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By R. J. Durrheim, B. Manzunzu, V. Midzi

Selecting ground motion prediction models (GMPM) is crucial in assessing seismic hazard levels in a specific region. This study investigates the influence of ground motion model (GMM) selection on seismic hazard assessment in Johannesburg, South Africa. Most seismic events affecting Johannesburg are related to mining activities and water ingress into the underground mine voids. The most seismically active regions in South Africa include areas around Klerksdorp, Welkom, and Carletonville. These regions experience a significant number of earthquakes, with mining activities being a major factor contributing to seismic events. Ten ground motion prediction equations were selected from regions of similar tectonics setting and were assessed to see if they correspond to the available local data. Six of these were also compared to the ground motions produced by the earthquake of 14 August 2014, which occurred in the Orkney area, one of the mining areas in South Africa. Sensitivity analyses were also carried out to assess the influence of ground motion prediction equations (GMPE) on the seismic hazard of Johannesburg. The results indicate that the choice of GMPM significantly affects the estimation of seismic hazard levels in Johannesburg. Different GMM can lead to varying ground shaking intensity predictions, impacting risk assessments and engineering design considerations. The findings highlight the importance of carefully selecting appropriate GMM tailored to Johannesburg’s specific geological and tectonic characteristics. Understanding how different models perform in this region is essential for accurate seismic risk mitigation strategies.

Jan 12, 2025

By S. Banisi, S. M. Mousavi, S. D. Tafvizi, Gh. A. Parsapour, M. Mahmoudi

Generally, regrind circuits are used to increase the degree of liberation of value minerals which are fed to flotation circuits. At the regrind circuit of the Sarcheshmeh copper complex, four ball mills are in closed circuit with their hydrocyclone clusters. In the initial design of the plant, feed and underflow percent solids, and pressure drop of the hydrocyclones were 39% and 65%, and 15psi, respectively. Over the years, due to a reduction in the feed grade from 1.17% to 0.67% and changes in the operational conditions, the feed rate to each hydrocyclone cluster has decreased from 401 to 70t/h and consequently the pressure drop, feed and underflow percent solids have reduced to 4psi, 17% and 25%, respectively. The main objective of this research was to audit the feed solids concentration and pressure drop of the hydrocyclones and make the necessary modifications based on the Plitt’s model. The results of sampling showed that water recovery to underflow was 59% which was higher than normal values. By reducing the number of operating regrind mills from 4 to 2, the feed rate to each mill increased. After this modification and taking necessary measures in the plant to implement the new operating approach, the pressure drop, feed and underflow percent solids increased to 18psi, 28% and 58%, respectively. The water recovery of the hydrocyclones underflow decreased from 59% to 12%. These changes in addition to increasing the circuit efficiency saved 1000 kWh energy and decreased ball consumption by 925 ton/year because of reduction in the number of operating ball mills. Keywords: Regrind mills, flotation, audit, troubleshooting

Jan 1, 2020

By H. Karabulut, S. Gündüz, K. Karacif, M. A. Erden

The corrosion properties of iron-based composite materials containing graphite and silicon carbide (SiC) reinforcement were investigated. The effects of silicon carbide reinforcement were investigated by adding 0.5% graphite and 1%, 2%, and 4% SiC. A powder metallurgy method was used to produce the composite samples. Iron, graphite, and silicon carbide powders were blended for one hour with a threeaxis mixer and then unidirectionally pressed under a pressure of 750 MPa. After pressing, the composite materials were sintered at 1100°C for one hour. The corrosion properties and microstructure, density, and hardness properties of the composite materials that can affect the corrosion properties were also investigated. It was determined that the pore ratio and hardness of the composite material increased, and corrosion resistance decreased, with increasing silicon carbide content.

Jun 2, 2022

By C. R. S. Needes, M. J. Nicol, G. T. W. Ormrod, N. P. Finkelstein

The industrial application of a dioxide electrode uranium by C. R. S. NEEDES, Ph.D. (London) (Visitor), M. J. NICOL, Ph.D. (Rand) (Visitor), N. P. FINKELSTEIN M.Sc. (Rhodes), Ph.D. (Liverpool) (Fellow), and G. T. W. ORMROD (Visitor) A correlation between the potential of a U02 electrode and the rate of recovery of uranium has been proved in laboratory and plant trials. When the recovery rates change because of variation in the concentrations of Fe(III), Fe(II), SO4 'and H+, a positive correlation is observed. However, an 2- increase in the concentration of phosphate in solution produces an increase in the U02 electrode potential but a decrease in the rate of leaching of U02. The correlation between the U02 electrode potential and the rate of leaching of U02 is then negative. It is concluded that, as a control device, the electrode cannot compete with the platinum electrode for use on certain plants. Nevertheless, the U02 electrode will act as a useful warning device if the total concentration of iron in solution decreases to below a level concomitant with the economic recovery of uranium. Furthermore, because of the positive correlation between the U02 electrode potential and the phosphte concentration, the electrode will also be of value in the detection of an increase in the phosphate level in solution. When it was incorporated in a suitable industrial probe, the electrode was found to be able to withstand the rigours of the leaching conditions in a large pilot-plant pachuca, and only failed after six weeks' operation.

Jan 11, 1975

By R. Pretorius, N. Mautsa

In a cobalt precipitation plant, phosphoric acid is used to eliminate excess uranium from the pregnant leach solution, resulting in a cobalt hydroxide product that has little uranium contamination. However, the amount of phosphoric acid added must be monitored and controlled to avoid financial and sustainability impacts and to prevent negative impacts on the final product quality. One possible solution to this problem is the use of online residual phosphorus measurement techniques to regulate the addition. By continuously monitoring the residual phosphorus levels in the solution, the plant can adjust dosing in real time to maintain the target residual phosphorus level. As a result, the cobalt precipitation plant can improve phosphorus level control, lowering the risk of overdosing, and ensuring consistent product quality. This approach can also improve process efficiency, reduce operational costs, and have a positive environmental impact

Jan 1, 2023

Council and Standing Committees - 1981/82 President: G. Y. Nisbet. Senior Vice-President: Prof. A. N. Brown. Junior Vice-President: Prof. R. P. King. Honorary Treasurer: Prof. D. G. Krige. Immediate Past President: Dr P. R. Joehens. Members of Council: B. C. Alberts, J. D. Austin, P. T. Fewell, C. E. Fivaz, J. J. Geldenhuys, Dr A. K. Haines, P. N. Harris, H. E. James, C. G. Knobbs, Dr B. K. Love¬day, Dr J. Lurie, C. S. MacPhail, D. G. Malan, J. C. Mostert, G. C. Thompson, Dr H. Wagner. Chairman, Witbank/Middelburg Branch: B. Rohrmann. Chairman, Orange Free State/Klerksdorp Branch: K. F. W. Eick. Chairman, Materials Engineering Specialist Division: G. Pienaar. Past Presidents serving on Council: Dr M. G. Atmore, H. Britten, Prof. D. D. Howat, Dr J. P. Hugo, D. G. Maxwell, Prof. R. P. Plewman, Dr R. E. Robinson, Prof. M. D. G. Salamon, P. W. J. van Rensburg, D. A. Viljoen, P. A. von Wielligh. Standing Committee Chairmen: Constitution, Rules and Policy, Dr P. R. Jochens; Membership, Prof. R. P. King; Training, Career Guidance and Education, P. A. von Wielligh; Journal, Prof. A. N. Brown; Monograph Series, D. G. Malan; Technical Programme - Metallurgy, C. E. Fivaz; Technical Programme - Mining, P. N. Harris; SAIMM Schools - Metallurgy, Dr B. K. Loveday; SAIMM Schools - Mining, J. D. Austin; 1982 CMMI Congress, Dr M. G. Atmore; Awards, Dr P. R. Jochens; Adjudication, Dr P. R. Joehens; Phoenix National Committee, Dr M. G. Atmore; Excursions, J. C. Mostert; Mines and Works, Prof. A. N. Brown; World Mining Congress - National Committee, Prof. R. P. Plewman.

Jan 1, 1982

By N. Naude, W. P. Roux, O. Kaba

Ceramic filtration plates are used for dewatering slurries with high solid concentrations and particles in the size range of 30 μm to 150 μm. After extensive operating times, the ceramic filter plates at Minas Rio in Brazil begin to blind due to the precipitation of barium sulphate on the surface of the ceramic filter plate, which reduces the overall efficiency of the filtration process. Further research is needed to identify the barium precipitate phases on the blocked filter plates and its thermodynamic and kinetic behaviour in the system. A crystallography analysis was performed on the sample and the results showed that there are two different sets of precipitates formed on the filter plate: grey crystals which were large and scatted on the filter plate and red micro crystals that covered the entire surface of the filter plate. The red microcrystals on the sample were identified with XRD, which indicated that the sample contained barium sulphate in the mineral form barite. Experiments were conducted to determine the optimum conditions under which barium precipitation will occur. The conditions tested as a possible driving force for barium sulphate precipitation were the effect of temperature, pH and concentration. The pH and temperature ranges were pushed to both the lower and higher boundaries. The effect of temperatures as low as 15oC was studied and pH levels of 7 and upwards. The first nuclei started appearing at a pH of 7 but significant growth is promoted at higher pH levels. The X-Ray diffraction analysis confirmed the phase of the precipitates formed, and the orthorhombic crystallographic structure formed is a characteristic of barium sulphate. Keywords: Iron ore, barium sulphate, temperature, pH, concentration, morphology, and ceramic filter plate

Jan 1, 2020

By A. M. Venter, C. W. Siyasiya, N. K. K. Arthur, M. G. Willemse, D. Marais

Although additive manufacturing is fast gaining traction in the industrial world as a reputable manufacturing technique to complement traditional mechanical machining, it still has problems such as porosity and residual stresses in components that give rise to cracking, distortion, and delamination, which are important issues to resolve in structural load-bearing applications. This research project focused on the characterization of the evolution of residual stresses in Ti-6Al-4V extra-low interstitial (ELI) additive-manufactured test samples. Four square thin-walled tubular samples were deposited on the same baseplate, using the direct energy deposition laser printing process, to different build heights. The residual stresses were analysed in the as-printed condition by the neutron diffraction technique and correlated to qualitative predictions obtained using the ANSYS software suite. Good qualitative agreement between the stress measurements and predictions were observed. Both approaches revealed the existence of large tensile stresses along the laser track direction at the sections that were built last, i.e., centre of the top layers of the samples. This in addition leads to large tensile stresses at the outer edges (corners) which would have the effect of separating the samples from the baseplate should the stresses exceed the yield strength of the material. Such extreme conditions did not occur in this study, but the stresses did lead to significant distortion of the baseplate. In general, the microstructures and spatial elemental mapping revealed a strong correlation between the macro-segregation of elemental V and the distribution of the β-phase in the printed parts.

Feb 6, 2023

By M. J. Latva-Kokko, CA Snyders, J. R. Peltola, M. K. Kostiainen

It is well known that carbon management is essential for minimising soluble gold losses in carbonin- leach (CIL) and carbon-in-pulp (CIP) circuits. Even so, carbon measurements remain predominantly a manual operation with a low amount of control and automation around CIL and CIP reactors. Carbon inventory, i.e. knowing the carbon concentration in each reactor, is crucial for good carbon management. CarbonSense, a novel in-situ measurement system, was therefore developed for continuous monitoring of the carbon concentration in each reactor and paves the way for more advanced control in gold operations. The carbon management and optimisation system is based on Outotec® HSC Sim dynamic process simulations where each process component is modelled in detail. Generated models are validated with real data from a particular operation. The simulator will allow for the carbon control sequence to be realistically tested and the efficiency optimised by controlling the feed and discharge pumps in a hazard- and risk-free process environment. Furthermore, by combining CarbonSense and Outotec® gold courier (online soluble gold measurements) continuous feed-forward and feedback information can be obtained. The optimiser will then define the best running parameters based on the cost function of gold production versus intrinsic factors such as utility costs and adsorption time. Eventually, the application can be installed parallel with a real process island and it can be continuously calibrated with real-time process data. The dynamic model will then create future predictions for the entire process island. The example case presents a CIL circuit, which is simulated using Outotec® HSC Chemistry Sim and operated through Outotec® ACT (Advanced Control Tool) application. Keywords: Carbon-in-leach, CIL, CarbonSense, carbon management, automated control, simulation

Jan 1, 2020

By F. Petersen, W. van Dyk, J. Bonsu, A. Isafiade

"This paper aims to demonstrate how a systemic approach can be applied to the analysis of the causes of accidents in South African mines. The accident analysis framework used was developed previously by the authors from the combination of the Mark III version of the Swiss Cheese model, Incident Cause Analysis Method (ICAM), the Nertney Wheel model, and safety management principles. Data on 91 accidents occurring from 2010 to 2012 at the site of a platinum mine in South Africa were used to populate the newly developed framework. The results obtained show that while routine violations (45% of all accidents analysed) were the most common form of human error, problems in the physical environment of workers were the most common workplace factor (39.6% of all accidents analysed). Furthermore, inadequate leadership was found to be the most common systemic factor responsible for accidents (51.6% of all accidents analysed). Some workplace factors were more commonly associated with particular unsafe acts than others, and some systemic factors were more associated with particular workplace factors than others. The outcome of this study demonstrates that systemic factors, rather than human errors and violations, are the chief causes of accidents in the mining sector. IntroductionThe mining industry is a very important sector of the South African national economy. A major factor threatening the sustainability of this industry is mining accidents, which frequently result in injuries or deaths, destruction of property, and pollution of the environment. In the past, mining accidents have led to the shutdown and threat of shutdown of mines (Ryan, 2008; Mail and Guardian, 2011). The country stands the risk of incurring significant losses if the mining industry continues to experience shutdowns. In 2012, the mining sector accounted for R262.7 billion (equivalent to US$32.83 billion) representing 8.3% of GDP directly, on a nominal basis (Chamber of Mines of South Africa, 2013).Mining safety is a global concern and has attracted significant international attention. This has precipitated various studies into different aspects of mining. Unfortunately, human error has been blamed for the majority of these accidents. A study by the US Bureau of Mines found that human error is the cause of almost 85% of all accidents (Patterson and Shappell, 2008). In Australia, it is the cause of two out of every three occupational accidents (Patterson and Shappell, 2008). Various mining companies maintain that they run efficient systems, and hence the behavioural problems of workers are to blame for most accidents. An understanding of accident causality could be a major step in the quest to reduce accidents. Only with a good understanding of the accident process can effective remedies can be designed."

Jan 1, 2017

By M. Splaine, W. Davison, D. C. Atkinson

"Since 1964, Nchanga Consolidated Copper Mines, Ltd., has been developing and using production scheduling methods for optimizing its metallurgical operations in the short term (up to one year). Medium-range metallurgical planning has been possible only by successive evaluations of a single-year L.P. A modified version of Rosenbrock's direct search technique has now been developed to allow multi-year optimization of both mining and metallurgy for medium-range planning. The modifications to the search technique have produced a marked increase in computational efffciency for this heavily constrained problem in many variables and the system is a usable planning tool, given a reasonably powerful computer. The plans are 'optimum' in the sense that they yield the maximum present value of the operations.Each of the resulting five-yearly mine plans forms the basis for further detailed metallurgical evaluation by the established production scheduling system."

Jan 1, 2014

By T. R. Marshall

SAMREC (The South African Code for the Reporting of Exploration Results, Mineral Resources and Mineral Reserves) Clause 7 notes that ‘Documentation detailing Exploration Results, Mineral Resources and Mineral Reserves from which a Public Report is prepared must be prepared by, or under the direction of, and signed by a Competent Person.’ Similar statements with respect to Competent Valuators (CVs) and Qualified Reserves Evaluators (QREs) are contained in the SAMVAL (South African Code for the Reporting of Mineral Asset Valuations) and SAMOG (South African Code for the Reporting of Oil & Gas Resources) codes respectively. What does it mean to be a Competent Person (CP) in the context of compiling/signing-off on SAMCODE (South African Mineral Code) compliant documents? What do the registration and experience requirements mean? Who is ultimately responsible for the report and what does such responsibility prescribe?

Sep 1, 2021

By E. Arghavani, S. H. Amiri, S. Zare, F. Sepehri, M. Ramezanizadeh

Mineral processing plants include different stages like crushing, grinding, classification and concentration, all of which have partially affect the final product. To identify and solve the related problems of each stage, process audition should be carried out continuously to find the major solutions of improving product and decreasing the maintenance and operating costs. The Iranian Gohar-Zamin iron ore beneficiation plant consists of equipment such as gyratory and cone crushers, high pressure grinding rolls (HPGR), ball mill, dry and wet double-deck vibrating screens, hydrocyclones cluster, magnetic drum separators, thickener and horizontal vacuum belt filters. The defects of initial design as well as current non-standard operating conditions of equipment were monitored and detected and the opportunities for process optimisation were presented as follows: establishing the control loop of power draw for cone crushers, the modification of feeding chute in cone crushers to minimise the non-uniform wear of parts, removing segregation in the fresh feed bin and screen’s circulating load chute in order to provide the proper feed to HPGR, reducing wear rate on HPGR rolls surfaces, decreasing the amount of rejected materials in screen, equalising the solid content and particle size distribution (PSD) of feed in all magnetic drum separators and equalising the PSD of hydrocyclones overflow. This paper provides a guideline for the mineral processing industry to focus its efforts on process design to deliver the efficiency with minimum capital costs. Keywords: Process audition, gyratory crusher, cone crusher, HPGR, screening, hydrocyclones, magnetic drum separators

Jan 1, 2020

By Y. Zhan1, T. Moodley, M. A. H. Zahid

Mining operations are under growing pressure to improve safety and efficiency while dealing with aging infrastructure, complex processes, and workforce constraints. Although many sites are equipped with surveillance cameras and control systems, critical events often go unmonitored or under-analysed due to the lack of intelligent interpretation tools. Cameras typically act as passive recorders, requiring manual review by control room operators; a process that is labour-intensive, error-prone, and reactive. Vision AI is emerging as a transformative solution, combining computer vision and artificial intelligence to deliver real-time, actionable insights. This technology has evolved along two key phases: traditional object detection, and more recently, multimodal large language model integration. This paper presents solution architectures, deployment results, and key insights from real-world implementations across underground operations, open-pit truck-shovel operations, and smelter operations, demonstrating how Vision AI is reshaping mining operations to become safer, more efficient, and more intelligent.

Mar 6, 2026

By M. Z. Emad, S. Raza, K. Jalil, M. A. Raza, M. U. Khan, S. A. Saki

Dimension stone mining is Increasing because of growing demand from the building and construction industries. Diamond wire saw cutting is a popular dimension stone mining technique around the world. Estimation of the production cost for this method is critical for these operations. n this research a production cost model was developed for the mining of granite using a diamond wire saw. Cost and production data were collected from a granitic dolerite operation in Pakistan for a 4.5-year period, and analysed to identify the cost components. Fuel (34%), labour (15%), consumables (40%), and maintenance (5%) were found to be the four major cost components in this operation. A regression-based dimension stone production cost model incorporating statistically significant variables was developed. The data presented a strong correlation of production cost with fuel, labour, and consumables costs. Finally, a production cost model based on the consumption cost of diamond wire is presented. The model was verified using actual production cost data, which indicated 95% (R2 = 0.95) variance in the data between the predicted and actual production cost values. The model may help field engineers in computing their dimension stone operational cost during the cutting phase.

Nov 6, 2023

By M. Asghari, R. Amiri, A. Haratian, M. Noue Parast, S. Haji

Today the roller screen has a wide range of applications in the steel-making industry. It is used for screening of green pellets before using the kiln. Since the appropriate size of a green pellet is -16+9 mm, there are different gaps between rollers that make green pellets classified in three categories: -9 mm (undersize), -16+9 mm (onsize) and +16mm (oversize). The efficiency of a roller screen is specified according to the weight percent of undersize in onsize as a fine material, and weight percent of onsize in oversize (loss). This efficiency is influenced by different operational parameters such as roller diameter, roller speed, and roller gap, material type of rollers and inclination of roller screen. This study investigates the effect of different material types of rollers in efficiency of Ardakan roller screens, located in the Yazd province of Iran. The rollers of the existing roller screens in this pelletising plant are made of polyurethane which according to this investigation, has a maximum lifetime of about six months. Operating the polyurethane rollers beyond its lifetime generates serious problems such as high wear of rollers, and consequently, material buildup on the roller surface which then significantly decreases the roller screen efficiency. So, after examining different roller materials, stainless steel 304 with higher surface roughness to help pellets move properly on the roller screen surface was selected as a solution to this problem. The new roller screen was constructed by Fakoor Meghnatis Spadana (FMS) and replaced the previous one. In this way, the maximum capacity of the roller screen was increased about 17% and the roller screen efficiency was increased about 15%. Keywords: Roller screen, green pellets, efficiency, onsize, operational parameters

Jan 1, 2020

By A. Rödfalk, P. Bloemer, J. P. Nilsson, N. Brogden

"Reliable and accurate metal transfer information during silicon tapping from an EAF is invaluable for decision-making and process optimization, while obtaining such information safely is a necessity.Elkem Thamshavn Norway, a producer of metallurgical-grade silicon, identified inherent safety problems with gauging fill levels in ladles using dip bars while molten metal was continuously pouring from a rotating EAF. Operator safety was a paramount concern, and an alternative automatic method of controlling the tapped fill level needed to be found.It was also considered that further benefits could be achieved such as monitoring the tapping flow from the EAF in order to identify any clogging, as well as the potential to use the live feed from such a system to assist decision-making regarding work around the taphole area.Agellis Group AB, Sweden, a company with over 30 years of experience in gauging molten metal levels in the metals industry, was able to design a solution for Elkem Thamshavn that would provide the required real-time process data while enhancing operator safety.This paper shows how the Agellis AB EMLI-L system was successfully installed at Elkem Thamshavn’s EAF continuous tapping area, how ladle fill levels were constantly monitored, and how full ladles were replaced by empty ones without the need for operators to be in the tapping area to take level readings. The results were used to compare the accuracy and reliability of Elkem Thamshavn’s current measuring methods with that of the EMLI-L system. The paper also covers how problems such as how to connect, run, and protect cables in and around the EAF tapping area, as well as connector and cabling survivability during the three day refractory pre-bake period, were solved. Finally, the paper discusses the potential production improvements, maintenance requirements, and data integration attainable through the installation of the system, as well as the major safety improvements that have been achieved."

Jan 1, 2014

By D. Odendaal, S. Bharat, R. D. Cromarty

The aim of this investigation was to determine the effect of high-temperature heat treatment on the electrical resistivity of charcoal. Samples of two different wood types (eucalyptus and black wattle) were pyrolised in a retort at a temperature of 700°C and the resulting charcoals heat-treated in an induction furnace at temperatures from 800°C to 1800°C and residence times from 60 to 120 minutes. After cooling, the resistivities of the samples were measured at room temperature using the four-point probe technique. It was found that as the heat treatment temperature increased the electrical resistivity of the charcoal decreased, approaching an asymptotic value at higher temperatures. Longer residence times decreased the resistivity, but this effect was not pronounced.

Oct 3, 2023

By Keith Rowley, Neal Harries, David Noon

The management of risks associated with slope instability is an essential process in the safe and economic operation of open cut mines. The ?slope stability radar? (SSR) has been developed to better manage those risks. The SSR remotely scans rock slopes to continuously measure any surface movement and can be used to detect and alert users of wall movements with sub-millimetre precision. The high level of movement precision and broad area coverage of the rock face can allow for a better understanding of the geomechanics of slope deformation, including magnitude of potential failures and additional warning time of impending instability. Additionally, radar waves adequately penetrate through rain, dust and smoke to give reliable measurements, 24 hours a day. SSR systems have been deployed in many mines in Australia, Indonesia, South Africa, Zambia, Chile and the United States. Greater than 70 rock falls and waste dump failures (from several to millions of tonnes) have been monitored, and on every occasion precursor ?warning? movements were recorded by the SSR. This technology enables a radical change in the management of risks in open cut mining. This paper will present recent case studies of the SSR operation in coal and metalliferous mines.

Jan 1, 2006

By J. Nell

Heavy mineral deposits often contain relatively high levels of radioactive elements (thorium and uranium in particular).It is difficult to obtain clean separation of ilmenite and monazite (the main impurity mineral containing radioactive elements), and physical intergrowths of the two minerals are, in fact, not uncommon. As a result, ilmenite concentrates obtained from such deposits often contain high levels of thorium and uranium. Because of the large negative free energies of formation of ThO2and U3O8boththorium and uranium report to the slag during smelting and if an ilmenite concentrate contaminated with monazite is used to make high titania slag, the concentrations of these elements in the slag end up about 40% higher than in the ilmenite feed. Previous work, patented by RGC Mineral Sands Limited, and subsequently confirmed by Mintek, showed that radioactivity may be reduced by roasting an ilmenite concentrate with borax at 1000°C to 1100°C and leaching it with hydrochloric acid1. It is evident that the cost of an ilmenite roast/leach process will be high and there may be economic benefits in removing the radioactive elements from the slag instead (the volume of slag to be treated is smaller than the volume of ilmenite feed). To remove radioactive elements from the slag it is necessary to know how these elements occur in the slag. Inother words, the distribution of uranium and thorium between the various oxide, silicate and metallic phases in high titania slag must be determined. Once the deportment of thorium and uranium between the various phases ha sbeen determined, an appropriate process for slag purification can be developed. Test samples High-titania slag was prepared in a pilot-scale DC furnace from ilmenite concentrates with different levels of uranium and thorium. Subsequently, ten slag samples representing a range of compositions were selected for bulk chemical analysis, scanning electron microscopy and micro-analysis. The samples were crushed to a maximum particle size of 1 mm and from each sample a 20-kg batch was riffled out for analysis. Bulk chemical composition Chemical compositions of the samples selected for test work are given in Table I. TiO2, Al2O3, SiO2, MgO, MnO, FeO and V2O5were analysed by ICP-OES, Na2O, CaO andCr2O3by atomic absorption spectroscopy and U and Th by XRF (the XRF detection limit for U and Th was around 4 ppm). The ?B? series has a higher silica content than the others as a result of small silica additions that were made during smelting. All samples have elevated alumina levels as a result of furnace refractory contamination during smelting. As expected, there is an inverse relationship between the concentrations of TiO2and FeO in the samples (Figure 1).The TiO2and FeO levels are similar to the levels found in industrial slags2. Extreme conditions of reduction under which reduction of more ?refractory? oxides (e.g., chromia, magnesia, silica, alumina and even urania and thoria) might take place were not explored in the study. Note that BB1and BBB1 contain more than 7% combined silica and alumina (SiO2as a flux addition during smelting, and Al2O3from refractory contamination) and they do not fall on the general trend defined by the other samples. The U and Th concentrations of sample E2 is noteworthy. In the preparation of slag E2, monazite concentrate was added to the ilmenite to increase the concentrations of radioactive elements in the slag. This was done primarily to facilitate the detection of Th and U during the phase chemical characterization of the slag. Radioactivity measurements Gamma ray emissions from the samples were measured [ ]

Jan 1, 2007