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By Arkady Senchenko, Yevgeny Zhagun, Yury Kulikov, John Starkey

"The paper contains description of a new project in Russia - gold-processing plant at Aleksandrovskoye deposit (start up in September, 2013). The paper includes a brief description of plant flowsheet, data for material composition and technological properties of ore, as well as information about the achieved parameters of ore processing over the first months of plant operation. The project is interesting because a new semiautogenous mill and a ball mill were purchased on the basis of SAGDesign Consulting Group recommendations after the testing of ore samples characterizing the deposit according to specific years of operation. The plant has relatively small design capacity - 750 000 tpa, but nevertheless is the biggest gold-processing plant in the territory of Zabaikalsky region. Major valuable component in the ore is gold, silver is recovered as a by-product. The ores are very hard to grind. The design grinding flowsheet includes a semiautogenous mill operating in closed circuit with a screen, and a ball mill operating in a closed circuit with hydrocyclones (SAB). Process technology includes gravity processing and flotation with subsequent cyanide leaching of concentrates. Mill operation analysis and conclusions about the compliance of the achieved values to target ones are shown, as well as the accuracy of SAGDesign method when applied to very hard ores of Aleksandrovkoye deposit are presented in this paper. Basic directions of technological flowsheet optimization are also given."

Jan 1, 2014

By Barun Gorain, Aparup Chattopadhyay

"Many double refractory gold deposits are characterized by the dominance of ""invisible gold"" (sub-microscopic gold) as solid solution or as colloidal-sized particles in different sulfides and other phases. These deposits are mainly composed of silicates and carbonates with moderate clay and mica content and with minor amount of sulfides and organic carbonaceous matters. The presence of highly preg-robbing and finely disseminated carbonaceous matter adversely affects gold recovery in leach circuits. Characterization of carbonaceous matters, commonly known as TCM and quantification of gold associated within these carbonaceous matters along with different sulfide and oxide phases is highly complex and challenging. Studies were initiated on various complex ore deposits and also on samples representing various process streams. This paper presents the development of a systematic approach to gold deportment studies using state-of-the-art mineralogy characterization techniques for quantification of invisible and visible metal contents in various species. The relevance of this mineralogy characterization to metallurgy will also be discussed in this paper."

Jan 1, 2014

By Paulo Braga, Carlos Junior, Silvia França

"Lithium is the lightest of the metals, with high reactivity and great electrochemical potential. It has a low thermal expansion coefficient and high caloric value, and it forms very light and resistant aluminium alloys. These properties make lithium an attractive element for use in battery manufacture and glass and ceramics production, in addition to its applications in the aeronautic industry. Today, two sources of raw material are economically viable for lithium production: pegmatite rocks and brine. The world production, in 2012, was approximately 150,000 tons of LCE (lithium carbonate equivalent), almost triple the production in 2000. The forecasted consumption for the current year, 2013, was approximately 162,000 tons of LCE, and for 2020, it could be as much as 280,000 tons of LCE, stimulated essentially by the growth of world production of electric (EV), hybrid (HEV) and hybrid plug-in vehicles (PHEV), the batteries of which are based on Li-ions. With the growth of world demand and increasing prices, lithium minerals such as spodumene, petalite and amblygonite, once considered uneconomical for the production of lithium carbonate, are regaining their economic value. New projects to produce lithium compounds based on mineral sources are being developed in many countries, aiming to produce battery-grade lithium carbonate (99.95% Li2CO3). Although Brazil has large lithium pegmatite reserves, the domestic production of lithium carbonate and hydroxide is very low, at approximately 600 tons of LCE, which represents 0.4% of the world production. The application of these products is mostly in the grease and ceramic industries. The national lithium market is under government protection due to its potential use for nuclear purposes. Thus, the industrialization activities and import and export of ores and lithium minerals, as well as organic and inorganic products, such as metallic lithium and lithium alloys, are controlled by the National Commission for Nuclear Energy (Comissão Nacional de Energia Nuclear - CNEN). The objectives of this work to quantify the real lithium demand in the Brazilian market, considering that a large amount of lithium is indirectly imported in the form of the Li-ion batteries used in equipment such as mobile phones, cameras, tablets, notebooks and e-bikes, and to compare this demand with the current national production of LCE. Finally, some technological alternatives will be discussed, with the aim of increasing the competitiveness of the lithium industry in Brazil."

Jan 1, 2014

By T. Fraszczak, U. A. Peuker, T. Mütze, T. Leißner, A. Wikedzi

The present paper highlights on the comminution and liberation properties of two greisen-type lithium bearing-mica ore blends (L1, L2) subjected to different breakage devices; cone crusher (CC), roller crusher (RC), rotor beater mill (RBM) and a screen mill (SM). The particle size distribution (PSD) of the products from each device were evaluated to search for an appropriate PSD model using Gates-Gaudin-Schuhmann (GGS) and Rosin-Rammler (RR) functions. In order to determine an appropriate function that could better describe the PSDs from the devices used, the coefficient of determination (R2) was used as a criterion. In terms of mineral liberation studies, due to costs, only products from rotor beater mill (RBM) were examined through an automated scanning electron microscope (SEM) technique. It was found that RBM, RC and SM products were better described by the RR model than the GGS model with higher R2 values (0.97-1.0). However, cone crusher products for L1 were better described by GSS model, while that for L2 were better described by RR model. In terms of the spread of size distribution as indicated by RR model parameters, RC products were more uniformly distributed compared to products from other devices, for both ore blends. Also the RBM products were more scattered than products from other devices. The results indicate that the composition of individual ore blends affected the comminution products PSDs since different PSD model parameters were obtained for samples comminuted by same devices. The modal mineralogy of the two ore blends indicate both to be rich in quartz, topaz, zinnwaldite and muscovite. Further, the result indicate that, for both ore blends, zinnwaldite phase is more enriched in the fraction < 250 µm. Moreover, better liberation of zinnwaldite is observed for L1 compared to L2. This could be explained by differences of the two ore blends in three aspects; the nature of mineral association, reduction ratio of the fractions analysed and the nature of spread of the size distribution.

Jan 1, 2018

By M. X. Jia

This paper discusses two mineralogy characteristics that may affect the flotation of sulfide ore. The first one, process mineralogy study on a Cu-Ni sulfide ore shows that valleriite and tochilinite are incline to form on chalcopyrite, pyrrhotite and serpentine surface, and the further guess is that the formation of valleriite and tochilinite may also causes the serpentine transform to talc, so the serpentine surface is a phase of talc or a transition phase from serpentine to talc and this enhances the flotability of the gangue minerals. The second discussion on the flotation behavior of the sulfide minerals from the point of view of the mineral semiconductor character.

Jan 1, 2014

By K. Lillkung

The use of secondary sources has become a very attractive option in the production of platinum group metals as the demand for these metals has increased. One of the promising sources are the spent catalysts, which provide an attractive source as they have relatively high metal content compared with the ores where the metal is originally extracted from. The concentration of platinum group metals in catalytic converters is in the range of 0.1-1 mg/g as the concentration in ores is usually less than 10 ppm. Aqueous chloride solutions are claimed to be a cost effective way in which platinum group metals can be brought into solution and concentrated. In this work the effect of different parameters on the dissolution rates of Pt, Pd and Rh were investigated. The parameters investigated were the Cl- concentration, the temperature and applied potential. Chloride concentrations used were 62.5, 90, 125 and 250 g/l. Temperatures were 25, 40, 60, 80 and 94°C. Potentials were 950, 1050, 1150 and 1250 mV vs. SCE for Pt and Rh and 380, 410, 440 and 470 mV vs. SCE for Pd. Dissolution rates were calculated from the current densities determined by potentiostatic measurements. Thin wire electrodes were used in the measurements. As expected, higher temperature, higher potential and higher chloride content generally increasedthe dissolution rate. However, the effect was nonlinear and slightly different for different metals. The results show that strongly oxidizing conditions are needed in order to achieve reasonable dissolution rates. With the highest chloride content and at potential of 1250 mV vs. SCE and 94°C the dissolution rate of Pt was nearly 1 mm/h, whereas in similar conditions Rh achieved a rate of only nearly 100 µm/h. Similarly, with the highest chloride content and at potential of 470 mV vs. SCE at 94 °C the dissolution rate of Pd was nearly 1 mm/h. Keywords: Pt, Pd, Rh, redox potential

Sep 1, 2012

By R. T. Dec

Current industrial compacting and briquetting practices are largely based on trial-and-error techniques. This paper introduces a two-dimensional finite element model of briquetting process in the roller press. Compared with other modeling techniques used in the past, finite element method offers the most versatile approach because it incorporates adequate information about powder behavior, geometry and frictional conditions and offers predictions for the density distribution, the velocity field, the stress distribution, roll force and torque. More over, when the model includes elasticity, it offers predictions on the internal stress state in the briquette after its exit from the roll. This enables to perform realistic computer experiments which are helpful for establishing the forming cavity geometry and process conditions necessary to produce briquettes with the desired properties. Three forming cavity profiles are analyzed. Results from model are verified on experimental roller press and best cavity profile is recommended for briquetting of sub bituminous coal fines.

Jan 1, 2014

By G. G. Xiong

Water-sealed cyclone is a new efficient equipment to use for grading,concentrating of slurry, it was researched and developed by the Kunming Metallurgy Research Institute in the 1980s , and ac-cessed to the 1990 national invention award and the national patent products (ZL02245313.X ). The equipment and technology are innovative, firstly, we design a set of micro-pressure (0.005~0.008MPa) water-sealed device, which eliminates the gas phase of three-phase of sol-id-liquid-gas of the traditional general hydrocyclone grading process, it only has solid and liquid phases. Secondly, the axial velocity envelope surface which is a factor of controlling the accuracy of grading changes to a wedge rotation; and the interface of upward flow to down flow changes from surface to the solid, it can improve grading accuracy. Thirdly, water-sealed box and catheter devices make the stilling which pass through the cyclone cone centrifugal force fields re-enter the pressure grading zone of catheter. The three innovations make water-sealed cyclone can reduce the loss of overflow and has less mud in stilling product. Because the excellent performance, the water-sealed cyclone has application in non-ferrous metals, ferrous metals, non-metallic and aluminum hydroxide industries for grading, desliming and concentrating since it has successfully developed.

Jan 1, 2014

By B. Rezai

Impeller speed and air flow rate are two influence parameters on coarse particles flotation and collision and attachment angles. So, in this research recovery of quartz particles at four diameter classes carried out and collision and attachment angles investigated. It is found that maximum flotation response was observed at Impeller speed of 1100 rpm and 15 L/h air flow rate. For either more quiescent (Impeller speed<1100 rpm) or more turbulent conditions, flotation recovery decreased steadily. Furthermore, amount of attachment probabilities is calculated using suitable equation. According to this study, with decreasing particle size, air flow rate and impeller speed, probability of attachment increased and with increasing contact angle, probability of attachment increased. For various air flow rates, impeller speed and particle size, collision angle has been calculated. Maximum collision angle obtained at with 15 L/h air flow rate, particle size of 256 µm and impeller speed of 700 rpm and minimum collision angle obtained at with 45 L/h air flow rate, particle size of 545µm and impeller speed of 1300 rpm. In this study, maximum attachment angle, , was around 75 L/h air flow rate, particle size of 256 µm, contact angle of and impeller speed of 1300 rpm and minimum attachment angle was with 15 L/h air flow rate, particle size of 545 µm, contact angle of and impeller speed of 1300 rpm. ?82.72 ?64 cr??33.39 ?90 ?13.0 ?60

Jan 1, 2014

By M. Brozek

The constant of flotation velocity is the value characterizing the kinetics of cyclic flotation. In the statistical theory of flotation its value is the function of probabilities of collision, adhesion and tearing off the grain from the air bubble. The grain ? air bubble collision plays a key role since there must be a prior collision before the grain ? air bubble adhesion happens. The probability of such an event to occur is proportional to the relation of the grain diameter to the bubble diameter. When the grain sizes are given, it is possible to control the value of collision probability by means of the size of air bubbles. Consequently, it is significant to find the effect of physical and physicochemical factors upon the diameter of air bubbles in the form of a mathematical dependence. In the pneumo-mechanical flotation machine the air bubbles are generated by the blades of the rotor. The dispergation rate is affected by, among others, the rotor rotational speed, the amount of air transported to the flotation chamber an time and the liquid surface tension, depending on the type and number of applied flotation reagents. In the proposed paper the authors will present the distribution of air bubble diameters on the grounds of the above factors, according to the laws of thermodynamics. The correctness of the de-rived dependences will be verified empirically.

Jan 1, 2014

By F. Ngoroma

Concentrators processing PGM bearing ores make use of polysaccharide depressants to reduce the recovery of the undesired naturally floatable gangue minerals, mainly silicates, present in the ore. Recent work has shown that high depressant dosages can completely depress naturally floatable gangue and thus prevent it from reporting to the concentrate. These high depressant dosages can, however, have a negative effect on the recovery of valuable minerals present in the ore by reducing the stability of the froth. In order to counterbalance the effects of depressant addition, frothers are added. It is, however, preferable to maintain independent control over bubble size and froth stability which is difficult to achieve with only one frother. An alternative strategy is, to use a blend of frothers, e.g. a weaker frother in combination with a stronger frother. Such a system allows an additional degree of freedom: changing the ratio of the two frothers, that would provide more independent control of bubble size and froth stability. This study demonstrates, through the use of batch flotation tests, how blending low molecular weight alcohols with commercially available frothers impact the solids and water recovery, as well as the valuable mineral recovery and concentrate grade in different PGM ores. Higher water and solids recoveries together with higher valuable mineral recoveries (>90% copper and >70% nickel) were obtained from tests using frother blends.

Sep 1, 2012

By Jianjun Tian, Changjiu Zhang, Chunmin Wang

Two lines of single stage autogenous milling circuits have been installed and commissioned as the primary grinding process for the Sino Iron project where magnetite ore is treated to produce iron concentrate via magnetic separation. Various challenges were encountered during the commissioning and ramp up stages which are discussed in the paper and include treating a highly competent ore in a closed circuit AG mill, operating the largest mills in the world and dealing with a number of engineering issues related to plant operability. Details of how these challenges were overcome are described as well as the observed operating characteristics of the mills and their optimisation through rigorous study, simulation and successful solution implementation. Further potential improvement opportunities are also discussed as part of the ongoing technical program at site.

Jan 1, 2014

By J. T. Liu

Packing in a flotation column is one way to increase separation efficiency and effective descending flotation-column height. In this paper, the difference between filling packing and sieve packing is described, and the flaws of filling packing in flotation columns in industrial application are pointed out. A change of flotation process and its effect on flotation results are reported. Based on sieve-plate filling, a high-efficiency mixed packing mode consisting of screen-plate packing and honeycomb-tube packing has been proposed, with the packing mode optimized in the cyclonic static microbubble flotation column in the separation zone. In the mixed packing mode, the honeycomb tubes are used to reduce the vortex effect at the base of the column and weaken the radial dispersion of jetting bubbles, and the sieve plates are used to comminute bubbles in the separation zone, to lengthen the bubble migration path, and to stabilize the foam layer. The superiority of honeycomb-tube packing is analyzed using bubble-particle collision theory, and the dynamic equations of collision probability are derived. The role of mixed packing in guaranteeing mineral recovery is analyzed by the axial dispersion method, and a dimensionless axial dispersion model is derived. When a high-turbulence flow is maintained, a static separation environment is formed in which secondary mineral processing is rendered more effective. In this way, a nonlinear separation environment is formed in the flotation column. Finally, mixed packing was applied in an industrial test. A large vortex developed at the base of the column. It was observed that the bubbles in the radial flow were homogeneously dispersed, the residence time of the pulp was prolonged, and the froth layer became thick and stable. Based on the test data, it was found that the sieve packing has the potential to yield a product of approximately 25.83% copper concentration with 91.78% recovery from a feed concentration of approximately 0.727%. If mixed packing were used, the product concentration could be further increased to 27.60% from a feed of approximately 0.739% concentration with 93.38% recovery.

Jan 1, 2014

By M. Saghaeian, R. Hejazi, M. Mohammadinejad, M. Zare

"Water quality and quantity at the Tailing Thickening Section of processing plants is considered to be a crucial factor and impacts the performance of several sections. Therefore, gaining stable and effective performance at the Tailing Thickener Section is one of the principal goals of minerals processing plants. Different factors such as: qualitative and quantitative sustainability of plant feed, the balance between the mass of input and output water flow, the dissolving method and distribution of flocculant and the amount of dirt, solid percent of thickener inlet pulp, affect the performance of Tailing Thickener. The present study investigates the successful improvement of Tailing Thickener performance at Jalal Abad Hematite Iron Ore Concentrate plant through optimizing the above operational parameters. For this purpose, the following optimizations have been done: homogeneity and sustainability of plant input feed rates, fine pulp removal collected by the bag filters at the input of the thickener, adding an quietness box before moving the tail pulp into the thickener to reduce the pulp turbulence, replacing flocculant pump and injection pipes, improving water mass balance which leads to optimizing and stabilizing the concentration of input tail pulp into the thickener, adding a mixer to increase the flocculant preparation time, increasing the locations for adding flocculant to thickener from 1 point to 6 points. Applying the above modifications and monitoring the Tailing Thickener performance over the course of months, has led to the improvement of recovered water quality from 500 ppm to 200 ppm, increasing the solid underflow of the thickener from 40% to 48.5%, and similarly, reducing water loss by 60%. Of other important effects, due to improvement of water quality, grade of final concentrate 0.5% increased and because of 73% increase in monthly working hour, concentrate tonnage 55% increased. Finally, sludge thickener optimization has had a significant effect in selecting and designing the dewatering system from the underflow of the sludge thickener."

Jan 1, 2018

By G. G. Dong

This paper presents BF flotation machines in brief which are manufactured by Beijing General Research Institute of Mining & Metallurgy (BGRIMM). Dimensional analysis and similarity criteria have been used to scale up BF flotation machines. These scale-up criteria can be used to determine mechanical structure and hydrodynamic parameters including mixing, solids suspension, air transfer and power and so on. Similarity criteria are used to design 40m3 flotation machine being based on data from 1.2 m3 to 20 m3 flotation machines. Hydrodynamic tests of 40 m3 flotation machine in water are discussed.

Jan 1, 2014

By V. Sheikhzadeh, M. Saghaeian, R. Hejazi, A. Abazarpoor

Green pellet strength including drop number and green compression is highly depended on particles size and shape. The used grinding method, ball mill or high pressure grinding roll (HPGR), directly vary the particle size and shape. Considering mode of pellet crack, green pellet is composed of particle-binder-moisture system. Different type of forces existed in such a system to create a stable green pellet: solid particle interaction, magnetic, binding and cohesive forces in the interface of particle-moisture. The pellet failure can occur at solid-liquid interface and/or through liquid phase. Pellet crack occurs when crack passed through entirely the plane failure. In this research, the effect of particle size and shape of pellet feed on green pellet strength has been investigated. It was deduced that green pellet strength highly improved by increase of specific surface area. The drop number and green compression strength of pellets prepared by HPGR was higher than ball mill. It was found that the main reason responsible for this difference was the particle shape. Capillary force is responsible for part of pellet force and improves by decrease of particle size. Also more elongated shape of HPGR particles resulted in higher capillary force due to thinner interface layer between particles. The less circular shape of particles lead to improvement of capillary force as can be occurred for HPGR particles. The rougher shape of HPGR particles resulted in higher wettability of particles and better diffusion of water among particles. In fact the rougher particles means lower connection angle. Aspect ratio of particles was of great importance of crack growth because the required energy of pellet failure increases directly. The required energy for pellet failure increases by increment of particle aspect ratio. The relationship among crack failure force, roughness and aspect ratio has been modeled considering 3 shape descriptors.

Jan 1, 2018

By L. K. Smith

Flotation work conducted by CSIRO on both single minerals and high-arsenic copper ores from a number of sources, has shown it is possible to produce separate low-arsenic copper concentrates and high-arsenic copper concentrates from high-arsenic copper ores. The procedure involves controlled separations at high or low pulp potential regions exploiting subtle differences in the flotation behavior of the arsenic-bearing and non-arsenic-bearing copper minerals. An overview of several case studies investigating the applicability of the controlled potential flotation approach to the separation of copper and arsenic from sulfide copper ores is presented. It highlights the variables which influence the efficiency of the separation which include mineralogy, liberation and reagent selection. The procedure can produce a saleable low-arsenic copper concentrate, which can be directly smelted without penalty, and a high-arsenic low copper concentrate, which will require further processing. Keywords: flotation, copper, arsenic, controlled-potential flotation

Sep 1, 2012

By Hideki Yamamoto, Norihiro Murayama, Junji Shibata

"Hydrothermal syntheses of zeolite from coal fly ash were carried out by using various alkali sources. NaOH, Na2CO3, KOH, K2CO3 and their mixture were applied for an alkali source of zeolite synthesis. The various physical properties of the reaction product, such as the kind of zeolite crystal, cation exchange property, surface texture and so on, was investigated through the zeolitization reaction from fly ash. The mechanism of zeolitization reaction was considered from these results.Zeolite P(NaP), hydroxysodalite(HS) and chabazite(K-CHA) are synthesized as zeolite species, when fly ash hydrothermally reacts in various alkali solutions at 393K. The crystal structure of the products obtained in NaOH solutions for 3h changes from NaP to HS with increasing NaOH concentration. K-CHA formation in KOH solutions needs 10h of reaction time, which is longer than that of NaP or HS.Dissolution, condensation and crystallization steps exist in the zeolitization reaction from fly ash, and the particle surface of products remarkably changes in each step. The fly ash is spherical particles and the surface is smooth(Fig.1(a)). The dissolution of fly ash occurs in the heating process until 393K, and the particle surface changes like unevenness(Fig.1(b)). In case of NaP, the condensation of aluminosilicate ions takes place at 373-393K, and the amorphous aluminosilicate is deposit on the unreacted fly ash(Fig.1(c)). The crystallization of NaP already begins to occur at 393K and the surface is covered with fine zeolite crystals for 24h(Fig.1(d))."

Jan 1, 2003

By H. L. Liu

With the exploitation of mineral resources, valuable minerals are more and more finer and poorer. Priority reclaiming liberation grind particle under rough grinding, will help to pervert loss of melts, raise dewatering efficiency of concentrate, reduce consumption of reagent. And it is propitious to reduce energy consumption and raise the utilization rate of resources. With the feature of coarse particle?s desorption and deposition, CLF flotation machine has special pulp circulating way, which is not only apply to treat coarse particle but also normal size particle. The paper advanced the history, the design principle, the structure feature and the application of CLF flotation machine.

Jan 1, 2014

By M. Eraydin

Dewatering fine particles (e.g., flotation concentrates) is inefficient, energy intensive and often requires large capital and operating costs. To address these issues, a series of advanced dewatering technologies have been developed at Virginia Tech. These include novel dewatering aids and a hyperbaric centrifuge. Typically, the moistures obtained using these methods are 30% to 50% lower than those obtained using conventional methods, as demonstrated in laboratory and pilot-scale test programs. With another novel dewatering technology that has been tested in bench-scale tests, the moistures can be reduced to levels once believed to be attainable only through the use of thermal dryers. In this communication, test results obtained with these advanced dewatering technologies are presented and compared.

Jan 1, 2014