Search Documents

By Edward S. Plotkin, Gary A. Almeraris, Thomas F. Peyton

The lining of the tunnel and shafts for a new section of New York City's- water system required extensive components to produce, deliver and place a continuous tunnel linning. The project placed approximately 153,000 CM (200,000 cy) of concrete for 5,340 M (17,520) of drill and blast 7.3 M (24 ft.) ID tunnel, located at depths of 152 M (500 ft.) to 213 M (700 ft.) . This section of tunnel will be connected to the surface water distribution system via four shafts of varying diameters ranging from 5.8 M (19 ft.) ID to 1.5 M (5 ft.) ID . All work was done beneath the streets of Manhattan under the rigid constraints of the City of New York and the Bureau of Water Supply regulations.

Jan 1, 1987

By E. A. Domínguez

La Espingarda kaolin deposit was formed by ?in situ? alteration of volcaniclastic rhyolitic rocks belonging to Jurassic Marifil Formation. Three volcanic lithofacies were identified: porphyric biotitic ignimbrites (PBI), a coarse lithic ignimbrite (ILG), a fluidal intrusive rhyolite (RFI), all kaolinized in different degrees. The alteration covers an ellipsoidal area of ~20,000 m2, with its alteration decreasing downwards and disappearing at 8-12 m from the surface. The length to thickness ratio of alteration is 60:1. An erratic silicification was found as small zones (<3 m2) of quartz stockwork. The mineralogy is kaolinite + quartz + feldspars + Fe-oxyhydroxides ± halloysite ± illite and interstratified I/S, although the relative proportions change in each rock type. Due to coarse grain size and high quartz content, natural kaolin is unsuitable for slip cast ceramics, unless beneficiated. Washed ILG kaolin has the best rheological properties and behavior in casting and drying for its mineralogy, particle size distribution, thin texture and surface activity, as well as a certain fusibility and firing kinetics. PBI and RFI kaolins, due to finer texture, smaller grain size, lower surface activity, and higher halloysite amount, have worse slip viscosity and thixotropy that are due also to soluble salts. For the same reason, they have good casting and drying properties, but their purity brings about higher softening temperatures and water absorption. Several parameters are used to discriminate between hypogene or supergene kaolinite genesis. The hydrothermal genesis is mainly sustained by fluid inclusion temperature (150-180ºC) in quartz veinlets, while weathering is supported by deposit morphology, simple mineralogy, kaolinite stable isotopes (d18O ? 18, 13; dD ? ?59; ?85) and paleoclimatic record. It is concluded that a weathering process formed the main alteration with some participation of steam-heated meteoric waters. Neither the contents of Au, Ag, As, Sb, Hg, nor drill data support the existence of any epithermal gold mineralization at the kaolinite bottom.

Jan 1, 2010

By E. O. Jacobs

A coupled solid and rock fracture mechanics model is used to analyze the blast driven fracture propagation phase, predict propagation rates, and directly measure shockwave and particle velocity. The study incorporates quasi-static pre-stress conditions for different depths below the surface. The scaled experiments include dynamic material properties and quasi-dynamic fracture mechanics which are shown to significantly affect the fracture propagation. The study was performed using three-dimensional cube-type laboratory models fabricated from Polymethylmethacrylate (PMMA). The test cubes are loaded with explosives and resulting fracture networks are studied. The dynamic evaluation of the spatial crack system is monitored using a high speed image camera. An experimental model set-up is designed to indicate the pre-stress effect on deep borehole blasting and is shown that the pre-stress conditions have a decisive influence on fracture profiles and orientation. It is found that shockwaves rapidly exceed the slower dynamic fractures and a majority of cracks occur due to detonation pressure. Experimental testing using different parameters validate that explosive fracturing can predict the outcome of fracture and crack propagation in any rock type with known material properties. This can be accomplished under great stress conditions deep below ground surface. The experimental study results can be applied to a variety of industries such as mining and quarrying, tunneling, oil and gas, and construction.

Feb 23, 2014

By Omar A. Muhtadi

Brohm Mining Corporation, in conjunction with Geobiotics, Inc. has nearly completed a pilot heap biooxidation test on sulfidic ore from the Gilt Edge Mine near Rapid City, South Dakota. Some results from the pilot testing have shown the correlation between the extent of biooxidation and the increase in cyanide gold recovery seen in the laboratory. Bench scale testing showed approximately a 1: 1 correspondence between percent biooxidation and percentage increase in gold recovery. The economics of large scale biooxidation were also evaluated in terms of increased gold recovery versus the time and cost of biooxidation. In the pilot test, the rate of biooxidation became limited by the acid water neutralization system. Later in the test, measures were taken to overcome this problem. Results from bench scale column bioleach testing showed that the Gilt Edge sulfide ore is quite amenable to biooxidation with a substantial increase in gold recovery with just partial biooxidation. Direct cyanide gold recovery of 51 % on ore crushed to -3/8" was enhanced to 82-85% after oxidation of37% of the sulfide as measured by iron. Laboratory experiments also showed that the slow rate of biooxidation of this ore could be accelerated by removal of metal sulfate build up from the leach liquor. The combination of these normally non-toxic metals became inhibitory to biooxidation if not removed by the neutralization circuit.

Jan 1, 1995

By A. Martikainen, H. Dougherty

"At the Kemi Mine, a recent expansion into the Surmaoja orebody required an increase in ventilation capacity. A new ventilation shaft was built with two main fans. The installation is near the entrance gate and only 1.7 kilometres from the nearest permanent dwelling. The main fans were first taken into use as exhaust fans in October 2014. Shortly after the fan installation, comments concerning fan noise were received from the neighbours. The first noise measurements were taken at the main fan installation site by Outokumpu personnel in March 2015. Due to higher than expected recorded values, during late June, 2015, a two-week environmental noise study was planned by the engineers and executed by a consultant specialized in noise measurement. The measurement results were analysed and compared to the requirements of the environmental permit and Outokumpu’s factory standards. While the measured values at the nearest dwelling were within the environmental permit limits, high noise values were recorded at the fan station. A second two-week study will be performed after construction of the main-fan heating station has been completed. Actions taken will depend on the outcome. INTRODUCTION The Kemi Mine is a part of the Outokumpu chain of integrated ferrochrome and stainless steel manufacturing in the Kemi-Tornio region in Finland. The mine itself is a large underground operation with a production capacity of 2.7 million tons of ore per annum. It is also the European Union’s only chrome mine, and at present (2015) the mine extracts 2.4 million tons of chrome ore per year. Safety, cost-effectiveness, and environmental friendliness are hallmarks of the Kemi Mine. Environmental impact produced by the operation of the mine is limited due to the insolubility of the oxide chromium ore, the gravity-based and chemical-free enriching process as well as the closed circulation system of the process water which serves both the whole mine and the enrichment process (Outokumpu, 2015). Importance of the environmental impact of the Kemi Mine is amplified by its closeness to the cities of Kemi and Keminmaa with the nearest habitants living less than 2 km away from the mine site. To show the cooperation with residents the Kemi mine organizes special “neighbour days” for the habitants of the areas closest to the mine. Also, information letters are sent to the neighbours, when changes that may affect the neighbours are being planned and executed."

Jan 1, 2016

By E. Bakhtavar

It is considered that the most economical method for the exploitation of Gol-e-Gohar Area 3 iron ore mine is to combine open-pit and underground methods. In this regard, the most critical problem is the determination of optimal final pit depth. In this paper, a method which was recently introduced on the basis of economical block models of open-pit and underground is used to determine optimal final open-pit depth of Gol-e-Gohar Area 3 mine with due regards to the future underground mining option. Considering a low cost and productive underground method as a feasible alternative for extraction of the lower part of this deposit, room and pillar was selected. It is concluded that after the assessment and comparison of different values for depth, optimal final open-pit depth was determined to be equal to 285 m.

Jan 1, 2010

By S. Phillipson

The Mine Safety and Health Administration’s Roof Control Division (RCD) evaluated the use of Shuttle Radar Topography Mission (SRTM) data to identify fracture traces on Earth’s surface. Results were compared to the analysis method employed by RCD for 30 years, which relies on LANDSAT-TM Band 4. SRTM elevation models are expected to provide a direct representation of bedrock surface, while LANDSAT-TM Band 4 represents reflected near-infrared radiation as an indication of moisture content and is only a proxy for possible structures. Three areas in southwestern Pennsylvania were chosen for ground-truthing lineaments derived from both methods, following a series of desktop comparisons in six areas of the contiguous U.S. Field studies that identified numerous instances in which SRTM lineaments corresponded with joints at the projected location, and were oriented within 10° of joint strike, indicating that those SRTM lineaments represented the structural grain of the area. In some cases, lineaments were associated with individual joint zones. Photo-lineaments derived from the existing LANDSAT-TM methodology appear to offer a higher coincidence with expected trends of joints on a regional scale when performing the desktop comparisons, while field observations indicated that SRTM-derived lineaments had a higher association with individual geologic structures in the case study field area. It appears that both methods can identify the structural grain of an area, and that both tend to identify linear segments of valleys where erosion has preferentially occurred along joint zones or other structures.

Jul 1, 2023

By Hamid Maleki

This paper reviews a study conducted for Australian Coal Research Limited (ACARP) to assist Anglo-American operations with better understanding of coal burst mechanics and control based on U.S. practical experience, investigations, and inspections in three major U.S. coalfields over the past 45 years. The study examined both nonviolent and burst-prone case studies to identify contributing risk factors and addressed failure mechanisms for major U.S. coalfields in Utah, Colorado, and Kentucky, which have diverse characteristics. To investigate the mechanics of coal burst, a multipronged approach is used. First, field measurements in three mines from East Mountain, Utah, are complemented with finite-difference stress analyses to address the importance of horizontal stress in coal pillar mechanics of violent failure. Second, the computational procedures for estimating seismicity resulting from slip along geological discontinuities are reviewed, as these measurements point to seismicity being the trigger mechanism for violent failure of marginally stable structures. This joint-slip seismicity mechanism is in agreement with the more recentimproved re-examination of mining-induced seismicity (MIS) data from the Crandall Canyon Mine, Utah by University of Utah (UOU). Third, a hybrid statistical-analytical methodology is applied for identifying significant factors affecting coal burst. It utilizes data from 30 case studies including those from Utah, Colorado, Kentucky, and other eastern U.S. mines. The statistical approach reinforces field measurements and points to strata rigidity, joint spacings, and horizontal stress field as significant factors affecting damage resulting from coal bursts. This provides practical capabilities for identifying operations of higher risk using a rigidity-cavability variable. Overall, the study provides valuable insights into the mechanics and risk factors associated with coal bursts in major U.S. coalfields. By utilizing a multipronged approach that incorporates both field measurements and statistical-analytical calculations, the study offers practical capabilities for identifying operations of higher risk and improving coal burst control.

Jul 1, 2023

By A. E. Jack Swanson, Brian P. Micke

INTRODUCTION Nevada Goldfields began underground mining development at the Kingston Project in September, 1986, followed by mill start-up in March, 1987. The first gold pour in April followed three years of preparatory work in establishing a North American operational base for the production of precious metals by Golconda Minerals N.L., an Australian mining firm. GENERAL CORPORATE BACKGROUND The Golconda Group of companies was established in early 1983 in Australia. It began operations by successfully retreating tailings at several old gold mining sites throughout Australia. With the limited reserves available for tailings retreatment, Golconda began to look toward the future by conducting a gold exploration program in Australia. However, the continued high price of gold in Australia had limited the possibilities of acquiring good properties at a reasonable cost and consideration was given to looking outside Australia in addition to Golconda&apos;s domestic exploration activities. North America was favored because of the proven potential for substantial gold deposits, the established infrastructure which would allow for rapid and cost-effective development of new projects and the advantages of similar political and economic climates. In mid-1984, Golconda established an office in California and began an extensive study of over 100 prospects throughout the United States. Two prospects were identified as a result of this study whch showed merit; one was located at Empire, Colorado and the other at Aurora, Nevada. Negotiations were then successfully undertaken to acquire these two properties. Golconda&apos;s U.S. offices were moved to Reno, Nevada in early 1985 to facilitate management of its projects. To operate and manage these projects, a small Canadian company listed on the Vancouver Stock Exchange, Cannon Minerals, was acquired by Golconda and renamed Nevada Goldfields Corporation. The current structure of the company is shown below in Figure 1. A private placement of 2,575,000 shares of common stock at US54.00 per share was arranged by Jacksons Limited of Australia in association with W.I. Carr (U.K.) Limited of London. This placement resulted in US510.3 million being available in May, 1986 for the acquisition and initial development of the Aurora and Empire projects. While the financing was underway, project planning commenced on both the Aurora and Empire projects. The Aurora project was selected as the one to be initially developed because of its relatively advanced stage of development. The

Jan 1, 1987

By W. Moser

During the ten year span from 1978 to 1987, the number of fires which occurred in under-ground coal mines doubled from the previous ten years. Anyone involved with underground coal mines is well aware of the associated tragedy that can result from these fires, both to personnel and to property. Every day mine management and mining personnel face this threat of a possible mine disaster or fire. Their ability to deal with such a situation safely and effectively depends on the level of emergency preparation developed and maintained. As a direct result of the ever-increasing interest in the Mine Emergency Preparedness Program and the Mine Fire Training Programs currently being conducted, the Emergency Preparedness Center was created. As a branch of the Mining Extension Service at West Virginia University, the Center provides preparedness training at several different levels on a varying range of topics. Classes are conducted at a new especially-designed training laboratory at the National Mine Safety & Health Academy in West Virginia. By maintaining the proper equipment and levels of training allowing for immediate response, the personnel who are part of the Center believe that the impact of a mine fire or other such emergency situation can be minimized. This paper will present recommendations for maintaining an efficient mine emergency preparedness program and will provide information regarding the Mine Fire Training Program as conducted by the Emergency Preparedness Center and describe the advantages of the newly constructed training facility.

Jan 1, 1993

By Philani Larrance Ngwenyama, Ronald CW Webber-Youngman

Through-the-Earth (TTE) communication systems were developed to provide post-accident communication in underground mines. Unlike primary tracking systems, they do not require any major infrastructure installations underground. Instead, they use the Earth’s overburden as the medium or channel for the transmission of electromagnetic waves between surface and underground. Under ideal conditions, TTE communication systems should be able to provide full-duplex, two-way voice, text and data communication. However, this will depend on the design and optimization of the different types of TTE communication systems (that is, antenna and electrodes), and understanding of the rock properties and their influence on the transmission of signals. This can help simulate and model the transmission efficiencies and predict the possible range and data rates. Being able to optimize the performances of these systems can enhance rescue missions, improving the chances of saving trapped miners, and ultimately reduce fatality rates across the mining industry.

Feb 1, 2025

By John J. Stetler

The Companhia Vale do Rio Doce in Brazil operates one of the most extensive systems in the world for the mining, transportation, processing, pelletizing and shipping of high grade hematite iron ore and pellets. Current shipping of unbeneficiated, sized, high grade ore from its ports at Tubarão and Vitória is now at the rate of 17,500,000 metric tons annually. An increase in this annual rate is now under study. Using the technology and facilities of Lurgi (1) and Arthur G. McKee company CVRD undertook a program to process and pelletize two types of fines - "Blue Dust" and ?Itabira Fines?. Blue Dust is a high grade fine ore which was bypassed while mining the direct shipping ores and which, also, exists as a very large ore body called the Conceição Mine. Itabira Fines is a lower grade of fine ore which is comprised of in-situ fines and, also fines which are generated in sizing the direct shipping ores for a rigid specification market.

Jan 1, 1970

By M. Baumann

Operating and maintaining the heavy equipment used in open-pit mining operations is an ongoing challenge for mines. Typical operations employ a combination of shovels, wheel loaders, and haul trucks to excavate and transport the material for further processing. As this is the first point of contact for the material after blasting, it is often a bottleneck of all downstream processes, thus, equipment uptime and efficiency is crucial. Automated systems for bucket tooth monitoring, payload measurement, proximity detection, and rock fragmentation analysis will be examined. The impact of these systems on operation safety, efficiency, and reliability, in real-world scenarios will be investigated. The process of managing all the above fleet of equipment in a mine can be streamlined by connecting the equipment monitoring systems to a central server. Using the central server, the distribution of this information can be automated to ensure that the right people see the data in a timely manner, improving both proactive and reactive responses to threats to safety and productivity.

Feb 23, 2014

By T. J. Batchler

"INTRODUCTION A variety of standing supports are being applied in underground coal mining operations to assist in providing stable mine entries. Standing support performance requirements depend on the nature of the ground deformation behavior, and therefore require a good understanding of the interaction between the support and ground to achieve an optimum roof support system. Mining operations often employ standing support strategies that are unique to their mine. A support system that functions successfully in one situation could fail in another situation. It is important that the design and installation of the standing support systems provide the highest probability of preventing roof falls. Considerable research and development has been conducted by support manufacturers to develop standing support technologies for the mining industry. The National Institute for Occupational Safety and Health (NIOSH) researchers, with the cooperation of various support manufacturers, have developed a testing protocol that evaluates performance characteristics of these standing support systems.. Using this protocol, each of these support systems has gone through rigorous safety performance testing under controlled loading conditions in NIOSH’s Mine Roof Simulator (MRS). It is important to understand the unique performance characteristics of each type of standing support. This information allows mine operators to determine if the support system is compatible with the conditions in the mine and to compare each support system and determine if that support will provide equivalent or improved support capability. This paper provides a comprehensive summary of support performance to facilitate this objective. SUPPORT DESIGN CRITERIA AND THE GROUND REACTION CURVE Standing roof support systems are designed to prevent unplanned roof falls. The selection of the standing support is based on the interaction of the support with the surrounding rock mass, and its function is to assist the primary support system in maintaining the integrity of the immediate roof. The standing support works to control the immediate roof structure by resisting deformation that contribute to delamination of the bedded layers and displacements that lead to separation of the bolted zone from stable roof structures above the bolted horizon (Barczak, 2005). Standing supports should be installed early enough and develop sufficient capacity to bring deformation of the ground into equilibrium before a critical deformation is reached that leads to a detached block condition, at which point the standing support will be required to carry the entire dead weight of the detached rock mass to prevent a roof fall from occurring (Mucho, 1999). The ground reaction curve (GRC) can be used to assist in determining the compatibility and design requirements for a support system. It is important to understand the significance of the ground reaction relative to the support design requirements. The ultimate objective is to match the support behavior to the ground response and create equilibrium (stability) of the rock mass. This equilibrium is accomplished when the support loading intersects the ground reaction curve (Figure 1). Essentially, the ground reaction concept implies that the convergence in the mine entry is controlled by the magnitude of the support resistance. However, as a passive support, the standing support develops its loading through convergence. As such, the support needs to maintain its load capacity through the associated deformation of the ground and resulting entry convergence until the equilibrium condition is reached. This requirement causes factors such as the support stiffness, peak capacity, yielding characteristics, and stability to be fundamental to proper support design and application. NIOSH contributes to providing this understanding through full-scale performance testing of support products in the Mine Roof Simulator."

Jan 1, 2017

By C. Newman

"Over the past decade, as conventional underground deposits have been depleted, mining operations have been forced to produce at greater depths and in more geologically and geometrically challenging conditions. As such, there has been a global increase in the application of cemented paste backfill (CPB) in tabular deposits utilizing open stope mining method with a delayed backfill placement. Despite the extensive use of CPB, many fundamental factors affecting the design of safe and economical fill structures are still not well understood. A critical issue in the design of backfilled stopes is the determination of stress states within the fill material itself as well as the surrounding rock mass. Analytical equations provide a means of quickly evaluating the effectiveness of a given design. However, in developing these equations large assumptions are implemented to simplify the design problem. It is important that one understands these simplifications as well as their effect on the overall design. This paper investigates common analytical equations utilized in the evaluation of single vertical backfilled stopes and their assumptions through comparisons to numerical modeling results. INTRODUCTION AND BACKGROUND As the mining industry continues to produce at greater depths and in more geometrically and geologically complex conditions, cemented paste backfill (CPB) has gained traction as a means of providing localized ground support in modern stope-and-fill mining operations. The application of CPB in stope-and-fill mining as a ground support material has led to the reduction of mine waste costs, while increasing both mine production and stability. In an attempt to achieve total extraction of the mining reserve, stope-and-fill mining operations often employ a primary-secondary excavation-support sequence (see Figure 1). In this practice, primary stopes are initially excavated and then backfilled in a two-stage pour; plug and final pours. During the first stage (plug), a CPB material with increased cementitious content is placed at the bottom of the stope providing a strong base from which to build a backfill structure as well as protect mine works from material breakthrough. Following placement, the backfill plug is allowed to cure to a given strength as designated by the mine design. Upon achieving the required cure strength, a less cementitious CPB material is used to backfill the remaining stope area. This is referred to as the final pour stage. With all primary stopes excavated and supported using backfill, the extraction of the secondary stopes commences as primary stopes are utilized as artificial pillars. While the application of CPB in a primary-secondary extraction-support mining sequence allows for a substantial increase in reserve recovery, it is imperative the mining personnel and planning engineers have a clear understanding of the material’s behavior and stress interaction with the surrounding rock mass to ensure the most efficient, cost-effective, and safe extraction of underground deposits."

Jan 1, 2018

By D. R. Zuchelli

The purpose of wrapping ball mills with thermal/acoustic blankets is twofold: 1) to maintain the desired temperature inside the mill, and 2) to reduce the sound emanating from the mill. This field case study focuses solely on the latter, evaluating and documenting the sound level reduction attributed to the installation of the blankets on ball mills and its potential to reduce the noise dose experienced by the process attendant. One of the three ball mills had already been treated (baseline) before the evaluation started. However, treating the remaining two mills still proved to be very effective, further reducing ball mill noise in the near field by as much as 10.0 dBA and producing far field noise reductions of 3.0 dBA or greater, extending as far as 35 feet from the mills and to the floor above. The model developed from the survey data shows that a process attendant spending a substantial portion of a shift in the mill building will experience a significant reduction in overall noise dose.

Jan 1, 2010

By Julio C. Martinez, Jeffrey L. Rice, Hayden Weschler

This paper details the extensive underpinning required to hold up the 39th street Bridge while demolishing its massive support piers and building a 30ft deep Cut/ Cover RR tunnel beneath it. The underpinning/SOE support required the construction of 16 large hand dug pits 36ft deep that were reinforced and concrete filled. In addition, an extensive steel support system was tied into the bridge super structure. All of the underpinning/tunnel construction was done while a 110ton crane sat directly atop the heavily trafficked – 66 ft. wide bridge. The tunnel excavation, concrete lining and final bridge pier support work will also be presented. All work was done within 5ft of active mainline tracks and that required tight grouting behind all lagging to eliminate any track settlement.

Jun 13, 2021

By Liming Yuan, A. C. Smith

Barometric pressure changes affect air density, leading to change in the mass of the gas in the gob. When the barometric pressure decreases, the volume of gas in the gob expands, while the volume of gas contracts when the barometric pressure increases, a process which causes the gob to “breathe” out and in. Although the concept of gob “breathing” is simple, its effect on spontaneous heating of coal in the gob area is not clear. In this study, computational fluid dynamic (CFD) simulations were conducted to model the spontaneous heating of coal in the longwall gob area under measured barometric pressure changes. A single longwall panel using a bleederless ventilation system was simulated. If there is no barometric pressure change, the intake airflow rate is equal to the return airflow rate. When the barometric pressure changes, these two airflow rates are no longer equal, and the difference between the two airflow rates represents the airflow rate the gob breathes in and out. The effect of inflow and outflow of gas on the potential spontaneous heating in the gob was investigated using the CFD model developed in our previous study. The effect of barometric pressure changes on the spontaneous heating was found to be dependent on the gob permeability and the coal oxidation rate. The effect of barometric pressure changes on oxygen concentrations in the gob was also examined.

Jan 1, 2010

By William R. Nash

Case histories of water problems in underground mine shafts and tunnels are outlined to illustrate varying degrees of sophistication in grouting techniques currently applied in such construction. The interception of water underground can be one of prior knowledge, i. e., the site investigation provides necessary data to plan a grouting program prior to construction start, or excavations may encounter "changed conditions" or unplanned water. The latter includes catastrophic inflows and emergency situations where the structural integrity of a building or concrete shaft lining are jeopardized. The presentation of this paper outlines some applications of grouting work in underground mine construction throughout the United States in a variety of geological provinces and for a variety of minerals.

Jan 1, 1984

By Hun-Joon Sohn

Chemical metathesis and electrochemical reductive conversion of chalcopyrite in the presence of cupric ions were studied in sulfuric acid solutions for temperatures up to 90°C. The process results in the displacement of iron in the chalcopyrite lattice by copper ions with rejection of ferrous ions to the aqueous phase. The rate of reaction was found to be very slow, requiring subsieve-sized particles for extensive reaction to occur. The reaction was insensitive to copper ion concentration. Stirred ball milling of chalcopyrite introduces lattice strain. The reaction rate with strained particles was markedly higher than with annealed chalcopyrite. The reaction rate was found to be diffusion-limited, showing two distinct reaction stages corresponding to the formation of CuS (covellite) followed by Cu1.8S (digenite). The experimental activation energy for the first stage was 102 J (24.4 kcal) and the second stage 123 3 (29.4 -kcal) per mole. The rate-controlling process is diffusion of lattice ions, probably iron. The enhanced rate after milling is attributed to a recrystallization process which provides new paths for diffusion along dislocations and grain boundaries.

Jan 1, 1984