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By Chi M. Phan, Anh V. Nguyen, Geoffrey M. Evans, Graeme J. Jameson

Surfactants are used to control the interfacial properties of the gas-liquid and liquid-solid inter- faces inflotation. This paper investigates the dynamic adsorption of surfactants at the gas-liquid intelface. The dynamic adsorption process was modeled by considering the surfactant mass transfer to the gas-liquid interface by dimion and the Langmuir and Frumkin adsorption isotherms. The numerical computation was applied to solve the non-linear governing equations. The dynamic adsorption was measured in tenns of the dynamic surface tension using the pen- dant drop method. The theoretical modek were compared against the experimental data obtained with non-ionic (Dowfroth 250) and ionic (sodium dodecylbenzene sulfate, SDBS) surfactants. The theoretical results agreed well with the erperimental data for SDBS, but not for Dowfrother 250, especially for the initial stage. Reasons for the variation in results are given in the paper.

Jan 1, 2005

By M. Sagisaka

The purpose of this study is to obtain carbon dioxide emissions by copper production systems and quantitative merit to use copper scraps in Japan. Electrolytic copper and sulphuric acid originating from the refining gas are produced in the system. In this study, the inventories such as the fuel consumption of the unit processes and the in-house electricity generation were obtained from published papers and public statistical data. The following observations were made based on the Life Cycle Assessment (LCA) method: (1) Carbon dioxide emissions from the production of electrolytic copper and sulphuric acid in the system are about 1.0 kg and 0.4 kg/kg-product respectively. The carbon dioxide emissions attributable to the transportation of copper concentrate correspond to 20% of the total emission. This emission is higher than that of zinc because the metal content in the concentrate is lower than zinc. (2) The carbon dioxide emissions from the system decrease with the recycling of copper scrap to the converting process because the consumption of copper concentrate is reduced. The reduction is estimated to be 0.18 kg-CO2/kg-Cu at the point of 0.1 kg-scrap/kg-blister Cu. This corresponds to 9% reduction for the present system. However, this recycling leads to the decrease of sulphuric acid by 450x103 tonne at the point. The recycling of scrap should be evaluated not only from the reduction of carbon dioxide emissions, but also in terms of sulphuric acid demands as well as advantage of waste management.

Jan 1, 2003

By Eduard Hamm

The main reasons for the development of higher heat levels in German coal mines are the increasing depth of working with the con- sequent higher rock temperatures, increased use of electrical equipment, and increasing coal output due to concentration and mechanisation of workings. In place of the normal decentralised underground cooling plants, schemes and pilot plants have been developed to produce the required cooling capacities in central air cooling units, which then supply the cold air to the underground working points where needed.

Jan 1, 1980

By K. A. Natarajan, M. K. Yelloji Rao

The effect of galvanic interactions among sulfide minerals such as chalcopyrite, galena, and sphalerite in the presence and absence of a grinding ball material on the flotation recovery of chalcopyrite has been studied. X-ray photoelectron spectroscopy (ESCA) studies were carried out to identify the reaction products on the sulfide minerals after different apes of galvanic interactions. Galvanic contact with active minerals such as galena and sphalerite, either alone or together, significantly affected the floatability of chalcopyrite mineral, such an effect being more severely felt in the additional presence of a grinding medium as well as oxygen. Surface analysis studies revealed the presence of oxyhydroxide species of iron on all the sulfide mineral samples which were in prior contact with the grinding medium. The formation of such oxyhydroxide species of iron was found to be dependant on the relative electrochemical activity of the mineral. Probable electrochemical reaction mechanisms are discussed.

Jan 1, 1990

By Wen L. Cai

This paper examines the effects of different block dimensions and cone bases on the economic open pit limit design based on case studies on a coal deposit consisted of two west- east elongated, near vertical thin seams starting with a base model dimension of 200x170x50 (NX*NY*NZ) with a block dimension of 10mx5mx4m (DX*DY*DZ), the blocks were combined along easting, northing and elevation directions. Two cone bases were used, one with a base radius of 10 meters, the other with a base radius of 0. Two pit design algorithms, one is the floating cone algorithm, the other is an optimum algorithm, were used to see which one of the two pit design algorithms is more sensitive to block dimension and cone base variations. The results are presented and analyzed.

Jan 1, 1992

By Walker Ian W., John D. Gow

The paper describes the exploration and development activity associated with a series of open pit gold deposits in the Laverton region of Western Australia with an aggregate resource base of 4 million tonnes at a grade of about 3 grammes per tonne. In September 1988, Hill Minerals N.L., now a wholly owned subsidiary of Ashton Mining Limited, completed the purchase of the Cork Tree Well treatment plant from Austwhim. This CIP plant had a rated capacity of 235,000 tonnes per annum, and is located within the Hill Minerals Laverton Project area. Ore is trucked by haulage contractors from each open pit mine to the central treatment plant at Cork Tree Well. Studies were completed and a plant expansion undertaken lifting throughput to 500,000 tonnes per annum. A contract was let for this expansion in November 1988, and construction completed in April 1989. Concurrent with the above project development work, heap leach metallurgical studies are being undertaken on low grade mineralisation associated with higher grade ore zones at several of the open pit mines, notably King of Creation and Craiggiemore. It is anticipated that heap leaching will provide a useful adjunct to gold production from milling higher grade ores.

Jan 1, 1989

By Misra M., P. Grimes, Chen. S.

The combustion of petroleum products produces emissions which contain oxides of nitrogen (NOx), hydrocarbons (HC), and particulate matter (PM) which have adverse health and environmental effects. In recent years there has been increasing interest in the use of water-fie1 emulsions as a substitute for conventional fuels. Emulsified fuels are emulsions of water in fuel, which are typically made of 10 to 20 percent of water mired with certain additives and fuel. Studies have shown that the emulsified diesel can significantly reduce the emissions of NO, PM and car- bon monoxide and increase the fuel efficiency. In order to produce a stable diesel emulsion, the development of an effective surfactant additive is critical. The stability of diesel emulsions is influenced by many factors, including size distribution of the droplets, the viscosity of the continuous phase, the physical properties of the interfacial film, and temperature. This paper describes a method to produce emulsified diesel and combustion results obtained from various tests. It has been found that the diesel emulsion made with this additive package was stable during the test, and the emissions were lower in NO, CO, and PM compared to the baseline diesel.

Jan 1, 2005

By R. Y. Wan, Corby G. Anderson, L. Ernest Krys, M. C. Fuerstenau

Since 1942, refractory precious metal concentrates at the Sunshine mine have been processed for antimony metal recovery using a novel leach-electrowin method. This is counter to most antimony production facilities where pyrometallurgical techniques are usually relied upon. The key step for removal of the antimony has been an ambient pressure alkaline sulfide leach. In 1990, a comprehensive laboratory study was undertaken to better understand this process. Factors studied included temperature, agitation, concentrate regrind, alkaline species concentrations, sulfur species concentrations and solids concentration. Details of these studies, as well as a brief description of Sunshine metallurgical processes, will be presented.

Jan 1, 1993

By Ian Sheppard, John J. Chen

This paper describes the development of the underground mining methods employed for narrow silver-lead-zinc orebodies at the Isa Lead Mine. Cut-and-fill methods were the chief underground mining methods for the narrow orebodies at the mine over 35 years ago. Benching methods were introduced approximately two decades later, and quickly replacing the cut-and-fill methods. The cut-and-fill methods and the benching methods are briefly reviewed in the paper. The benching methods and technologies have been continually evolving and one of the recent achievements is a multi-lift benching method. The multi-lift benching method is described in detail.

Jan 1, 2001

By Kevin D. Lofftus

This paper presents a dynamic model for column flotation. The model equations are normalized and the dimensionless groups that are directly responsible in determining the column flotation behavior are identified. The resulting model equations are incorporated for computer simulation. Numerical results from computer simulations are analyzed to gather information about design and operation of column flotation devices.

Jan 1, 1988

By Monica Pavlik, Thomas Wildeman

Water from the Forest Queen mine adit near Silverton, Colorado drains into a natural wetland. Because the pH of the water averages 5 and the iron concentration averages 18 mg/L, it was thought that the wetland might naturally treat the water. Of most concern with respect to the aquatic environment is zinc whose concentration averages 0.60 mg/L. Starting in October 1997, the surface waters, ground waters in the peat substrate, and the sediments in the wetland were sampled and analyzed four times over the course of four months. The adit water primarily remains as surface water where Fe, minor amounts of Al, and no Zn are removed. After the adit water enters the peat, then it is found that the pH rises to 5.8-6.5 and sulfate is reduced. The removal of Zn and A1 is caused by these two changes. However, Fe in its reduced state is quite soluble and may be remobilized in the reduced environment of the peat.

Jan 1, 2000

By K. J. Stratford

The selection of a suitable mathematical function for the modelling of the partition curve for dense medium cyclones is discussed. Five alternative functional forms (based on three basic functions) are compared using data obtained in the course of an extensive experimental study of a 610mm dense medium cyclone. It is shown that, for adequately sampled tests, any of the functions may be used, although a function based on the Weibull distribution is shown to be most suitable. Where data are poor, all functional forms exhibit disadvantages, notably in terms of a reduction in precision of parameter estimation. This problem can be exacerbated by the complex numerical techniques required to estimate the parameters of a particular function. A set of ideal requirements for a performance function are presented.

Jan 1, 1986

By S. K. Kawatra, S. J. Ripke

Iron ore pellets use bentonite clay as binder at dosages from 0.5to 1.0% (10 to 20 pounds per ton) of moist iron ore concentrate. Bentonite is typically shipped hundreds of miles from Wyoming to the Lake Superior iron ore district. It is therefore best to know how effective a bentonite will be before it is shipped and used to bind concentrate into pellets. Current tests of bentonite effectiveness include: plate water absorption, methylene blue uptake, free swell, exchangeable cations, and glycolated layer expansion. However, these tests have many disadvantages: First, they only measure the ability of a bentonite to expand, disperse, or absorb, not how well it will bond. Second, most of the tests require up to 20 hours to perform. Bentonite only has a few minutes to interact within the concentrate before it is indurated (sintered). These long-term tests may not reflect the true behavior of bentonite. Third, the tests are tedious and often results are inconsistent between different iron ore concentrates, labs, and technicians. Fourth, some of the testing equipment is difficult to procure. Fifth, procedures are often difficult to standardize. In this paper, the Binder Effectiveness Strength (BESt) test to evaluate binders for iron ore pellets is presented that: measures the ability of bentonite to bond, requires only about two hours to complete, is simple and reproducible, and utilizes readily available equipment that has been standardized for decades.

Jan 1, 2003

By Thomas C. Wilder, Firoze E. Katrak

As part of a survey on the long range supply of gallium, a comprehensive review of the chemistry of commercial gallium extraction was undertaken Owing to its very small concentration in all commercial minerals, gallium can be produced economically only as a by-product of major extraction processes for other materials. A summary is presented for the chemistry of gallium extraction from many of these process streams included are several procedures for gallium recovery from bauxite, currently the most prevalent source Other processes described are from waste streams from the production of zinc, phosphorus from phosphates, aluminum from kaolin clays, and from coal ash, the largest potential resource A brief review of development of solvent extraction as a unit process for gallium recovery is also presented

Jan 1, 1983

By R. Frenette, A. W. Mo, H. A. Hamza

Fine particles present major technical and economic problems to those who deal with solid/liquid separation processes. In the coal industry the problem is compounded by the large amounts of produced fines such as those present in Western Canadian coals. Flocculants in the form of high molecular weight water soluble polymers are commonly considered an effective solution for the enhancement of the separation process. These reagents are relatively expensive especially when considering a low-price commodity such as coal. Optimization of the use of these reagents is therefore an operational necessity. Six polymers were evaluated as to their effectiveness in flocculating a fine coal tailing. Results were compared with those for a reference flocculant, in-use at that time in the washery. It was shown that, in general, flocculants significantly improve the solid/liquid separation process. The ranking of the flocculants as to their effectiveness in settling and filtration indicated that the best flocculants for settling were not necessarily the most effective for filtration. Flocculants that showed the best filtration improvement were generally cationic and those best for settling were anionic.

Jan 1, 1988

By Haydn H. Murray

The three major catalyst markets that utilize industrial minerals as raw materials are petroleum refining, chemical processing, and emission control. Because of economic, competitive, and regulatory pressures, catalyst producers are pushed to develop products with improved performance to meet changing environmental standards. Also, refiners are demanding new families of cracking catalysts that will crack residual fuels. In 1987, worldwide cracking catalyst sales amounted to $457 million (Occelli, 1988a). Recently enacted federal and state laws to improve air quality have prompted strong growth for environmental catalysts, which in 1989 accounted for more than a third of the $1.9 billion catalyst market in the United States (Farrauto, Heck, and Speronello, 1992). A catalyst is a material that promotes or enhances a chemical reaction but does not itself enter into the reaction. One of the more important mineral groups used as catalysts is clays. The first recorded use of clay as a catalyst was its use in the dehydration of alcohol (Bondt et al., 1797). Clay minerals that are used as catalysts are kaolinite, halloysite, smectite, palygorskite, and sepiolite. Minerals used as catalysts, catalyst supports, or as a raw material to make zeolites are kaolinite, halloysite, sodium montmorillonite, calcium montmorillonite, hectorite, palygorskite, sepiolite, talc, calcined kaolinite, gibbsite, chlorite, and titanium dioxide.

Jan 1, 1994

By William J. Ferguson

At Henderson Operations the 24-kilometer conveyor system consists of three main conveyors with lengths of 1.2 km, 16.7 km and 6 km. Upon commissioning of the conveyor system, the Henderson maintenance department was challenged with the inspection and monitoring of over 50,000 idlers. To take a proactive approach to idler maintenance, an idler tracking database system was developed. Using the idler tracking program, the Henderson Crush & Convey department now has the ability to provide data for engineering solutions to idler problems and to manage thousands of idlers for priority replacement work and warranty purposes. Recognizing the potential for injury to Henderson employees in the process of idler handling, Henderson approached idler replacement as a material handling process. Material handling solutions have resulted in failed idlers being replaced and discarded from the underground environment without ever touching a human hand. This paper will detail how Henderson tracks idlers in all primary conveyor belts and how an innovative idler handling system can result in reduced risks to conveyor maintenance employees.

Jan 1, 2004

By Elif Çevik

This study deals with the mineralogical-geochemical characteristics and the industrial usage of the olivine from the dunites that crop out on the west of the Topuk village (Orhaneli). Mineralogical compositions of non-altered dunite samples are averagely as: Olivine (>90%), serpentine (1-4 %), opaque minerals especially chromite, magnetite, pyrite (1-3 %), and secondary minerals as magnesite, chlorite (1-2 %). X-Ray Diffractograms of the dunite samples indicate that olivines are in forsterite (93 on an average) composition, and chlinochrysotile and lizardite accompany to the forsterite. Chemical analyses of the dunites show that MgO, SiO2, Fe-,03 and LOI contents vary from 40,99 to 50,2 %, 34,67 to 40,6 %, 6,8 tol3,7 %, 0,11 to 11,27 %, respectively. SE-TAT Mining Company states that the study area has 400.000.000 tonnes proved, 800.000.000 tonnes probable and totally 1.200.000.000 tonnes olivine reserve. Consequently, all studies indicate that Orhaneli Olivin has convenient mineralogical and chemical properties and the grain size (0.04-40 mm) for industrial usages such as abrasive, olivine sand products, steel slag conditioner, balast and covering material in industry: Orhaneli olivines are demanded especially from the firms related to refractory industry, iron-steel factories, naval forces and shipyards. SE-TAT Mining Company also exports these olivines to different countries such as Macedonian and Spain.

Jan 1, 2005

By Yuusaku Tominaga

A flexible expert system for a personal computer has been developed to take countermeasures for prevention of emergency in underground coal mines. The system makes a diagram to estimate maximum airflow rate of a specified branch such as coal face or advancing face, etc. under the conditions of opening regulators set in any two different branches, by computer simulation. The system approximates the ventilating condition underground by using both measured values and safety factor derived from the rules in the system. The probability of happening gas explosion, spontaneous combustion and mine fire underground is shown on a display and countermeasures in a data base in the system are selected according to a confidence factor. When it is recognized in the system that either safety factor or confidence factor of countermeasure has a small value, the system sends information relating to reasoning in the system to registered human experts by computer communi¬cation and facsimile. The replies in file transfer from the experts are stored in the system and reconsultations for estimation of underground condition are started automatically. As the replies in facsimile are shown on the display, user inputs new rules and, values for reconsultation. It is shown that the system is available to take better countermeasures as the condition' of a network in coal mine is changed by mining day by day.

Jan 1, 1992

By Richard R. Klimpel

This paper reviews some of the factors involved in selecting amine flotation reagents used to remove silica from ores. A comparison is made between the chemical reagent design approaches used to identify flotation reagents that are used to recover silica- and oxygen-containing minerals and the chemical reagents used to recover sulfide minerals. This introduction gives practitioners who are involved with oxide- and carbonate-type minerals and who may not be familiar with sulfide mineral flotation some ideas of the chemical reagent design challenges that exist with froth flotation on a broader scale and why oxide type mineral flotation reagents are what they are. This is followed by several sections that discuss various classes of available amines. The closing sections emphasize that the optimal choice of an amine collector depends not only on that amine's specific chemical characteristics and costs but also on the operating conditions, especially the flotation feed particle size distribution.

Jan 1, 1999