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By V. M. Benson

A simplified, routine method for determining lithium in lithium-bearing rock is presented. The sample is decomposed by repeated treatments with nitric, hydrofluoric, and perchloric acids. Since this procedure does not appreciably dissolve beryl, interference by beryllium (the principal interfering cation) is minimized for most samples. The salts are brought into solution with water and enough citric acid-ammonium citrate buffer is added to make the final volumetric dilution 0.20 M with respect to citrate. The addition of citrate greatly reduces anion interference in the hydrogen-oxygen flame, slightly increases the intensity of the lithium 671 millimicron emission line, and reduces the effect of most of the interfering cations to the extent that analytical separations are not necessary. The accuracy of results of single determinations of lithium in a pegmatite containing spodumene, lithium-bearing mica, and beryl are approximately equal to that obtained by other flame methods, INTRODUCTION This investigation was undertaken in Bureau of Mines laboratories to develop a reliable, rapid, routine analytical method for determining lithium in lithium-bearing minerals. The requirements of the procedure were that the method should be applicable to the analysis of a variety of lithium-bearing ores and test products, and the results would be reasonably accurate for materials containing 0.05 to 8 percent Li20.

Jan 1, 1961

By James Paone

This report shows the feasibility of predicting drillability, analytically, by using regression analysis techniques. The approach is new in diamond-drilling research. Further, the study shows that this technique may be of value to drill manufacturers and others in mathematically delineating performance characteristics of new drills in specific rock types. Another application might be the prediction of penetration speeds in extraterrestrial material based on the physical properties of the materials as samples become available. Prediction equations for penetration rates are presented for 9 rocks drilled in the laboratory and for 20 rocks drilled under field conditions. The prediction equations are based on drill operating parameters and on characteristics of the rock penetrated. No single physical property appeared consistently in the best predictor equations, and all the physical properties were found to be highly correlated with each other.

Jan 1, 1966

By Manuel Gomez

Carbon number distributions were obtained for tar acid fractions from five low-temperature tars by low-ionizing voltage mass spectrometry. Quantitative data for phenols representing seven structural compound types were examined by statistical analysis. It was shown that for the phenols discussed, the data could be represented by regression equations expressing phenolic concentration as a function of the reciprocal of the carbon number and the carbon-to-hydrogen ratio of the parent coal. The total concentration of each structural type present was found to depend on the molecular weight and boiling point of the initial member of the group. Carbon distribution data for the tar acid fractions studied support the view that low-temperature tars contain the same chemical compounds but in different proportions.

Jan 1, 1965

By P. E. King

The U.S. Bureau of Mines is conducting an ongoing research project to better understand the phenomena involved within electric arcs utilized in electric furnace steelmaking. With a better understanding of the physical and electrical characteristics involved, dynamic or predictive control of electric arc furnaces may be possible. A mathematical model is presented, but not solved, and the system of coupled equations is analyzed. Characteristic parameters are used to determine relative importance. In this manner, significant quantities are dermed. The parameters found to contribute little to the system of equations of motion are ignored. A resultant simplified system is identified, and directions for further study are indicated toward control of electric arc furnaces.

Jan 1, 1990

By Marvin L. Whisman

This report describes the preparation of tritium-labeled organic compounds to be used by the Federal Bureau of Mines in studying the role of certain gasoline constituents in gum-forming mechanisms. The gasoline constituents that have been investigated boil within a range of approximately 90 to 230° C. and can be classified as paraffins. naphthenes, olefins, diolefins, monocyclic aromatics, polycyclic aromatics, and organic sulfur, nitrogen,: and oxygen compounds. The technique of Wilzbach has been applied to more than 50 samples. Purification techniques have been developed that accomplish rapid and effective purification as well as removal of labile tritium in a one-step operation. Data are presented to show the rate of exchange between tritium and hydrogen that can be expected for a variety of compounds common to a full-boiling-range gasoline. These values should be useful to other investigators using tracer programs involving tritium labeled compounds.

Jan 1, 1961

By Joseph J. Wallace

1. The Pittsburgh is the most important bed in Washington County from the standpoint of present production and recoverable reserves. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 short tons per acre-foot of coal in place, are estimated at 4,181 million short tons as of January 1, 1954. Of this total, 4,132 million short tons is in beds 28 inches and more thick. Areas in some beds were omitted from the estimate because available data relative to the bed characteristics are too meager for making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1955

By Stephan Stecura

Crystallographic modifications and kinetics of solid-state phase trans-formations were determined for five rare-earth" sesquioxides--La2O3, Nd2O3, Sm2O3, Eu2O3, and Gd2O3. Oxides used for crystal modification studies were prepared by thermal decomposition of the following high-purity salts of the five rare-earth elements--carbonates, chlorides, fluorides, nitrates, oxalates, and sulfates. X-ray diffraction patterns of the cubic and hexagonal oxides were indexed by a graphical method and patterns of the monoclinic oxides by Ito's method. The kinetics of crystallographic transformation were determined by high-temperature X-ray diffractometry. The kinetic data were interpreted using a shrinking sphere model. All of the transformations followed first order kinetics. Activation energies were calculated by application of the Arrhenius equation. These solid-state phase inversions were concluded to occur by a reconstructive transformation mechanism.

Jan 1, 1965

By R. S. Dean

The development of metallurgical processes may be divided into periods : First , the discovery of a basic reaction which brings about the production of the desired product from the available raw material ; second , a long stage of mechanical development during which little or no attention is paid to the reaction itself ; and third , a careful study of the reaction . Most metallurgical processes are to -day approaching the end of the second period . This we may illustrate by the steel process . The reaction of carbon with iron ore to produce pig iron and the subsequent refinement of the pig iron by an oxidation reaction is very old . Development in modern times has been almost entirely mechanical , the development of the blast furnace , furnace , the Bessemer process , the Siemens process , and even the Aston process for wrought iron being mechanical improvements almost entirely . Metallurgy is now entering a phase where the reactions are being considered . The question of how far can they be made to proceed is being repeatedly asked . As mechanical processes are improved , we approach a limit to which our basic reactions can be pushed which is determined by the nature of the reactions themselves . We want to know : How far can iron be decarbonized by iron oxide ? How low can the oxygen of copper be reduced by any given reaction? How efficiently can the fuel in a zinc reduction process be used ? The demand for purer metals and lower production costs has forced these and similar questions upon us . How are we to answer them ? The determination of these equilibria or end points of metallurgical reactions by direct means is fraught with difficulty because here we must overcome mechanical difficulties which too often become the limiting factors even in the laboratory and we do nottherefore get the actual limit to which the reaction itself may be carried . Further , there are so many reactions of metallurgical materials that to survey each separately is a job to give pause to any experimenter or group of experimenters .

Dec 1, 1930

By Stephen Utter

Stresses induced by block-caving mining were estimated from in-place measurements of strain or deformation in rock and concrete around mine openings. The four types of gages used for measurements in the Climax Molybdenum mine during 1959-61 were Whittemore gage, Carlson strain meter,2 Valore strain cell, and Climax extensometer. Gage performance in the laboratory was evaluated by stressing instrumented rock and concrete specimens in a universal testing machine and by comparing measurements taken by the gages and a standard gage. Gage performance in the mine was evaluated by comparing measurements taken during an 18-month test. The Whittemore gage, Carlson strain meter, and the Climax extensometer proved suitable for the investigation; the Valore strain cell, effective in the laboratory tests, gave erratic measurements in the mine.

Jan 1, 1965

By H. D. Baylor

This is the first of a series of papers describing mining methods and costs at cement plant quarries throughout the United States and deals directly with those methods employed and costs obtained at the quarry of the Louisville Cement Co. located at Speed, Ind. ACKNOWLEDGMENTS The author wishes to acknowledge the assistance of Mr. J. M. Buohheit, superintendent of quarries, and Mr. H. E. Schoonover, quarry engineer, in furnishing data and in compiling this report.

Jan 1, 1930

By R. T. Johansen, R. J. Heemstra

In water flooding the gradual accumulation of insoluble materials on the sand face causes the injection pressures to increase while decreasing the amount of water injected . This plugging material often is composed primarily of insoluble precipitates of calcium , iron , and magnesium . Treatment with sodium tripolyphosphate ( STP ) either eliminates or reduces the formation of precipitates . Field tests are discussed showing the almost immediate effects of using STP in the injection water . Methods of treatment , solubility of STP in fresh water and brines , and precautions to observe when starting to treat a waterflood with this chemical are given . Laboratory data show that the preferential wettability of a crude oil for reservoir rock can be reversed by adding a small amount of STP to the flooding water . This reversal in wetting tendency should not only decrease the injection pressures but also increase oil recovery by improving the sweep efficiency of a water flood .

Jan 1, 1964

By R. G. Travis

1. Reserve estimates have been made for eight coal beds in Monongalia County, W. Va., but only the Pittsburgh, Sewickley, and Upper Freeport beds are important at this time. The Pittsburgh, Sewickley, Waynesburg, and Upper Freeport beds contain the largest recoverable reserves. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 short tons per acre-foot of coal in place, are estimated at 3,526 million tons as of January 1, 1954. Of this total, 3,294 mil-lion tons is in beds 28 inches and more thick. Areas in each bed except the Pittsburgh were omitted from the estimate because available data relative to the bed characteristics are too meager for making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1956

By O. C. Blade

"INTRODUCTION This report on the properties of aviation gasolines and aviation jet fuels produced in the United States during 1952 was mode under a co¬operative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior.Analytical data are presented for 94 samples of aviation gasoline which include for the first time in this series of reports, data on five samples of grade 108/135 aviation fuel. Data also are given for 34 samples of aviation jet fuel. The analyses were made on samples typical of the manufacturers' production in their laboratories and the results sub¬mitted to the Bureau of Mines for compilation. The products of 20 manufacturers of aviation gasolines and of 16 producers of aviation jet fuels are represented.SUMMARYA comparison of certain properties of the commercial aviation gasolines produced in the United States during 1950, 1951, and 1952 is presented in table 1, the 1952 data being average values from tables 3 through 7 of the present report. Trends in certain characteristics of these fuels may be seen in figures 1 through 5 which also indicate the minimum and maximum values. As may be observed, the properties of commercial aviation gasolines have not varied greatly during recent years. A list of aviation-fuel survey reports published by the Bureau of Mines is given on page 7.Table 2 presents a summary of data from table 8 and compares properties of aviation jet fuels of 1952 with summarized data on jet fuels of October 1951."

May 1, 1953

By Irving Hartmann

1. Under the conditions of the tests described herein, the proper use of an incombustible stemming plug of the type discussed prevented ignitions of gas in all tests during the firing of 21 single shots of permissible explosive in cool. In two tests with multiple blasting (four and five shots each) no ignitions resulted. 2. The results of a few tests in this investigation and of numerous tests made previously indicate that fire-clay stemming of the same weight as an incombustible plug provides about the same degree of protection as the plug against gas ignitions during blasting of coal by permissible explosives. 3. The hazard of gas ignition on firing charges of non-permissible 40-percent gelatin dynamite in coal was reduced but not eliminated when the shot holes were stemmed with one or two incombustible plugs or with an equivalent weight of fire clay. 4. On the basis of this investigation, the Bureau of Mines considers the proper use of incombustible stemming plugs of the design tested, under the conditions of the tests described in this paper, to be of equivalent safety as the same weight of fire-clay stemming. This report does not constitute approval or disapproval of the incombustible stemming plugs by the Bureau of Mines. 5. The test data indicate that misfired charges in shot holes stemmed with the incombustible stemming plug cannot be disposed of with certainty by the procedure recommended by the manufacturer. In this investigation the misfired charges failed to detonate in 30 percent of the trials.

Jan 1, 1950

By Robert R. Perron

The U. S. Bureau of Mines is engaged in many diverse programs for improving mine safety. Of particular interest to the Bureau are new and improved means for minimizing the hazard of fire which can be initiated by prolonged low energy electrical faults on trolley line systems. When a high energy fault occurs on a trolley line, wherein the current exceeds the magnitude normally drawn by legitimate loads, such as locomotives, then the circuit breakers at close-by power rectifier sets trip. Tripping of the breakers not only protects the equipment at the rectifier sets, but also disconnects the energy source from the fault and thereby minimizes the fire risk. However, the fault current is frequently of a level substantially below that required to trip the overload breakers. When the fault is a substantial percentage of the set level of the breakers, the energy dissipated by the fault is frequently sufficient to clear the system by rapidly burning itself clear. Such a fault is often short-lived and does not present as serious a fire risk hazard as a prolonged, much lower energy fault, wherein the energy level is too low to clear the system. The breakdown of a trolley line insulator, in which there was a 15 to 30 ampere fault to ground, would represent such a fault or illegitimate load and a substantial fire risk.

Jan 1, 1975

By Charles Vaught

The U.S. Bureau of Mines evaluated the self-contained self-rescuer (SCSR) donning proficiency of 243 miners. These workers were from eight underground coal mines in the eastern United States. The objectives of the study were (1) to gather information on skill levels, since all miners in the study had prior instruction and opportunity to practice donning the apparatus, and (2) to summarize a quality control procedure useful in conducting periodic evaluations of donning proficiency. The sampling procedure used proved to be both reasonable and efficient in gathering information on training effectiveness_ It also provided a good statistical base for making informed site-specific decisions regarding SCSR training needs. Results from the observed samples at each of the eight mines indicate a wide variability across sites. The rate at which miners failed to isolate their lungs varied from 33 to 40.0 pct. Concomitantly, proficiency rates (miners either performing adequately or demonstrating a perfect 3+3 sequence) ranged from 13.3 to 63.3 pct.

Jan 1, 1991

By T. E. Howard

The western phosphate field, comprising parts of Idaho, Montana, Wyoming, and Utah, contains one of the world's largest known reserves of phosphate rock. Although phosphate-rock deposits of good-grade have been known since before the turn of the century and production has been recorded since 1906, real development of this important field did not begin until immediately after World War II. Since then fertilizer-manufacturing facilities using western phosphate rock have been expanded, and three electric-furnace plants for producing elemental phosphorus have been installed, resulting in a rise in mine production from 323,955 long tons2/ in 1945 to 1,653,916 long tons3/ in 1953. Interest in the field is increasing, and it is reasonable to expect that the western phosphate industry will continue to expand. Before 1945 all western production was from underground mines. In that year the first strip mine in the field was started near Montpelier, Idaho,~ and in sub-sequent years a number of other open-pit mines were opened in southeast Idaho and western Wyoming. At present the major part of the production comes from surface mines. Underground mining has continued, and new underground mines have been opened in the field, but recent exploration by operating companies has been aimed primarily at developing additional deposits suitable for low-cost surface mining. Preliminary reserve estimates by the Federal Geological Survey5/ indicate that only a very small part of the total resource may be recovered by surface methods and that the industry eventually must depend largely on underground mining. Because one function of the Bureau of Mines is promoting the conservation and development of the Nation's mineral resources, it is appropriate that research be conducted to develop low-cost maximum-recovery underground mining methods applicable to western phosphate-rock deposits.

Jan 1, 1956

By E. G. Davis

Large-scale ultrafine grinding tests of a coarse kaolin were made using the Bureau of Mines developed attrition grinding process in continuous open-and closed-circuit systems. A 20-inch diameter attrition grinder, designed and constructed at the Tuscaloosa Laboratory, was used. Studies included single- and multiple-stage open-circuit grinding, and also continuous grinding tests in closed-circuit with a 6-inch-diameter solid bowl centrifuge. Clay feed, containing 9.0 percent minus-2-micrometer esd, was used at fates up to 840 pounds per hour. Multistage grinding tests gave better results than single-stage treatment when equivalent clay feed rates were used. Closed-circuit grinding tests yielded ground products containing slightly more minus-2-micrometer-esd clay than the open-circuit grinding when using the same clay feed. Energy consumption was lower in closed-circuit grinding than in batch or open-circuit grinding. A modified two-stage closed-circuit grinding system gave the best grade of product and amount of minus -2-micrometer-esd clay produced per pound of clay feed. The ground product from this test contained 88.5 percent minus-2-micrometer-esd material and electrical energy consumption was 327 kilowatt-hours per ton of minus-2-micrometer-esd material produced.

Jan 1, 1973

By James Paone

The Bureau of Mines studied the behavior of rocks at the initial state of crater formation that results from the stresses created under a drill bit to determine which mechanical properties of rock are important in rock fragmentation by drilling. Although a definite relation between the drilling strength and relevant mechanical properties has not been established, maximum yield strength of rock is apparently a parameter of drillability of rock. The strengths of rock were considered from the Mohr-Coulomb criterion from which the surface of failure was constructed. The results from previous tri-axial tests on Solenhofen limestone were adopted to verify the criterion of failure. Inelastic behavior of some rock types was observed under a low-velocity impact of a hemispherical bit and under static indentation with a similar bit. Quantitative determinations of strengths of Solenhofen limestone) Indiana limestone, and Tennessee marble were made under static indentation. The maximum yield strength estimated from the average stress over the indented area was used as the crushing strength of rock under a drill bit.

Jan 1, 1966

By Margaret R. Egan

This Bureau of Mines report presents results from experimental studies on wood crib fires in an intermediate-scale fire tunnel. Gas concentrations, smoke particle characteristics, heat release rates, and ventilation rates were determined. These measurements form a data base for wood, which can be used with previous analyses for coal and future studies of other mine combustibles, to comprehend the potential hazards of these materials in underground mine fires. A knowledge of the combustion products emitted from these materials will benefit fire detection and control. Results show the changes in burning rate and heat release rate produced by different crib configurations and ventilation rates. Also included are the effects that the burning rate has on smoke characteristics and gas production.

Jan 1, 1986