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By G. H. Cobb, J. L. Johnson, H. H. Heady

An infrared absorbance technique is described for analyzing anodic gases produced during the electrowinning of uranium , thorium , and rare - earth metals in molten fluorides . Typical components determined qualitatively in a gas sample are CO , CO₂ , CF4 , C₂ Fe , C3F8 , COS , CS₂ , and SiF4 . About 20 minutes are required to record and interpret the spectrogram , and report quantitative results for CO, CO₂ , CF4 , and SiF . The procedure is used for control during electrolysis .

Jan 1, 1964

By W. K. Collins

Engineered scavenger compounds (ESC's) developed by the U.S. Bureau of Mines are a novel class of compounds that selectively can recover a desired element from a solid or molten alloy. Lithium titanate (L2Ti307 or Li2O?3Ti02) is used as an ESC to recover lithium (Li) from aluminum-lithium (Al-Li) alloys. X-ray diffraction measurements have shown that Li2Ti307 undergoes a phase change during scavenging from an orthorhombic structure to a hexagonal structure. This change is due to the incorporation of lithium in the matrix of the material and the effect of temperature. Although both phases are metastable, the hexagonal phase that forms during the scavenging of lithium from Al-Li alloys appears to be the more stable phase. Recovering lithium from the ESC by electrodeposition does not cause the structure to revert to the orthorhombic phase. The orthorhombic and the hexagonal structures of Li2Ti307 have similar scavenging capacities for lithium. This report proposes a new mechanism for the phase transformation.

Jan 1, 2010

By J. H. Field

Results of studies by the Federal Bureau of Mines on a pilot-plant scale for removing hydrogen sulfide and carbonyl sulfide from gas mixtures by the hot carbonate system are given in this publication. Gases containing up to 10 pet. hydrogen sulfide and 48 grains carbonyl sulfide per 100 cu.ft. were treated. In most tests carbon dioxide also was present and was removed simultaneously with the sulfur compounds. Because the rate of absorption of hydrogen sulfide is much more rapid than that of carbon dioxide over a wide temperature range, selective removal of hydrogen sulfide occurred in the bottom section of the absorber near the point of gas entry. Hydrogen sulfide was removed to pipeline specifications with carbonate solutions by using split-stream flows in the absorber and regenerator.

Jan 1, 1960

By Gregory J. Chekan

The Bureau of Mines, in an effort to improve planning and development in coal mining, is investigating strata interactions associated with mining of multiple coalbeds. Two common interactions that occur between adjacent coalbeds are subsidence and pillar load transfer. The study described involves underground observations and measurements conducted at two Pennsylvania mines, each affected by one of these interactions. At the mine affected by subsidence, measurements show that undermining had little effect on upper mine pillar stability, but had a more severe effect on the development and maintenance of entries. Roof-to-floor measurements recorded over four times more convergence in entries developed over gob as compared with entries developed over support pillars in the lower mine. At the mine affected by pillar load transfer, Initial in situ measurements have shown the existence of a pressure arch in the lower workings. Prior research has shown that arch interaction between two adjacent openings can create stress concentrations in the in-nerburden. Underground measurements and results obtained from both mine sites correlate with theoretical and photoelastic multiple-seam models, and eventually these field data will serve to refine model accuracy. Further study of multiple-seam interaction mechanisms will lead to improved mine planning, increased resource conservation, and a safer working environment.

Jan 1, 1986

By H. F. Yancey

This report, dealing with the separation of coal from its associated impurities by means of a pulsater-type jig, continues the series of reports that have been issued by the Bureau of Mines, in which detailed study has been made of the efficiency and mechanism of separating coal and impurities in various coal-cleaning appliances. The previous reports have dealt with the piston jig, coal-washing table, pneumatic table, and Baum-type jig. Such studies of the separation accomplished by any form of concentration device are essential and necessarily preliminary to any intelligent attempt to improve the performance of such equipment Object and Plan The pulsator-type jig was developed recently by G. A. Vissac. Although two articles(2) describing plants using this typo of cleaning unit appeared in 1936, both dealt principally with plant design and layout rather than with plant performance The object of the stork described in this report was to determine the efficiency of the separation made by the pulsator jig on a sized feed, the specific gravity at which the separation between coal and impurity was effected, and the influence of the specific-gravity composition of the coal on the character of the separation made.

Jan 1, 1938

By H. F. Yancey

This report, dealing with the separation of coal from its associated impurities by means of a pulsator-type jig, continues the series of reports that have been issued by the Bureau of Mines, in which detailed study has been made of the efficiency and mechanism of separating coal and impurities in various coal-cleaning appliances. The previous reports have dealt with the piston jig, coal-washing table, pneumatic table, and Baum-type jig.5/ Such studies of the separation accomplished by any form of concentration device are essential and necessarily preliminary to any intelligent attempt to improve the performance of such equipment Object and Plan The pulsator-type jig was developed recently by G. A. Vissac. Although two articles(2) describing plants using this type of cleaning unit appeared in 1936, both dealt principally with plant design and layout rather than with plant performance The object of the stork described in this report was to determine the efficiency of the separation made by the pulsator jig on a sized feed, the specific gravity at which the separation between coal and impurity was effected, and the influence of the specific-gravity composition of the coal on the character of the separation made.

Jan 1, 1938

By R. S. Fowkes

Jetstream pressure distributions and coal cutting rates were determined for a number of nozzles and under different operating conditions. The jetstrearn pressure distribution data were fitted to an assumed curvilinear equation by the utilization of a numerical least-squares technique with the aid of a digital computer. Subsequent manipulation of the approximation equation showed that the total force of the jetstream, rather than its maximum pressure or total kinetic energy per unit Lime, was the most significant quantity affecting the coal cutting rate. A shorter method for assessing the ability of a nozzle to cut coal was found.

Jan 1, 1968

By Dean H. Ambrose

Using three-dimensional (3-0) graphics computing to evaluate new technologies for computer-assisted mining systems illustrates how these visual techniques can redefine the way researchers look at raw scientific data. The U.S. Bureau of Mines is using 3-D graphics computing to obtain cheaply, easily, and quickly information about the operation and design of current and proposed mechanical coal and metal-nonmetal mining systems. Bureau engineers developed a graphics simulator for a continuous miner that enables a realistic test for experimental software that controls the functions of a machine. Some of the specific simulated functions of the continuous miner are machine motion, appendage motion, machine position, and machine sensors. The simulator uses data files generated in the laboratory or mine using a computer-assisted mining machine. The data file contains information from a laser-based guidance system and a data acquisition system that records all control commands given to a computer-assisted mining machine. This report documents the first phase in developing the simulator and discusses simulator requirements, features of the initial simulator, and several examples of its application. During this endeavor, Bureau engineers discovered and appreciated the simulator's potential to assist their investigations of machine controls and navigation systems.

Jan 1, 1992

By V. R. Miller

The Bureau of Mines conducted research on substitute brazing filler alloys with properties similar to those of silver filler alloys in an effort to conserve silver and reduce hazards from cadmium emissions. Experimental work was conducted first on the commercial silver brazing alloys BAg-I, BAg-la, BAg-2, and BAg-3 to establish criteria for evalu-ating the substitute alloys. Properties investigated included the wettability of copper, brass, and steel substrates, and the strength of joints made with the filler alloys. A series of experimental alloys containing 50 to 60 pct Cu, 20 to 28 pct Mn, and 17 to 30 pct Zn was prepared and evaluated, together with Cu-Mn-Zn alloys with 5 pct Pb or 2 pct Ni. Wetting properties and joint strengths were not as good as those for silver filler alloys, and the high application temperatures reduced the copper and brass base metal strengths. However, experimental alloys containing 70 pct Cu, 15 to 20 pct Mn, and 10 to 16 pct Sn had wetting and strength properties approaching those of the silver filler alloys. The application temperatures for these alloys were high-er than those for silver fillers, but not as high as those for the Cu-Mn-Zn alloys. With the Cu-Mn-Sn alloy fillers, copper alloy joint members are less deteriorated by recrystallization than when applying Cu-Mn-Zn alloys. The Cu-Mn-Sn system has potential for further devel-opment as a substitute brazing alloy system, particularly if the melting temperature can be reduced by the addition of other elements without decreasing the ductility and wetting.

Jan 1, 1983

By James J. Dowd

The investigation to evaluate the reserves of coking coal is being made by the Bureau of Mines in three parts: (1) To estimate known (measured plus indicated) recoverable reserves of all coking coal, (2) to upgrade marginal coals through effective preparation, and (3) to study the carbonizing properties of coal and coal blends not now widely used for metallurgical coke making. This is the seventh of a series of reports giving the results of studies by counties under part (1) of the investigation. (See appendix.) This report covers Floyd County, KY., which comprises parts of the Paintsville, Prestonsburg, Harold, Hindman, and Pikeville quadrangles. (See fig. 1.) A base map for each bed in each quadrangle was made to the scale of 1 inch equals 1,200 feet. Maps of mines, locations of drill holes, bed and total coal thicknesses, and the outcrop of the bed were plotted on the maps. With all avail-able data plotted, isopach lines were drawn to limit areas of known unmined reserves in beds up to 14 inches thick, 14 to 28 inches thick, 28 to 42 inches thick, and over 42 inches thick. These areas of coal reserves also were divided into "measured" and "indicated" categories. All areas in each thickness range and in each category, mined-out areas, areas excluded from the estimate but which may contain reserves based only on geologic inference, and areas outside of the outcrop were measured by planimeter on the base maps. Estimates of total reserves 14 inches and more thick and maps for individual beds were prepared from these data.

Jan 1, 1951

By R. A. Beall

This paper summarizes the development of a furnace for producing titanium castings. The general problem is outlined and chronological details are given on the construction and operation of four different casting furnaces, all utilizing consumable-electrode arc heating and water-cooled copper crucibles. Of the two methods of pouring, the tilt-pour technique has been more satisfactory than bottom tapping. Mold design, electrode fabrication, and deep-pool production are discussed. INTRODUCTION In the early summer of 1953 the Bureau of Mines was contacted by the Department of the Army through Watertown Arsenal to explore the possibility of conducting research on casting titanium metal. The objective of the program was "to develop a technique for producing formed castings of titanium metal not less than 40 pounds in weight and without introduction of deleterious contamination."

Jan 1, 1956

By Francis X. Cannaday

The purpose of this investigation was to find whether the moduli of elasticity obtained were the same for the following methods : ( 1 ) Deformation of a borehole in a prism subjected to uniaxial stress ; ( 2 ) deflection of a thin beam of uniform cross section uniformly loaded ; ( 3 ) sonic - pulse velocity measurements , and ( 4 ) strain measurements on a prism under uniaxial stress . The rock tested was chosen for its good elastic behavior and relatively good homogeneity and elastic isotropism . The same rock was used for all methods . Results indicate that for given environmental and stress conditions the moduli obtained by each of the four methods check one another within the limits of experimental error and that the differences introduced which are characteristic for each method are smaller than physical variations within the rock tested .

Jan 1, 1964

By E. C. Lane

This paper is a preliminary report of the results of the Bureau of Mines' twenty-second semiannual survey of motor gasoline marketed in the United States. A more detailed discussion of the whole survey is in preparation and will be published as a companion, report. The second paper, in addition to giving a more complete summary of the data included in this report, will present results of the determination of copper-strip core lion (method 530.22), color (method 10.11), sulphur content (method 520.11) evaporation residue (method 530.1), and gum content as given by the Bureau of Mines steam oven method.9 The retail price at the time the sample was taken and tax will also be stated for each sample. The present paper deals specifically with data relating to gravity, vapor pressure, and distillation. It has been the feeling of some investigators that the practice, followed in previous semiannual surveys, of grouping all types of motor fuel together without discriminating between "competitive price gasoline," benzol blends, Ethyl gasoline, "high-test" fuels, etc., has detracted from their usefulness because the data did not permit drawing conclusions in regard to any one type of fuel, and tended to obscure differences between fuels of the various types. Therefore, in order to remedy this condition, the samples of the present survey have been divided into two groups; one called "competitive-price gasoline" and a second group called "premium-price motor fuels."

Jan 1, 1930

By E. C. Lane

This paper is a preliminary report of the results of the Bureau of Mines' twenty-second semiannual survey of motor gasoline marketed in the United States. A more detailed discussion of the whole survey is in preparation and will be published as a companion, report. The second paper, in addition to giving a more complete summary of the data included in this report, will present results of the determination of copper-strip corrosion (method 530.22),5 color (method 10.11),6 sulphur content (method 520.11) copper-dish evaporation residue (method 520.11),7 and gum content as given by the Bureau of Mines steam oven method.9 The retail price at the time the sample was taken and try will also be stated for each sample. The present paper deals specifically with data relating to gravity, vapor pressure, and distillation.

Jan 1, 1930

By William A. Beck

This paper is one of a series, describing current practice in diamond drilling for production at various mines throughout the United States. It describes the drilling and blasting methods, used at the Tennessee Copper Co., which started using deep-hole drilling for blasting in 1927, employing inde- pendent, rotation percussion drills with sectional drill steel. Since 1942 the company has employed diamond drills for deep-hole drilling. This method has now passed the experimental stage and promises to become permanent. The elimination of rock dust and safer working conditions for the drill crews are listed as the main advantages. The higher initial cost of equip- ment is the principal disadvantage.

May 1, 1948

By Richard L. Rains

During this study in 1983, the U.S. Bureau of Mines examined one mine and five prospects in the Greenwater Valley Wilderness Study Area (WSA). No mineral resources were identified within the WSA. Principal mineral commodities in the WSA are gold and silver with minor lead, and zinc. Two properties have significance; sample analyses indicate the Salsberry Prospect may have gold-silver-lead-zinc resources, and the Graham Jem Mine may have gold resources. The likelihood for development is greatest at the Salsberry Prospect, although the only recorded production from the study area was from the Graham Jem Mine; in 1908 less than 1 ton of gold-bearing ore valued at $25,000 per ton was produced. Gold, silver, lead, zinc, and copper minerals in the WSA are associated with rhyolite dikes and quartz veins in Precambrian gneissic rocks, commonly concentrated in sheared zones along the dikes and veins. Although known to contain silver-lead deposits elsewhere, Precambrian Noonday Dolomite sampled inside the WSA contained no significant mineral values. Much of the WSA is covered by relatively unmineralized Tertiary and Quaternary volcanic rocks. The Bureau collected 140 rock samples at four adits, nine shafts, four trenches, and 33 prospect pits in the WSA. In 1983, 14 lone claims and one millsite within the study area were current. No patented claims, placer claims, or coal, mineral, oil and gas, or geothermal leases were in the WSA.

Jan 1, 1985

By H. S. Auvil

[Coals of low-volatile rank cannot be coked without admixing large proportions of high-volatile cod in the used type of byproduct-coke oven, because they expend excessively and. exert side thrust, which ruins the oven wells. Some medium-volatile coals also give trouble. Since high-rank coals produce a strong, blocky coke, it is desirable to have the rank as high as practicable, particularly in the manufacture of foundry coke. Accordingly, it has become the practice to mix or blend high-volatile shrinking coals with as much low-volatile coal as possible and still have a mixture that mill not deform the walls or cause difficulty in pushing the coke. Occasionally, the safe limit of low-volatile cool has been exceeded and ovens have been damaged. It is desirable, therefore, to have a reliable method of determining the expending tendencies of mixtures before they are charged into the ovens. Furthermore, coal changes somewhat in its properties as mining progresses, end therefore, mixtures found to be safe at one time may cease to be so subsequently, particularly if nearly the maximum allowable percentage of low-volatile coal is being used. ]

Jan 1, 1938

By E. Wittenau

This paper describing the concentrator practice of the Copper Queen Branch of the Phelps Dodge Corporation at Bisbee, Ariz., is one of a series of papers on milling methods and costs being prepared by the United States Bureau of Mines. The Copper Queen Concentrator treats 4,000 tons of copper ore daily by preferential flotation, whereby the copper sulphides are floated and considerable iron pyrite is depressed. During 1929 the heads to the concentrator averaged 2.15 per pent of copper, the recovery was 91.32 per cent of the total copper, and the concentrates produced contained 12.92 per cent of copper.

Jan 1, 1931

By W. D. Mcmillan

The Dempsey tract in Washington County, Mo., had a small production of lead-zinc ore from shallow workings. Old dumps from early-day lead mining contain about 25,000 tons of ore averaging about 3 percent combined zinc and lead. Because of the urgent war requirements for lead and zinc, the Dempsey property was examined by Otto Ruhl, formerly an engineer of the Bureau of Mines in August 1942 and selected for further investigation by churn drilling twenty holes totaling 1,309 feet were bored in the fall of 1943. The results of the work are presented in this paper.

Jan 1, 1948

By D. W. Mitchell

This Bureau of Mines report summarizes experience and past research on methods for sealing abandoned areas of a coal mine and areas from which the pillars have been wholly or partially extracted. The Federal Coal Mine Health and Safety Act of 1969 requires that such areas be ventilated or sealed with explosion-proof bulkheads, but the present study indicates that bulkheads alone cannot isolate areas in a coal mine in which methane and other dangerous gases have accumulated. Gas-air exchanges between sealed and open areas must be controlled.

Jan 1, 1971