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By W. W. Adams

The first full year of the second World War for the United States presented a picture of the metal-and nonmetal-mining 4 industry which, without proper analysis and explanation, would convey a distorted view of achievements during 1942, especially because employment at gold and silver (lode and placer) mines-the largest group-declined to such an extent that the over-all totals for the country were reduced even though increases were made at mines producing copper, lead-zinc, iron, miscellaneous metals, and non-metals. A complete panorama of the metal-and nonmetal-mining industry, exclusive of coal mining, reveals a decrease in the number of men employed, the man-hours of employment, and the accident-frequency rates. Were the gold and silver (lode and placer) mines to be considered as a separate category; it would be seen that the number of men employed at all the other groups of mines increased appreciably over 1941. These other increases must be considered important, since these mines produced the vital war minerals that made valuable contributions to the military successes of the United States and its Allies during the year. A separate analysis of each of the various groups of mines may be found elsewhere in this bulletin. For the purpose of maintaining continuity in this series of bulletins, however, the discussion in this introduction will be confined to the entire metal-and nonmetal-mining industry (excluding coal mining, for which a separate bulletin, No. 462, has been published).

Jan 1, 1945

By C. P. Bowie, George L. Gates

"INTRODUCTION Experience in drilling oil and gas wells has shown that the voidance of blow-outs, twist-offs, fishing jobs, loss of circulation, and heaving and caving of shale formations into the drill hole depends largely on how well the drilling-mud fluid serves its purpose. A possible method for the control of the drilling fluids may be seen from a study of the relation between the particle-size distribution and some of the important drilling-fluid properties, such as the ability to build quickly a relatively impervious mud sheath on the wall of the hole in the porous formations penetrated by the bit during drilling operations. In a wartime economy, which urgently requires conservation of steel, proper functioning of the drilling fluid is particularly important because, as Parks 4/ has stated, intelligent use of good drilling fluids makes possible drilling of wells for thousands of feet in open holes without the necessity of setting protective strings of casing to control the movement of salt water, gas, and troublesome formations into the borehole; consequently, especially in deep wells, of proper drilling fluids materially reduces the need for casing and lowers the cost of drilling and completing the wells."

May 1, 1942

By E. Robert Ruhlman

["Phosphate rock" is a broad term applied to natural deposits of minerals valued chiefly for their phosphorus content. More specifically, phosphate rock may be defined as a natural rock containing one or more phosphate minerals, usually calcium phosphate, of sufficient purity and in sufficient quantity to permit its use directly, or after beneficiation, in the manufacture of phosphorus-bearing products. The grade or quality of phosphate rock is expressed either in terms of its phosphorus oxide (P20S) content or the equivalent in tricalcium phosphate (Ca3(P04)2). The trade name for tricalcium phosphate is bone phosphate of lime (B. P. L.).]

Jan 1, 1958

By Charles A. Seitz

This Bureau of Mines report describes a chromatographic method for analyzing impurities in helium that utilizes a helium carrier gas contain-ing 25 to 30 ppm Ne. An example of the effect of trace amounts of nitrogen, methane, and moisture on the detector's response is shown. The added neon in the carrier does away with irregularities of the analysis which were experienced when the carrier contained up to 3 ppm Ne. The addition of 25 to 30 ppm Ne causes a loss of sensitivity, but the re-maining sensitivity is adequate for routine analyses. The high-neon carrier allows positive and more linear responses for eight impurities: neon, hydrogen, argon, oxygen, nitrogen, methane, carbon dioxide, and ethane. Neon concentration levels of 0.02 to 125 ppm in helium carrier gases were studied. The high-neon carrier has been in successful rou-tine use in Bureau of Mines helium facilities since October 1981.

Jan 1, 1985

By H. C. Fowler

Hydrogen sulphide associated with the gasps and vapors from certain crude oils now produced in the United States has forced a serious health and safety problem upon the petroleum industry. Although the presence of hydrogen sulphide in or occurring with Mexican crudes has been known for some time, it was not until recently that crude oils which give off poisonous amounts of hydrogen sulphide have been produced to any extent in the United State. The injurious effects of this poisonous gas were first recognized by the refiners along; the Atlantic and Gulf Coasts upon receiving shipments of crude petroleum from Mexico. The problem of combating the hazards of the gases and vapors given off by this petroleum become more important as the use of Mexican crude increased. In 1925, the Bureau of Mines and Public Health Service under cooperative agreement with the American Petroleum Institute, studied the causes rend effects of hydrogen sulphide poisoning. Bureau of Mines Bulletin 2312 is report of this investigation, and although written with special reference to refineries, it nevertheless contains much information that is of value to the producer of petroleum.

Jan 1, 1927

By Larry A. Haas

A major problem encountered in dump leaching operations is the plugging of both the dump and the piping by precipitated iron compounds. Bureau of Mines research to obtain basic data on agitation leaching and dump leaching methods has shown that the addition of organic chelating reagents can significantly enhance the lixiviant permeability through the ore and the concentration of the metal values in the liquor. For example, the addition of 5 giL citric acid (CA) to a conventional sulfuric acid lixiviant almost doubled the fluid flow rate through 5-cm-diameter laboratory columns containing copper ore. After 185 h of per-colation leaching, the metal concentrations with (and without, in parentheses) CA were 1.7 (1.5) giL Cu, 200 (70) ppm Mn, 160 (40) ppm AI, and 6 (3) ppm Co. The enhancement of metal concentrations with chelating reagents such as CA was confirmed by determining the solubil-ity of several metal ions as functions of pH and chelating reagent con-centration. When ferric ions became insoluble at pH values above 3, the concentrations of other ions also decreased. The addition of che-lating reagents kept iron, as well as the other dissolved metals, in solution even at pH values as high as 5. Citric acid was a more effective chelating reagent than gluconic acid, oxalic acid, or sodium lignin sulfonate.

Jan 1, 1985

By B. B. Letson

The heats of formation of lithium chloride and lithium oxalate were determined with the aid of a Bureau-developed, glass Dewar-type solution calorimeter which uses thermistors as its temperature sensing element. Values obtained at 298.15° K were -98.38 ± 0.54 kcal/mole for lithium chloride and -329.02 ± 0.79 kcal/mole for lithium oxalate, using graphite as the standard state for carbon.

Jan 1, 1965

By G. B. Shea

In 192b, there wore 47 fatal accidents in the California petroleum industry, 14.6 per cent more than occurred in 1927 when 41 men lost their lives in the drilling, producing, manufacturing, and marketing divisions of the industry. This increase in the number of fatal accidents for 1928 has caused the first upward trend in the fatality curve of the California petroleum industry since 1923. In no other year during the 6-year period have the fatalities in any one year been greater than those for the preceding year. This fact should be given serious consideration and study by the petroleum industry, and an endeavor should be made to cause the number of fatalities again to decrease and conform to the previous gradual declining trend of the fatality curve. The following chart shows the trend of fatal accidents during the past six years:

Jan 1, 1929

By Jr. Gabler

World resources of cobalt appear ample for the foreseeable future; however, political and economic events have caused concern over the availability and reliability of an uninterrupted supply. Because of this concern, the U.S. Congress requested that the U.S. Bureau of Mines initiate a study of the flow of cobalt in the economy that would delineate and quantify the production areas where metal values are lost. As a result, the Bureau has developed a computerized commodity flow model. A major attribute of this model is that it is amenable to updating as supply, demand, and/or production data change. This report follows the flow of cobalt through its metallurgical and chemical applications and highlights areas where significant losses occur due to downgrading, export, or disposal. The study indicates that about 4,300,000 lb of cobalt-bearing materials are lost each year, representing 24 pct of U.S. domestic demand.

Jan 1, 1990

By C. W. Schultz

The vapor pressure of manganese in equilibrium with a series of liquid iron-manganese alloys was determined by the carrier gas method over a broad range of alloy composition. From these data the activities of manganese in the iron-manganese system were calculated. The system appears to be ideal.

Jan 1, 1966

By R. B. Tippin

The heavy liquid separation (HLS) process was investigated by the Bureau of Mines to develop a means of concentrating minerals from natural ores, Various spodumene ores were tested in a 0.4-inch diameter cyclone using pure tetrabromoethane (TBE) as the heavy liquid. Studies were initiated to examine the influence of (1) pulp density (2) feed grade, (3) cyclone pressure, (4) cyclone apex opening size) (5) cyclone vortex finder opening sand (6) mineral particle size on the separation efficiency. Each of these factors was found to affect the heavy liquid separation in some degree; the mineral particle size exhibited the greatest effect and the ore feed grade the least. Conditions necessary to yield an 85 percent spodumene concentrate with an 85 percent recovery were determined to be: 70 psig pressure, 10 percent solids, 0.08-inch apex opening, 0.11-inch vortex finder opening and a minimum amount of minus 200-mesh fines in the feed. Operation of multiple cyclones in series resulted in spodumene concentrates assaying over 90 percent and indicated mineral recoveries exceed-in 90 percent.

Jan 1, 1967

By Steve W. Webb

The Bureau of Mines is researching a new technology for dewatering clay suspensions that consists of flocculation by high-molecular-weight poly-ethylene oxide (PEO) polymer and subsequent removal of water from the floes via a trommel. The minimum amount of PEO required to dewater the clays depends on the ions adsorbed on the surface of the elay particles. Infrared studies were performed on clays with Li+, NH4+, K+, Mg2+, Ca2+, Ba2+, or 8r2+ adsorbed, with and without adsorbed PEO, to develop data to aid in understanding the dewatering mechanism. Hydroxyl stretching modes between 3,400 and 3,250 em-I, associated with water adsorbed on the clay, showed changes in intensity proportional to the ionic eharge-to-radius ratio; that is, the ionic potential. In addition. a water-bending vibration of adsorbed water at 1,630 cm-1 showed variations associated with water desorption. The data are consistent with changes in adsorption of PEO resulting from variation of the acidity of water coordinated with the exchange ions, induced by the variation in field strength of the ions with the ionic potential.

Jan 1, 1986

By Arno C. Fieldner

Six years ago, I addressed the annual meeting of the American Society for Testing Materials on "Fuels of Today and Tomorrow."3/ Since then, our country has been drawn into another great war of veritably global extent, with unprecedented demands on fuels, foods, and materials in general. My purpose in this address is to review the changes in fuel supply and demand since 1937 and to give you my views on the outlook for the future. CONDITIONS IN. 1237 Daring 1936 the United States produced and consumed one-third of the world production of coal, two-thirds of the petroleum, and about 95 percent of the natural gas. Two-thirds of the oil produced in all countries since the discovery well was drilled in 1859 had come from American wells. With the exception of the three depression years 1931, 1932, and 1933, new oil reserves were being discovered since 1924 well in excess of our increasing rate of consumption. Discoveries of natural gas, likewise, were tremendous in volume, and this fuel was being transported to most parts of the country by pipe lines; some of them more than 1,000 miles long. We had all kinds of mineral fuels in abundance and at prices that did not stint anyone in the maximum utilization of the mechanical devices that were being developed on every hand. No one suspected that the time might come in a few years when, gasoline would be doled out to some of us at the rate of 1-1/2 gallons a week or that many of our fuel-oil furnaces would have to be converted to burn coal. Of course, these restrictions are due to unusual war conditions, such as lack of coastwise tanker transportation, unprecedented demand for aviation gasoline, and the shortage of rubber for automotive tires. However, these shortages do call our attention to the vital part of petroleum reserves in our country's future position among nations. Therefore, it is of special interest to review briefly the relations of recent supply and demand with respect to our various mineral fuels.

Jan 1, 1943

By Otto Ruhl

The Oronogo-Webb City-Duenweg district is in the northeastern part of the Tri-State zinc and, lead field. Its metal-mining history dates from the early 1850's. For some years prior to 1918 it ranked as the leading producing area of the entire Tri-State field, but by 1920 most of its mines had been abandoned and allowed to fill with water. Its mine operators had-been attracted, to the newly discovered and richer deposits around Picher, Okla. In 1943, the Orenogo Mutual Mining Co. was exploiting the Oronogo Circle deposit in the northern end of the district, and the Federal Mining & Smelting Co. was preparing to mine on its holdings in the southern part near Duenweg. The area between these two operating units ranked as the largest single block of ore reserves under water in the Tri-State field. In 1942, engineers of the Bureau of Mines, in collaboration with the William Stewart Engineering Co. of Joplin, collected all available mine maps, mine reports, and logs of old drill holes in the inundated area. From a careful study an appraisal of these data, the reserves in the block were calculated at 20,647,800 tons of ore containing 606,440 tons of 60-percent zinc concentrates and 46,970 tons of 80-percent lead concentrates. The ore was estimated to contain 1.76 percent recoverable zinc and 0.18 percent recoverable lead.

Jan 1, 1949

By Jr. Gabler

Because of concern over the availability and reliability of an uninterrupted supply of manganese and other materials, the U.S. Congress requested that the U.S. Bureau of Mines (USBM) study the /low of strategic and critical materials in the economy to delineate and quantify the production areas where metal values are lost. As a result, the USBM developed a generic computerized commodity flow model that is readily amenable to updating. The original model developed for cobalt, with slight modifications, was used to track the flow of manganese. This report follows the flow of manganese through its metallurgical and chemical applications and highlights areas where significant losses occur owing to downgrading, export, or disposal. The study indicates that materials containing 695,000 short tons (st) of manganese were consumed domestically in 1990. Scrap recovery specifically for manganese recycling was insignificant. However, considerable manganese was recycled through processing operations as a minor component of ferrous and nonferrous scrap and steel slag. The major loss category is manganese lost in steel processing, 323,156 st or 46 pet of the 1990 apparent consumption. Most of this loss reports to steelmaking slags. Recovery from slags is technically feasible, but is not economically feasible.

Jan 1, 1995

By Jacob Schoder

This is one of a series of papers published by the Bureau of Mines on mining and milling methods and costs. The Tennessee-Schuylkill Corporation, Chloride, Ariz., mines and mills a lead-zinc ore containing gold, silver, and a small amount of copper. The mill products are lead and zinc concentrates that are shipped to smelters. The company was the second largest producer of lead and zinc in Arizona in 1937 and was seventh in gold production. Operations discussed are those being conducted at the mine in October 1938 and are representative of the complete operating period from 1936 to date.

Jan 1, 1939

By Oliver Bowles

Granites are classed as igneous rocks ; they have been formed by the solidification of rock magmas or solutions from deep within the earth . It is an almost invariable law of nature that magmas which cool quickly form fine- grained or glassy rocks , while those that cool slowly are completely crystallized and are coarser- grained . Granites , being of the latter class , are regarded as having attained their solid form at considerable depth below the surface under conditions of high temperature and pressure . The constituent minerals crystallized out slowly , the crystals interlocking with one another . The great depth of overlying rocks that must have been present when crystallization took place has been removed by erosion over large areas on the surface of the earth , in consequence of which granites appear at or near the surface in many localities . The chief minerals of which granites are formed are feldspars , quartz , and either mica or hornblende . All the essential constituents except mica are as hard as , or harder than steel , therefore granites are difficult rocks to cut and dress . Granites are usually red , pink , or gray , depending on the color of the feldspars . If hornblende or black mica is abundant the rock may be dark green or almost black . Granites are characterized by massive homogeneous texture . They are classified as fine- grained , medium- grained , or coarse - grained . Medium- grained granites are those in which the feldspar crystals average about one- fourth inch in diameter . If relatively coarsegrained crystals appear in a fine -grained ground mass the rock is designated a porphyritic granite . Uniformity in texture and grain size are desirable in building and ornamental stone , although occasionally rocks of variable texture , such as the porphyritic granites , are used . A rock may have the mineral constituents of a granite but show a banded or platy structure due to recrystallization , folding , or other changes while the rock was in a plastic or semimolten condition . Such metamorphic rocks are called granite gneisses . They are used occasionally for building purposes but not as commonly as the uniformly textured granites . - Granites are named from the most abundant mineral other than quartz and feldspar that they contain , being called , for example , biotite granite or hornblende granite . - Commercially other igneous rocks granitoid in texture but more properly classified as syenites , diorites , or gabbros may be classed as granites . Thus the " black granite " of Little Falls , Minn . , is a diorite , and the " black granite " of Eastern Pennsylvania consists of diabase or gabbro . The question is sometimes raised as to the depth to which a granite occurrence may extend . In this respect granites differ notably from limestones , sandstones , or other sedimentary rocks . The sediments were originally laid down in relatively thin beds , and individual formations providing rock of economic value may be quite limited in thickness . Usually the usable beds range between 40 and 200 feet in thickness . On the other hand , granite comes up from below . Its depth is unknown , but in general is very great . It may even be measurable in miles . The reserves of material at depth are to be measured , therefore , by the economic depth of working rather than by the vertical extent of the rock mass . Exceptionally , granites of commercial quality may occur in sills or sheets of limited thickness flanked on either side by rocks of different character , as , for example , at Westerly , R. I.

May 1, 1930

By Jos. R. Guiteras

This paper is one of a series published by the Bureau of Mines on mining and milling methods and costs. It describes operations in the Alma district of Colorado in September 1937, supplemented by some additional data collected in July 1938. ACKNOWLEDGMENTS The author wishes to express his appreciation of the friendly cooperation extended him by the mine operators in the district. The greater part of the information was obtained from mine and mill superintendents to whom individual acknowledgment is made in the text.

Jan 1, 1940

By C. M. Harrer

This paper describes the location and general features of iron occurrences in Colorado. Most of the deposits were examined; many are in forested and mountainous areas at altitudes of 5,000 to 13,700 feet. Iron is known to occur in 30 counties of western Colorado. Transporting the ore to market is a handicapping economic factor involving long truck and railroad hauls; the nearest purchaser of smelting ores is the Colorado Fuel and Iron Corp., at Pueblo, Colo. When the ore can be sold locally for special purposes and at higher prices than can be obtained at iron smelters, small-scale operations can supply that market.

Jan 1, 1959

By H. P. Greenwald

About mid-December 1936, the safety director of a large coal corporation visited the authors at the Bureau's Experimental coal mine to discuss a rock-dust barrier he had invented primarily for use in trackless entries of coal mines. The rock dust in this device was carried in its original paper containers and means were provided for ripping these open so that the dust might be scattered in the path of an explosion. The inventor termed the device a "bag barrier", and this term has been adopted in the present paper for convenience. At that time the device was in an early stage of development, and the inventor felt that the barrier should be tested to determine whether it had enough promise of being successful to justify further development. The matter was taken under consideration and finally three tests were made during the week of February 15, 1937. It was concluded that while the device did stop an explosion in two of the three tests, it was much loss effective than ordinary rock dusting, and that too few data were obtained to permit direct comparison with tests of other barriers. Apparently, the conditions under which the device could, be successful were somewhat limited, out the limits could not be defined without additional tests.

Jan 1, 1938