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By A. J. Kraemer

This paper is the second and concluding report of the results of the Bureau of Mines' twenty-second semiannual survey of motor fuel marketed in the United States. The first paper Was published as Report of Investigations 30634 and reported data relating to gravity, vapor pressure, and distillation range of the samples. The present paper deals particularly with results of the determination of copper strip corrosion (method 530.22),5 color (method 10.11),6 sulphur content by the lamp method, 7 copper dish evaporation residue (method 530.1),8 and "gum" content as given by the steam-oven method as developed by the Bureau of Mines. 9 The price at the time the sample was taken and the tax are also stated for each sample. The sample numbers used throughout this report are identical with those used in Report of Investigations 306310; ?for example, No. 225 of this report is the same sample as No. 225 of Report of Investigations 3063.

Jan 1, 1931

By E. H. Denny

This paper discusses accident experience and costs in 150 Colorado coal mines for the 5 years 1929-33; these mines produced 62 percent of Colorado's coal tonnage during this period. This and similar studies by the United states Bureau of Mines in other States (listed in the appendix to this report) make available comparable information on mine-accident costs and bring out clearly the importance of accident reduction from the humanitarian as well as from the economic standpoint. Compensation insurance costs constitute a considerable part of the cost of coal output. The tendency toward greater liberalization of workmen's compensation laws and increased benefits thereunder may mitigate to some extent the seriousness of an accident to a worker and his dependents, but no compensation is paid ultimately, not by an insurance fund but by the mine operator and the general public, which includes the miner. The one really effective method of reducing compensation costs is to reduce the number and severity of accidents.

Jan 1, 1935

By M. Carrales

This Bureau of Mines publication presents short-range projections of domestic liquid hydrocarbon production through 1980. Appraisal of future crude oil production was made by evaluating the relationship between primary and enhanced oil recovery and the total crude oil producing trends in each of the oil-producing areas of the United States. Future natural gas liquid production was generally estimated by projecting historical production. Estimates of production were prepared for each of the oil producing areas and summarized for the Petroleum Administration for Defense (PAD) districts and total United States. From 1975 to 1980, crude oil production for the conterminous United States is expected to decline from 7.8 to 6.4 million barrels of oil per day (BOPD), and it is expected to increase from 8.0 to 8.2 million BOPD for the total United States. However, these estimates do not include additional production expected from the Elk Hills field in California and the Yates field in Texas. If included, 1980 production for the conterminous United States would be 6.7 million BOPD and 8.4 million BOPD for the total United States.

Jan 1, 1977

By E. W. Dean

A previous report of the Bureau of Mines* has supplied data for the physical and chemical properties of samples of crude petroleum produced in the eastern fields of the United States. It was issued as a preliminary chapter of a bulletin which is to cover the results of a survey of the entire country. The present report is a second preliminary chapter including figures that are available for the producing fields of the Rocky Mountain district. Work is being continued. with a series of samples from the States of Kansas and Oklahoma which will be described in a third preliminary chapter, to appear at a subsequent date. Acknowledgments. The obtaining of samples was rendered possible through the courtesy of representatives of a number of producing and refining companies operating in the Rocky Mountain district. The Bureau hereby acknowledges its appreciation of the hearty spirit of cooperation that was universally encountered.

Jan 1, 1921

By P. J. Remington

Field measurements utilizing a seat pad accelerometer were made on 61 surface coal mining machines in order to quantify the vibration levels experienced by the operators. Those data were combined with information on the statistics of the operating times of those machines in order to compare the operator's vibration exposure to the criteria in ISO 2631, ?A Guide for the Evaluation of Human Exposure to Whole Body Vibration.? The comparison showed that about ha]f of all surface coal mining machine operators can be expected to be exposed to vibration exceeding the fatigue decreased proficiency criterion, whereas only on the order of 15% would be expected to experience vibration exceeding the exposure limit. Detailed exposure statistics are presented and the implications of the results are discussed.

Jan 1, 1983

IN 1949 the Government Printing Office issued Bureau of Mines Bulletin 468 3 and previously (in 1948) Bulletin 467 4 as part of the program under the Synthetic Liquid Fuels Act of April 5, 1944 (30 U. S. C., 321-325, and amendments). The two bulletins, relating to oil shale and its products, were published to present abstracts of all patents in this field from 1845 to 1945 5 or before the Synthetic Liquid Fuels Act was passed. Also, as part of this program, bulletins were published on patents relating to the pressure hydrogenation of coal e and the Fischer-Tropsch synthesis.7 The Synthetic Liquid Fuels Act was not extended beyond April 1955, but it inspired much increased activity in the field of oil-shale research, and many patent applications were filed. It is the purpose of this bulletin to abstract the patents issued in the United States, the United Kingdom, and Europe from 1946 to 1956, inclusive. A few older patents omitted in the previous bulletins have been included.

Jan 1, 1959

By James Westfield

This report covers the calendar year 1953 and has been prepared and submitted in accordance with the provisions of Sec. 106(a) and Sec. 212(c) of the Federal Coal Mine Safety Act (66 Stat. 692; 30 U.S.C. Secs. 451-483). During this first full calendar year of operations under the Federal Coal Mine Safety Act, the coal-mining industry of the United States attained the best injury records in its history - improving the former best records (made in 1952) by 91 fatal and 10,020 nonfatal injuries. Whereas, the mandatory provisions of the act were intended and designed to prevent major mine disasters, apparently the effects have reached beyond the scope thereof in reducing mine accidents generally.

Jan 1, 1954

By G. W. Jones

In a previous report results were given and a method outlined whereby from a knowledge of the composition of the natural gas and of the inflammability limits of the individual constituents composing the natural gas, the limits of inflammability of natural gas and air mixtures could be closely calculated. This method is based on the application of Le Chatelier's law as modified by Coward, Carpenter and Payman, to apply to a mixture of any number of combustible gases. This law must not be used indiscriminately, because many exceptions have been found. For example, when ethylene, acetylene, hydrogen sulphide, or chlorinated hydrocarbons are present the law may not hold. For a discussion of the rally exceptions which have been found, reference should be made to a report by Coward and Jones. Before this method can be used the inflammable limits of the individual constituents must be known. Also, the composition of the complex combustible mixture, and representative mixtures besides, must be tested both experimentally and by calculation to prove whether Le Chatelier's law may be applied.

Jan 1, 1933

By F. E. Diebold

The methodology for describing the geochemistry of elements in a coal seam have been developed. This has been applied to the Rosebud Coal Seam, which is an economically important member of the subbituminous coals of the Fort Union Formation in Eastern Montana. The method development has involved a detailed study of two popular techniques for determining the metal geochemistry of coal, namely, whole coal analyses and coal physical fractionation. The mathematically contrived element associations (whole coal analyses technique) and the element concentration trends in the float and sink fractions (physical fractionation technique) are considered to lead to only qualitative conclusions concerning the chemical associations of the elements in coals. Additionally, the processes taking place with the coal during low temperature ashing in an oxygen plasma are experimentally investigated and shown to be of sufficeint extent that the use of such low temperature ash for deciphering element geochemistry is questionable. The method developed in this study is a chemical fractionation that involves the sequential leaching of coal with water, 0.5 N HC1, 3 N HC1, 2 N HNO3, and 48% HF. These leach solutions are shown to selectively dissolve the predominate inorganic phases, sulfates, Ca and Mg carbonates, Fe sulfides and K alumino-silicates and quartz, respectively. These phases were identified with the use of XRD, SEM, EM and leaches (water and 0.3 N HC1) of whole coal and low temperature ash. The incorporation of the anion-exchange step in the leaching scheme was investigated and was observed to warrant further study of such intensity to be, at the time, unuseable. The use of this sequential leaching technique on several coal samples from the same seam generates element concentration trends that can be quantitatively interpreted with respect to the chemical associations of the minor and trace metals in the coal seam. The properties of the various seams of economic importance in the Fort Union Formation in Eastern Montana are compiled and presented. The subsequent conclusion is that there is not a large variation in the properties of these coal seams and that the variations within the Rosebud are within one order of magnitude. The chemical fractionation technique, investigated in this study, was applied to composite tipple samples of the Rosebud seam. Each composite sample represented 76,800 tons of coal. A minimum of 32% of the Ca and Mg are present as separate water soluble sulfates. An excess of the sulfate ion in the water extracts shows the predominating influence of the ion exchange capacity of the organic compounds in the coal. Based upon the CO content of the coal and the HC1 leachate data, 25 to 30% of the alkaline earth elements exist as separate carbonates and the remainder are associated with the organic compounds. The small fraction of the illite that dissolves in the HC1 and HNO3 leachates accounts for the K and Al. Slight dissolution of the pyrite in the HCl solvent occurs, the small amounts of Li and As do not relate to any known phase and Mn is present as a separate carbonate phase. Fe and a significant amount of the As exist in the pyrite that is dissolved in the HNO. Se is equally partitioned between the pyrite and the organic compound~. Most of the trace elements are found in the HF solutions. Li, V, and Cr were interpreted to be associated with the clay minerals (kaolinite and illite). Ni and Pb appear to be present as separate phases and 50% of the Hg is HF soluble but is not chemically related to any known inorganic phase.

Jan 1, 1983

By C. T. Sheeran

The Bureau of Mines investigated a microprocessor-based real-time control and monitoring system for uranium mining applications. The system is capable of controlling and monitoring up to 768 stations within 3 km of the central processor on a common four-wire cable. It can be used in conjunction with detectors to continuously monitor and display radiation working levels at points throughout the mine. Surface alarms are sounded for critical situations such as rapid radiation buildup, loss of power to monitors or fans, and changes in air door position. Permanent records of all changes are automatically printed out with their time of occurrence. Printouts can also be obtained for shift reports or trend logs. The system can be used to remotely control fan startup and shut-down, and also can alert miners of underground conditions by blowing horns or turning on lights. Battery backup keeps the system operative for up to 4 h in case of a mine power outage. A special software feature permits automatic, time-delayed, sequential restart of fans.

Jan 1, 1984

By W. S. Sanner

Seven samples were analyzed from the major reserves of the Bottom Red Ash bed, Northern anthracite field. The data show variations in thickness and geo-logic structure and in the amount of coal that can be recovered. Recovery of market-grade (less than 17 percent ash) coal is high for all samples, ranging from 76 tp 95 percent in the 3-1/4-by 9/16-inch sizes. The occurrence of coal containing less than 5 percent ash varies from 19.5 to as much as 57.5 percent. Crushing the coarse sizes to minus 9/16 inch increased recovery of market-grade coal in six of seven bed samples. Crushing released sufficient impurities to cause substantial increases in yield of coal containing less than 5 percent ash for all samples. Analyses of the float coal indicate that the quality of coal is comparable for all samples.

Jan 1, 1967

By Piyush K. Dutta

This report describes the design, development and manufacture of production stoper drills and results of their field tests, it is shown that underground stoper drill noise level can be reduced from 118 dBA to below 100 dBA by using these pneumatic drills. The design concept of these drills is a radical departure from the standard valved rifle bar type drill machine design to a drill featuring a valveless independent rotation system, use of an integral muffler and a shroud tube. Six drills were manufactured in a standard commercial drill manufacturing setup and organization. The design and production technology proved that commercially viable quiet drills can be made available for mine use.

Jan 1, 1983

By T. A. Sullivan

The Bureau of Mines investigated modified sulfur concretes as one part of a program for utilizing sulfur in construction materials. The use of modified sulfur was studied as a means of preventing the stressing action in the concretes caused by the allotropic transformation of sulfur on solidification. Unmodified sulfur concretes have been prepared that have compression, flexural, and tensile strengths equivalent or better than Portland concretes. However, most of these concretes have been vulnerable to deterioration by weathering, temperature fluctuations, and freeze-thaw cycling. The sulfur was modified by reaction with dicyclopentadiene or dipentene before use as an aggregate binder. Sulfur concretes and modified sulfur concretes were pre-pared from acidic and basic type aggregates. Physical properties of the optimum mixtures were determined and compared with each other and with Portland cement concretes. The best results were obtained by reacting sulfur with 5 pct dicyclopentadiene to prepare modified sulfur concretes. Field testing of the concretes are in progress. Present results show that modified sulfur concretes are superior to unmodified sulfur concretes and equal or better than Portland concretes in compressive, flexural, and tensile strengths. Long-term aging characteristics of both modified and unmodified sulfur concretes are being determined.

Jan 1, 1976

By R. B. Anderson

As a part of a Bureau of Mines program on the conversion of coal to liquid and gaseous fuels, the kinetics of the Fischer-Tropsch synthesis on iron catalysts was investigated. Nitrided catalysts were studied at 21.4 atmospheres using feed gases ranging from 2H2+1CO to 0.25H2+1CO, and at 7.8 to 21.4 atmospheres using 1H2+1CO gas. The overall apparent activation energy increased with increasing carbon monoxide content of the feed gas from 19.5 kcal/mole for 2H2+1CO to 23.7 for 0.7H2+1CO. The rate of synthesis with 1H2+1CO feed increased linearly with operating pressure from 7.8 to 21.4 atmospheres. A semifundamental rate equation of the form [r=a'PH2 0.6pco 0.4- ?r0.5PH200.5] was shown to fit the data satisfactorily. The relative usage of hydrogen to carbon monoxide decreased with increasing conversion, passed a minimum, and then increased. Apparently water is the principal primary product and carbon dioxide is produced by subsequent water-gas shift reaction. In another group of experiments water, carbon dioxide, argon, and methane were added to 1H2+1CO feed to a nitrided iron catalyst. Argon and methane were only diluents. Carbon dioxide was a slight inhibitor and water vapor was a strong inhibitor to the rate of synthesis. Water accelerated the water-gas shift and usually increased methane production. Important factors of catalyst geometry in determining rate were found to be particle size and extent of reduction. Apparently the active portion of the catalyst is confined to a layer of 0.01 to 0.02 cm from the external surface of particles. A special solution was made of differential equations relating re¬action at the catalyst surface to diffusion in pores of the catalyst for spherical particles with an active layer surrounding an inert core. The equation derived expressed the experimental data reasonably well. Diffusivities determined by this equation varied from 3 to 24X10-6 cm2/sec; these values are of the same magnitude as observed for the diffusion of gases in liquid. The appendix presents a group of synthesis experiments at pressures of 21.4 to 103 atmospheres. In this range the rate of synthesis on nitrided iron catalysts increased with pressure to the 0.74 to 0.84 power.

Jan 1, 1964

By Robert J. Evans

The Bureau of Mines is sponsoring a variety of long-term, high-risk research to advance state-of-the-art technology in U.S. underground coal mining. This report reviews the status of many Bureau projects that support fundamental underground coal mining operations; the project areas include cutting coal from the solid (extraction), hauling coal from the face (transport), and activities that sustain daily operations (logistics). Innovative equipment and technology have been developed, with these major objectives: to significantly improve coal mine productivity, to further advance coal recovery and personal safety within the mining industry, and to reduce the time needed to develop longwall panels. The majority of the prototype equipment covered in this report either has undergone or will undergo comprehensive evaluation at Bureau surface test facilities so that performance and reliability can be improved before the equipment is tested and evaluated in a working section underground.

Jan 1, 1988

By Clarence Hall, Spencer P. Howell

Among the more important factors involved in the use of high explosives in blasting operations is the means employed to bring about the detonation of the charge. When flame is applied to high explosives many of them may burn if not confined; but all of them when burning under certain conditions of confinement may detonate. Detonation may also be effected by mechanical means, such as frictional impact caused by a blow or by rubbing between surfaces. By this means, however, the full effect of the explosive charge may not be developed, so that a partial detonation, often accompanied by the burning of the explosive, results. When nitroglycerin was first used it was fired by the application of flame, but considerable difficulty was experienced in exploding it with certainty and in obtaining uniform resl'llts. In 1864 Allred Noble, a Swedish engineer, discovered that nitroglycerin could be surely and completely detonated by exploding in contact with it a small quantity of an initiatory explosive. Mercury fulminate was the substance then found capable of producing the best results There are many other fulminates and other substances that will produce complete detonation of commercial" high" explosives, but detonators or electric detonators containing mercury fulminate as the characteristic ingredient are still almost exclusively used in this country. The term" detonator" is used in the publications of the Bureau of Mines to designate what the miner calls a "blasting cap "-a copper capsule containing a small quantity of some detonating compound that is ignited by a fuse. The term" electric detonator" is applied to a blasting cap that is similar except for being ignited by means of a small wire which is heated to incandescence or fused by the passage of an electric current. One of the conditions prescribed by the Bureau of Mines for a permissible explosive a is that it shall be :fired by a detonator, or preferably an electric detonator, having a charge equivalent to that of the standard detonator used at the Pittsburgh testing station. A further requirement is that this charge shall consist by weight of 90 parts of mercury fulminate and 10 parts of potassium chlorate (or their equivalents). At the request of a manufacturer of permissible explosives, an investigation was undertaken by the bureau to determine the relative strength of detonators and electric detonators having different compositions. The tests of electric detonators herein reported were conducted by H. F. Braddock, junior chemist; J. W. Koster, J. E. Tiffany, junior mining engineers; and A. S. Crossfield, junior explosives chemist, at the Pittsburgh testing station of the bureau. Similar tests of detonators were not conducted because it was believed that the results would not show sufficient variation to warrant such tests. It is hoped that the conclusions drawn from the tests made will be of service to those using explosives by enabling them to select the grade of detonator or electric detonator that will insure the most effective results. The conclusions are given in this bulletin, which is published by the Bureau of Mines as one of a series of publications dealing with the testing of explosives and the precautions that should be taken to increase safety and efficiency in the use of explosives in mining operations. The results of tho experiments described in this bulletin show that the average percentage of failures of explosives to detonate was increased more than 20 per cent when the lower grades of electric detonators were used instead of No. 6 electric detonators, and was increased more than 50 per cent when these lower grades were used instead of No. 8 electric detonators. It is noteworthy, however, that when sensitive explosives, such as 40 per cent strength ammonia dynamite (p. 33), were tested under conditions ideal for detonation, the same energy was developed irrespective of the electric detonator used. When tests were made with a less sensitive explosive, such as a 40 per cent strength ammonia dynamite containing nitrosubstitution compounds (p. 32), the energy developed increased with the grade of the electric detonator used. For example, the average efficiency of four different explosives was increased 10.4 per cent when a No.6 electric detonator was used instead of a No.4 electric detonator, and 14.9 per cent when aN 0.8 electric detonator was used (see tabulation onp.45). The results of the tests emphasize the importance of using explosives in a fresh condition, but as fresh explosives can not always be had in mining work, strong detonators should be used in order to offset any deterioration of explosives from age.

Jan 1, 1913

By R. G. Nelson

This report covers investigations of the Bureau of Mines for the period of June 15, 1952, to June 15, 1953, on a research project for the Materials Laboratory, Wright Patterson Air Force Base, Dayton, Ohio. The primary purpose of this investigation was to make high-purity chromium-base alloys having room-temperature ductility and high-temperature strength. The Nonferrous Metals Branch of the Bureau of Mines, Albany, Oreg., has, during the past 7 years, developed on a laboratory scale a hydrogen treatment method for making high-purity chromium that can be fabricated into thin sheet and wire. This material can be bent at room temperature. The object of this investigation was to use this material to develop improved chromium-rich alloys for high-temperature uses.

Jan 1, 1955

By J. G. Kirby

According to the Bureau of Mines annual survey, there were 318 petroleum refineries in the United States with a total daily crude throughput capacity of 8,632,390 barrels as of January 1, 1956. Compared with the previous year the total number of refineries declined 8 while the crude throughput capacity increased 211,760 barrels daily. Three refinery districts accounted for 90 percent of the crude-oil capacity increase, the California district 34 percent; the Texas Gulf Coast district, 31 percent; and the Indiana-Illinois-Kentucky district, 25 percent. Decreases in capacity during the year were reported for the East Coast, Appalachian #1, and the Arkansas-Louisiana Inland districts. The capacity of the average refinery to process crude oil increased during 1955 from 25.830 barrels daily to 27,145.

Jan 1, 1956

By B. J. Moore

This Bureau of Mines publication reviews U.S. helium resources as of January 1, 1973. These resources, estimated to be 693.7 billion cubic feet, are broken down into four classifications, as follows: helium in storage, 34.9 billion cubic feet; helium in measured helium-rich natural gas reserves, 119.5 billion cubic feet; helium in measured helium-lean natural gas reserves, 62.8 billion cubic feet; and helium in indicated or undiscovered natural gas resources, 476.5 billion cubic feet. The helium in undiscovered natural gas is considered a national resource; however, this gas may not be discovered depending on many factors beyond the scope of this paper, and most of the helium in natural gas will be dissipated as the gas is consumed for fuel and other purposes.

Jan 1, 1976

By Russell R. Trengrove

The Copper Canyon lead-zinc mine is in the Battle Mountain. District, Lander County, Nev. It was discovered in 1866 and mined for copper until 1935 and for copper and gold until l948, when the main production became lead-zinc ore. The rocks in the area are carboniferous (Pennsylvanian and Mississippian) sedimentaries that have been intruded by quartz monzonite of Mesozoic age. They have been intensely folded, faulted, and tilted. Lead-zinc ore occurs as sulfides disseminated along fractured zones in a conglomerate arid hornfels. Development was carried out by the Bureau of Mines in cooperation with the U. S. Geological Survey and comprised a study of the geology, making maps and. cross sections, and exploring the deposit by diamond drilling from underground. Eighteen holes were drilled, for a total of 2,594 feet. This report contains a brief history of the property and a description of mining methods and beneficiation of the ore, geology, ore deposits and drilling done by the Bureau of Mines. It also contains detailed analyses of the ore samples taken and logs of the holes drilled.

Jan 1, 1951