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By G. Cavanough, A. Torrance

Emulsions have been developed for over forty years to become the most common water-resistant explosives used in the mining industry. An emulsion is a common commodity, with many examples in our day to day lives of one immiscible liquid dispersed in another. They have varying degrees of stability from a few seconds to years. What makes their application in explosives unique is twofold. They contain a high concentration of salts in the dispersed phase and also have a far larger volume of dispersed phase than continuous phase. The continuous phase contains at least 75% by weight of an oxidizer such as ammonium nitrate dissolved in water. The crystallization point of these solutions is often >60oC which means that the formation of the emulsion has to occur at an elevated temperature. Once the emulsion is cooled, its structure helps to prevent the formation of crystals in an otherwise unstable system. At room temperature there is a considerable potential for the small oxidizer droplets to crystallize which is countered by the strength of the oil layer and also the size of the emulsion droplet. If the emulsion droplet is too large then crystals can form which may lead to rapid deterioration of the emulsion and overall crystallization, accompanied by a temperature rise as the heat of crystallization is released from the emulsion. The size of the emulsion droplet is critical in preventing crystal growth and subsequent droplet coalescence and emulsion break down. One method of examining emulsions and understanding their structure is to use optical microscopy to measure droplet size and also emulsion deterioration from shearing, temperature cycling and when contaminants are introduced, such as detergents, different oil types, coating agents and dust particles. This paper reports on advanced techniques to quickly assess emulsion quality and stability

Jan 1, 2024

By Tom Paynter

In an underground mining environment, the primary method of firing a blast is using a combination of an electric detonator and a detonating cord to initiate the Nonelectric detonators. This method has been in use since the 1970’s. A firing line is used which can be subjected to damage and the need for constant testing and maintenance.

Jan 1, 2017

By Dirk Voogt, Quentin Steyl, D. Scott Scovira

A South Africa iron ore mine reported a decline in blast performance and ore and waste fragmentation. Preliminary investigation by the explosives services company found that the straight gassed bulk emulsion was breaking down and collapsing inside of some loaded slept blastholes. The bulk emulsion loaded at the subject site was manufactured in country and shipped to various clients throughout the region, with normal function in blasts at other sites. Historically, the bulk formulation emulsion being used at the subject mine site also performed well and without issue. This raised the question, “why is this bulk emulsion now breaking down and not firing in blastholes?”. Iron ore mines are not typically associated with reactive or acidic ground, and ground sample reactivity testing against the emulsion confirmed this. So, if not reactive ground or acidic water, then what is causing the emulsion to breakdown?

Feb 6, 2023

By Ethan Steward, Robert Eades, Kyle Perry

Shock tubes, either gas or explosively driven, are often used for physical modeling of free field explosions or arena testing. The use of shock tubes often requires less setup time of subjects and smaller driving forces to create pressure versus time waveforms similar to that of arena testing. However, the effects of the shock tube cross sectional geometry on waveform properties is uncertain while free field explosion wave propagation and estimation is well studied.

Jan 1, 2018

By J. Pizarro

Any organization that subjects its activities to a continuous improvement methodology, aiming to optimize their processes and services, must be able to adequately measure the results of the implemented changes to pursue better outcomes. This is no different for mining companies. When it comes to blasting, an accurate fragmentation analysis can correlate blast design and rock mass parameters to particle size distribution, enabling us to further analyze the correspondence of specific design patterns, applied to specific rock mass properties and the result in measured fragmentation indicators. Over time, many tools were developed for us to obtain PSD data, albeit each of them had their own shortcomings. The first ones to be developed involved photographing the muck pile including a scale object, uploading those photos to a PC, and using specialized software to analyze each one. As a result, analysts would get a PSD curve that served as reference for the performance of the blast. This method, which is still used, has major shortcomings. The most obvious one is that it is only able to capture a slice of the blast, which corresponds to the exposed section of the muck pile the analyst has access to, and even there its reach is limited to the areas that are safe for getting close enough for placing the scale, which are not many. Consequently, this is a very limited way to get a fragmentation performance assess for a blast. Currently, autonomous systems are capable of taking continuous pictures of the muck pile. Installed on a shovel, conveyor belt or crusher feed, these systems can take a continuous stream of pictures that are later analyzed automatically without the need of human intervention. These systems greatly increase the volume of data and, consequently, we have a PSD curve that is more representative of the blast performance. However, this technology still had issues when trying to sample front end loaders mining operations or getting results from underground blasting due to the inherent difficulties of these operations. New algorithms used for capturing and processing data for front end loaders can overcome the harsh environment of their operations and produce PSD data in high vibration environments and difficult mining angles. For underground mining, algorithms can be used to sample each truck exiting the mine, giving a reliable source of fragmentation analysis that can be traced back to their stope of origin. The development of this technology extends the existing system’s capabilities and helps us in our efforts to improve fragmentation results with each blast.

Jan 1, 2024

By Brian Sandhuas, Robert McClure

All flyrock incidents have the potential to result in injuries or fatalities that can result in loss of company reputation, license to operate with clients, and bear the exposure to high cost liability. From 2007 to 2009, one North American Quarry and Construction Business experienced a series of flyrock incidents. In the spring of 2009, this business declared that the frequency and severity of Flyrock Incidents had reached an unacceptable level. A Flyrock Elimination Program was launched.

Jan 1, 2012

By D. Scott Scovira, Thomas Gustavsson

The potential of hydrogen peroxide explosives was introduced to Thomas Gustavsson and Robert Håkland by Dr Miguel Araos through his development of hydrogen peroxide gel compositions (HPG). In 2020, Thomas and Robert developed a concept project with Boliden Minerals and received Swedish government funding to evaluate HPG technology in a mine environment. The project showed HPG reacted violently with mine mineralization and concluded that HPGs did not offer a commercial solution due to safety concerns. Thomas and Robert engaged with Stefan Nilsson to develop hydrogen peroxide emulsion (HPE) compositions and the process techniques to manufacture them. In 2021, laboratory work produced a promising low carbon intensity, nitrate free, ammonia free, emulsion formulation based on industrial grade hydrogen peroxide and a fuel-emulsifier phase. Design and construction of an HPE pilot plant and underground charging unit commenced. The manufacture of hydrogen peroxide emulsion shares several similarities with the production of nitrate-based emulsions in that the plant is a facility to blend a strong oxidizer solution with a liquid fuel phase into a finished emulsion. A key differentiator between HPE and nitrate-based emulsion is that the manufacture of HPE is a cold production technology in that neither the oxidizer phase (HP) nor the fuel-emulsifier phase requires high temperature heating to prepare raw materials. A successful proof-of-concept HPE evaluation ran from April 2022 to October 2022 at Boliden’s Kankberg underground mine in Sweden. This evaluation demonstrated HPE technology's safety, performance, production, handling, and indicative environmental benefits.

Jan 21, 2025

By Calvin J. Konya

For proper blast design, one must make the assumption that all blastholes release nearly ideal energy. In many types of blasting operations, blastholes release very little useful energy. These blastholes are called malfunctioning blastholes. Recent studies indicate that as many as 30 percent of all blastholes are malfunctioning. These malfunctioning blastholes are not an unusual occurrence.

Jan 1, 1988

By Kai Nielsen

A model has been developed for sensitivity analysis of open pit bench blasting. The model simulates the cost effectiveness of various blasting designs in relation to the equipment used for drilling, loading, hauling and primary crushing. The simulations will give an indication of the optimum powder factor giving the lowest over-all costs for drilling, blasting, handling and crushing.

Jan 1, 1985

By A. Cobbii, M. Kasliki, W. Birchi

The Department of Mining and Mineral Engineering at the University of Leeds has a long history of research into the environmental impacts of blasting from quarries and opencast mines. This paper gives an outline of a detailed case study into the structural damaged induced in a rock walled tunnel with a brick lined crown due to close proximity quarry blasting. The test site Taffs Well Quarry is located in South Wales in The United Kingdom and has a disused railway tunnel situated within the south eastern comer of the quarry site. Quarry development plans included the working of this area and therefore the deliberate destruction of the central section of the tunnel.

Jan 1, 2001

By Sven-Erik Johansson, Gosta Rundqvist, Donald Jonson

In Stockholm a new road traffic system called Södra Länken (Southern Link) will be in operation in late 2004. The total length of the road system is 6 kilometres of which 4,5 kilometres run through tunnels under suburbs immediately south of Stockholm inner City. The new traffic tunnels together with existing Metro tunnels, which mostly are in rock, will be the determining factor for blast design for many projects in the future. To set reasonable and safe permitted vibration levels the Swedish National Road Administration, Stockholm Region and Stockholm Transport Rail System have together financed a project to determine guide levels for blast-induced vibrations in traffic tunnels in rock. The purpose of the project has been to establish guide levels that are appropriate for different types of rock tunnels.

Jan 1, 2004

By John Brennan

Necessity, they say, is the mother of invention. Certainly that sentiment held true during the early stages of explosive engineering. While seaside forts were concerned over static ignition of their black powder caches in the 14th century1, the mining industry in the 1800s were plagued by accidents surrounding the ignition methods for their black powder blasts.

Jan 1, 2011

By Robert Hopler

CHAPTER I. DEFINITIONS AND CLASSIFICATIONS. Definition of Explosives. SECTION 1. The term “Explosive” or “Explosives” whenever used in this ordinance, shall be held to mean and include any chemical compound or mechanical mixture that contains any oxidizing and combustible units, or other ingredients, in such proportions, quantities or packing that an ignition by fire, by friction, by concussion, by percussion or by detonator of any part of the compound or mixture may cause such a sudden generation of highly heated gases that the resultant gaseous pressures are capable of producing destructive effects on contiguous objects or of destroying life or limb, and includes all the articles specifically mentioned in Section 3 herein, and all other similar articles

Jan 1, 2013

By Norman Paley, John Kells

The climate and location of the Red Dog Mine present several challenges to blasting operations. The mine is located north of 68º latitude, in an area of continuous permafrost. Ground temperatures are below freezing year-round and air temperatures range from -40 to 70°F (-40 to 20°C). Because there is no overland access to the mine, the entire year’s supply of bulk explosives, approximately 7,000,000lbs (3,175,000kg) is shipped in by barge during the 100 day shipping season when the port is ice-free. The first week in July is the earliest that new product arrives at the port. Emulsion usage is maximized from mid April through October when surface water fills the blastholes during drilling. This necessitates that a considerable portion of the bulk explosives are stored for 10 months or more before usage. The emulsion is routinely pumped from the ISO containers at temperatures of 20ºF (-7°C). The mine engineers conducted a testing program during the 2001-2 blasting season to identify the bulk explosives best suited for the conditions at the mine. A secondary goal was to decrease the usage of sensitized emulsion, as this is the most difficult portion of the explosives order to ship. To ensure repeatability when transferring the results to the day-to-day blasting operation, the majority of the testing was incorporated into normal blasting operations in the field. The mining methods used at Red Dog Mine make direct fragmentation analysis impractical and performance testing in the field relied primarily on VOD measurements. The products were also tested for their ability to be pumped in cold temperatures.

Jan 1, 2004

By Dr. Bronwynne Victor, Quentin Steyl, D. Scott Scovira

Bulk emulsions and emulsion blends may be formulated with a single salt, dual salts, or multiple salts. Blasting professionals familiar with single salt ammonium nitrate emulsion products may be less acquainted with dual and multiple salt emulsion products that may include calcium nitrate, sodium nitrate, and urea in their formulations.

Feb 1, 2020

By Braden Lusk

This paper includes results from analysis of recorded Acoustic Responses of Structures to Blasting. The analysis was performed to determine specific characteristics of sounds experienced inside homes during blast events. Data was collected in a typical house within the Boone North No.2 Coal Surface Mine in Ashford, WV which was instrumented for several blast vibration and acoustic responses. The instrumentation consists of four acoustic microphones distributed throughout the internal areas of the house and three geophones buried near the house. Two additional channels collect the trigger signal and Air Blast information. For each blast event recorded by the system, the mine blast reports were used to obtain major blast characteristics such as distance from the blast to the instrumented house, weight of explosive used, number of boreholes, delays, and other important parameters. This information allowed study the relationship between the acoustic response and the blast design. From a database of 43 records, five records were chosen for complete analysis. These records were chosen based on distance from the blast to the house, and specific blast parameters. This paper presents the result of the relationship between the frequencies and amplitudes for the entire trace of acoustic records, the response due to ground vibration (GV), and the response due to air-blast (AB). Frequency content was obtained through Fast Fourier Transforms (FFT), using D-Plot software. The records have a typical shape that permits cutting and analyzing each part of the signal with respect to GV and AB separately. Some conclusions are reported concerning the relationship between blast parameters and acoustic response of structures.

Jan 1, 2009

By Per-Anders Persson

TIGERWIN, now on CD, is a user-friendly personal computer code (running under Windows) which determines the detonation and expansion state of an explosive from its known chemical composition. TIGERWIN is intended for users in the mining and commercial explosives industry who do not routinely program or run Fortran codes. The code allows the user to open a window on the computer screen and enter the initial density and the weight percentage composition of an explosive, ingredient by ingredient. Alternatively, the code can balance the composition with one or more ingredient percentages fixed, while proportionally adjusting the others automatically to give a total of 100%. The equation of state and its parameters can be user-selected from several proven and tested versions of the BKW, the JCZ, and the ideal gas equations of state. TIGERWIN allows the user to select several options for different additional calculations, such as determining the constant volume explosion, the Chapman-Jouguet (C-J) point, the detonation Hugoniot, the expansion isentrope from the C-J point, and point calculations with selectable specific volume and temperature. Additional options include calculations of detonation data with one or more ingredients partially reacted, assuming either temperature equilibrium between reaction products and unreacted material, or keeping the unreacted material “cold” at the initial temperature. Thus the code can run both ideal and non-ideal detonation calculations. The code automatically saves the input and output files in a separate directory for future reference. The output from several calculations can be displayed and printed in the form of a comparison table. In it, the key results of up to five calculations with different explosive compositions can be compared. The results from an individual calculation can be displayed graphically and printed with expansion work, pressure, or temperature as functions of specific volume. A complete listing of the details of the calculation results, similar to those from the original Fortran Tiger calculations, can also be displayed and printed. No computer experience is required to run the code and workshop participants are encouraged to bring in their own formulations to try out on TIGERWIN

Jan 1, 2000

By Brent Coleman, Wade Hutchison

The Montgomery Bell Academy project is a parking garage structure topped by a soccer field. This project included expanding parking and moving the present tennis courts. The project is located adjacent to an affluent historic neighborhood that posed some special public relations challenges.

Jan 1, 2012

By Conny Postnpaok, Mark E. Hammele

"A major problem that has continued to plague the surface oil industry is blast induced damage to the coal seam. Atlas Powder Company has addressed this situation through several years of field research in full-scale production environments. Many operations across the United States havebeen evaluated ."

Jan 1, 1989

By Michael Wieland

Work-principle computations for explosions underwater or in rock reveal the way the thermodynamic characteristics of surrounding material influence the resulting shock and heave. To reach total thermodynamic equilibrium under such transitory dynamic circumstances, reactions must quickly readjust to changing circumstances, which works for molecular (military) explosives where the fuel and oxidizer type atoms are originally in close proximity. For non-molecular mixtures with their dispersed zones of oxidizer or fuel, in particle or droplet form, there are numerous unproductive collisions, increasing the wait time required to reach chemical equilibrium. Underwater test data for molecular explosives compare rather well with the shock and heave resolved from the work-principal model, while the non-molecular explosives normally used in mining tend to yield a noticeable discrepancy. Years ago, it was recognized that the underwater shock was lower than expected and the heave was higher than expected for ammonium nitrate fuel oil (ANFO), though their resultant sum for the total work was roughly what was expected. When the readjustment of thermodynamic equilibrium warrants quicker chemistry than occurs in underwater or rock shooting, the time-retarded chemistry reduces the shock and raises the heave within the surrounding material without reducing the total work, unless the reaction retardation is quite severe. This technical complication in reality is a nonequilibrium issue that is difficult to resolve with just thermodynamics, though a rational set of transformation factors is formulated herein to represent those circumstances.

Jan 1, 2008