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By R. C. Bates

Uranium mine workers? daily exposure to radon daughters was estimated by two methods of sampling, detailed and spot-check. Both methods involve time- weighting measured exposure levels to arrive at an average exposure figure. Random sampling, or sampling without regard for the duration of exposure, has proved inadequate for estimating average exposure levels. During the first phase of the study, the breathing zones of eight workmen in three underground uranium mines were sampled for an entire shift; 20 to 36 radon-daughter samples were collected per man-shift, Analysis of these data indicated that a suitably accurate estimate of the full-shift exposure could be made by time weighting a considerable lesser number of representative radon-daughter samples. This analysis led to the spot-check method of estimating full-shift exposures to radon daughters. Additional detailed studies were made in seven mines to Learn more about the full-shift radon-daughter exposures and to test the spot-check method, In all, 617 radon-daughter samples were taken in 10 underground uranium mines during 26 man-shifts, and the spot-check method was tested 35 times.

Jan 1, 1962

By David J. Kusler

A gravimetric method for the determination of carbon dioxide, carbon monoxide, hydrogen, methane, and oxygen in blast furnace top gas is described. Nitrogen may be determined directly by volume measurement or by difference. The method is direct, permits continuous as sampling, and provides an averaged analysis over a selected range of sampling intervals from 1/2 to 24 hr or more. Neither expensive equipment nor specialized personnel are required. The method is suitable for routine analysis, and the results compare favorably with those obtained by established methods.

Jan 1, 1963

By W. M. Dressel

A simple, reliable field test for beryllium in rocks has been developed by the Rolla Metallurgy Research Center of the Federal Bureau of Minas. A small portion of the pulverized rock is fused with a sodium carbonate-sodium hydroxide flux in a wire loop. The fused mass is dissolved in water, a few drops of quinizarin solution are added, and the solution is viewed under ultraviolet light. A pink-to-orange fluorescence reveals the presence of beryllium in a sample containing as little as 0.013 percent beryllium (0.26 percent beryl). INTRODUCTION New and potential uses for beryllium make necessary a more intensive search for this metal, which is so similar to aluminum in its chemical reactions that it is not separated from aluminum in ordinary chemical analyses. The principal ore mineral of beryllium is beryl, a beryllium-aluminum silicate, which contains only 5 percent beryllium. This mineral is so similar to quartz in appearance that it is not always possible to distinguish one from the other in the field. While the distinction may be made easily with a petrographic microscope, few prospectors have access to such an instrument, and fewer still know how to use it.

Jan 1, 1960

By Richard D. Smith

The Bureau of Mines evaluated the emission control methods, including the capital investments and operating cost, necessary for further reducing lead levels in ambient air at the Glover, Herculaneum, and Buick smelter-refineries in Missouri and the East Helena, MT, smelter. The U.S. Environmental Protection Agency (EPA) has proposed more stringent lead in ambient air standards than those currently in effect. This report presents theoretically achievable lead emission reductions and estimated capital and operating costs. Lead emission inventories theoretically can be reduced from 1985 levels by 2,421 lb/d at the three Missouri operations by containing and filtering fugitive emissions within structural enclosures and baghouses. The aggregated capital and operating costs in 1986 dollars using conventional environmental and workplace technologies are estimated to be $250,014,100 and $18,507,800, respectively. Estimated total incremental cost is $0.063/lb as refined lead. Additional regulatory costs attributable to Occupational Safety and Health Administration (OSKA), U.S. Department of Labor, workplace standards are included since proposed environmental controls may otherwise degrade workplace conditions. Continuous drossing is evaluated as an alternative to conventional OSHA controls. Substituting continuous drossing for conventional work- place technology results in an estimated aggregated capital and operating costs of $258,344,800 and $15,719,600, respectively. Estimated total incremental cost is $0.062/1b as refined lead. For comparison, the average open market price of refined lead during the first quarter of 1986 was $0.184/lb.

Jan 1, 1987

By T. Estelle Gardner, A. R. Taylor

Heat capacity measurements were made on sodium bromide ( NaBr ) and sodium iodide ( NaI) in the temperature ranges of 7 ° to 300 ° K and 56 ° to 300 ° K using an adiabatic calorimeter . Smooth values of heat capacity, entropy , enthalpy function , and free- energy function were calculated from the heat capacity data at 10° K intervals and at 273.15° and 298.15° K. Entropy and free energy of formation values at 298.15° K also were calculated for the two compounds using entropy values determined in this study and other data reported in the literature . The entropy values calculated at 298.15 ° K were 20.75 ± 0.06 entropy units (eu ) for sodium bromide and 23.55 ± 0.07 eu for sodium iodide .

Jan 1, 1964

By Charles L. Kimbell

The year 1986 was not a good year for the world's mineral industry from several viewpoints. Levels of production, both of crude minerals and processed forms, registered declines in the cases of a greater number of commodities than the number that recorded increases. The overall value of world crude mineral production was estimated to have increased, but only very slightly in terms of constant dollars to nearly $997 billion. Although there were modest increases in the consumption of all major fuels and most major metals, the latter at least apparently resulted more from drawdowns of inventories than from increased production (fuel consumption increases did come from higher output levels), and consumption of most major fertilizer and chemical commodities (nitrogen, phosphate, and sulfur) were at lower levels than those in 1985. Prices for a number of mineral commodities declined, headed by the very substantial drop in world crude petroleum prices, but also including downturns for a number of metals and industrial minerals as well. There was insufficient information to reliably fix the level of the dollar value of world trade in minerals, for while output was up in the case of some large-volume materials such as iron ore, coal, and crude and refined petroleum, suggesting that the volume of trade in physical units may have increased, declining prices may well have offset quantitative gains.

Jan 1, 1988

By D. J. Hawk

The mechanical properties of coal are often represented by the orthotropicmaterial model, which consists of nine elastic constants. The material symmetries involved are found in coal primarily because of the natural process by which it was formed. In this thesis the material properties of five U.S. coals, as obtained from cubical testing, are examined, using as a basis for comparison the assumption of the orthotropic material model. An analysis is performed on each set of coal material data in order to examine its conformability to other, less complex material models, these being the transversely isotropic model consisting of five elastic constants and the 'isotropic model consisting of two elastic constants. In addition, the material properties of two American shales are analyzed, based on the assumption that they comply with the transversely isotropic model. An analysis similar to that performed on the coal material is applied to the shale in order to determine the conformity of its material properties to the isotropic model.

Jan 1, 1980

By Harold M. Smith

Among the more important raw materials now utilized for the commercial production of synthetic organic chemicals is natural 'gas. Natural gas has been used as a fuel and source of energy almost from its discovery, but its potentialities as a chemical raw material were not realized until recently. Research in the use of natural gas for Chemical synthesis received great impetus from the discovery by Brooks and Humphrey4/ in 1918 of alcohols in the diluted ?acid oil? obtained by sulfuric acid treatment of cracked petroleum distillates. Experimental data soon showed that hydrocarbons from natural gas could be converted to these same products. Laboratory methods for chlorination of natural-gas hydrocarbons, particularly of methane for the production of methyl chloride, methylene chloride, carbon tetrachloride, and chleroform were known before that time but were not developed commercially. Methods for obtaining alcohol by oxidation of hydrocarbons derived from natural gas also were known before 1918 but had not received commercial consideration. Since 1918, and particularly during the past 15 years, the work of chemists and chemical manufacturers throughout the world has resulted in an accumulation of data regarding the reactivity of natural-gas hydrocarbons, and related hydrocarbons found in refinery gases or made synthetically. These data have been used to develop methods for converting hydrocarbons into chemical products and thus form the basis for a large and growing industry.

Jan 1, 1947

By J. G. Walters

Analyses of light oils produced from the fluidized carbonization of coal at 485°, 550°, 600°, and 660° C are presented. Tar vapors from 485 C fluidized carbonization were thermally treated at 600°, 700°, and .800° C, and the analyses of light oils produced by this treatment are also presented. Procedures were developed for analysis of coal carbonization light oil by gas chromatography to permit a more definitive analysis than can be obtained by the conventional distillation procedure. An increase in low-boiling olefins, benzene, and toluene, a decrease in low-boiling paraffins, and little change in the remainder of the aromatics was observed with increased temperature of carbonization.

Jan 1, 1965

By B. J. Moore

This publication contains routine analyses and related source data for 419 natural gas samples from 22 States collected during calendar year 1964 as part of a continuous survey of the United States for occurrences of helium in natural gas. This survey has been conducted by the Bureau of Mines since 1917. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4863/ and 576.4/ Six previous publications have been made to present the results of 6,293 gas analyses made by the Bureau of Mines, Helium Activity, prior to 1964. The first three, Bulletins 486,5/ 576,6/ and 617,7/ contain analyses and related source data on 5,214 gas samples collected from

Jan 1, 1966

This report briefly describes the broad program of research and technologic work conducted by the Bureau of Mines on coal and related subjects during 1966. In addition to n description of investigations on mining, preparation, and utilization of coal, an account is given of the Bureau's work in mine health and safety, coal resources, mine explosives, and environmental conditions relating to coal mining and utilization. Details of most of the projects are reported in publications cited throughout this report. Centers and laboratories conducting the coal research and related investigations appear in appendix A; organizations, institutions , and companies contributing to the Bureau's coal research and technologic program are listed in appendix B.

Jan 1, 1967

By G. E. McElroy

"while investigating the presence of heavy strata gases* in certain mines of the East Tintic mining district of Utah, a small, local body of light, very hot gas of high-nitrogen composition was noted in one of the mines. Observations and analyses indicate that this light gas was resulting from very rapid oxidation of finely disseminated pyrite, in lead-silver sulphide ore. The gas was actually mine air which had lost a large proportion of its oxygen content by reaction with the pyrite. This body of gas was hanging in a local high spot about 5 by 5 by 5 feet in size, caused by caving, at the end of a crosscut. Fifty feet from this spot, an air current of 6000 cubic feet per minute was entering the 5 by 7 foot cross-cat from a raise from below.On account of the vapor contained in the gas, the bottom level of the gas could be plainly seen and was practically a horizontal plane, but of slightly wavy appearance, coinciding with the point where an acetylene light was extinguished. This body of gas was visited on three occasions and samples obtained by means of evacaated bulbs and by water displacement. The temperature of the gas was ap¬proximately 175 degrees P. on all three occasions, so that sampling required thick gloves and quick action. Air three feet below the vapor line had a temperature of only 120 degrees F., and a relative humidity of 27 per cent. The stratification of the air and gas mixtures was so sharply defined that the sampler could hold his head a few inches below the vapor level for an appreciable period of time without any noticeable effect other than that due to the high temperature. At one foot below vapor level, it was 135 degrees F., and the relative humidity was 30 per cent. When a candle and an acetylene light were raised into the gas from below, the candle flame was extinguished at a point two inches lower than the acetylene flume, indicating a drop in oxygen content from about 16 per cent to 12 per cent (oxygen content of normal dry air 20.05 per cent) in the distance of two inches."

Sep 1, 1921

By W. P. Yant

This report describes result of a study of the carbon monoxide and particulate matter in the air of the Holland, Tunnel and metropolitan New York made by the Bureau of Mines (which had participated in the development

Jan 1, 1941

By Clarence Karr

RESINS from a bituminous pitch, a bituminous coal, a lignite tar, a subbituminous pitch, and an electrode binder pitch wore investigated by the Bureau of Mines. The compositions of these resins were determined by four independent methods of structural detemination: (1) Molecular formula and ring analysis, including ring (2) infrared and ultraviolet spectra; (3) combined pyrolysis/gas chromatography, and (4) catalytic dehyrogenation followed by spectra and pyrolysis. The resin structure was correlated with coal structure, and it was concluded that pitch resins probably consist of essentially unaltered coal molecules carried over with the tar vapors in low-temperature carbonization.

Jan 1, 1966

By R. W. Stahl

A survey of firefighting facilities and practices in coal mines conducted by the Bureau of Mines3/ showed such variations in equipment and apparent attitude toward fire protection that a comparison with other industry seemed advisable. Although other industry is confined generally to surface operations and the hazards probably are not as great, the same general methods of extinguishment are employed, so that the cost and protection at least should be comparable. An investigation of industry other than mines revealed a generally greater emphasis placed on fire-combating equipment, fire-brigade training, fire-fighting facility inspection, and fire-hazard elimination, as well as a greater average expenditure for fire protection.

Jan 1, 1959

By Wesley Hermanson

Canopies were designed, fabricated, installed, and demonstrated for mining machinery in 3-foot coal seams. A Wilcox PJ20 Auger miner, a Wilcox Bolter, a bee Norse 245 miner, and an Elkhorn Scoop AR3 modified to AR4 were fitted with canopies. The Wilcox Bolter canopy was hydraulically adjustable in height; the rest were manually pin adjustable. The machine operators' comments were adverse in each case. Restriction of visibility and body constriction into unaccustowed and tiring attitude were major objections, causing increased hazards and fatigue. Recommendations are made that roll bar protection be furnished in place of canopies for 3-foot seams to provide partial protection by deflecting and supporting roof falls but not covering the head of the operator. In this way, the effect on visibility would be minimized and fatigue from body restriction would not be increased.

Jan 1, 1976

By Forrest T. Moyer

In 1969, the number of fatal injuries in the coal mining industry was lower than in any previous year and the number of nonfatal injuries was lower than in any preceding year except 1968. Fatal injuries in 1969 totaled 203 with frequency rates of 0.85 per million man-hours of worktime and 0.36 per million tons of coal These rates were new annual lows. Nonfatal injuries totaled 9,917 with frequency rates of 41.76 per million man-hours and 17.42 per million tons. The severity rate for fatal and nonfatal injuries combined was 7,359 days lost or charged per million man-hours. The average severity was 173 days lost or charged per injury. These statistics represent the injury experience of an average of 133,302 employees per day working an average of 225 days in 5,955 coal mines for a total of 237-5 million man-hours worked and a coal output of 565 2 million tons

Jan 1, 1973

By D. K. Steele

The domestic primary copper industry generates in excess of 600 million t of mining and mineral-processing waste annually. Most of the waste poses negligible environmental threat, but a small fraction, because of toxic or corrosive characteristics, may be subject to regulation under Subtitle C of the Resource Conservation and Recovery Act (RCRA) or other pertinent regulations. Among the wastes generated by various copper producers are flue dusts, slags, refinery-bleed solutions, and. acid-plant wastes. The U.S. Bureau of Mines (USBM) has researched methods to mitigate the environmental threat posed by copper-processing wastes while recovering valuable metals from these materials. Acid-leach processing of flue dusts has been demonstrated feasible along with sulfide treatment of liquid refinery wastes and acid-plant-bleed and gas-cleaning solutions to precipitate dissolved metals. In, addition, the feasibility of removing copper and molybdenum from slag, as well as stabilization of precipitated sulfide wastes by vitrification, have been investigated.

Jan 1, 2010

By N. E. Hanna

Originally developed for use in coal mines where on-shift blasting with explosives was prohibited, compressed-air blasting has been used for the past 15 years as a substitute for fixed explosives. With the current commercially available compressed-air systems -Airdox and Armstrong -coal is dislodged by a high-pressure discharge of air from a pressurized shell placed in the coal borehole. In the original systems stationary compressors were mounted on the surface or in the underground ventilated areas. These proved so successful that a mobile compressor unit was developed for use at the working face. Because of the possibility that such a unit might operate in a gassy atmosphere, the Bureau of Mines has investigated the hazards associated with operation under conditions where firedamp could accumulate in explosive concentrations. ACKNOWLEDGMENTS Grateful acknowledgment is made of cooperation of C. E. Carter, H. R. Hiller, R. E. Kennedy, H. Kohn, H. D. Metzinger, J. Mahoney, J. Nickovich, G. So Scott and I. Spolan in the experimental work.

Jan 1, 1956

By W. T. Millar

"INTRODUCTION The purpose of the Star Lake project was to investigate, by geophysical surveying and diamond drilling, the magnetite deposits in the northwestern Adirondacks, the ultimate objective being to increase iron production in eastern United States,ACKNOWLEDGMENTSIn its program of investigating mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to the national security and economy. It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclu-sion. The Mining Branch, Lowell B. ""Moon, chief; conducts preliminary examinations, performs the actual investigative work, aid prepares the final report. The Metallurgical Branch, Oliver C. Ralston, chief, analyzes samples and performs beneficiation tests.The chemical and spectrographic analyses included in this report were performed at the Eastern Experiment Station of the Bureau of Lines at College Park, Md., under the general supervision of J. B. Zadra, chief, College Park Division, Metallurgical Branch, and under the immediate direction of Dr. Alton. Gobriel in charge of the laboratory service unit.The mineral exploration was under the general supervision successively of John D. Bardill, district engineer, and McHenry Mosier, chief, College Park Division, Mining Branch. The work was done under the immediate supervision successively of J. P. Ryan, N. A. Eilertsen, and W. T. Millar, project engineers."

Sep 1, 1947