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By D. D. Banerjee, S. K. Kawatra, T. C. Eisele

To reduce their sulfur emissions, many coal-fired electric power plants use wet flue-gas scrubbers. These scrubbers convert sulfur oxides into solid sulfate and sulfite sludge, which must then be disposed of. This sludge is a result of reacting limestone with sulfur dioxide to precipitate calcium sulfite and calcium sulfate. The majority of the sludge is simply landfilled, but with increasing landfillimg costs this can cost the plant millions of dollars per year. As a result, this option is rapidly becoming less attractive. Producing marketable materials from the sludge is a far more promising avenue, provided that the products can meet the necessary specifications at a reasonable cost. In this paper, a method is described for using froth flotation and water-only cyclones to remove unreacted limestone from scrubber sludge. The water-only cyclone was found to be very effective for removing the coarser unreacted limestone, grinding ball chips, gravel, and similar coarse impurities. Froth flotation was found to remove fine unreacted limestone, with a minimum of reagent addition.

Jan 1, 1995

By A. Unal

Coal resource characterization usually calls for estimating more than one variable over a block or node simultaneously. Within the realm of geostatistics, each variable has been evaluated independently from the others assuming a lack of significant correlation. Research conducted with coal seams, however, has shown that the variables of immediate interest, such as seam thickness, ash, sulfur content, and density depict some correlation schemes in distinct zones, if not throughout the entire area. The above findings have two immediate consequences : (1) correlation analyses provide guidelines to determine the geologically distinct zones, and (2) where possible, cokriging should be used instead of kriging. This will maximize data utilization decreasing the frequently criticized high estimation errors. The cokriging formulation will also provide more accurate estimates for under sampled variables using better-sampled ones. This is a common case with coal with regard to the non-cored reconnaissance drill holes for which only very few variables were recorded. A case study illustrates the improvements that may be obtained by taking advantage of the intervariable correlations.

Jan 1, 1986

By S. S. Peng, V. Z. Sun

One of the major concerns of ground control in a coal mine is the prevention of roof, pillar and floor failures of the mine entry. To better design and evaluate the stability of a mine entry within a certain level of confidence, a reliability approach is introduced. The advantage of using the reliability approach, rather than the conventional safety-factor (SF) method, is that it not only takes variability of both rock/coal properties and stress into consideration but also assesses the stability of each component and the mine entry as a whole. Therefore, it is anticipated that by using this approach the current ground-control technology in a coal mine will convey a better sense of confidence. The results of a case study show that there is a significant difference in mine entry stability between the current design method and the reliability approach.

Jan 1, 1999

By J. J. Kellar, W. M. Cross, H. Du, C. D. Struckman, D. A. Boyles

Silane coupling agents have been used in the filler industry for years. One particularly unique feature is the ability of the coupling agents to enhance the adhesion between filler and polymer matrices. This paper will review the use of coupling agents for polymer matrix composite applications and discuss a new approach to coupling agent chemistry, namely, direct formation of a silicon-carbon non-hydrolyzable linkage between glass and coupling agent. The grafted silane monolayers were evaluated by infrared spectroscopy to ascertain their surface coverage and relative stability. Finally, composite specimens were fabricated and their mechanical properties were compared with traditional silane coupling agent treatment.

Jan 1, 2003

By D. E. Ranta, M. G. Schulz

Mining of Molybdenum at Questa, New Mexico has been accomplished by block cave methods since August, 1983. As caving progresses, a periodic geologic evaluation is made of the rock types present in finger raises on the Grizzly Level of the mine. The production maturity of the cave can be monitored by relating this data to geologic cross-sections through the orebody. The draw point mapping program is a simple and effective tool that is used in making draw control decisions at Questa.

Jan 1, 1992

By A. G. Belova

Conversion of coal into high-value gases via gasification offers significant pollution reduction and efficiency improvement benefits associated with controlled combustion of clean gases for power generation. However, current gasification-based electricity production technologies, such as IGCC do not address carbon dioxide emissions. The focus of the study is CO2 capture on CaO prior to combustion of coal-derived gases. To overcome kinetic and stability limitations associated with its utilization, CaO is distributed on high-surface area -Al2O3 and supported on a ceramic honey-comb monolith. The proposed method allows for efficient capture of CO2 from a gas mixture, as studied in a flow-through reactor system. This novel method of CO2 capture is used here to argue for pre-combustion capture of CO2 in coal gasification-based power plants. When CaO is present during the steam reforming of coal gasification gases, continuous withdrawal of CO2 from the system provides for higher yields of reforming products (hydrogen gas) by influencing the thermodynamic equilibrium of the entire system.

Jan 1, 2009

By K. Verghese, H. M. Lee, R. P. Gardner, K. Boateng

Results of work on the development of a phenomenological model for the continuous flotation process wing short-lived radioactive tracer techniques for determining model parameters is reported. A model that incorporates a flotation first-order rate constant and a residence time distribution based on the cross-flow finite-stage (CFFS) model has been derived and investigated. The short-lived radioactive tracer techniques and the nonlinear search methods necessary to extract the model parameters have been developed. The conditions under which all the model parameters can be extracted from a single radiotracer experiment are detailed and illustrated. A micro- computer-based unique data logging system has been designed, assembled, and implemented for collecting the necessary transient radiotracer data. Results are reported for a continuous laboratory flotation process for the two systems, mica ore and coal.

Jan 1, 1987

By S. C. Brown, R. C. G. Oliveira

Surface wettability, or contact angle, dictates a number of multiphase ensemble interactions that influence particulate dispersability and adhesion behavior (e.g., filler compatibility] in addition to a number of other phenomena including biocompatibility and bulk powder segregation. The wettability of particulate surfaces significantly impacts nearly all process industries; however, the available techniques to access this quantity are either relative, or tedious-and are application or industry specific. In this study, key features of existing techniques have been combined to design an improved method to delineate particle wettability that is simple, versatile and capable of providing reproducible measurements in an industrial environment.

Jan 1, 2003

By Gary Schaffer, Anthony Stentz

Surveying of mines is a necessary step in coal mining to assemble maps which are used for tracking progress in the development of the mine and to plan future coal removal. A first approach for automatically building high-resolution two-dimensioml maps of underground coal mines is presented. The technique assembles laser rangefinder scans obtained from several locations within the mine into a consistent global map of the mine. Each range scan comprises thousands of data points collected in one second, thereby achieving higher resolution and much faster measurement compared to a human using a transit. The raw data (range scans) are processed to fuse them into a consistent representation. This paper describes a first approach to automated surveying and presents initial results of merging range scans. Improvements to the scan-merging algorithm are proposed.

Jan 1, 1993

By R. A. Jankowski, R. Gong, R. Bhaskar

Full-scale laboratory studies were performed to evaluate the effect of passive barriers and spray airmovers on airflow patterns at a continuous miner face and in reducing underboom boilout and operator exposure to dust. Tasks included baseline data collection, smoke trace tests, detailed performance testing using tracer gas, and data analyses. Data collection was performed using a state-of -the-art gas analysis system and custom-developed software. The data were used to calculate operator exposure at various locations and to develop gas profile maps to analyze airflow patterns. The effects of the proposed underboom airflow modification devices on operator exposure and airflow patterns were examined. Based on the results obtained from the study, the base case condition, with no barriers, appears to result in the lowest operator exposure.

Jan 1, 1992

By D. Denton, C. Peppin, D. Tesarik, D. Bayer, J. B. Seymour

Hecla Mining Company and NIOSH cooperated in a study to document the safety of rock support supplied by reinforced cemented paste backfill at the Lucky Friday Mine. Data are presented on backfill modulus values from laboratory tests and compared with modulus values from in-mine wall closure on the backfill. It is theorized that a compressive zone is created in the backfill between the upper and lower bearing plates on the reinforcing bolts, and that the backfill remains stable as long as the compressive zones from adjacent bolts overlap.

Jan 1, 2001

By Richard J. Adams

Coal jigs have played a predominant role in U. S. coal preparation for fifty years. Recently, an improved fine coal jig has been used to prepare the middle size range coal. These efficient machines are changing the historical thinking about jigs and is consistent with trends in coal preparation throughout the world. The performance achieved and operating cost savings are causing a change in fine coal cleaning strategy. With the exception of a handful of operators, fine coal jigs are generally not well understood by the industry. The objective of this paper is to provide some insight into the past use of fine coal jigs and their potential in the future. Improved Fine Coal Jig Since the mid 701s, an improved fine coal jig has been employed to an important niche in preparation, the 19 mm x 100 M range of cleaning. Several factors due to mining and liberation considerations have caused an expansion of this middle range of coal resulting in a host of challenges for coal preparation engineers. Fine coal jigs have been commissioned in several installations in North America to handle these important applications as shown in Table No. 1.

Jan 1, 1988

By Thomas Fenner

Surface and underground mining operations are often hindered by unknown tunnels and slopes and the precise locations of adjacent workings. Mine safety and planning are adversely affected especially in previously undermined areas where historical records are incomplete or nonexistent. The results of several ground penetrating radar (GPR) studies for the detection of known mine tunnels in underground coal, salt and gold mines are presented. A case study to locate unknown, abandoned mine workings at a surface gold mine successfully located all workings to a depth of 11 m (36 ft).

Jan 1, 1996

The application of Kirchoff's laws to two adjoining mine ventilation network meshes containing fans results in the construction of two general quadratic equations. These equations may be solved to give the resultant airflows and hence fan duties within the system for given network parameters and fan characteristics. This technique has a wide application for calculating the duties of fans in various combinations within a mine ventilation system. Recent difficulties in economically maintaining environ- mentally safe conditions in underground working areas distant from main ventilation fans has led to increasing interest in the use of controlled partial recirculation of ventilation. This paper develops a recirculation model which can be solved directly using mathematical techniques obviating the need for iterative techniques such as the Hardy-Cross method. The advantage of a direct mathematical analysis is that mathematical algorithms may be constructed to completely describe the ventilation system under a wide range of operating conditions. This technique is applied to controlled partial recirculation ventilation systems to demonstrate its advantages for mine ventilation planning.

Jan 1, 1989

By J. E. Hoffman, T. J. Keefe, Michael E. Stout, O&apos

M.A. Industries, Inc. has developed and is now offering on a commercially available basis, complete systems to recover and recycle lead from spent SLI batteries. The system begins with the breaking and separation of the component parts of the batteries and subsequent treatment of the effluent water produced by this operation. The recyclable materials recovered from this process are metallic lead, lead paste and polypropylene. The lead paste is introduced into a process to convert it from a lead sulfate to a lead carbonate. The process also regenerates the salt solutions into reusable carbonate. The lead carbonate is then leached into an acid bath where it is later recovered by a proprietary electrolytic process. The metallic lead is recovered in a short rotary furnace producing metal for further refining and alloying. The polypropylene is further washed and then introduced to a reclaim extruder along with the proper modifiers and additives. The resulting resin can then be sold on the open market to injection molding processors. This complete system greatly reduces the amount of waste to be disposed of and completely complies with all applicable EPA guidelines.

Jan 1, 1993

By Norbert Patzelt, Johann Knecht, Wolfgang Baum

High pressure roll grinding (HPGR) is a mature but still expanding comminution technology. In the metals mining industry, HPGR is slowly gaining acceptance as a cost-efficient, high-throughput alternative for plant optimization. The increasing need to treat ores with progressively lower grades, complex mineralogies, refractory metal occurrence and variable rock types requires an energy-efficient comminution technology that reduces metallurgical problems inherent in conventional crushing and grinding, while stabilizing leach and flotation circuits and increasing metals extraction. This paper will summarize our latest HPGR pilot test results for gold and copper projects in the United States and South America and their confirmation through the first HPGR operation in copper mining. This paper will also stress the use of the high pressure grinding roll as a metallurgical tool. The application of HPGR for the treatment of heap leach SX-EW ores, semi-refractory gold ores, waste rock material and concentrator feeds will be illustrated.

Jan 1, 1998

By A. S. Ibrado, D. W. Fuerstenau

The adsorption of the cyano complexes of Ag(I). Cu(l), Hg(II), Cd(II), and Zn(II) on activated carbon was investigated as a function of pH and correlated with the speciation diagram for each metal. The results show marked changes in uptake with pH, closely resembling the predominance profiles of their neutral and singly charged cyano complexes. Multicharged negative complexes are repelledby the negatively charged carbon surface. The sensitivity of activated carbon to the charge of the adsorbing species indicates that silver adsorbs as an anion, not chemically bound to the coadsorbing counterions. For the same reason, activated carbon is selective to metals that preferentially form neutral and singly charged cyano complexes, namely gold and silver.

Jan 1, 1990

By Barbara C. Williams

U.S. Bureau of Mines researchers conducted field studies at an abandoned copper-gold mine tailings impoundment. Pore water quality was analyzed in the vadose and saturated zones. Three statistical procedures were employed to summarize the variability within and between the two zones. The results indicated that linear combinations of those variables reflecting sulfide oxidation and aluminum-silicate weathering best summarized the variability in each zone, and that the zones were most different on the basis of sulfide oxidation variables. The geochemical computer code WATEQ4F was used to assess the solubility status (saturation index) of minerals. Saturation indices of sulfide oxidation and aluminum-silicate weathering minerals were different in the two zones. It was demonstrated that the statistical analyses produced similar and complementary results to the geochemical code.

Jan 1, 1992

By L. Henry Smith, David C. Arthur

The Williams Mine is Canada's largest gold producer, with annual production of 14,000 Kg (450,000 ounces) from 2,300,000 tonnes of ore. Highly mechanized and automated underground mining practices are employed in order to achieve and maintain high levels of productivity and minimize costs. The Mine Ventilation System is modified to include a new Vent Raise and Variable Pitch Vane-Axial Fan. This addition allows several fan installations underground to be decommissioned. A substantial net savings in installed horse power is achieved. Heating costs associated with underground ventilation air are a significant portion of mine operating costs. Air heating costs are substantially reduced by recovering heat from upcast exhaust air, mine water and compressor cooling circuits. This waste heat is used to supplement propane fired air heating systems for underground ventilation air. An additional benefit is the availability of a heat sink for summer cooling of the compressors. System design, energy savings data and payback calculations are presented.

Jan 1, 1997

By D. D. Runnells, D. C. Keith, G. A. Doyle, J. Tilk

Until the suspension of conventional operations in 1996, the White Pine Mine was the second-largest active underground copper mine in the United States, underlying an area of approximately 30 km2 (13 sq. miles) in the Upper Peninsula of Michigan. The mine operator intends to initiate in-stope solution copper mining by circulating a solution (lixiviant) of mine water, sulfuric acid and ferric iron through rubblized ore. As planned, the solution would be retired in the mined-out stopes following completion of the solution-mining activities. Investigations into the fate of the retired solution indicated that the solution, through time, would change from an acidic, metal-rich solution to a near-neutral, reducing solution containing much lower concentrations of metals. Investigations included reaction-path modeling (EQ3/6) and laboratory and in-mine tests. The combination of neutralization and reduction will result in precipitation of most metals, primarily as metallic sulfates, chlorides and sulfides.

Jan 1, 1998