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By J. Roger Loebenstein

This report presents a U.S. Bureau of Mines study of the flow of arsenic-containing materials in the United States, based on the best data available in 1991, includes a consideration of arsenic as a byproduct of the processing of nonferrous metals, the fate of arsenic in manufacturing wastes, the quantity of arsenic used in products, tile fate of arsenic in dissipative uses, and the useful life of discarded products. Where possible, estimates are given of the amounts of arsenic lost from the materials flow. Arsenic byproduct of mining nonferrous metals. Historically, most U.S. production has been from the states of Montana, Washington, and Utah. The smelters in these states are believed to be the areas of the country where arsenic is most concentrated in the soil, tailings ponds, and waste dumps. Since the closure of the last domestic producer of arsenic in 1985, all arsenic has been derived from imported sources. Historically, arsenic was important in agricultural applications as an insecticide, herbicide, and cotton desiccant. As the environmental movement gained momentum and the toxicity of arsenic became better understood, most of the agricultural uses for arsenic were banned. Beginning about 1975, the use of arsenic as a wood preservative began to grow. After 1980, wood preservative uses became more important than agricultural applications. By 1990, 70% of the arsenic consumed in the United States was used by the wood preservative industry and 20% by the agricultural industry. The major source of domestic arsenic emissions in 1989 was from the U.S. copper processing indus¬try. About 7,800 mt/yr of arsenic was discarded in leach dumps, tailings, and slag. Another 800 mt/yr was liberated to the atmosphere and 1/100 mt/yr was exported in copper concentrates. On the consumption side, 9,200 mt/yr was lost, mostly from dissipative agricultural uses and the disposal of obsolete arsenical products.

Jan 1, 1994

By E. R. Palowitch

This report is the result of a series of coal-cleaning tests using a dense-medium cone-type washer. Detailed results are given for 2 tests using a magnetite medium and 4 tests using a pulverized-refuse medium. Approximately 120 float-and-sink tests and over 500 separate chemical analyses were made in conjunction with these tests. In these tests higher recovery efficiencies and sharper separations were obtained when using a magnetite medium, especially on coal sizes below one-half inch. When sizes above 1 inch at low specific gravities of separation are cleaned, the pulverized refuse medium compared favorably with the magnetite medium.

Jan 1, 1956

By Rogers F. Davis

This publication has been prepared to supply manufacturers and industrial users a listing of mobile diesel-powered equipment and subassemblies approved and certified by the Bureau of Mines for use in noncoal mines. Testing of diesel-powered equipment is one phase of the Bureau's program of health and safety that concerns approval of electrical and diesel equipment designed to prevent explosions, fires, shocks, or toxic hazards in underground mines, when such equipment is used and maintained properly. Manufacturers submit machinery and component parts to the Bureau for study of their design, safety features, and use. Equipment must pass exacting tests and must meet strict requirements established through research and experience and listed in the Bureau's permissible schedules before the Bureau approves it as permissible for safe use in mines.

Jan 1, 1963

The coal reserve base is defined for coalbeds having sufficient thickness for underground mining within a depth range compatible with economic recovery. The reserve data are compiled by the Federal Bureau of Mines by updating and reevaluating previous estimates of the U.S. Geological Survey, State geological surveys, and others. Through the application of computer techniques, the tonnages are compiled by State, county, coalbed, and rank. Coal reserve base is allotted to sulfur categories by a statistical apportionment of data from available Bureau of Mines reports and records. The coal reserve base in those States east of the Mississippi River, minable by underground methods, is estimated to be 169 billion tons in coalbeds greater than 28 inches in thickness to a maximum depth of 1,000 feet. Excluding those coals in reliability categories other than measured and indicated, the underground reserve base includes 162 billion tons of bituminous coal and 7 billion tons of anthracite. Of the total, 27 billion tons contains 1.0 percent or less sulfur. Most of this low-sulfur coal is in the southern Appalachian area. Approximately 16 percent of the underground reserve base is without available analyses. Included in this report is a glossary of terms applicable to a classification system for coal resources and reserves. The purpose of this system is to provide a common yardstick for determining coal resources and reserves.

Jan 1, 1974

By David E. Swanson

The U.S. Bureau of Mines undertook a basic investigation of collimated abrasive water-jet behavior because a more complete understanding of the fundamental process may lead to further technical advances. Laboratory experiments used 2-mm water-jet nozzles and new entrainment apparatus to analyze collimated abrasive water jets operating under varied conditions. Maximum water pressure was 69 MPa to permit use of conventional hoses with a burst-to-operating-pressure ratio of 4. Nozzle and induction line pressures, abrasive induction rates, and jet reactive thrust forces were recorded for each operating condition. Average jet velocity and power were determined from component mass flow rates and reactive thrust force measurements. Relative velocity and cross-sectional distribution of abrasive particles were determined using impact analysis techniques. Other jet characteristics were determined photographically. Properties of free water jets, collimated water jets, and collimated air-water jets were determined for comparison.

Jan 1, 1989

By R. W. Huber

While conducting an investigation on electrolytic reduction of magnesium oxide in 1943, it became necessary to obtain accurate data on the conductivity and density of various mixtures of fused chlorides. AZ the required information was not available in the technical literature, or there were inconsistencies in the data from several investigators, an independent study was made at the Bureau of. Mines laboratory at Salt Lake City on the conductivity and density of the molten chlorides MgCl2, CaCl2, BaCl2, KCl, and NaCl and the binary mixtures of MgCl2 with the other four chlorides. Studies were also made on the binary system KCl-CaCl2 and on certain portions of several ternary systems. Measurements covered a temperature range from the melting point to 1,000° C. The results of this study were reported in an intra-Bureau report prepared early in 1944. Since then the Bureau of Mines has received several requests for data on fused chlorides; the results of the previous study, therefore, are being published to make the data available.

Jan 1, 1952

By Andrew A. Cochran

Laboratory-scale research was conducted by the Bureau of Mines to develop a new process for treating electroplating and other wastes. Various acid and alkaline cyanide wastes were combined under controlled conditions to neutralize the wastes and to almost completely precipitate the metals and cyanides. The metals were subsequently recovered for recycling; the cyanides can also be easily recycled. The process was successfully used to treat the major types of electroplating and etching wastes, containing Cd, Cr, Cu, Ni, and Zn, and to treat both concentrated and dilute wastes. The economic aspects of treating concentrated electroplating, etching, and anodizing wastes are especially attractive because of the low cost of mixing two wastes, the high value of the recovered metals, and the simplicity of the recovery procedures. The filtrates from the waste-plus-waste step were relatively harmless compared with the original wastes and met Public Health Service standards for free cyanide content. Free cyanide ions were not detected in most of the filtrates; the limit of detection was 0.03 ppm. Only small amounts of HCN were produced during the neutralization; the HCN was collected and neutralized.

Jan 1, 1974

By Robert M. Strong

The following report is a summary of the commercial results which 'Were obtained from 2,000 tests conducted by the technologic branch of the United States Geological Survey at St. Louis, Mo., and Norfolk, Va., in 1907 and 1908, under the technical supervision of R. H. Fernald, engineer in charge of the producer-gas section. The tests dealt primarily with gasoline, forming part of the investigation of mineral fuels provided for by acts of Congress. To determine the relative economy and efficiency of gasoline it was compared with denatured alcohol. The tests, many of which were undertaken in connection with work for the Navy Department, supplemented, to a certain extent, the work of previous investigations, but only so far as was necessary to emphasize some of the more important points and to lead up to the defining of conditions required for the economical use of gasoline and alcohol. In order to determine and eliminate the affecting engine conditions as far as possible, the investigation was commenced by making comparative gasoline and alcohol tests on the same engines. These tests were repeated on other engines of approxiElately the same size and speed, having different degrees of comFression, different methods of governing, and different carburetors. The final report will include much material that may be of use in engine design, but that side of the investigation was not pursued any further than was necessary to obtain the best possible results, for alcohol and for gasoline with the engines at hand, and to prove that the minimum fu·el-consumption rate for each could be obtained in approximately the same manner. The effects of engine and of operating conditions both have a bearing on the commercial deductions but will be discussed only in a general way at this time.

Jan 1, 1911

By A. J. Kraemer

This report on the physical and chemical properties of crude oils of California is one of a series on the producing districts of the United States. It includes a short discussion of results, tabulated data, and individual analyses of California crudes. Analyses of crude oils from the fields of Fresno, Kern, Los Angeles, Orange, and Ventura Counties have been published in Serials 25952 and 26083. The analyses reported in this paper corer samples that were obtained subsequent to the publication of Serials 2535 and 2608. The samples were obtained by members of the San Francisco office of the Bureau of Mines. The collecting of samples was facilitated by the courtesy of representatives of oil companies in California.

Jan 1, 1927

By G. L. Oldright

[Processes by which silver alone is extracted from ores that also cant contain base metals are usually associated in the mind of the period when mines were changing from the production of noble metals to the production of base metals containing noble metals as a by-product. In this transition period the mixed arcs of the partly oxidized ore zone had to be treated instead of the free-milling ore that had been treated in the past or the deeper-lying sulphide ores that were to be smelted subsequently under improved economic and technical conditions.]

Jan 1, 1929

By W. J. Long

As a part of the strategic mineral exploration program, examining engineers of the Bureau of Mines collected samples of ore from four manganese properties in Yavapai, Yuma, Maricopa, and Mohave Counties, Ariz. As all of the ores were too low in grade to be acceptable by manufacturers of ferromanganese beneficiation studies were made to determine the amenability of the ores to concentration.

Jan 1, 1948

By John Ward Smith

Detailed oil yield, lithologic, and mineral distribution data are presented for core and drill-cutting samples from the Western Oil Shale Corp. Project Utah EX-1 Corehole (WOSCO EX-I), drilled to sample a deeply buried oil-shale sequence in the Green River Formation of Utah's Uinta Basin. Drilling of this corehole was part of the evaluation of this site for possible oil-shale development by nuclear explosion. Sections sufficiently thick for nuclear development average 15 gallons per ton or less and consist predominantly of low-grade shales. Some properties of low-grade shales may be advantageous to a nuclear experiment by facilitating breakage, fracture development, and in situ retorting. The formation correlates precisely with the well-studied oil shales 25 miles east near the Colorado border. A 235-foot mineralized section containing nahcolite, shortite, and searlesite whose bottom lies 300 feet above the Mahogany zone is described.

Jan 1, 1972

By C. L. Severy

The Reeder No. 1 well was drilled by the Bureau of Mines in cooperation with the Geological Survey as agents for the Defense Plant Corporation. The well is south of Crescent Junction near Thompson, Grand County, Utah. It was started May 5, 1942, and completed August 3, 1942, for the purpose of con-firming the presence of magnesium salts in a deeply buried bed. Drilling was done under contract by the Mack Drilling Co. This report contains an outline of the physical features of the well, a brief history of drilling, and a description of the deposits and occurrences of oil and gas encountered in the drill hole. The work performed by the Bureau of Mines is described in considerable detail, with particular emphasis on drilling procedure and sampling. The report is concluded with a brief description of core-sample preparation for analyses. Appendix A comprises a log of the drill hole, and appendix B is a tabulation of analyses of cores.

Jan 1, 1949

By Arthur E. Bruszak, Marcel Vanpée

In many practical combustion systems ignition may occur through contact with hot burned gases . Such a process plays a vital role in flame stabilization on bluff bodies . It is also of importance in the ignition of firedamp by the hot spent gases of explosives used in mines . Also , in the communication of flames through narrow channels , a problem of practical importance in flameproofing electrical equipment , the propagation of the flame is essentially a reignition process in which hot burned gases are the agent of ignition . In the actual ignition problem a great variety of conditions may be visualized . Ignition may occur where pockets of hot gases are surrounded by cold explosive mixtures or where pockets of cold mixture may be surrounded by hot gases . Alternately , a flowing stream of combustible mixture may be initially in contact with another stream of hot combustion products , or a jet of hot gases may flow into a cold quiescent mixture ; the jet may be laminar or turbulent , continuous or discontinuous . The hot gas may also consist of the oxidant ( air for instance ) and the cold combustible pure fuel . This study by the Bureau of Mines is concerned only with ignition produced by a continuous jet of gas ( hot ) flowing into a practically quiescent cold mix- The investigation of ignition by bursts of hot gases or by turbulent jets is outside the scope of this report , and work performed on this phase of the problem has been published elsewhere

Jan 1, 1963

By L. C. IlsLey, H. H. Clark

In various publications relating to safety in mining the Bureau of Mines has called attention to the hazards attending the use of openBame lamps. An open-flame lamp is a potential source of danger in any coal mine. It may start a fire in a dry mine or an explosion in a gaseous mine. The type of open-flame oil lamp now used in mines is the product of long evolution; its principal merit is simplicity. That such a light is unsafe in an atmosphere containing gas (methane) is evident, and Sir Humphrey Davy immeasurably increased safety in coal mines when he found means of protecting a lamp flame so that it would not readily ignite gas. The safety lamp, however, gives less light than the open-flame lamp, is not as simple in construction, is more cumbersome, and must De carried in the hand .. Consequently, some miners are reluctant to abandon the open-flame lamp for the safety lamp, and risk their own lives and the lives of their fellow workers with the one rather than to be hampered by the other. When small electric bulbs, with their clear, white light, and small electric storage batteries became available, the advantage of combining these elements for a miner's lamp seemed manifest. The combination looked simple and safe, but was soon found to have elements of danger and weakness peculiar to itself. The Bureau of Mines showed, in 1911, that the breaking of a miniature electric bulb in an inflammable mixture of gas and air might ignite the mixture, so that only the fragile glass of the lamp bulb might stand between the miner and injury or death. There Was also a possibility that sparks from the small battery would ignite gas, and the accidental spilling of the contents of a battery on the miner's clothing or skin was a possible source of injury. The first portable electric miner's lamps that were carried in the hand, or with the battery strapped to the back and the light carried on the head, were exceedingly crude and were designed without appreciation of the sources of danger. The possibility, however, of producing a safe and practical miner's lamp by the proper combination and design of the elements available promised to increase safety so greatly that the Bureau of Mines attemr>ted to stimulate better design and construction by careful investigations and the establishment of an approval system that would be an assurance to the miner and an advantage to the maker of the lamp. As a result various manufacturers submitted types of lamps, cords, and bulbs for test and cooperated with the bureau in efforts to so improve the safety features of these devices that the lamps would P&$ specific tests for approval.

Jan 1, 1917

By N. P. Kripakov

The Bureau of Mines has developed a unique new mine design procedure to determine the changing static load distributions imposed on under-ground support structures during the mining cycle. The procedure reduces the complexities associated with analyzing a three-dimensional problem. A combination of the multiple-seam displacement-discontinuity model and a two-dimensional finite-element window model produces refined results for a specific area of interest by assuming displacement compat-ibility between models. Input to the procedure includes the geometry of mined-out areas in up to two adjacent seams, the rock mass characteris-tics of the surrounding geology, the in situ stress conditions, and the mining sequence. The displacement-discontinuity program calculates ex-pected loadings for mine structures affected by the mining cycle and/or by overlying or underlying seams. Pseudoelastic finite-element analysis using a yield-factor approach determines the stability of coal pillars by simulating the degree and extent of nrogressive rib failure and sub-sequent load transfer. Application of the procedure is demonstrated on a field problem. In-duced stress changes predicted from the numerical model analysis are in reasonably good agreement with stress measurements obtained from an instrumented chain pillar affected by remnant workings in an upper seam.

Jan 1, 1988

By R. A. Cattell

Progress of Bureau of Mines research related to oil and gas during the past fiscal year has been marked by the publication of more than 40 reports on the various phases of the work . These include papers dealing with the production of oil and gas , transportation of gas , chemistry and refining of petroleum , thermodynamic properties of hydrocarbons , and the processing and utiliza- tion of helium . As an additional service to Pennsylvania oil operators , a new suboffice was opened in Bradford , Pa . , during the year . With this addition , the work of the Petroleum and Natural Gas Branch of the Bureau of Mines is now conducted in two large stations , the Petroleum Experiment Station , Bartlesville , Okla . , and the Petroleum and Oil Shale Experiment Station , Laramie , Wyo . , and three field offices and laboratories at San Francisco , Calif . , Dallas , Tex . , and Franklin, Pa., and two suboffices, Wichita Falls, Tex., and the newly opened suboffice at Bradford, Pa. In addition, this Branch operates large-scale helium-production plants in Texas, Kansas, and New Mexico, and maintains ex- tensive helium-bearing gas reserves in Texas and New Mexico. All helium opera- tions are supervised from headquarters at Amarillo, Tex. A small headquarters staff is in Washington, D. C. A backward glance at the road traveled during the past several years by the Petroleum and Natural Gas Eranch of the Bureau of Mines brings out a general background for the events of the fiscal year 1949. Throughout the fiscal year 1945, the activities of the Branch were still mainly concerned with such war activities as making special field studies for the Petroleum Adminis- tration for War, finding ways of increasing rates of production, and supplying data pertaining to the manufacture of aviation and jet-propulsion fuels. A period of adjustment came in 1946, characterized by a turning from war to peace procedures and efforts to give wide distribution to technical facts ob tained in wartime research; also, there came a realization that the demands of war had broadened the horizons of research. This was emphasized in 1947, when a peacetime program was restored, based upon the long view of the Bureau's place as a research agency in oil and gas. Close attention was given to tech- nical detail in 1948, and emphasis was placed on maintaining a balance between the industrial need for technical knowledge and Governmental-research possi- bilities in the fields of (1) withdrawal of petroleum from natural deposits, (2) utilization of petroleum and its products, and (3) commercial utilization of helium. Studies of petroleum production and utilization and helium production and utilization are the normal functions of the Branch. These functions (sometimes expressed in different words) have been the mainstay of this organization since initiation of the work. The details of approach vary with changing conditions, but, fundamentally, the functions have been the same in both peace and war. The work of the past fiscal year has emphasized the advantages that accrue when Government and industry join in a wise use of technical and scientific knowledge gained through research. Outstanding evidence of the beneficial results of cooperative effort by the Bureau of Mines and various organizations is found in the following typical examples, the details of which are discussed in the body of this report. Working in close cooperation with operators along the Gulf Coast, the Natural Gasoline Association of America, and the National Association of Cor- rosion Engineers, the Bureau found, through field testing, that corrosion protection by means of chromates in high-pressure gas-condensate wells costs less than $1 per million cubic feet of gas produced. Laboratory experiments to measure the corrosion effects of carbonic and propionic acids on various steels and alloy steels gave data that will serve as guides in the selection of new. materials for the construction of well equipment to be tested by industry under actual service conditions.

Feb 1, 1950

By J. W. Town

Studies were made by the Bureau of Mines to determine the influence of textural features on the beneficiation of phosphate minerals (pellets) from selected bed and composite samples representing different rock types of the Western Phosphoria Formation. The particle size of the samples was reduced by attrition grinding to minus 20-, 28-, or 48-mesh depending on ore grade and gangue matrix. Sizing of the ground material showed that the phosphate pellets would concentrate in the plus 200-, 270-, or 325-mesh size fractions sufficiently so that the phosphate content was above the 31.5 :cent P2O5 required for acidulation. The phosphate content of essentially pure phosphate pellets was shown to range from 33 to 39 percent P2O5. Microscopic identification of the particles in each size fraction showed that the phosphate was either in the pellet form and readily liberated or so intimately associated with the gangue matrix that size reduction necessary Co obtain liberation was impractical.

Jan 1, 1967

By John C. Edwards

Standard smoldering and flaming combustion tests using smaIl coal samples have been developed by the U.S. Bureau of Mines as a method to evaluate the response of a smoke detector. The tests are con-ducted using a standard smoke box designed and constructed according to Underwriters Laboratories. The tests provide a standard, easily reproducible smoke characteristic for smoldering and flaming coal combustion, based upon a comparison of the smoke optical density and the response of a standard ionization chamber to the smoke. With these standard tests, the range of threshold limits for the response of a smoke detector and the detector's reliability can be evaluated for nearly identical smoke visibility and smoke physical characteristics. The detector's threshold response limits and reliability need to be well defined prior to the instrument's use as part of a mine fire warning system for improved mine safety.

Jan 1, 2010

By J. A. Herdlick

"INTRODUCTION The BeVan quartz crystal prospect in the Indian Creek mining district of Lemhi County, west-central Idaho, was examined by an engineer of the Bureau of Mines 3/ on July 9, 1943. As quartz crystals possessing peizoelectric properties were on the critical list of strategic war minerals, further exploration of the deposit was recommended. The Bureau of Mines exploration began in December 1943 and continued through January 1944. Additional trenching was completed during May and June 1944. This report presents the data obtained by this exploration.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. The Mining Division, Lowell B. Moon, chief, conducts preliminary examinations, does the actual exploratoiy work, and prepares the final report. The Metallurgical Division, O. C. Ralston, chief, analyses samples and makes beneficiation tests.The quartz crystals found during the exploration were examined and classified at the Bureau of Mines College Park, Md., laboratory and checked at the National Bureau of Standards, Washington, D. C.Fred BeVan, of North Fork, Idaho, and Edward F. Cenis, of the Montana Coal & Iron Company, Spoane, Wash., provided much information on the history and past production of the property."

Mar 1, 1948