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By Mark S. Dunsbier, Steven J. Schatzel

Large roof outbursts began occurring in November 1986 at Domtar's Sifto Salt Mine in Goderich, Ontario, Canada, working the bedded Salina A-2 Salt unit. The outbursts, measuring about 13-20 m in diameter, released high concentrations of methane from cavities that extended into carbonate roof units. Spontaneous ignitions of methane gas during an outburst seriously burned a mine technician. The Canadian Ministry of Labour contacted the U.S. Bureau of Mines for technical assistance to aid in mine managements1 efforts in alleviating the problem. Initial gas content determinations of salt samples from the outbursts by acoustic test methodology revealed no methane enrichment. In- mine core drilling and subsequent methane content testing indicates the main source of methane in overlying roof units. Drilling the roof units demonstrated the potential of draining methane from areas showing signs of impending outbursting and alleviating the danger. Three mechanisms are considered the most likely means by which methane was introduced to the mine environment. These are (1) hydrocarbon gases released from brines, (2) gas transport along horizontal bedding planes or gas accumulations in bedding separations, and (3) mining-induced fracturing. The abundance of higher hydrocarbons in gas yielded by non-evaporite rock samples from the Goderich mine may be indicative of a former association with liquid petroleum.

Jan 1, 1989

By Severn P. Brown

Cement plants in the central Hudson River valley utilize limestones of the Helder-bergian Series of the Lower Devonian. Chiefly calcilutites, calcarenites, and cherty calcisiltites, these rocks represent progressively deeper environments, from lagoonal to neritic, with scattered reef deposits. Stratigraphic continuity is marked, and a layer-by- layer analysis shows strikingly constant chemical compositions. The structural picture varies from flat-lying and relatively unfaulted beds on the northwest, through gently folded and faulted beds on the north, to complex overturned beds with closely spaced imbricate faults on the south. Operating techniques are simpler in the north, where grade control is effected chiefly by the initial layout of the faces. In the south, grade control requires flexibility and frequent adjustment of faces or scheduling. A system of quarrying along strike has been developed, grade being computed from a cumulative foot-per cent graph of the critical oxides in each mappable layer. Balancing shovel production among the many faces is simplified by comparing production requirement ratios with ratios of the various types of rock in each face. Drilling and blasting limits are geologically controlled if warranted, or large blasts embracing several rock types are shot and the resulting pile of broken rock is staked along shovel limits.

Jan 1, 1966

By Janusz S. Laskowski

The most important type of potash ores, sylvinite, contains sylvite, halite and a small percentage of insoluble gangue [sulfates (anhydrite), carbonates (dolomite), and clay minerals]. Primary normal long-chain amines are exlusively utilized to float sylvite from halite, but since mines are also adsorbed by insoluble slimes, the process requires prior desliming. This is carried out either by mechanical means, or by flotation of slimes and blocking off the adsorption centers on clays with the use of polyelectrolytes. Fractional crystallization is employed to produce fertilizer grade KC1 from disseminated ores with a high content of slimes. An extender oil is needed in addition to mine to float coarse sylvite fractions. The process is carried out in a saturated brine at mine concentrations exceeding the solubility limit and is strongly affected by temperature fluctuations. All these important features, which make this process differ from a conventional flotation, result from a high electrolyte concentration.

Jan 1, 1994

By A. L. Muler

Since 1956, when Broadbent and Callcott 1 proposed to analyze breakage processes by matrix methods, several authors and their co-workers have proposed various models of grinding that, in principle, could lead to fully automated grinding circuits. In particular, Meloy and Gaudin2, Gardner and Austin3, Kelsall and Reid4, Neloy and Bergstrom5, Callcott and Lynch 6, and Draper and Lynch have, by either computer simulation or by experimental data, or by a combination of the two, verified that comminution is reasonably well described by at least two functions: a selection function and a breakage function. The stage concept proposed by Callcott and Lynch6 requires that a classification matrix be included to completely describe breakage in an open circuit rod mill. The purpose of this work, portions of which are herein described, is to accumulate sufficient information on the breakage characteristics of quartz and magnetite in an open circuit rod mill, so that several of the theoretical and experimental approaches proposed in the literature can be compared with each other. Data is being gathered to compare the experimental method used by Kelsall and paid against the stage approach of Callcott and Lynch.

Jan 1, 1968

By F. M. Doyle, P. E. Richardson, E. Peters

A number of studies have attempted to correlate the semiconducting properties of mineral sulfides with their chemical reactivity. Frequently such studies are conducted on polished or abraded electrodes. Defects produced by abrasion may mask the influence of the semiconducting properties of electrodes, e.g., by pinning the Fermi level at the surface or by reducing the lifetimes of photogenerated charge carriers. It is shown that pyrite and galena electrodes have photocurrents that are extremely sensitive to abrasion of the electrodes. On freshly fractured galena surfaces, the space charge layer is readily polarized. Wet-abrasion is shown to produce a relatively thick ptype layer on galena electrodes and this p-type layer has a pronounced effect on the photoresponse. On freshly fractured pyrite surfaces, the Fermi level at the surface is pinned by a surface state. Wet-polishing reduces the magnitude of the photocurrent by over an order of magnitude.

Jan 1, 1993

By K. G. Wallace

In 1982, the US Congress passed the Nuclear Waste Policy Act (NWPA) to provide for the development of an underground repository for spent nuclear fuel. This development will be managed by the US Department of Energy. In 1986, the President selected three areas for site characterization to determine their suitability for the development of an underground repository. Those sites were: (1) a site in volcanic tuff located at Yucca Mountain in Nevada, (2) a site in bedded salt located in Deaf Smith County in Texas, and (3) a site in basalt located in Hanford, WA. At present, conceptual repository designs are being developed for each site. A key element of a repository design is the underground ventilation system required to support construction, nuclear waste emplacement, and potential waste retrieval. This paper describes the preliminary ventilation system designed for the repository in tuff. The concept provides separate ventilation systems for the construction and waste emplacement activities. The paper further describes the means by which acceptable environmental conditions will be reestablished to allow reentry into previously closed rooms for the purpose of inspection, maintenance, or retrieval.

Jan 1, 1988

By Ian J. Duckworth, Pierre F. X. Mousset-Jones

A detailed heat flow project was conducted at the Homestake Mine in Lead, South Dakota. This paper presents results obtained from a stope sensor system installed in the mine. The design and installation of the system are described in detail in a previous paper (Duckworth et al., 1992). The major project objective was the construction of a comprehensive heat flow data base to allow the design and testing of a new climate prediction model applicable to irregularly shaped underground excavations in non-homogeneous surrounding rock types. A mechanized cut-and-fill (MCF) stope contributes a substantial overall heat source in a mine, and the effect of this source on the working environment must be considered when planning future ventilation and refrigeration requirements. The relative magnitudes of the component heat sources encountered with the MCF mining technique are presented, having been computed from actual stope beat flow data collected over a one-month study period. The percentage of the overall heat load that is removed from the scope for each component heat sink is evaluated, and the overall energy balance is analyzed. A one-month study length was considered a sufficient period of time to allow stope monitoring for a complete range of mining conditions.

Jan 1, 1993

By Louis L. Sirois, Kwang S. Moon

The flotation mechanisms of various flotation machines are briefly reviewed. The counter current column flotation mechanism is described in more detail. The merits of counter current column flotation include; improved metallurgical performance in terms of grade and recovery, effective cleaning action in the long cleaning zone with a blanket of fresh water, smaller floor space required due to the vertical configuration of a flotation column, low capital, operational, and maintenance costs due to the absence of moving parts and finally, easier flotation control due to the simplified circuit. The results of column flotation studies on various minerals and coal at CANMET are discussed. Some of the industrial experiences with the Canadian flotation column on various sulphides, oxides and coal are also presented.

Jan 1, 1988

By John Clarke Holman

Industrial growth and survival in today's competitive world means both economic efficiency and technological superiority. Superior technology includes not only exploiting the best methodologies and techniques presently available, but also a continuous search for and development of, better ones. In practical terms this translates into an investment of substantial sums of money. Of course, even a relatively small investment will not be justified if the fruits of the project cannot be secured to the investor and the inventor alike. There are at least three ways to protect new or improved technology. If the improvement reaches the height of an invention, "patenting" usually is the preferred mode of protection. If, however, the improvement is novel and valuable but does not satisfy the requirements of the patent laws, one may then consider "trade secret" agreements as a means of obtaining appropriate return for the investment made so long as the improvement is capable of being maintained in secret and cannot be "reverse engineered." If one develops a new and useful organism and seeks immediate protection from infringers, current thinking is that the copyright law may afford such protection simply by publishing the genetic code. Here is one instance where you may publish without perishing! This paper will endeavor to highlight the pros and cons of various legal mechanisms and their applicability to the frontiers of technology.

Jan 1, 1985

By S. C. Lamey, P. A. Hesbach

This study evaluated the use of regionally produced coal combustion products to neutralize and remove metals from acid mine drainage (AMD). Synthetic AMD mixtures were treated with a number of fly ashes and fluidized bed combustion (FBC) ashes. All of the ashes reduced the volume of the sludge produced and gave a faster settling rate than the sludge produced by treatment with lime. Faster settling allows greater throughput rates. In addition, the FBC ashes, which generally contain alkaline components used for sulfur capture, completely neutralized the acidity and, if desired, raised the pH above 10. The fly ashes, on the other hand, reduced the final volume of sludge but required additional neutralizing agents to attain a pH >5. The pH of the AMD can be taken to above 10 to insure complete removal of manganese, or it can be taken to a more neutral pH of 7 or 8 to allow for the safe introduction of the aqueous phase into ponds or streams. The process combines two industrial waste products to reduce the disposal volume of one of the waste products and to produce an environmentally safe aqueous discharge.

Jan 1, 2002

By D. R. Tweeton, L. W. Lake

A modified push-pull field test and a computer model of cation exchange were developed to aid in evaluating cation exchange parameters prior to in situ mining. Reliable determination of these parameters is essential when modeling restoration of ground-water quality. The field test involves a much larger volume and much less disturbance to the ore sample than is feasible with laboratory measurements. This test can be per¬formed in two or three weeks. It is relatively inexpensive, requiring one injection-production well and two or more wells for collecting samples of leach solution. The use of the model in interpreting test results is illustrated with field data from an in situ uranium mine. Much of the research was performed by the University of Texas at Austin and was partially funded by the US Bureau of Mines.

Jan 1, 1987

By Vi-Duong Dang

Lithium requirements in the next few decades for batteries and controlled thermonuclear fusion reactors (CTR) may exceed the availability of the current mineral and brine reserves. It is thus prudent to search for new reserves and resources to satisfy these and future lithium applications. The lithium content of the waters from the Smackover oil field. located in the Gulf Coast region of the United States, ranges from 100 to 500 mp/l and could represent a substantial new reserve. Experimental evidence described in the literature indicates that a specific chelating agent dipivaloylmethane (DPM), of the diketone type, has a specific selectivity toward lithium in the presence of other metal ions in aqueous solutions. Based in part on this unique property of dipivaloylmethane, a conceptual design of a full-size plant to extract lithium from the Smackover brine is presented in this paper. This study includes alternate flow-sheet development, design information on the major units of the process, energy requirements, and an economic analysis of a facility capable of producing 106 kg of lithium per year. The economics of three different process concepts depend primarily on the amount of water needing to be evaporated from the initial oil-field feed waters in concentrating the brine. The results, as a function of production rates, are indicated only in a general manner.

Jan 1, 1978

By Ken J. Fair, Vicken H. Aprahamian, Gus Van Weert

A consortium of Canadian mining companies, engineering firms and the Ontario Government has supported Hydrochem's efforts in the last year to design and cost a 10 tpd NITROX PROCESS® demonstration plant. A 5 kg per hour mini plant was installed at the Hydrochem facilities in Brampton, Ontario. This paper describes design testwork on Dickenson Mines arsenopyrite concentrate and application of the findings to the demonstration plant flowsheet. The control of nitrates in discard solids and stack gases is discussed in detail. Nitric acid oxidation of arsenopyrite results in significant ele- mental sulphur formation, enough for it to be detrimental to sub- sequent cyanidation. Flowsheet variations aimed at dealing with this process characteristic are discussed and testwork results on one option (hot liming) are described.

Jan 1, 1988

By Robert A. Haney

During the last ten years, longwall mining systems have undergone many changes. Panel widths and lengths have increased. Longwall faces have become more automated. Average production from individual longwall panels has increased from 1,000 to 3,600 tons per shift. To control the dust generation resulting from the higher production, longwall dust control systems have integrated various dust control techniques. Systems designed to control dust generated at the crusher/stageloader, shearer, and supports are common to most longwall faces. A survey was made of the dust controls that are currently in place on all the longwalls in the U.S. This survey addressed the types of controls used to reduce dust generated at the crusher/stageloader, shearer and roof support movement. Additionally, information on face ventilation rates, cutting cycle and level of automation was obtained. The purpose of this paper is to review the dust control practices that have been implemented throughout the United States and to identify those controls that are being used on high production longwall faces. Additionally, a model is used to demonstrate how ventilation and automation affect occupational exposure. Automation of roof support movement can offer some of the greatest reductions in occupational dust exposures. While technically feasible, its full benefit has not been fully realized by the industry. Until technology to fully automate longwall mining systems becomes more reliable, future dust control systems must rely on increased ventilation, application of headgate dust collectors, improved shearer dust controls and improved shield dust suppression systems.

Jan 1, 1995

By John A. Herbst, K. Rajamani

Process improvement is probably the most widespread objective of mineral process plant operators in the late 1980's. An important part of such improvements is dynamic optimization which involves reacting to inevitable plant disturbances in such a way that productivity is maximized at every instant of time. This paper describes the way in which mathematical models can be and have been used in dynamic optimization. Both off-line and on-line model applications are described.

Jan 1, 1989

By R. Hiebert, M. Canty, S. Beckman

An innovative biological process is described for the treatment of cyanide-, metals- and nitrate-contaminated mine process water. The technology was tested for its ability to detoxify cyanide and nitrate and to immobilize metals in wastewater from agitation cyanide leaching. A pilot-scale demonstration is described in which a pilot plant was constructed to demonstrate the technology on a mine process-waste stream at a mine in Nevada. The demonstration was performed jointly under the Mine Waste Technology Program (MWTP), funded by the US Environmental Protection Agency (EPA) and jointly administered by the US De¬partment of Energy's (DOE) Western Environmental Technology Office (WETO) under Interagency Agree¬ment Number DW89938513-01-0. The Superfund Innovative Technology Evaluation (SITE) demonstration program was also involved in the project. MSE Technology Applications Inc. (MSE), Butte, MT, was the contractor responsible for conducting the project, and Pintail Systems Inc., Aurora, CO, was the technology provider. The pilot-scale unit was field-tested at Echo Bay's McCoy/Cove Mine southwest of Battle Mountain, NV. The biotreatment process was considered successful in destroying cyanide in the mine process water. The process was also determined to be effective in removing metals. The pH was consistently neutralized and nitrates were successfully removed from the mine process water. From the results of these pilot-scale tests, it was concluded that the biotreatment process potentially of¬fers an innovative, cost-effective alternative for the treatment of mining wastewaters.

Jan 1, 2000

By Ning Liu, Xuming Wang, Yongqiang Lu, Jan D. Miller

Bench-scale flotation experiments have been conducted to study the effect of nonionic polyethylene oxide (PEO) polymer surfactants on the flotation of Florida phosphate rock. It has been found that PEOs having a molecular weight from 1,200 to 8,000 are effective. Flotation results demonstrate that the addition of nonionic PEO has a favorable effect on phosphate flotation, especially on the flotation of coarse phosphate feed. At about the same collector level, phosphate recovery can be improved by 10-30% with PEO addition. The surface chemistry of phosphate flotation using the fatty acid/fuel oil/PEO system has also been studied to better understand the phenomena involved. The increase in phosphate recovery with PEO addition has been attributed to improved dispersion of fatty acid, which leads to better froth stability and a more hydrophobic surface state.

Jan 1, 1999

By L. L. Newman, K. D. Ferguson

Traditional methods for mine waste management produces two waste streams and the construction of separate disposal facilities. Tailings impoundment design is usually controlled by physical stability problems. Alternatively. the waste rock offers high stability characteristics but hydraulic properties that create ideal conditions for oxidation. The problem of oxidation is significantly reduced for tailings due to a fine texture that augments water saturation. This paper introduces concepts for the co-disposal of tailings with waste rock and evaluates the physical behaviour of an integrated waste system. 'he potential benefits of co-disposal are shown for a typical mine such as Equity Silver.

Jan 1, 2000

By Jeffrey J. Schwoebel, Jianliang Li, Daniel J. Brunner

A United Nations (UN) administered degasification technology transfer project, funded by the Global Environmental Fund (GEF) is underway at the Shihao Mine of the Songzao Coal Mining Ad- ministration in the province of Sichuan, Peoples Republic of China. This mine exploits multiple seams at depths ranging from 300 to 600 m below surface. In-seam boreholes and frequently spaced in-mine vertical boreholes, developed from underlying galleries constructed specifically for this purpose, currently degasify the seams in advance of mining at the Shihao Mine. Because of ventilation system constraints and the in-situ gas con- tent, longwall mining of the coals at this mine could not proceed without some form of pre-mining degasification. This paper presents a simulation based degasification plan of long, in-seam horizontal boreholes for the Shihao Mine. Simulations with a coalbed reservoir program assessed time dependent degasification characteristics of both vertical and in-seam horizontal boreholes. The simulations used input data from reservoir and desorption tests conducted at the mine site. The results produced system design nomograms to assist mine engineers in defining the appropriate borehole spacing necessary to degasify the seam in the time available for pre-mining drainage. The predicted effectiveness of the current vertical degasification scheme was compared with that for a horizontal borehole program and served as the basis for the recommended in-seam borehole configuration for the project at the Shihao Mine. The horizontal borehole degasification program requires substantially less gallery and borehole development than the present vertical degasification scheme.

Jan 1, 1997

By J. Brent Hiskey

INTRODUCTION Metal electrodeposition processes are of fundamental technological importance to a number of fields. Electrorefining, electrowinning, electroplating, and electrogalvanizing have all been the subject of intense study for over a century. More recently, electrochem- ical deposition has played a critical role in advances in microelectronics and lately has been an enabling technology for the production of certain nanostructured materials. Electrometallurgists have most frequently been concerned with the structure and morphology of massive deposits. For example, in metal recovery steps such as electrorefining and electrowinning, deposits demonstrating adherent coarse-grained characteristics are most desirable. In the case of electroplating, a bright fine-grained, tenacious and strongly adherent deposit is required. The fabrication of microelectronic devices and the production of nanoscale structures such as nanoparticles, nanowires, and nanorods requires a keen understanding of early stage deposition effects. The initial stages of metal deposition, usually referred to as electroclystallization, are fundamentally linked to nucleation and growth phenomena. Early stage deposits are typically very ordered. Whereas, bulk metal deposition structures are much more ran- dom. In both cases, the discharge of a metal ion at an electrified interface is represented by simple cathodic reduction as follows: [ ] Me(H2O)xn[ ] is a hydrated metal ion residing in the bulk solution and Me is the metal atom occupying a crystallographic lattice position. A similar reduction reaction can be

Jan 1, 2005