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By F. Tailoka, G. Zhao

Pb is an unwanted impurity in Al for which there is no established method of removal. As it interacts strongly with alkali metals, separation was achieved by adding Na or K to molten Al at 953-1 003 K. Direct Na addition led to considerable evaporative loss but in-situ addition by electrochemical titration from a eutectic NaCl-KCl or KCl-BaCl2 mixture was found far more effective, in some cases reducing Pb content below detection levels within 2 h of titration. K appeared more effective than Na at low Pb concentrations but the use of Na was preferred as it is less toxic and explosive. Na removal from Al-Na and Na-Pb alloys was also carried out electrochemically, the use of these two alloys rather than the eutectic salt as a source of Na avoiding liberation of Cl2 at the anode

Apr 1, 1995

By Schwartz M.

Respect for mining in Botswana is long-standing. This article looks at Africa's most transparent mining regime and some of its ambitious plans. Botswana's mining industry value is forecast to average 5.2% growth from 2014-2018 with solid growth for the diamond sector and acceleration of coal production. Respect for the country's mining regime is maintained in the Fraser Institute 2014 annual survey where Botswana occupies the 26th position of 122 administrations. Botswana's transparency is illustrated by Mupane gold mine near Francistown, Ghaghoo diamond mine in the Gope area and the Morupule coal mine

Mar 1, 2015

By J. S. Mason

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Detailed paragenetic studies of the post-tectonic fracture-hosted vein mineralisation have demonstrated a complex paragenesis, reflecting a multi-phase combination of regional metallogenesis and tectonics through time. Previously published work regarding paragenesis and zoning was oversimplified. Two major epochs of mineralisation resulted in the emplacement of the A1 group of assemblages, from which lead, copper and silver were the main metals mined, and the A2 group, whose galena is only moderately argentiferous but which were major sources of lead and zinc. Tectonic and tentative isotopic evidence points to post-orogenic relaxation as the mechanism for development of the A1 assemblages in the early Devonian, whereas the A2 assemblages are believed to reflect Variscan extensional regimes and regional metallogenesis in the early Carboniferous and Permian

Jun 19, 1905

By P. E. J. Pitfield, S. D. G. Campbell

The regional structure of shear and deformation zones in the belt, which is recognisable in plan view on Landsat TM images, is interpreted in terms of a conjugate-shear model. Gold mineralisation is related to this framework at a variety of scales. The principal recurrent structural geometries hosting deposits at mines such as Motapa, Durban, Charliesona, Cecil, Sunace, Turk group, Queens district, How, Peter Pat, Matabele Sheba, Goodenough, Old Nic and Bushtick are associated with shear zones and folds and include conjugate systems (shears, shear intersections, kink sets), side-step systems (en echelon segmentation, duplexes, monoclinal inflections, antiform-synform couplets) and interactions of the two. Linear sections of shear zones are generally poorly mineralised. The same geometries are identifiable on all scales from local to regional, so sections of regional structural lineaments or areas within mines should be prioritised for further investigation or development on the basis of the gold-bearing geometries observed to be dominant locally

Apr 1, 1996

By P. Golledge, A. D. S. Gillies

An investigation has been carried on samples of three Queensland coal dusts to determine the potential explosibility of dust-gas mixtures. The explosion potential of the samples was classified by the lean and rich limits of explosibility and the limiting oxygen concentrations for each sample. Plotting of these points showed 2-dimensional flammability limit surfaces for coal dust/oxygen, methane/oxygen and coal dust/methane mixtures. From these plots the 3-dimensional flammability envelopes defining the explosibility of the mixtures were defined. The explosion limits of the coal dust/methane/oxygen system were seen to be influenced most by the explosibility characteristics of coal dust. Methane exerted a stronger influence over the explosion limits when the coal had a low volatile content

Jun 19, 1905

By M. Foguenne, A. van Lierde, P. Henry

Leaching experiments were carried out on a spent catalyst sample with a honeycomb structure, containing 47.5% Ti, 5.8% Mo, 2.7% Si, 2 035 ppm As, 52 ppm Pb and 8.8 ppm Hg. More than 93% of the Mo and As was removed by direct alkaline leaching after grinding to 80% -36 micrometres. The residue contained 0.3% Mo and 60 ppm As. To obtain a TiO2 matrix with 30 ppm As, acid leaching at controlled pH with 90 kg/t Al scrap was followed by oxidising alkaline leaching. Treatment of the direct alkaline leach solution or of the mixed solutions from the two-stage process involved two successive operations: purification by neutralisation with Al(OH)3 addition to raise the Al concentration to 4 g/l, and ion exchange on Amberlite IRA 94 S resin. Whatever the type of solution treated, elution with 200 g/l NH4OH solution gave an eluate of very high purity containing 164 g/l Mo, less than 70 mg/l V and less than 2 mg/l As

Jun 19, 1905

By P. A. Davies

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 11pp., 15 refs. Hazards such as vibration, dust emission and fragment projection can result in an area called the Danger Zone being set around a blasting site. Traditionally Danger Zones have been set solely on the basis of consequences (e.g. based on the maximum distance of rock projection or expected ground vibration plus a defined safety margin). Advances in risk assessment and its growing acceptance as a safety management tool have led to the setting of Danger Zones based on both consequences and frequency of occurrence. This allows distances to be optimised on the basis of acceptable risk levels rather than the potential consequences of infrequent events. The setting of a flyrock Danger Zone is used to demonstrate a risk-based approach compared with a traditional consequence approach

Aug 1, 1995

By C. A. Pickles, J. M. Toguri

The refining of two molten Ag-Cu alloys, containing 7.5 and 11.2 mass% Cu, with a borosilicate slag was investigated using both air and pure O2 to determine the effects of the following variables: flow rate of oxidising gas; injection time; mass of sodium borosilicate flux; and injection of the oxidising gas into either the slag or the metal. The results demonstrate that more than 90% of the Cu can be removed with Ag losses of less than 5% and that refined metal with a Cu content of less than 0.5 mass% can be produced. Ag losses to the slag increased with the amount of Cu removed, and a mechanism is proposed to account for this

Dec 1, 1995

By R. A. D. Pattrick, R. A. F. Ixer

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. At Calliachar Burn, 14 steeply dipping quartz-sulphide veins, with and without gold, infill master joints that crosscut gently dipping metasediments and metabasics of the Pitlochry Schist Formation. The wallrock is extremely bleached and enriched in sericite, chlorite and carbonate. Gold grades vary from high with quartz-galena-pyrite to low with galena-chalcopyrite; the gold forms electrum inclusions smaller than 20 micrometres in pyrite or, rarely, arsenopyrite. At Urlar Burn, gold is present in small amounts in 4 quartz-galena-chalcopyrite veins. Although much of the mineralogy is similar to that at Calliachar, there are significant differences in Sb-, Te-, Bi- and Hg-bearing phases. Fluid inclusion data suggest mineralisation occurred over the range 320-140 degrees C, from fluids with significant CO2 and 2-13 wt% equiv. NaCl. Mantle-derived fluids appear to have been generated during the late Caledonian and focused by the Urlar Burn fault

Jun 19, 1905

The reduction of zinc from slags by a molten, carbon-saturated bath was examined in a laboratory study under conditions of continuous slag feeding. The results show that it is possible to reduce the bulk of the zinc from the slag before there is a net reduction of iron. However, the recovery of zinc was not as high as in batch tests performed in an earlier study. Lead in the slag was reduced simultaneously with the zinc to very low levels and was volatilised. Copper in the slag was reduced and dissolved in the alloy. An attempt was made to identify potentially commercial ways of treating zinc slags using an iron bath. The approaches that appear to have the greatest potential are reduction in a batch process using electrical heating and reduction in a continuous process with co- or countercurrent flow of the slag and alloy. In the latter the alloy would be prepared in a separate furnace before being contacted with the slag. The purpose of this would be to superheat and carburise the alloy so that no additional heat or reductant would have to be supplied in the slag-alloy reactor

Jul 1, 1991

By T. J. Serenko

The epithermal deposit is hosted by Tertiary volcanic rocks that lie between mid-Miocene normal faults of the Northern Nevada Rift. Petrographic, laser-ablation and metallurgical observations suggested that the gold occurs in two principal forms: native (and electrum) and disseminated in arsenopyrite. It was proposed that gold is distributed between two parageneses with distinct mineralogical associations. Detailed downhole geochemical study supported the observations. Concentrations of Au, Ag, As, Sb and Se were determined from drill core and reverse-circulation cutting composites and contoured on cross-sections. Gold was indeed shown to have a bimodal distribution with the two parts separated spatially and perhaps temporally, implying that two separate genetic processes acted to concentrate gold at Mule Canyon

Aug 1, 1995

By M. A. Leosson, S. H. Bottrell, R. J. Newton

Sylvite at Boulby is mined 1 140 m beneath the sea and the mine suffers from the influx of water. This is of two kinds: persistent flows originating in the Sherwood Sandstone aquifer and entering the evaporite sequence through fractures in the intervening mudstone, and impersistent flows which are transient in nature and of uncertain origin. Water from the overlying sandstone has become enriched with NaCl and large amounts of KCl and some Mg and Br have been added by interaction with the evaporites. Waters from the transient flows are isotopically distinct from those in the Sherwood Sandstone, being enriched in H and O. They are also saturated with respect to halite and sylvite, but have higher K/Na than the persistent flows and are much more enriched in Mg and Br

Jun 18, 1905

By R. A. Lord, H. M. Prichard

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The complex exemplifies a class of olivine-rich, platiniferous ophiolite complexes generated by unusually high degrees of hydrous melting above a subduction zone. Crystallisation of abundant olivine from unusually picritic magmas produced an exceptionally thick sequence of crustal dunite cumulates. Significant (1-4 ppm) concentrations of Pt+Pd occur where sulphide-bearing dunites are spatially associated with podiform chromite concentrations. In the area north of the Balta Sound, the chromitites appear to lie in distinct stratigraphic zones. A detailed programme of lithogeochemical and soil-rock interface geochemical exploration led to the intersection by diamond drilling of three stratiform horizons of sulphide-bearing dunites and associated precious-metal mineralisation. Patterns of cryptic geochemical layering, at scales from 200 m to less than 1 cm, suggests open-system fractionation

Jun 19, 1905

By R. A. Halatchev

A risk model for assessment of the uncertainty in the forecasts of the planned profit is developed. It is based on the selling price of the metal recovered from the ore and the production per shift of the excavators. These two critical variables characterise the economic and technical aspects of the mining venture. Time-series methodology is used to describe the behaviour of the economic variable, which improves the adequacy of the modelling. A hypothetical open-pit gold mine is used to illustrate the application of the model. Results obtained show that the model is a good alternative to sensitivity analysis in taking account of the stochastic character of the price of the metal recovered from the excavated ore and the production per shift of the excavators used. The model can be extended by the inclusion of new variables that have a probabilistic nature

Dec 1, 1996

By D. W. Taylor, I. W. Farmer, N. Mojtabai

Rittinger's and Bond's descriptions of rock crushing relate the energy input required to fracture rock and the surface energy required to form new fractures to the change in specific surface area of feed and product during comminution. The potential applicability of this approach to blasting is illustrated, using the results of data from bench blasting tests on Pinal schists and production blasting of Carboniferous limestones. The approach contributes to understanding of the mechanisms involved in blasting and to the design of test blasts. A modified form is presented of the relationship between blasting energy, specific surface area of the muckpile and a rock energy constant related to the discontinuity structure of the rock. The modified equation fits observed data and offers a simple basis for further experiments

Jun 19, 1905

By P. G. Flood

A simplified conceptual model shows how the arc flank to arc fringe areas adjacent to ignimbritic centres form a prospective zone for natural zeolites. Large alkaline lakes that serve as the repository of voluminous ash-fall tuffaceous material provide the ideal chemical setting for pervasive alteration of silicic glass to zeolites. The unusually old age of the Escott deposit demonstrates that any silicic volcanic province that contains low-temperature, unmetamorphosed sequences is a potential zeolite exploration target and that age should not be used as a criterion to exclude potential areas. It has also been demonstrated that heulandite and mordenite, formed by diagenetic alteration of silicic glass, do not always change to analcite and albite through the ageing process

Jan 1, 1991

By B. S. Terry, C. L. Harris

Reduction kinetics from slags containing CuO(0.5), ZnO, PbO, NiO and SnO into a Cu-based metal phase were subjected to computer simulation using a previously developed model for the kinetics of metal-slag-gas reactions that assumes mass-transfer control in all phases. The effects were examined of changing bulk Fe oxide activity, gas reducing potential, temperature, Fe content of the Cu phase and metal/slag ratio. The results permit practical conclusions to be drawn about industrial slag-cleaning practice, but the model is still limited in terms of thermodynamic inputs and the idealisation of reaction conditions

Aug 1, 1995

By G. S. Camm

Gwynfynydd is a small, high-grade black shale-hosted vein-gold deposit. The Chidlaw Link Zone is the only area being mined and contains 24 000 t ore grading 15.2 g/t gold. Within the Link Zone a complex vein structure occurs consisting of a mother vein up to 5 m thick and narrow (less than 0.5 m) leader veins. The former shows minor variations in dip, strike and thickness, whereas the latter show marked changes in all three. The leader veins are hosted within the footwall zone of the mother vein and both are composed of quartz with galena, sphalerite, chalcopyrite, pyrite and minor arsenopyrite. The vein system is transected by a series of cross-vein and intra-vein dip-slip faults. Pockets of gold occur at vein intersections or branches and within the complex footwall zone and are often related to variations in vein attitude and/or geometry. The Chidlaw Link Zone displays a complex, erratic distribution of gold mineralisation and a multi-stage history of structural activity, fluid flow and mineral deposition

Jun 18, 1905

By L. Villa, O. Suarez, D. Arias, L. G. Corretge

The deposit comprises two vertical, lenticular bodies emplaced in the allochthonous block of a Variscan thrust. Epigenetic mineralisation occurs as replacement of carbonated volcaniclastic rocks of Cambro-Ordovician age. The dominant sulphide minerals are sphalerite and galena with minor chalcopyrite; the main non-metallic mineral is quartz and there is hydrothermal silicification, chloritisation and sericitisation. Sulphur isotope values for sphalerite and galena are heavy and reflect the fundamental relationship between delta-34S in ZnS and in PbS, suggesting isotopic equilibrium. Four sphalerite-galena pairs yield temperatures between 163 and 218 degrees C, in good agreement with the 187-207 degrees C estimated by the Ga/Ge-sphalerite geothermometer. The ore sulphide was leached by the hydrothermal solution from diagenetic pyrite in the host rocks and disseminated sphalerite and galena in Cambrian carbonates

Jun 19, 1905

By D. Large, M. H. Davies, B. Driedrichs, U. Matzander

Synthesis report on a project carried out under the EC-funded BRITE-EURAM programme. A prototype high-resolution electromagnetic system, based on the theory of controlled-source magnetotellurics, was developed. The electrical source field is fed into the earth by dipoles at preselected frequencies and a multi-channel receiver measures five electric and three orthogonal magnetic fields. Suitable mapping algorithms and spatial filters are applied to the data and a new technique permits calibration during measurement. The system was field tested over a blind orebody, at 250-550 m depth, in the Aguas Tenidas area of the Iberian Pyrite Belt. Ten lines totalling 12 000 m of profile length were completed in seven days and the orebody was identified. Tests in the Irish Midlands suffered from strong electromagnetic interference of cultural origin

Jun 21, 1905