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By C. M. Frost

Crude shale oil produced by gas combustion retorting of Green River oil shale was hydrocracked over a cobalt molybdate catalyst at operating pressures of 500, 1,000, 1,500, and 3,000 psig, an operating temperature of 8900 F, and a liquid hourly space velocity of 1.0. Hydrogen feed rate was maintained at 6,000 scf/bbl. The volume-percent yields of total liquid product were directly proportional to the operating pressure. Weight-percent conversion and volume-percent yields of gasoline were directly proportional to the log of the operating pressure. Catalyst deposit percentages were inversely proportional to the log of the operating pressure. Nitrogen and sulfur removal rates as well as saturation of the liquid products increased as the operating pressure was increased.

Jan 1, 1973

Reduce the time, complexity and expense of dissolving metal and mineral samples in solution in preparation for chemical analysis. Approach In earlier research, the Bureau of Mines developed a rapid and inexpensive method for the dissolution of mineral and metal samples in plastic pressure bottles heated in a boiling water bath. Using this technique, samples could be prepared for chemical analysis in less than one hour compared with several hours by traditional dissolution methods (see Technology News No. 85, December 1980 for further details). By heating in a microwave oven, sample dissolution time can be reduced to approximately 5 minutes.

Jan 1, 1983

By Ann G. Kim

Gas samples containing 02, N2, H2, He, CO2, CO, CH4, and trace amounts of C 2 to C6 hydrocarbons are analyzed by a gas chromatographic method that utilizes both thermal conductivity and flame ionization detectors. A porous polymer support and molecular sieve columns are used with argon as the carrier gas. A column selector valve makes it possible to perform a complete analysis either on one 1-ml sample in 40 minutes or on two samples in 20 minutes, one sample for each detector. Samples are introduced either by on-column injection or through a gas sampling valve. By varying operational parameters, the speed, sensitivity, and accuracy of analysis may be modified to suit a particular situation.

Jan 1, 1974

By Sabri Ergun

The method of constant compositions involves the determination of the time required for the attainment of a given conversion at various temperatures. Heretofore, it has been used in evaluating the energy of activation only. A development of the method, made in the present study, makes possible the evaluation of the functional dependence upon composition and the frequency factor in addition to the energy of activation. INTRODUCTION Kinetics of reactions are best analyzed in the light of the mechanism, energy requirements, and forces involved in the reaction. Such physico-chemical information is not often available in solid state phase transformations. The reaction rates are followed by changes in a physical property during the course of the reaction, and repeating the experiment at different temperatures permits the determination of activation energy only. The possibility of a complete kinetic analysis by such a purely "phenomenological" approach has been questioned.4/ In this report a method is developed making possible the evaluation of the functional dependence upon composition and frequency factor in addition to the energy of activation. The application of the method to a study of solid state order-disorder changes is demonstrated.

Jan 1, 1960

By Fred N. Kissell

Methane-flow and pressure data taken from a mine in the Pocahontas No. 3 coalbed are compared with flow rates from lump coal obtained in laboratory experiments. From this, it is concluded that the main source of gas is the intact coalbed rather than a "crushed zone" near the working face. The permeability and sorption capacity of the intact coalbed are calculated and gas emission rates are theoretically accounted for.

Jan 1, 1972

By Robert M. Becker

A thick-wall cylinder solution applicable to the evaluation of anisotropic elastic parameters is derived for the interpretation of stress relief data. For a restricted class of problems, a special relationship among certain orthotropic moduli yields stress distributions for the plane orthotropic problem that are identical to the corresponding isotropic case. A ring or hollow cylinder with these specialized anisotropic properties subjected to uniform radial loads is one of the problems in this class. Consequently, known stress solutions are used to develop the strains and displacements for a specialized orthotropic thick-wall cylinder under uniform pressures. The results are consistent with anisotropic equations used in the evaluation of in situ rock stresses.

Jan 1, 1968

The National Institute for Occupational Safety and Health (NIOSH) recommends that occupational exposures to respirable coal mine dust and respirable crystalline silica* be controlled by complying with the provisions presented in this document. These recommendations are designed to protect the health and provide for the safety of workers exposed to respirable coal mine dust and respirable crystalline silica for up to 10 hr/day during a 40-hr workweek over a working lifetime. The information presented in this document demonstrates that underground and surface coal miners are at risk of developing simple coal workers' pneumoconiosis (CWP), progressive massive fibrosis (PMF), silicosis, and chronic obstructive pulmonary disease (COPD). Adherence to the recommendations in this document should prevent or greatly reduce the risk of adverse health effects in workers exposed to respirable coal mine dust and respirable crystalline silica. NIOSH recommends that preventive efforts be focused primarily on reducing worker exposures. Effective health and hazard surveillance and medical screening are also useful components of a comprehensive prevention effort.

Jan 1, 1997

By G. M. Wilemon

The Bureau of Mines conducted preliminary investigations on the use of an acid-alcohol leaching technique for recovering phosphate values from phosphate matrices. H2S04 and methanol were used as the leaching agents. Starting-matrix particle size and acid-apatite ratio were found to significantly affect the efficiency of phosphate leaching. Phosphate extractions of more than 80 pct were obtained when minus 200-mesh ore was used and the acid-apatite ratio was 8:1 or more. The iron and aluminum oxide impurities (R203) present in the crude acid products were monitored, and R203-P205 ratios are reported. Phosphate extractions in excess of 80 pct also were obtained when phosphatic clay wastes were leached. Typically, leach slurries filtered using test leaf filters ex-hibited filtration rates of 100 lb/(h·ft2) or more.

Jan 1, 1987

By W. A. Calhoun

The purpose of this investigation was to develop a procedure for removing excess iron from representative samples of bauxite ore from the Quapaw deposit of American Cyanamid Co., Saline County, Ark., in order to produce a beneficiated ore suitable for use in the alum industry, At the request of the sponsoring company, the samples were reduction-roasted at 800° C. and then magnetically separated. Although some rejection of iron was effected under these conditions, the general results were not satisfactory, A much more successful procedure, from the standpoints of both rejection of iron and recovery of alumina, consisted of a short (l5-minute), low-temperature (400° C.) oxidizing roast, followed by a 2-minute interval in a hydrogen atmosphere, then cooling to room temperature, and, finally, high-intensity magnetic separation to remove the iron.

Jan 1, 1957

Investigate the use and placement of lightweight concrete to improve ground control technology in deep mines where deformation occurs under heavy ground conditions and where there is danger of rock bursts. Approach Investigations of lightweight concrete properties and placement methods were conducted in the laboratory and in the field. Three test sections were completed: a monolithic, portal-type structure with integral walls and arch constructed aboveground; an underground test section constructed in a mine drift using plywood forms; and a test section constructed in a mine drift using an air-supported formwork. In the two underground test sections, the light-weight concrete was placed using a piston pump with concrete discharge line. A cooperating mine also used lightweight concrete, in the density range of 25 lb/ft3, to replace timber blocking in a raise preparation structure (the enlarged area across a vein where chutes and manway access arc placed). Other experiments included the use of precast lightweight concrete blocks in situations where ground support was needed, such as fur mine, ventilation doors, stoppings, and barricades.

Jan 1, 1990

Use water-jet-assisted cut-ting technology to reduce the exposure of mi ne workers' to respirable dust. Approach Install water-jet-assist on mining machines and evaluate its impact on respirable dust. How It Works Water-jet-assisted cutting involves a mechanical cutting bit working in combination with a moderate pressure (generally up to 10,000 psi) water jet directed just in front of, or through, the bit tip. One of its advantages is reduced dust generation because the jet wets the face of the material being cut more efficiently than a conventional low-pressure water spray, thus capturing much of the dust before it ever becomes airborne. It also removes loose cuttings ahead of the bit before they are pulverized by the bit into respirable dust. Total water consumption is about the same as for conventional low pressure dust control water spray systems. However, there is some increase in power consumption because of the energy needed to provide the high pressure water.

Jan 1, 1987

By R. V. Lundquist

Past reports by the Bureau of Mines have described the extraction of alumina from numerous aluminum silicate materials by the lime-soda sinter process. The results from pilot-plant investigations of six materials, with alumina-to-silica mole ratios from 0.3 to 8.7, indicated a relationship between the alumina-silica ratios and the processing characteristics of the sinter. A series of laboratory tests was conducted to define this relationship. Sinter and leach tests determined that an alumina-to-silica mole ratio of 0.90 or greater resulted in the best alumina and soda recoveries while leaving the leach slurries practically free from any tendency toward gelation. The widely different chemical and mineralogic properties of the various aluminous materials used in compounding the mixes had no perceptible effect on the leaching characteristics of the sinter. The blending of low-cost, high-alumina materials with aluminum silicate materials to give an alumina-to-silica mole ratio of 0.90 or greater would improve alumina and soda extraction and minimize operating problems in the lime-soda sinter process.

Jan 1, 1970

By D. G. Kesterke

Research was conducted to determine the feasibility of extracting elemental oxygen from silicate-bearing melts by high-temperature electrolysis. The method was based on a modification of existing processes for electrowinning metals from their oxides dissolved in molten halide systems. Electrolyses were performed at temperatures ranging from 1,050° to 1,250° C in boron nitride cells that incorporated a silicon carbide cathode and an iridium anode. The electrolytes contained volcanic scoria as the oxygen source, plus mixtures of BaF2 and LiF as fluxing agents. Cell gases containing almost 14 volume-percent oxygen were obtained. The average anode current efficiency for several experiments of extended duration was calculated to be 55 percent. Cell design and operating conditions are described, and some of the problems associated with the process are discussed.

Jan 1, 1971

By Dennis Dolinar, Christopher Mark, Gregory M. Molinda

In 1999, 2,087 unplanned roof falls were reported from 841 mines. Nearly 55% of all mines reported at least one roof fall, and nearly 17% of the mines reported five or more falls. In order to investigate the variables that contribute to roof falls, the National Institute for Occupational Safety and Health (NIOSH) compiled a national database of roof performance from 37 coal mines. Geotechnical factors and their effect on roof fall rates were compiled from over 1,500 miles of drivage. The factor that is the best predictor of roof fall rate is the Coal Mine Roof Rating (CMRR). For a low CMRR (#30), almost all cases have high roof fall rates. Conversely, high roof fall rates are rare for strong roof rocks (CMRR $ 60). Roof fall rates were also higher in deeper mines, probably because of greater stresses. Intersections were much more likely to fall than roadways, and four-way intersections were more prone to fall than three-way intersections. In a controlled comparison of the effect of increasing bolt length on roof fall rates, it was found that longer bolts reduced the roof fall rates in 11 of 13 cases. A relationship between the roof fall rate, the intersection span, and the CMRR was also found. Finally, a systematic method for tracking roof performance and geotechnical variables was demonstrated.

Jan 10, 2000

Determine safe practices for surface mine blasting near pressurized gas, oil, and water transmission pipelines. Background Surface mine blasters regularly have to address the issue of how blasting affects transmission pipelines that run near and sometimes through their permit areas. Regulatory approaches to blasting have ranged from no regulation at all to strict limits intended to prevent cosmetic cracks in plaster interior walls of homes, but they have not directly addressed the impact of blasting on nearby pipelines. Concerned with both productivity and safety, the mining industry and its regulators have requested guidance on safe practices for mining near pipelines. The Pipeline Research Group of the American Gas Association has sponsored studies of the effects of small close-in blasts because of vibration concerns related to the installation of new pipes into existing pipeline right-of-ways. By contrast, the recent study in which the U.S. Bureau of Mines (USBM) took part is the first addressing large-scale mining blasts.

Jan 1, 1995

By Ronald D. Hill, Elmore C. Grim

Mining as an extractive process alone is outdated and unacceptable to today's environmentally concerned public. Multiple land use must be considered as well. Only through effective preplanning can the full potential of reclamation result in a lasting asset for future generations. The coal industry is now recognizing that reclamation of mined lands is part of the mining cycle that must be planned and carried out in a timely and orderly manner. It is also finding that planning reclamation in advance of mining is cheaper and more effective than waiting until mining is completed. The decision to open a strip mine must be based on the results of studies to determine if successful reclamation can be achieved and whether the economic benefits to the company will be justified(1). Information regarding the physical, chemical, hydrologic and biologic systems operative at the site must be under- stood or reclamation will be a failure. Working together, engineers, management and reclamation specialists should design the actual mining and reclamation plan before mining is begun.

Jan 1, 1974

By Dhaval Patel, Kim Witte, Charles Vaught, Michael T. Stephenson, Steve Booth-Butterfield, Cynthia Zuckerman, Brian L. Quick

This longitudinal field study was designed to encourage Appalachian coal miners in West Virginia and Pennsylvania to engage in hearing-protection behaviors. Method: Participants were mailed postcards that featured either a positive, negative, or neutral message on the outside of the postcard and a message encouraging hearing protection behaviors on the inside. The first posttest measurement of the effectiveness of the persuasive messages was conducted about a week after the postcards were mailed. The delayed posttest measurement was conducted six weeks later. Results: Responses from 307 coal miners revealed that the positive or neutral messages generated significantly more self-reported hearing protection behaviors than the negative message. Identical results were obtained in a delayed posttest assessment of miners' self-reported hearing protection behaviors. The positive message was also more effective than either the neutral or negative message in preventing defensive mechanisms from emerging over time. Impact on Industry: Positive and neutral messages were convincingly more than negative messages in facilitating self-reported hearing protection behaviors among coal miners. Similarly, the positive messages kept defensive processes at bay. Keywords: Hearing protection; Hearing loss; Coal miners; Campaign; Messages

By R. F. Abernethy

A chemical method of determining microgram quantities of arsenic in coal was investigated by the Bureau of Mines to supplement a semiquantitative spectrographic method of determining arsenic in coal ash. In accordance with a method recommended by the International Organization for Standardization, 1-gram samples of coal are decomposed by wet oxidation with boiling sulfuric acid (H2S04) and nitric acid (HN03) to remove the organic matter. After heating to fumes of SO3 to remove HN03, the arsenic is separated as arsine by the action of zinc in H2S04 solution. The arsine is absorbed in dilute iodine solution in which the arsenic is determined colorimetrically by the molybdenum-blue reaction. Two modifications of the method for obtaining the arsenic in solution, in addition to the wet oxidation method, give satisfactory results. The modifications are (1) furnace ashing with MgO added to the coal, followed by treatment with H2S04, and (2) extraction of arsenic from the coal by dilute HNO3 without ashing. Float-and sink-tests show that arsenic is associated mainly with mineral matter in the three coals examined. High-temperature ashing tests show that very little arsenic is volatilized from coal ash below 1,000° C, but it is virtually all removed from the ash at 1,300° C.

Jan 1, 1968

Increase the recycling of critical and strategic materials by simplifying the indentification and segregation of scrap. Background Because the United States is dl-most totally dependent on imports of such critical metals as chromium, cobalt and nickel, Bureau of Mines research has been directed towards conserving these metals by increasing the recycling of the complex scrap materials that contain them. Experienced scrap sorters, using the traditional techniques of object recognition, spark tests, chemical spot tests, color, apparent density, and magnetic properties, can adequately sort a wide variety of alloy groups. However, the complex nature of new materials entering the scrap market has made sorting both more difficult and more important. Some new alloys contain so many components that separation by discrete alloys becomes a prerequisite for effective recycling. The Bureau has completed Investigations on two methods for rapidly sorting complex scrap mixtures. One method uses a combination of two low-cost instruments. The other uses a single sorting instrument. Both approaches are reported.

Jan 1, 1986

Provide an operator cab to assure protection, comfortable use of controls, and good visibility. Approach A cab which raises and lowers by pivoting about d horizontal axis was Installed on two S&S cleanup tractors and tested in two underground working mines. How It Works Hydraulic cylinders actuated by a lever inside the cab cause the cab to pivot about a horizontal axis. This action raises or lowers the cab height. The total cab excursion is 14 inches. A release valve in the hydraulic system allows the cab to lower automatically if struck by a roof load or overhead obstruction. The pivoting action of the cab is engineered so that the operator maintains comfortable use of all controls at all cab heights. The movement is such that the angular relationship of the operator's ankles With the tram and brake foot controls IS consistently within 90 to 100 degrees. Figure 1 outlines the approximate position of the operator at three cab elevations.

Jan 1, 1977