochemically and visible gold grains were recovered by panning.Gold and other multielement geochemical data were plotted using proportional symbols to highlight anomalous areas and to demonstrate how to evaluate and interpret a very large geochemical dataset. Thresholds for identifying anomalous concentrations of Au in till samples, defined using the 95th percentile, are 1500 ppb and 12 ppb for the heavy mineral and fine fractions, respectively. The heavy mineral fraction of older ti1ls and to a lesser extent, Matheson Till, display a number of significant gold anomalies in the study area, which in a few cases, are associated with base metal anomalies. The vertical position of gold anomalies in Matheson and older ti1ls varies from directly on bedrock to several meters above the bedrock surface and can provide information of relative ice transport distances."

Jan 1, 1994

By S. Eckert, M. Reuter, O. Keplinger, D. Obiso, N. Shevchenko, M. Akashi

We report on laboratory experiments focusing on bubbling phenomena arising from gas injection through a top submerged lance (TSL) in a liquid metal layer. The objective of this study is to reveal the characteristics of the formation and behaviour of the particular bubbles at different gas flow rates and submergence depths of lance. Visualization was performed in the eutectic alloy GaInSn using X-ray radiography. Argon bubbles were injected through the injection positions at three different submergence depths. Essential parameters such as the bubble size, bubble shape, detachment frequency and the two- dimensional gas distribution in the flat vessel were obtained by image processing. The results show that the deep position of the submerged lance causes an asymmetric large-scale circulation inside the fluid vessel. Bubble detachment frequencies were calculated by Fast Fourier Transformation from fluctuations of the image intensity in the vicinity of the nozzle injection point. This frequency does not show strong variations with respect to changes of the gas flow rate and the submergence depth of the nozzle. An increasing gas flow rate results in an increasing two-dimensional projected bubble area and the occurrence of a significant number of small bubbles being trapped by the strong fluid flow in the liquid metal layer. INTRODUCTION The Top Submerged Lance (TSL) process has been an essential component of the metallurgical industry since the emergence of first concepts about 50 years ago (Floyd, 2005). The process, which is characterized by blowing reactive gas through the submerged lance into a liquid bath, was developed mainly for improving the tin smelting process and has been applied for waste treatment or the production of several metals such as copper, lead, nickel and zinc. The productivity of the reactor is determined mainly by the efficiency of the chemical reaction between the gas or solid particles and the liquid. To achieve a high efficiency requires good exchange between the gas-liquid phase and therefore a large interface area. The efficiency changes greatly with the number and size of bubbles injected from the nozzle and the extent of splashing on the free surface. The degree of turbulence in the bath plays a decisive role here. For the reason, the design of an efficient TSL process requires a profound knowledge of the fluid dynamics especially for complex multiphase flows.

Jan 1, 2019

By R. Stauber, B. Friedrich, S. Hilgendorf, G. Homm, C. Gellermann

Due to recent regulations limiting tolerated lead concentrations in copper alloys, new recycling strategies have to be considered. This study investigates the suitability of technical approaches in order to recycle leaded copper alloys exemplified by CuZn39Pb2 and produce an alloy in compliance with future lead regulations in the European Union. Three pyrometallurgical methods are considered to achieve this goal, namely vacuum distillation, intermetallic precipitation and fractional crystallisation. The impact of essential process parameters i.e. pressure, temperature, time, atmosphere and quantity of additives are identified using thermochemical and kinetic modelling. An experimental implementation reveals a general suitability of all three refining processes. However, the individual efficiency of the different methods strongly differs. Thus, a detailed assessment is carried out in order to provide an evaluation on the efficiencies of these methods from a technological, economical and environmental point of view. Taking a possible industrial realisation into account, the authors recommend the approach of vacuum distillation, although the energy demanded is comparatively high due to the enthalpy of evaporation for zinc, or rather, lead. However, required lead concentrations can be reached quickly without introducing an external element to the material. The prediction of selectivity and evaporation speed, which are immanent variables for a successful implementation, can be validated experimentally. INTRODUCTION In 2016 approximately 1 million tonnes of leaded copper alloy semi-finished goods with an average lead content of 2.1 Ma% have been produced in the European Union (EU). The global production in the same period exceeded 5.5 million tonnes, while the lead concentration has stayed constant at around 2.4 Ma% for the last 50 years. Up to 80 % of the current production volume is covered with end-of-life scraps, which are used for direct re-melting, depending on the alloy composition. Lead has been a popular alloying element in copper alloys in general, and in particular in brass due to its positive impact on various mechanical, physical and chemical properties, especially machinability. Health and environmental concerns were drivers for many governments to implement limitations on lead. In order to further utilise the resource potential of leaded copper scrap, it is inevitable to develop methods to efficiently eliminate lead from circulation as far as possible. (Glöser, Soulier, & Tercero Espinoza, 2013; Soulier, Glöser-Chahoud, Goldmann & Tercero Espinoza, 2018)

Jan 1, 2019

Heap leaching accounts for around 20% of the global production of copper. In heap leaching coarsely crushed ore particles are contacted with an aqueous lixiviant percolating through large packed beds (heaps) of the ore particles, with the loaded solution collected at the foot of the heap for metal recovery, solution make-up and recycle. While dominant for copper oxide acid leaching, it finds application also in copper sulphide (bio) leaching. Despite their apparent simplicity, heaps are in fact complex chemical reactors in which a number of competing sub-processes determine the overall rate of metal extraction. Therefore, meaningful prediction of copper production rates from heaps, as well as operational optimisation and control, all hinge on a comprehensive and quantitative understanding of these complexities. The paper gives a comprehensive overview of the various sub-processes in copper heap leaching and their interactions, including those relating to mineral-particle-solution-gas phase interactions at the micro-scale bulk transport and distribution of solution in unsaturated dense beds at the macro-scale. On the basis of a more fundamental understanding and modelling, the potential for optimized operation offers new opportunities for the extraction of value from both low-grade and complex polymetallic ores. INTRODUCTION Heap leaching is one of the percolation leaching technologies, which includes in situ leaching, dump leaching, heap leaching and vat leaching (Bartlett, 1998). The common phenomenon in all these technologies is the transport of leach solution through a fixed bed of ore particles, which interacts with the solid as it migrates along its path. The target minerals are released into solution and with its flow are carried out of the bed. The targeted dissolved metal species are recovered from solution through various hydrometallurgical techniques, especially solvent extraction (SX), before the barren solution is returned to the leach process. Heap leaching is practised in three main types of applications: sulphuric acid leaching of copper oxide ores, cyanide leaching of gold ores as well as the oxidative acid leaching of secondary copper sulphide ores, usually with the assistance of certain microorganisms and, more recently, in the presence of chlorides (CaCl2, sea water). While gold heap leaching dates back to the 1960s, large scale copper heap leaching commenced in Chile from the 1980s, and sulphide heap leaching emerged essentially as a consequence of acid leaching from mixed oxide/sulphide ores from the 1990s (Watling, 2006).

Jan 1, 2019

By Esa Peuraniemi, Hanna-Leena Heikkilä

Boliden Harjavalta has been operating a copper flash smelter since 1949. Thus, in 2019, the smelter is celebrating its 70th anniversary of flash smelting. Slag formation is an integral part of the smelting process; currently the processing of slag is based on froth flotation at the slag concentrator. It provides high recovery of copper but restricts slag utilization; the final copper slag is deposited in a landfill. The Harjavalta smelter commissioned a new landfill area for final slag in May 2018. This paper describes the full project from permitting to commissioning of a new landfill area. The permitting process is described comprehensively, including environmental impact assessment together with the environmental and dam safety monitoring. During the environmental impact assessment, observations on rare animals protected on European level were made as well as archaeological findings. Successful completion of the permitting allowed the construction phase to start on time. After six years of intensive work, the new landfill was commissioned in May 2018. The new landfill area provides a sustainable way to store the smelter’s slag for decades to come. INTRODUCTION Slag processing Sulphide based concentrates have always formed the main raw material stream at Harjavalta’s copper smelter. During the smelting and converting steps, the iron included in the concentrate is oxidized and fluxed using a silica-based sand. Originally, the slag was processed by using an electric slag cleaning furnace after which the final slag was water granulated. Froth flotation has been utilized for slag treatment since 1966. In the beginning, the slag was cooled in open ditches. In 1984, controlled slow cooling of slag was licenced to enhance copper recovery at the flotation plant. Today, the slag from both the smelting and converting is tapped/skimmed to slag ladles and treated in the following steps: Slag ladle transportation from the smelter to the cooling area by slag hauler Slow cooling of slag in the ladle to allow mineral precipitation Unloading the slag by tilting the ladle; causing the slag to crush as it drops from the ladle Feeding the crushed slag (-500 mm) by wheel loader to a slag concentrator’s feed funnel followed by a conveyor belt transporting the slag to the concentrator plant Crushing and grinding using lump and pebble mills Froth flotation of the valuables Recycling the slag concentrate back to the smelter feed after dewatering Pumping the final copper slag to the landfill area.

Jan 1, 2019

By I. Mc Dougall, H. Joubert, G. de Villiers

The use of sidewall copper cooling systems to prolong furnace campaign life is becoming an accepted technology solution in the base metals industry. Tenova Pyromet has designed and installed a number of sidewall copper cooling systems in base metals furnaces, including the platinum industry. Apart from increasing the furnace campaign life through the formation of a stable freeze lining, a well-designed copper cooling system enables the plant operator to focus more on optimizing the process to achieve throughput and recovery targets, and to accommodate more varied and available concentrate feed blends. The paper discusses the design of sidewall copper cooling systems for copper smelting and converting furnaces to achieve the above objectives. More specifically, the design of copper cooling systems for top submerged lance furnaces are discussed. An overall increase in furnace heat losses has been raised as a concern for intensively cooled sidewalls. The paper explores the overall heat loss expectations for copper cooled furnaces versus traditional refractory lined furnaces. In addition, the potential use of alternative cooling media is discussed. INTRODUCTION Base metal smelting and converting furnace technologies have been evolving continuously over the past century to satisfy the need for higher throughput, improved efficiency, and longer campaign life. To accommodate these demands, in particular higher smelting intensity and throughput, furnace bath containment systems had to improve. The use of pure refractory lining systems has slowly made room for the use of more intensively cooled lining systems (Joubert, Nikolic, Bakker & Mc Dougall, 2016). These cooling systems evolved from external shell cooling, such as shower or film cooling, to copper plate coolers extending into the furnace refractory lining, and high intensity stave or panel coolers (Verscheure, Kyllo, Filzwieser, Blanpain & Wollants, 2006). Consequently, an increasing number of base metal smelting and converting furnaces are equipped with copper cooling systems, including flash furnaces (Bryk, Ryselin, Honkasalo, & Malmstrom, 1958; Yasuda, Motomura & Kawasaki, 2014; Marx, Shapiro & Henning, 2010), top submerged lance primary smelting and fuming furnaces (Bhappu, Larson & Tunis, 1994; Kim, Lee & Lee, 2000; MacRae & Steinborn, 2018), top submerged lance converting furnaces (Viviers & Hines, 2005; Nikolic, Hogg & Voigt, 2018), primary platinum smelting electric furnaces (Nelson, Stober, Ndlovu, De Villiers & Wanblad, 2005; Jones, 2005; Hundermark, De Villiers & Ndlovu, 2006; Mc Dougall, 2013), and electric slag cleaning furnaces (Joubert, Nourse, Masters & Hundermark, 2005).

Jan 1, 2019

By F. F. Roberto

Sulfuric acid has been demonstrated to be an efficient lixiviant for in situ extraction of copper in the past. It has also been proposed that microbial production (by iron-oxidizing acidophilic bacteria) of acidic ferric solution either in situ or ex situ could provide an economic strategy to generate an effective lixiviant for secondary copper sulfides like chalcocite and covellite. Copper heap bioleaching also takes advantage of this approach. One of the major environmental challenges for in situ copper recovery projects is the containment of acidic solution within the ore deposit, and ultimate restoration of the depleted ore body to its original state. A perhaps overlooked aspect of projected site operations is the possibility that transient acidic conditions and pumping of solutions from surface reservoirs into the subsurface could stimulate the growth of iron- or sulfur-oxidizing species of acidophilic microbes in the ore body, leading to additional generation of sulfate, acid, and ferric iron. This outcome would benefit extraction of copper in mixed oxide/sulfide deposits in the near term, but could complicate restoration activities. Possible impacts of pumping acidic solutions into the subsurface on microbes resident in, or introduced into the extraction zone will be discussed in the context of our understanding of copper heap bioleaching and acid rock drainage. INTRODUCTION As high-grade deposits of metals such as copper continue to decline, conventional mining methods have evolved to mine and process larger and larger quantities of ore. What is currently defined as ore today often contains less metal than the tailings of past operations. The throughput of current-day mines also leads to tremendous amounts of waste rock and tailings that may threaten the environment and communities around the mines, as has recently been experienced by 3 major tailings disposal facility (TSF) dam failures in the past 5 years. Community acceptance of large mine operations thus becomes more difficult to achieve—loss of the social license to operate. In response, the mining industry urgently pursues innovations that can fundamentally change the way in which metals are mined. In situ recovery (ISR) of metals represents one approach to a more sustainable mining industry, by virtually eliminating the need for a pit or underground excavation, eliminating the excavation and transportation of ore to a process plant and the ensuing noise and dust that is generated, and any need for waste rock dumps or TSFs. An ISR mine could have very little visible footprint beyond a network of wells, pumps, and piping to transport pregnant solution to a recovery facility, such as a solvent extraction- electrowinning (SX-EW) plant for copper. Some solid waste streams and/or storage ponds may still be necessary to treat and store bleed streams, PLS and raffinate, or as part of groundwater restoration activities. Thus capital and operating investments would be potentially much lower than that required for a conventional mine. In theory production could also be controlled to adjust to subsurface ore grade and match market demand. A not insignificant challenge of in situ recovery is the requirement for an efficient, low-toxicity, and ideally selective lixiviant for the metal that is targeted.

Jan 1, 2019