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By I. Iwasaki, K. A. Smith, X. Cheng

The reaction mechanism for the cathodic decomposition of pyrrhotite in deoxygenated solutions at natural, near neutral pH levels was studied using potential and cyclic voltammetric measurements. Reaction products on the pyrrhotite surfaces were examined by Auger Electron Spectroscopy (AES), by X-ray photoelectron spectroscopy (XPS) and by analyzing the voltammograms for the electron balance of the reactions. Surface properties of the pyrrhotite/solution interface were characterized using an ac impedance technique. The parameters of an equivalent circuit were determined by the nonlinear least-squares fit (NLLSF) technique. The effect of cathodic polarization on floatability was investigated by performing microflotation tests. Possible implications to the flotation separation of chalcopyrite-pyrrhotite ores are discussed.

Jan 1, 1995

By Arthur B. Steiker

Digital simulation was used to model a proposed underground' train system. The trains are to haul ore from numerous loading points beneath the production area of the mine to a central underground dump location, and then return to the mine. The purpose of the simulation was to aid mine engineers in studying various alternatives and configurations regarding track layout, crusher (dump point) specifications, dispatch procedures, fleet size, and train length, among others. The simulation' model can also be used to study the same aspects of existing haulage systems. To accommodate a wide and initially unknown range of system designs, a modular model structure was developed with major components devoted to track routing, train movement, loading process, dumping process, and dispatch. Key statistics tabulated were number of trains dumped during a simulated week, queueing delays in the mine and at the crusher, crusher utilization, cycle time, and percent of time for each: activity (loading, moving, dumping, etc.). The simulation results were instrumental in identifying a train system design which would reduce queueing delays and meet production goals with a minimum of trains and track mileage.

Jan 1, 1982

By Kumara S. Rachamalla

Mineral activity in Ontario represents an annual production in excess of $4 billion. The Ontario government encourages the mining industry to undertake mineral development through grant programs and incentives offered by mineral resource taxation. Computers are playing an increasingly important role in improving productivity in the administration of incentive programs and the Mining Tax Act in Ontario. This has meant speedier processing of grant applications and tax returns which is resulting in a streamlined approach to incentives and taxation in Ontario. The use of computers has resulted in significant contributions to key areas of concern such as assessment of mining tax returns, analysis of the changes, if any, to the Mining Tax Act and modeling of the Ontario Mineral Exploration Program (OMEP). Implementation of state-of-the-art technology such as Local Area Networks (LAN's), fourth generation languages and integrated micro-mainframe information processing has resulted in improved productivity as well as lower costs. As a result, the respective services provided to the mineral industry by these two programs are now delivered in an efficient and cost-effective manner utilizing the latest available computer technology.

Jan 1, 1986

By J. E. Gebhardt, J. A. Herbst, K. Y. Lee

Benefits of proper control of reagent usage in flotation circuits are typically improved metallurgy and savings in reagent costs. Improved metallurgy can mean more consistent product quality, i.e., final concentrate grade, better recovery of product values from the feed, or higher plant throughput at existing target recovery, and grade values. Flotation performance is sensitive to a variety of process disturbances which occur in operating plants, such as changes in flow rate, percent solids, size distribution. flotability of mineral species, etc. A way to handle these variations is to fully understand the dynamic flotation responses to disturbances and to implement a suitable control strategy to compensate for these disturbances. Depending on the objectives of the control system, various types of control strategies are available which employ different levels of refinement to achieve the desired performance. Typically, variables such as collector and frother dosages and reagent addition points can be manipulated to affect the performance of the circuit. In the case of sulflde mineral flotation, manipulation of the process electrochemical potential, in flotation and in grinding, offers another degree of process control. Because of the complex and interactive nature of flotation process variables, optimized reagent control requires consideration of all, or at least the most important, interactive variables of the flotation circuit. Model- based optimizing control provides a framework to handle the complex and dynamic nature of flotation reagent process control.

Jan 1, 1994

By Hasan Sevim

A computerized heuristic model for an efficient and economic design of belt haulage networks in underground coal mines is discussed. The model is versatile, easy to use, and is valid for all mining methods singly or in combination. It may be used to design new networks or to analyze existing networks. The input data required are 1. maximum production rates from a section, 2. probabilities of production rates, 3. equipment costs, and 4. data necessary for network coding to represent different cases. The objective function is the "expected minimum cost per ton of coal hauled" while meeting production requirements. The output includes belt width, motor horsepower, bin size etc. and also values of operating parameters for each belt such as belt speed, effective tension, power consumption etc. A detailed account of the cost involved is also provided for each unit as well as for the entire network. Description of the model and an example of the design of a belt network in a mine with two longwall and four development sections are presented.

Jan 1, 1986

By G. H. Roybal, J. M. Barker

Humate mining in New Mexico is a small industry [455 m3 (16,079 cu yd) valued at $395,894 for 1983] with three mines active in 1985. Either humate (carbonaceous claystones rich in organic matter) or weathered coal ("leonardite") high in humic acid are mined. The humic acid content needed to meet consumer specifications determines which type is mined. The humate and "leonardite" now mined in New Mexico are used primarily as soil conditioners or as drilling mud additives. The potential resource for both are very extensive within the coal-bearing formations of the San Juan Basin in northwest New Mexico.

Jan 1, 1987

By Charles N. Alpers, D. Kirk Nordstorm

A variety of approaches have been used in the recent literature for the estimation of pre-mining (or natural background) metal concentrations in areas affected by mining. The following is a list of some of these approaches: (1) historical and anecdotal data, (2) remote analogues (other similarly mineralized areas), (3) proximal analogues (nearby mineralized areas), (4) sediment sampling (streambeds, lakes, estuaries, floodplain deposits, and soil profiles), (5) stable isotopes (hydrogen, oxygen, sulfur, and carbon), (6) geochemical modeling (forward, equilibrium-based), (7) geochemical modeling (forward, kinetic- and transport-based, and inverse), (8) statistical analyses, (9) mass balance on oxygen flux, (10) mass balance with age determination of weathered material. Examples of each approach are described, and the strengths and limitations of each approach are discussed.

Jan 1, 2000

By R. A. Bergman, P. G. Thornhill

Development of the Falconbridge Ferronickel Process for treatment of lateritic nickel ores began with laboratory work in 1955, the year the Company commenced exploration of its concession in the Dominican Republic. Process development centred on selective reduction originally directed to producing calcines amenable to ammonia leaching, but later found suited to electric smelting. The reduction step of the process was developed in a 25 tpd shaft furnace pilot plant located in the Dominican Republic, to which was later added an electric melting furnace. After almost 3 years of development work on this scale the plant was expanded to 100 tpd for fixing design data for a commercial plant. This took the form of the 30,000 ton per year Nickel Ferro-nickel Complex of Falconbridge Dominicans, which started up in 1971.

Jan 1, 1979

By Wilson I. L. Lim, Jonathan J. Campbell, Luis A. Tondo

An important issue in the use of high pressure grinding rolls when grinding ores is wear of the rolls. Due to the abrasive nature of the ores, significant wear rates have typically occurred. Attempts to address the wear problem require a better understanding of the wear mechanisms. A probable wear mechanism is the abrasion of the rolls surface due to extrusion of the compacted material as it leaves the rolls. This paper presents the results of a study on a number of ores to examine the extent of extrusion that occurs. The study involved laboratory, pilot and full-scale high pressure grinding rolls. The effect of variations in parameters such as grinding pressure, rolls speed, initial gap settings, feed topsize and moisture was investigated. The results indicate that extrusion increases with increasing grinding pressure and rolls diameter, while the use of studded or profiled rolls significantly reduces the extrusion effect compared to smooth rolls. It was also found that rolls speed and feed moisture can have significant effect on extrusion, depending on the material.

Jan 1, 1998

By J. F. T. Agapito, J. B. Page

This paper describes part of a geotechnical study based on stress determinations and convergence measurements conducted to assess the long-term stability of an experimental room-and-pillar oil shale mine. A rock mechanics program was initiated in 1971 at the Colony Mine as part of a large study conducted for the design of a commercial operation. The Colony Development Operation is a joint venture currently consisting of four active members; Ashland Oil Inc., Atlantic Richfield Company (Operator of the project), Shell Oil Company, and The Oil Shale Corporation. Although oil shale commercialization plans are presently suspended, rock mechanics instrumentation has been continued as part of Colony's policy in maintaining readiness to proceed with a commercial shale oil plant when national energy policies became better defined. The property is located in the southern edge of the Piceance Creek Basin in northwestern Colorado, approximately 200 miles west of Denver. Experimental mining operations were conducted from 1965 to 1972 with one of the major objectives of the pilot mine being the assessment of opening and pillar sizes for the determination of extraction ratio and life of the property. Mining was conducted in a 60 foot thick portion of the Mahogany Zone in the Parachute Creek Member of the Green River Formation, at depths of 600 to 850 feet by a one-bench system. Pillar dimensions were 58 feet by 58 feet and rooms were 55 feet wide.

Jan 1, 1977

By S. W. Kan, M. G. Kakarkis, J. Zelanco

Grouting has been used in underground mining for more than 20 years. Chemical grouting is often used as a remedial measure when the implemented ground-control program is unable to completely prevent structural failures or when there is a need for preventing a structural member from unraveling. The utilization of polyurethane grout is restricted by its limited range of physical and mechanical properties. To overcome some of the drawbacks of polyurethane, research is being conducted on a newly developed polyester based grout. The polyester resin, identified by Sandvik as Strata Grip, provides a number of features, including variable gel times and a much-reduced chemical hazard. Equally important are the mechanical properties of the product. The strength and deformability of any chemical grout must be compatible with the intended purpose of grouting and the expected deformation of the rock that is to be grouted The assessment of the mechanical properties of polyester grout is the focus of this work. Field experiences and laboratory research defined the properties of an effective grouting material. Experimental results indicate that the polyester grout meets or exceeds the recommended properties for many injection applications. Furthermore, the results suggest that the ability to adjust mechanical properties via resin formulation has the potential to expand the applicability of chemical grouting in ground control.

Jan 1, 1999

By Ronald C. Bethard, Kenneth W. Ely

The liberation of methane during underground coal mining causes serious safety concerns. During a mining cycle, with mechanized mining equipment, thousands of cubic feet of methane are released from coal seams, discharged to return air courses, and vented to the atmosphere through mine fans. This has been the traditional way of removing the explosive hazards of methane gas from the mine. Through horizontal and vertical degasification techniques, this hazard can often be handled in an equally safe and much more profitable manner. Basically, degasification allows for the controlled reduction of inseam methane content of coal prior to its mining. It is the responsibility of mine management to evaluate these degasification programs and ensure that the program itself does not introduce some new risk to the mining process. The removal of methane gas from underground coal mines using horizontal and vertical degasification is a relatively new concept. Products and systems used in degasification continue to evolve. Site conditions vary also, so no one system or equipment can be said to be the safe answer for degasification in all situations. A constant process of cooperation and evaluation by mining and degasification management should result in a safer and more profitable mine.

Jan 1, 1989

By Uday Kumar

This paper presents details of an availability study for a fleet of diesel engine operated load-haul-dump (LHD) machines used in a Swedish mine. For the purpose of this study, the LHD machines have been considered as a system comprised of many subsystems like engine, brake, transmission, etc., in series. As availability is dependent on both the reliability and maintainability characteristics of the system, together with reliability, the concepts of maintainability are also discussed. The need for exploring the data for the presence of any structure, which is very common in repairable system data sets, is emphasized with suitable examples. Simple graphical techniques are used for verifying the independent and identically distributed (IID) assumption for the data set. The error introduced due to the use of the exponential distribution in place of more appropriate distributions in estimation of availability and reliability characteristics is analysed.

Jan 1, 1989

By William H. Dresher

World trade has increased significantly during the last quarter century. However, a new rational for protectionism is emerging which argues for the restriction of trade as a means of preserving and protecting the environment. Fearing lower environmental standards in the Third World, environmentalists are calling for new trade barriers between the developed countries and the developing countries to combat what they see as "eco-dumping." The "greening" of protectionism and the merging of environmental standards into international trade agreements could fundamentally change the world trading system as well as seriously impact the availability of raw materials to provide for the needs of the peoples in both the developing and the developed worlds. This discussion will deal with the agreements and regulations that promise to influence the trans boundary shipment and recycling of scrap metals and wastes containing metals and their projected impact on world trade and metal prices. Emphasis will be placed on the Base1 Convention, whose restrictions concerning trans boundary shipment of scrap metal and metal-containing wastes for recycling took effect on December 31, 1997.

Jan 1, 1998

By G. Bhaskar Raju, S. Prabhakar

The amenability of column flotation for the beneficiation of fluorspar was investigated, and the overall performance of the column, flotation was compared to the performance of the existing conventional flotation cells at the plant. It was estab¬lished that improved grades and recoveries could be obtained by adopting column technology. Acidspar concentrates as¬saying 97% CaF2, suitable for HF manufacturing, can be produced by adopting two-stage column cleaning in place of multistage cleaning by conventional cells. Similarly, metspar concentrates assaying 90% CaF2, suitable for metallurgical applications, can be achieved in a single-stage cleaning by column flotation. This is an improvement over what is now being achieved using the existing conventional rougher and three-stage cleaning cells in the plant. The number of stages, i.e.,four in the acidspar circuit and four in the metspar circuit, including rougher stages, can be eliminated by adopting a three-column configuration. Thus, the cost of production, the complexity of the circuit and the power consumption can be effectively reduced with other attendant benefits.

Jan 1, 2000

By S. Chander

A comparison of gold, platinum and sulfide ion selective electrodes was made for determination of Eh in solutions containing hydrosulfide ions as a model system. The comparison was made in terms of the accuracy of the measured response, response time, pH dependence, and reproducibility of measurement. The sensitivity of each electrode towards changes in hydrosulfide ion concentration was measured in terms of the change in measured Eh per decade change in concentration. On the basis of a detailed investigation of the electrode processes occurring at the surface of gold and platinum electrodes, it was postulated that within the pH range investigated these electrodes respond to changes in the hydrosulfide ion concentration in solution. In comparison, the sulfide ion selective electrode is known to respond to changes in the sulfide ion activity in solution. Although the potentials measured with gold and platinum electrodes were mixed potentials, pretreatment procedures can be used to obtain a signal suitable for process control. For control of hydrosulfide ions in flotation pulps, the use of a gold electrode pretreated at 1.0 V with respect to a standard hydrogen electrode is recommended.

Jan 1, 1992

By M. R. Peterson, C. R. Ferguson, T. H. Jeffers

The ability of microorganisms such as yeast, bacteria, and various aquatic flora to sorb metals from dilute aqueous solutions is well documented. Although microorganisms have significant potential in decontaminating waste waters, techniques and equipment suitable for bioassisted decontamination are limited. The Bureau of Mines has investigated the use of microorganisms immobilized in porous polysulfone beads for extracting toxic and heavy metals from dilute waste streams. The minus 8- plus 12-mesh beads were fabricated from high-density poly- sulfone dissolved in dimethylformamide (DMF). Dried, thermally killed yeast, algae, duckweed, xanthan gum, and alginates were blended into the polysulfone-DMF, and spherical beads were formed by injecting the mixture into water. Microscopic analysis revealed microorganisms immobilized within the bead pores. The beads had excellent handling characteristics and were tested in stirred reactors, fixed bed columns, and fluidized bed columns for their ability to remove metal contaminants from several waste waters. The effluents resulting from these waste waters met or exceeded the National Drinking Water Standards for cadmium, copper, manganese, and zinc. Other heavy metal contaminants readily sorbed by the beads included arsenic and mercury. Elution of metal values from the beads was accomplished using dilute nitric acid or sodium carbonate.

Jan 1, 1989

By M. J. Shulman

The exploration geologist is frequently confronted with the problem of allocating his resources, i.e., exploration effort, among various areas. Although geologic, financial, and logistic considerations influence the allocations, no objective criterion is usually given that determines the optimal allocation. Maximizing the expected gain in information, subject to the constraint of a limited exploration budget, is used as the objective criterion to allocate airborne reconnaissance effort. The information function, I(x), quantifies the expected gain in information, where x is the scale of exploration. To calculate the information function, the following probabilities are required: the probability that an area contains a deposit; the probability that an anomaly is produced by the target; and the probability that an anomaly is produced by a barren area (false signal). Alternatively, the barren areas can be replaced by other targets. To illustrate the allocation method, the optimal number of line kilometers, i.e., the optimal line spacing per area, is determined for an aeromagnetic survey for iron in Egypt.

Jan 1, 1987

By F. D. Mendes, A. H. Martins

The high copper grade in the Igarapé Bahia (Brazil) gold-copper ore restricts the direct application of the classical cyanidation process. Copper oxide and sulfide minerals react with cyanides in solution, causing high leach-reagent consumption, raising processing costs and decreasing gold recovery. According to studies, a feasible solution would be to pretreat the ore to remove copper minerals prior to cyanidation. The goal of this experimental work was to study the conditions for the removal of copper from the Igarapé Bahia gold-copper ore by sulfuric acid leaching, applying a statistical approach to the experimental design. By using the Plackett Burman method, it was possible to select the variables that exhibited the largest influence on copper extraction at the sulfuric acid leaching stage. These variables were leach solution temperature, stirring speed, sulfuric acid concentration in the leach solution and ore particle size. The individual effect of these variables and their interaction influences on the experimental response were analyzed by applying the replicated full-factorial design method. Finally, the selected variables were optimized by the ascending-path statistical method, which determined the best leach experimental conditions for maximum copper extraction. The optimized leaching conditions resulted in a copper extraction of 75.5%. Keywords: Copper, Gold, Extraction, Sulfuric leaching, Optimization

Jan 1, 2003

By J. B. Zachwieja

Cationic reagents have been utilized in mineral processing since the mid 1930's and are based upon fatty nitrogen derivatives. The initial commercial development was centered around a flotation collector capable of separating potassium chloride from sodium chloride - potash flotation. The first commercial sale for Akzo, known then as Amour and Company, was realized in the summer of 1940 to a potash producer in Carlsbad, New Mexico for the flotation of potash. The success of the potash flotation collector led to the development of other cationic mineral processing reagents. Flotation collectors for iron ore, phosphate, calcium carbonate, silica sand, feldspar, and other silicates materialized into a large commercial business. Another area that realized commercial success was the development and use of anticaking/antidusting reagents for hygroscopic salts, fertilizer mixes, and granular fertilizers. A more recent development has found use in the trona industry as a defoamer and crystal growth modifier during the crystallization of sodium carbonate liquors. A review of cationic reagent chemistry and applications will be given and the potential for new application areas will be explored.

Jan 1, 1994