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By Y. L. Ding, N. A. Warner

Cylindrical pellets made from graphite and chromite mixtures were reduced in high-carbon ferrochromium melts at 1 600-1 695 degrees C, under an atmosphere of almost pure CO. The reduction rate, as measured by gas evolution, increased with increasing melt temperature and graphite addition and with decreasing pellet diameter or height, although reductant particle size had a very limited effect on kinetics. At a pellet size, heat and mass transfer were significant in controlling the early stages of reduction of large pellets while at chromite grain size, gas diffusion was probably a rate-controlling step. The time required for dissolution of unfluxed pellets into the melts was significantly longer than that for reduction. This indicates that pellet dissolution may be the limiting factor in determining the operating parameters for a proposed new process to produce high-carbon ferrochromium using melt circulation

Jun 19, 1905

By S. Vardy

The paper notes that the extraction of 22% of the remaining workable reserves in the north western area involves a risk of spontaneous combustion higher than is normal in Britain. Mining systems have been tailor made in order to minimize the risk of spontaneous heatings, and these systems are described. Well-proved methods of combating spontaneous combustion are referred to, as well as the limitations which now apply to them as the result of the introduction of modern mining techniques. A substantial part of the paper is devoted to the circumstances in which spontaneous combustion occurs underground in the north western area. Several actual incidents which have occurred in the last few years, along with the practical application of the lessons learned, are described. Of particular note are: a) the procedure adopted in the north western area to equalize pressure differences across stoppings using pressure chambers, and b) a retreat mining system, primarily designed to deal with high methane emission and steep gradients, which also affords some protection against spontaneous combustion.

May 23, 1905

By A. J. Naldrett

"Synorogenic mafic intrusions are a common feature of the northern Appalachians. Two sulphide-bearing intrusions in central Maine that have been investigated revealed a number of important features that illustrate sulphide-silicate interaction that relates to magmatic sulphides. The Moxie Pluton is a large mafic intrusion emplaced during the Devonian Acadian orogeny. The Katahdin gabbro is a small mafic body that is probably genetically and temporally related to the Moxie Pluton. Both intrusions were formed bv the intrusion of variably fractionated magmas into irregular chambers and feeder zones. The southern half of the Moxie Pluton contains three small sulphide accumulations, whereas the Katahdin gabbro hosts a large, predominantly massive, sulphide body. Textural evidence clearly documents the magmatic origin of these sulphides.The three Moxie Pluton sulphide bodies are located at or very close to the intersection between the intrusion and the sulphidebearing Hildreths Formation. Sulphur assimilation, suggested by this relationship, is supported by the isotopically light (634S = —8 to —25) and the selenium-poor (S/Se - 25 000-48 000) character of the Moxie sulphides and correlation with the Hildreths Formation sulphides (S34S = —25, S/Se = 25 000-48 000). Isotopically light sulphur (534S = —20 to —21) and high S/Se ratios indicate that the majority of sulphur in the Katahdin sulphide body was also derived from an unexposed country rock source. The volume of sulphide in this example illustrates the potential efficiency of the sulphur assimilation process—so efficient in this case that marked dilution of the economic chalcophile elements resulted from the addition of so much external sulphur.The three Moxie Pluton sulphide occurrences are all impoverished in Ni and Cu (1.87-0.44% Ni; 0.72—0.32% Cu in massive sulphide), but contain normal Co contents (0.22-0.13%) relative to typical magmatic sulphides. The Katahdin sulphides show a greater Ni and Cu impoverishment (0.2% Ni; 0.1% Cu in massive sulphide) with similar Co (0.17%). The Ni content of the Moxie Pluton olivines document the fractional removal of sulphides during crystallization of the host magma, which resulted in the progressive depletion of the chalcophile metals in this magma. Modelling that involved the fractional crystallization of the magma coupled with the fractional removal of a specified proportion of sulphide has successfully duplicated the Moxie Pluton sulphide compositions. A similar magmatic model has been postulated for the Katahdin sulphides with a greater degree of sulphide fractionation. This latter model is again supported by extremely low Ni/forsterite ratios in olivines, though the compositional range is insufficient to document fractionation. These magmatic models are not unique, but they provide a relatively constrained and consistent explanation for the sulphide compositions.The Ni contents of olivines are the most important indicator of sulphide-silicate interaction in mafic magmas and have exploration potential. They provide a means of assessing the timing and extent of sulphur saturation in an intrusion and are a guide to the Ni content of a sulphide accumulation in equilibrium with olivine. In the Maine examples they provide strong evidence of the magmatic origin of the sulphide accumulations and justification for magmatic modelling."

Jan 1, 1984

By P. C. Kapur

Several empirical and semi-empirical laws of comminution, which describe the relationships between the cumulative grinding energy input and the degree of size reduction of brittle solids, have been rationally derived in the time-domain in a unified manner, starting with an integro-differential equation of grinding kinetics. The analysis leads to and provides explicit interrelationships between the energy-size reduction laws associated with Kick, Rittinger, Holmes, Bond, Charles and others, and gives useful estimates of their relative merits and validity. It is shown that Holmes' expression is, in fact, a solution to the grinding equation; consequently, this classical law is compatible with the modern theory of comminution based on population balance on particulate species

Dec 1, 1971

Paper presented at the Mining Institute of Scotland's annual general meeting held in Glasgow, 8th April 1916. Although there is nothing novel or difficult about the sinking described, circular shafts are not numerous in Scotland so the details connected with such a sinking may be of interest. The shaft was sunk at Dykehead Colliery, Larkhall, which has been worked for over 50 years from the upper seams. It became necessary to sink another shaft to serve as a replacement downcast, by which the output might be maintained and some of the lower seams won. As the sandy clays regularly caused bulging into the rectangular shaft and sinking of the surrounding ground it was decided to make the new shaft circular and to enclose its mouth in a foundation-block of concrete resting on the solid clay. Details are given of the sinking, brick seating and lining, kettle strike, water-rings and doorhead lintels as well as the permanent fittings, winding gear and the cages themselves

Dec 1, 1916

By W. H. McAllister

The paper considers the geology and the coalfields that comprise the Scottish south area. It traces the history of known sources of spontaneous combustion and indicates the collieries concerned, with the position of the seams in the geological series where heatings have occurred. The methods of work over the years are described. It relates in detail the circumstances surrounding a fire at Bilston Glen Colliery in the Lothian Coalfield, and the heating at Killoch Colliery in the Ayrshire Coalfield, and the steps taken to deal with them. It also describes some of the difficulties in steep seam working. Methods adopted to prevent spontaneous combustion throughout the area are discussed, and some detail of the UNOR gas analyser is given. Finally, it comments on the present techniques in use in the area, particularly at Bilston Glen Colliery, to prevent spontaneous combustion.

May 23, 1905

By A. D. Read

Selective flocculation was investigated as a possible method of recovering values from mineral slimes which are too finely divided to be treated by conventional mineral processing methods. It has proved possible to flocculate selectively either haematite or a silicate from a stably dispersed mixture by varying the anionic character of the high-molecular-weight, partially hydrolysed polyacrylamide employed. Different separation methods have been developed for hard and soft water media. Electrokinetic and infrared techniques have been employed to elucidate the mechanism whereby selectivity has been attained in the different cases. The following influences on the various selective flocculation parameters have been investigated: (a) the level of the different reagent additions and (b) the shear conditions during and after flocculant addition. A feature of the particular system studied was the high solids content at which it was possible to achieve good selectivity. Probable reasons for this are advanced, and the possibilities and potentialities of the process are discussed.

Dec 1, 1971

By Tuncel M. Yegulalp, Selamet G. Ergelebi

A description is given of a method of analysing modern mining systems in terms of reliability and their effects on productivity. Non-exponential distributions, such as the Weibull and lognormal distributions, for failure and equipment repair times are also considered. The resulting non-homogeneous Markov process is solved by the method of stages. A longwall mining system is analysed as an example.

Jan 4, 1993

By E. A. Brocchi, D. H. Gameiro, P. K. Jena

Carbon tetrachloride was found to be a very efficient chlorinating agent for anatase concentrate, even at the low temperatures that were investigated (250-400 degrees C). For example, at 400 degrees C about 90% of the anatase concentrate was found to have been chlorinated within 60 minutes

Jun 13, 1905

By S. G. Tsimas, A. K. Moutsatsou, S. G. Tsivilis, G. K. Parissakis

(NH4)2SO4 can be used with success as a leachant to remove gypsum contained in celestite ores. The process, which is applied before flotation, provides an upgraded feed and problems related to the simultaneous flotation of CaCO3 and SrSO4 are reduced. The process is independent of the gypsum content of the feed so that each leaching stage decreases the gypsum content by almost 50%. The use of (NH4)2SO4 has an insignificant effect on the co-leaching of SrSO4 (0.45 wt.%) at each stage

Jun 13, 1905

By E. C. I. Hammerbeck

"Geological controls and constraints in space and time define the milieu of the nickel deposits of Southern Africa. Primary, magmatic deposits are of two types, e.g. synvolcanic or syntectonic deposits confined to certain orogenic domains, and those related to intracratonic, post-orogenic magmatism, e.g. the Great Dyke, the Bushveld Complex and the Insizwa intrusion. Epigenetic and supergene deposits form a separate, unrelated group and are of minor economic importance.The metallogenic evolution of syntectonic nickel deposits is particularly well illustrated in the Zimbabwean Province, where the relationships between Archaean greenstone development and nickel mineralization are best illustrated. Volumetrically subordinate, nickel-poor greenstones in the 3500 m.y. old Sebakwian Group are followed by more common komatiite development in the Lower Greenstones (3000 m.y.), and, finally, by very significant komatiites with important nickel mineralization in the 2700 m.y. old Upper Greenstones of the Bulawayan Group. Comparable nickel mineralization is not known in the Raapvaal Province, in spite of ubiquitous komatiitic magmatism of the Onverwacht Group (3500 m.y.) and other greenstone sequences. No komatiitic rocks younger than about 3200 m.y. are known in this region, orogenic activity in the Kaapvaal tectonic province having ceased at about 3100 m.y., whereas the Zimbabwe Province remained tectonically active until at least 2600 m.y.The tectonic environment, host-rock petrology and mode of emplacement, as well as some details of the nickel mineralization, are the parameters employed to classify the Southern African magmatic nickel deposits. A rating of the deposits is introduced that reflects the original resources of the deposit, its average nickel content, its mining history and potential to facilitate ready comparison with and assessment of the nickel deposits listed in the classification, as well as some important nickel deposits worldwide."

Jan 1, 1984

By D. C. Yates, G. V. Jolliffe

In the five coalfields of Staffordshire, there have been some 43 incidents of spontaneous fires and heatings which have required special attention in the past ten years. This total excludes incidents in the Thick Coal Seam of South Staffordshire, which was worked until 1967, and which was subject to an almost continuous series of heatings. The incidents have been classified to show the sites of occurrence, the contributory factors which may have caused them and the treatments applied to them. The remedial techniques, as practised in Staffordshire, are dealt with in detail, with particular reference to standard methods of stopping-off. Precautionary measures taken are described, including a "liability to spontaneous combustion" classification of all seams, and the setting up of an emergency organization with emergency stocks of materials and equipment. The paper is concluded by a few words on the organization and control at the time of an incident.

May 23, 1905

By C. J. V. Wheatley

Recent studies of the mineralisation at Avoca in southeast Ireland, Parys Mountain in Anglesey, and Coniston in the Lake District result in the proposal of a new metallogenetic model for mineral deposits in the Southern Caledonides. A regional pattern of metal zoning exists, an axial belt, including the major copper deposits, being bordered by areas with lead-zinc deposits. Conformable lenticular pyritic zones occur in the central belt, closely associated with acid volcanic sequences and, often, post-dating them. These zones are thought to have been formed in a marine environment, mineral growth taking place below the sediment-water interface, whereas magnetite-rich zones developed under different Eh and pH conditions. Stockworks containing appreciable copper and, in some cases, lead and zinc were developed at a later date, stratigraphically below the pyritic zones, by migrating hydrothermal chloride and metal-rich fluids. Complex lead-zinc-pyrite mineralisation resulted from the reaction between pyritic zones and the final fraction of the hydrothermal fluids. Crosscutting vein-type fissure infilling mineralisation occurs in every mineral field. These deposits apparently comprise a pulsatory metasomatic sequence, closely related to tectono-stratigraphic controls, ore localisation being influenced by the coincidence of suitable structures and pyritic shale horizons. The implications for mineral exploration are considered and it is concluded that the model offers an explanation for the existing pattern of metal zoning; and it may have wide applicability to mineral deposition in geosynclinal sequences.

Dec 1, 1971

By Z Hu

The technique of reclaiming disturbed land by use of a hydraulic dredge pump (HDP) (which is a set of hydraulic machines for earthwork), termed 'digging deep to fill shallow has been used in the reclamation of subsidence areas in Chinese coal mines. This paper discusses the operational principle of the technique and summarises its reclamation procedures, which are being used in current reclamation practice. The soil condition reclaimed by the HDP was studied. The results showed that the pioneer crops to be planted in the reclaimed soil should be the ‘pulse’ family crops, and that improvements to the reclaimed soil and the HDP technique itself are needed. Bused on the analysis of the previous technical processes, a new rational technical model for the HDP reclamation method is presented in this paper.

Jan 4, 1996

By C. M. Lesher, R. R. Keays

"The komatnte-associated Fe-Ni-Cu sulphide mineralization at Kanihalda, Western Australia, is generally believed to be magmatic in origin, but a number of postmagmatic processes significantly modified the original distribution, structure, texture, mineralogy and chemistry of the ores. Two important types of mobilized magmatic sulphides are interpillow/interbreccia sulphides and hydrothermal vein-type sulphides. Interpillow and interbreccia sulphides occur interstitial to pillowed or volcaniclastic footwall metabasalts beneath or adjacent to the stratiform contact ore horizons. They are mineralogically and compositionally similar to massive ores (and are similarly depleted in PGE relative to the compositions of bulk samples of mined ores), but normally do not contain the distinctive chalco-phile ferrochromites characteristic of contact ores. They are interpreted as magmatic sulphides that have been mobilized from the overlying or adjacent massive sulphide layer during peak tectono-nietamorphism.Hydrothermal sulphide-quartz + albite veins also occur in the footwall metabasalt and contain unannealed deformation fabrics indicative of emplacement during retrograde metamorphism. The high Ni and Pd contents of these sulphides (7-13% Ni, up to 70 ppm Pd) indicate that the metals have been derived from the spatially associated komatiites and/or contact ores, consistent with the Pd depletion previously inferred for massive ores. Very low Ir contents and high Pd/Ir ratios of the vein-type sulphides confirm an aqueous transportation-deposition mechanism; hydrothermal transfer of PGE results in strong decoupling of Pd from Ir.There appears to be a complete continuum of sulphide mobilization at Kambalda ranging from whole-scale phy sical dislocation (fault offset ores) and selective mobilization (stringer sulphides) through nietamorphie replacement (interpillow/interbrec- cia sulphides) to jiydrothermal dissolution and redeposition (vein-type sulphides)."

Jan 1, 1984

By M. G. Fleming, F. Warner, R. W. Boswell, M. J. Cahalan

The annual dinner of the Institution was held at the Savoy Hotel, London W.C.2, on 22 April, 1971. The President, Mr. M. J. Cahalan, was in the Chair; members and guests numbered 320. The toasts of The Queen and Queen Elizabeth The Queen Mother, Prince Philip The Duke of Edinburgh, The Prince of Wales, and the other Members of the Royal Family were proposed and loyally honoured. R.W. Boswell proposed the toast of the Institution of Mining and Metallurgy, the president responded, Professor M.G. Fleming proposed the toast of the guests and Sir Frederick Warner replied

Dec 1, 1971

By J. Ostwald, L. T. Matthews, C. E. Loo

Australia has large reserves of pisolitic limonite. Mining recently commenced on the Yandicoogina deposit to produce a high-grade sintering ore. The ore contains about 10 wt% combined water and simulated sintering temperature profiles indicate that progressive dehydration of ore particles occurs in the temperature range 300-700 degrees C. Studies by optical microscopy show that although the dehyrdrated ore particles contain numerous cracks, there is no change in the microstructure of the ore because topotactic transformation to haematite results in the formation of compact masses of very fine-grained haematite microcrysts. When the ore is held at around 1 200 degrees C for 1 min significant recrystallisation of these microcrysts occurs, resulting in the formation of optically visible, micrometre sized haematite crystallites. Studies to simulate the behaviour of ore particles during sintering (as nuclear particles surrounded by a standard adhering fines mixture) show that the recrystallisation process occurs much earlier at temperatures of about 900 degrees C. Further studies indicate that CaO in the adhering fines mixture enhances the recrystallisation of the ore nuclei. The results of the investigation indicate that the pseudo-relict haematite in sinters produced from ore blends that contain significant levels of pisolitic limonite consists of dehydrated goethite that has undergone significant recrystallisation and grain growth, a phenomenon that is facilitated by the presence of lime derived from the sintering melt.

Jan 12, 1992

By J. Drzymala, K. L. Wolters, T. Chmielewski, T. D. Wheelock, D. H. Birlingmair

Microflotation tests were conducted with a modified Hallimond tube equipped with a fritted glass disk and magnetic stirrer to determine whether the results would support an equation that predicts a linear relationship between particle size and the reciprocal of particle density in water for a specified flotation recovery in a given time. Data obtained with the tube for either hydrophilic or hydrophobic solids fit the equation satisfactorily. It was also shown that the natural flotability of molybdenite is somewhat less than that of elemental sulphur and that sodium dithionite is a good depressant for sulphurised pyrite. In addition, it was found that the untreated pyrite and galena used in the study were hydrophilic and did not float by particle-bubble attachment.

Jan 4, 1992

By D. W. Holliday

The major deposits of anhydrite and secondary gypsum in Jamaica occur discontinuously at a single horizon within the Lower Eocene succession of southeast Jamaica. They are not intruded from other horizons of different age, as has previously been supposed. The gypsum and anhydrite occur in a regressive sequence at the junction between marine (Richmond Formation, Halberstadt Volcanics, Halberstadt Limestone) and overlying non-marine (Wagwater Formation) sediments. They are thought to have been formed in an arid supratidal (sabkha) environment. A variety of 'nodular' structures occurs in the gypsum and anhydrite which can be related to early diagenetic processes and compaction effects. All gradations exist between single isolated anhydrite nodules and structureless anhydrite due to closer packing and coalescence of nodules. The structures and textures in the anhydrite are thought to be consistent with penecontemporaneous formation from gypsum crystals rarely more than 2 cm in diameter. Single anhydrite nodules are not usually larger than 2 cm; nodules of greater size are compound, due to the coalescence of several smaller nodules. Some large compound nodules may have developed from single sand crystals or rosettes. Compaction of anhydrite appears to have been largely mechanical, but some rocks have an aligned fabric, suggesting later flowage

Dec 1, 1971

"The Archaean komatiite-associated nickel sulphide deposits at Kambalda, Western Australia, exhibit a number of stratigraphic features that are indicative of a strong volcanic control on ore localization, including (1) a restriction to specific basal cumulate metakomatiite host units, (2) confinement within distinctive synvolcanic embayments in the footwall and (3) variations in the internal structure and composition of overlying and adjacent barren metakomatiite flow's and the distribution of interflow metasediments with proximity to the ore zones.The high magnesium content of the host units (up to 45% MgO volatile-free) in comparison with that of aphyric or spinifex- textured lavas (16-32% MgO) has been considered previously to indicate either magmas/lavas rich in intratelluric olivine or selective accumulation of olivine phenocrysts. The marked linear trend of the oreshoots, basal host units, footwall embayments and the volcanic stratigraphic relationships have been used as evidence for local linear feeding fissures. Rare relict igneous olivine in some host units is, however, demonstrably not intratelluric, and there is no direct or indirect evidence of a proximal eruptive site (e.g. footwall feeders, pyroclastic breccias, ultramafic intrusives) at Kambalda such as at some other deposits of this type. Kambalda is interpreted as a distal rather than proximal volcanic environment.Emplacement of the komatiite sequence at Kambalda was probably controlled by the locations of a few specific eruptive sites relative to regional topographic gradients and influenced by the topography of the pre-existing volcanic surface. Olivine enrichment in the basal host units occurred by in-situ fractionation and cumulus crystallization of olivine during longitudinal lava flow within linear lava conduits, possibly centralized on depressions between non-overlapping footwall basalt flows. The distinctive stratigraphic relationships are attributed to localization of lava conduits along the volcanic pitchline, flanked by more slowly moving parts of the flows. There are analogies with the physical volcanology of Modern basaltic and Proterozoic komatiitic lava flows.A corollary of this model is that the lava conduits thermally eroded and assimilated sulphidic sediments, contributing additional sulphur to sulphur-saturated komatiites or possibly inducing sulphide separation in originally sulphur-undersaturated komatiites. The latter would account for the restriction of ores to linear cumulate komatiite host units (thermally active lava conduits) and the locally mutually exclusive, but stratigraphically equivalent, relationship between the ores and sulphidic metasediments at Kambalda."

Jan 1, 1984