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By V. L. Burdick

A literature review of current uses of Mn02 in ceramic applications with suggestions for future research. Historical background, oceanographic distribution, geology, exploitation, law and politics. Uses of Mn02 in ferrites, semiconductors, catalytic processes, thermo-luminescence and photochromic materials. Select bibliography of 33 items, plus 129 references.

Jan 1, 1980

By Alexander E. Morrow

Oxygen breathing apparatus for use in mines was introduced to the United States in 1907. Despite their intended purpose of safeguarding lives, the apparatus led to the deaths of many men because of inherent or developed defects in the equipment, lack of training,, physical shortcomings of wearers, and improper procedures. The Bureau of Mines pioneered in research and training to curb logs of life among users of such apparatus and promoted development of safer equipment and procedures. As a consequence, deaths have been far less frequent. In 1944 the Bureau issued Information Circular 7279, Loss of Life Among Wearers of Oxygen Breathing Apparatus. That publication listed the case histories of 26 deaths that had occurred since the introduction of such equipment to American mining. The author, the late G. W. Grove,3/ asserted that further loss of life could be avoided if good equipment were used, teams were properly trained, and the basic principles of safe procedure were followed. This publication is a sequel to I.C. 7279 and contains information on eight deaths among wearers of oxygen breathing apparatus that were overlooked in the original compilation. It also describes the single death that occurred since I.C. 7279 was published.

Jan 1, 1959

By J. A. Woolf, E. S. Leaver, N. K. Karchmer

"In the cyanidation of silver ore, the need of oxygen is well recognized. Various methods have been introduced for supplying the oxygen. In usual practice, air is the source of oxygen and the methods of application are mechanical.This article gives the results of touts made to show the rate of dissolution of silver from each of the common silver minerals in cyanide solution, under conditions similar to those used in the practical recovery of silver from its ores. The effect of oxygen in aiding the dissolution of the silver from each mineral is also shown by a comparison of the methods of supplying the oxygen. Oxidation by preliminary roasting (500°C.) of each mineral sample gives the maximum extraction of the silver by treatment with cyanide.Each silver mineral5 used in these experiments was as pure as could be obtained from the mineral dealer. In their natural occurrence, silver minerals are not usually free from mineral impurities. They are usually closely associated with other minerals often forming, a complex mixture. The form of crystallization, the proportions, and properties of the diluent that incases or has been dispersed with the silver mineral may decidedly affect the dissolution rate of the silver from each mineral. While the following results should aid in the cyanidation of silver ores, each ore should be studied from the basis of the form and condition of the silver that is to be recovered.All the tests reported in this article were made on synthetic samples, prepared by mixing the particular silver mineral with clean sea sand. Each mineral was ground in an agate mortar to pass 100-mesh before mixing with the sand which had previously been ground in a porcelain pebble mill to 100-mesh. Such proportions of each mineral and the sand were used as to give a head assay of approximately 20 ounces of silver per ton to the synthetic sample.Agitation was carried on in stoppered bottles approximately one-third full of pulp, method apparently supplied all the atmospheric oxygen that would be taken up by the solution under usual conditions, because tests conducted in open bottles did not show increased recovery,"

Jan 1, 1931

By G. E. McElroy

Tae purpose of this paper is to present types of charts adapted to aid in the graphic solution of fan-performance problems of selection and operation, and to urge the adoption of similar charts by the National Association of Fan Manufacturers as standard forms for presenting fan-performance data. As matters now stand, it is difficult for the average engineer to solve such problems because a laree number of variables are involved, and performance data are not presented in a manner that permits their direct application to many problems encountered in practice. The performance of any centrifugal machine is determined not only by the machine itself but also by the fluid-flow system on which it operates. Actual performance of centrifugal fans is therefore e matter of the type, size, and speed of fan, on the one hand, and of the relation of pressure to quantity of flow, as determined by the physical condition of the airway system, on the other.

Jan 1, 1936

By G. E. McElroy

[The purpose of this paper is to present type: of charts adapted to aid in the graphic solution of fan-performance problems of selection and operation, and to urge the adoption of similar charts by the National Association of Fan Manufactures as standard forms for presenting fan-performance data. As matters now stand, it is difficult for the average engineer to solve such problems because a large number of variables are involved, and performance data are not presented in a manner that permits their direct application to many problems encountered in practice. The performance of any centrifugal machine is determined not only by the machine itself but also by the fluid-flow system on which it operates. Actual performance of centrifugal fans is therefore a matter of the type, size, and speed of fan, on the one hand, anti of the relation of pressure to quantity of flow, as determined by the physical condition of the airway s: stem, on the other.]

Jan 1, 1936

Major activities of the Bureau of Mines Explosives Research Center during fiscal year 1966 (July 1, 1965 to June 30, 1966) are reviewed briefly. Part 1 summarizes significant accomplishments of the projects that were active during the report period. Part 2 presents short abstracts of the publications that appeared in the Bureau series and in other media during fiscal year 1966. Publications issued after June 30, 1966, are noted where pertinent in foot- notes but are not abstracted. ACKNOWLEDGMENTS The Bureau of Mines gratefully acknowledges the support given through cooperative agreements by the following organizations to investigations conducted by the Explosives Research Center during fiscal year 1966: Manufacturing Chemists' Association. The Sulphur Institute.

Jan 1, 1967

By D. Harrington

The record of fatalities from mine explosions in the United States during the past 3 years has been the best in the history of the mining industry. During these 3 fiscal years, mine explosions have resulted in an average of 4I0 deaths per year, as compared with an average of 153 deaths per year for the preceding; 5 years; an average of 542 deaths per year for the 3-year period 1907-09, inclusive, just before the organization of the U. S. Bureau of Mines; and a yearly average of 265 deaths per year for the 20-year period prior to 1929. This remarkable reduction in deaths from mine explosions demonstrates clearly that mine explosions can be controlled; in fact, they can be prevented when or if the mining people of the United States see fit to take the readily available precautions necessary to bring about this desirable objective. Several large coal-producing States, which in the past have had numerous disastrous explosions, have been free from such disasters for continuous periods of as much as 6 years or even longer. The bituminous mines of Pennsylvania, the largest coal-producing State, give a good example of what can be done to prevent explosions; this State has had only one major explosion (and it resulted in 7 fatalities) during the past 6 years, and no explosion occurred in the several hundred bituminous-coal mines of the State during the past fiscal year. This is a truly remarkable record when compared with past performance in any year in the operation of coal mines in Pennsylvania.

Jan 1, 1936

By Jr. Reed

Cassiterite was discovered in Coosa County, Ala. in 1880 by Judge John S. Bentley. Since that time intensive surface prospecting has revealed the presence of cassiterite in pegmatite bodies that occur in a zone about 20 miles long and 3 miles wide. Numerous trenches and test pits and several shafts were sunk, and one attempt was made to nine and concentrate the cassiterite commercially. The problem of a domestic tin industry and the question of the extent of the Alabama tin deposits have long been of public interest and concern. The deposits have been examined by numerous geologists and several governmental agencies, including the Geological Survey of Alabama, the Geological Survey and the Bureau of, Mines. of the Department of Interior, and others. The Bureau of Mines and the owners of the properties, Charles A. Dean and Robert A. Russell, investigated the Coosa County tin deposits under a cooperative agreement from October 1, 1948, to June 10, 1949. Sixteen hand trenches totaling 527 linear feet and 33 machine trenches totaling 6,780 linear feet were dug. Two shafts wore sunk for a total of 72 feet, and 44.4 feet of drifting was done. Thirty-one diamond-drill holes totaling 2,776 feet were drilled.. Four hundred thirty samples, representing 1,192.6 linear feet, were taken for assay and wore analyzed by the Southern Experiment Station at Tuscaloosa, Ala.

Jan 1, 1950

By D. Bienstock

Using a nitrided fused-iron catalyst, the Bureau of Mines investigated the Fischer-Tropsch reaction in the oil-circulation process. The nitrided iron was quite stable and permitted the longest run obtained thus far in the oil-circulation process without the need for reactivating the catalyst--3,700 hours of operation. The effects of several operating variables--temperature, pressure, gas-recycle ratio, space velocity, synthesis-gas composition, and synthesis with and without reflux of oil to the reactor--on the production of oxygenates were studied. The importance of removing reflux oil and of high gas recycle in increasing the oxygenate content was shown. A finished gasoline containing 28 percent by weight alcohols was produced. The research octane number (RON) was 92.9 clear, increasing to 98.5 with the addition of one milliliter of tetraethyl lead (TEL). INTRODUCTION The Federal Bureau of Mines has been engaged since 1944 in a research and development program on the synthesis of gasoline from coal. Gasification of coal with steam and oxygen to yield a "synthesis gas"--a mixture of carbon monoxide and hydrogen--is being investigated at Morgantown, W. Va., and the synthesis of gasoline by catalytically reacting carbon monoxide and hydrogen over iron by the Fischer-Tropsch reaction is being investigated at Bruceton, Pa.

Jan 1, 1960

By B. W. Madsen

The Bureau of Mines conducted a large-scale (6.4 t), long-term (2,165 days) test to gain a better understanding of the leaching characteristics of chalcopyritic ores. An ore sample containing 0.77 pct Cu was leached in a fiberglass column by downward percolation of acidified ferric sulfate solutions. Three sets of leaching conditions were investigated: (1) ambient temperature leaching, (2) elevated temperature (50° to 60° C) leaching, and (3) elevated temperature leaching after inoculation with thermophilic bacteria. Leaching at ambient temperature resulted in a copper extraction rate of 0.44 pct per 100 days. Increasing the temperature to 50° to 60° C resulted in decreased activity of natural mesophilic bacteria, and the leaching rate decreased to 0.22 pct per 100 days. The pH was lowered from 2.0 to 1.6, and nutrient solutions that contained thermophilic bacteria were added. This procedure resulted in an increase in the ferric-to-ferrous iron ratio and an increase in the copper leaching rate. However, the increased leaching rate was not sustained, and 120 days after inoculation the bacterial activity declined, the ferrous iron content increased, and the copper leaching rate decreased.

Jan 1, 1983

By K. L. Williams

The Bureau of Mines tested a prototype tapered-element oscillating microbalance (TEOM) dust monitor for measuring respirable coal mine dust. The monitor uses the inertial behavior of a vibrating element to measure the mass of sampled dust. Tests were performed to determine variability, drift, the effect of humidity, placement of collection filter, and element orientation during analysis, and comparability with gravimetric measurements of respirable coal dust. Variability was about 1.6 µg. Over about 26 h at 46 pct relative humidity, drift was very slightly negative. When the relative humidity was increased to 78 pct, all units showed a total positive change less then 40 µg over about 70h. Filter placement variation on the tapered element resulting from in- consistent sizing of the filter mounting bases caused significant error (up to 0.2 mg). In practice, calibration of the system for each new filter will eliminate that error. Orientation of the element during analysis did not introduce significant error, but care is necessary when mounting the canister that houses the element to avoid damping oscillation of the element. Dust tests were performed in an aerosol chamber using coal dust. Measurements made by the TEOM dust monitor agreed to within 10 pct of simultaneous measurements by gravimetric personal samplers.

Jan 1, 1986

By Bernard S. Covino

The Bureau of Mines is conducting a study of methods to improve the efficiency of the process used to pickle stainless steels. A review of the literature on pickling of stainless steels showed that the chemistry of several process operations involved in the pickling of stainless steels is not fully understood, and that further research could improve the pickling efficiency. The benefits of this research would be a reduction in the annual loss of several thousands of tons of critical minerals such as nickel and chromium, and a reduction in the amount of solids and spent acid solution that are currently discarded. The conclusion from this review is that further research is needed in four operations that either directly or indirectly influence the pickling process: hot working, annealing, conditioning, and the actual operation of pickling, Laboratory studies of the pickling operation are presently in progress.

Jan 1, 1984

By Manuel Gomez, V. F. Parry, John B. Goodman

"INTRODUCTION The need for an accurate and precise analytical method for determining moisture in coals of high water content has been recognized by the coal industry as well as the fuel technologist. Interest in this particular phase of coal technology extends back to the early work of German investigators on the brown coals of Central Europe. Studies by these workers led to the establishment of a direct immiscible liquid-distillation method 4/ as the accepted moisture determining technique in European laboratories. Direct moisture determining methods, those methods that utilize various techniques to drive off the water from a given sample of coal and either collect the water in a calibrated receiver or selectively trap the water driven off in a suitable absorber, have found little favor in the United States. They have been treated merely as research tools.5/ The problem of moisture determination in low-rank coals of the United States has not been given much consideration because such coals contribute only about 2 percent of the total United States production. With renewed activity in low-temperature carbonization and with the growth of interest in coal and coal-tar hydrogenation, the American coals of lover rank containing 20 to 40 percent bed moisture will be subjected to extensive investigation. If the low-rank coals of the United States are to be accurately appraised, the need for qualitative and quantitative analytical proceeded becomes more pronounced. These coals, especially the lignites of Texas and North Dakota, are highly susceptible to oxidation, a process that proceeds to a greater or less extort when low-rank, high-moisture coals are treated by oven-drying methods. The extent of this atmospheric oxidation has been described and evaluated by numerous workers. 7/In many respects, the problem of moisture determination in low-rank coals, those found in the United States and the high-moisture coals of Central Europe, is similar. Conversely, the problem of moisture determination assumes a different aspect when the coals of the eastern and the middle-west sections of the United States are considered. Present methods, the loss in weight gravimetic-type procedures, serve adequately to test these low-moisture coals. The determination of moisture in coals containing 20 to 40 percent water should be approached from a direct method rather than from an indirect gravimetic-type procedure because of the oxidative tendencies of these coals and the demonstratrated inability of a loss-in-weight technique to remove all the water in a given sample of coal."

May 1, 1953

By Fei-chiu Huang

The principle of time domain reflectometry (TDR) is being used by the U.S. Bureau of Mines to monitor strata displacements induced by mining. The Northwestern University TDR Signature Analysis (NVTSA) Program was developed under contract with the Bureau to allow for visual comparison of three TDR waveforms quickly and easily. This program is interactive, and on-line help is available. The Northwestern University Remote Control TDR Data Acquisition System and Modification of Tektronix SP232 Host Application Program (NUMOD) was then developed to allow acquisition of TDR wave-forms from a remote cable tester via modem. The NUMOD system utilizes commercially available software while the NUTSA program is available from the Bureau. This report begins with a discussion of TDR principles followed by a description of the NUMOD system. An interactive example of signature analysis is then used to demonstrate features of the NUTSA program.

Jan 1, 1993

By Robert C. Johnson

Single crystal whiskers of ZrO2 and TiO2 were grown by solution and crystallization of these oxides in molten baths. Mixtures of Na2B407 and LiC1 were the most suitable growth media for zirconia. Sodium borate alone and Na2CO3 plus SiO2 were best suited for titania. The solubilities of zirconia and titania in molten sodium borate were determined, Whether zirconia whiskers were dendritic or nondendritic depended on the temperature used. The best single crystal whiskers were grown below 1,100° C. Titania whiskers always grew as single crystals. The tensile strengths of zirconia and titania whiskers were about 15,000 psi and 50,000 psi, respectively. Modulus of rupture was about 49,000 psi for zirconia whiskers and 75,000 psi for titania whiskers. Chemical analyses showed the zirconia and titania whiskers to be pure. The zirconia and titania whiskers were shown by X-ray analysis to be, respectively, baddeleyite and rutile.

Jan 1, 1965

By John R. McWilliams

This is one of a series of reports being published by the Bureau of Mines on mining methods and costs at various mines throughout the United States. Including the Holden mine in this series is particularly appropriate at this time. The mine was operated on a low-cost, large-scale production basis to compensate for low-grade ore. Even with the best conditions and the most efficient methods, the margin of profit was small. Under the present situation of rising costs and lowering metal prices, the profit margin vanished. On June 28, 1957, the mine operations ceased; therefore, this report can review the entire life span of the mine.

Jan 1, 1958

By James R. Boyle

The value of mineral production in-creased 13% in 1977. Nearly all commodities registered an increase in production and value, continuing a trend that started in 1976. In addition, practically all commodities registered an increase in unit value. Alabama led the Nation in the production of crushed marble, was second in bauxite and scrap mica third in kaolin and oyster shell, and fourth in bentonite, dimension marble, and fire clay.

Jan 1, 1981

By Roy L. Soderberg

The Bureau of Mines has conducted substantial research on the design, construction, and operation of metal and nonmetal tailings ponds. This design guide, like related Bureau publications that preceded it, is produced to assist the industry in the management of mill tailings disposal. It covers the site selection, sampling, laboratory testing, design, construction, operation, and inspection of tailings embankments. The effects of environment, topography, and hydrogeology are also included, and various methods of stability analysis and factors affecting stability are reviewed. Because of the diversity of problems encountered in tailings embankments, specific solutions are not intended. The guide is, however, a useful checklist for designers, operators, and inspectors of this type of structure.

Jan 1, 1977

By J. A. Kost

A dust-control manual was prepared for use by mine operations personnel. The manual documents state-of-the-art control techniques, dust sampling, and use of personal protective devices. Content addresses advantages/disadvantages of control techniques, design and operating specifications, and implementation and maintenance guidelines. An indexed list of selected references is also included. In addition to the completed manual, this report documents work performed in the course of its preparation.

Jan 1, 1981

By Joseph D. Davis, G. S. Scott, Palmer B. Place

In the course of investigations made by the Bureau of Mines in cooperation with the Trent Process Corporation, into the properties of mixtures of oil and coal, a comparative study was ma.de of the 'behavior of these mixtures and their cons ti tuents on destructive distillation. Mixtures of a petroleum oil and bitminous coal were first distilled under carefully controlled conditions, and then charges of the eame oil and coal were distilled separately under similar conditions. The quantity and quality of the distillation products were determined, and. resul. ts were compared. This comparison furnished a basis tor judging whether grea, ... er values in products can be obtained by distillation of oil and coal in mixtures than· b:, their separate distillation. In making the mixtures, the method used in t~e Trent process for cleaning coal was followed. The paste or plastic emulsion of oil and coal obtained is called "amalgam".••• When finely pulverized wet coal is mixed with approximately one-third its weight of. oil and agitated with a large excass of waj;er, the coal and oil agglomer-. ate to form a paste or amalgam. A large portion of the extraneous ash original.17 in the coal remains suspended in the water, with which it can be decanted from the amalgam. Ir the latter is now thoroughly drained and kneaded after the manner ot working butter, most of the excess water enclosed can be removed. This, .in brief, constitutes the Trent process for cleaning coal, The effectiveness of the process for cleaning coal has been studied••••. by the Bureau, and the results of the study show, in general, a high ash reduction an:l good recovery of combus ti bl e f'rom coals of medi ,mi and hi~ rg,nk. With coals of tht lowest rank, such as li@!Rlites, the process is only moderately auccessf'ul, owing to the difficulty attending the preparation of coherent amalgams, Oil losses to wate~ and refuse are small, and apparently it would be practical to rotate the same oil in the cleaning process if some efficient method were devised for recovering it from the amalgam, so a distillation process naturally suggested itself.

Dec 1, 1921