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By Parker A. J, Muir D. M

Solutions of acetonitrile in water dissolve water soluble copper(I) chloride. Removal of volatile acetonitrile from the resulting solutions, by distillation with low grade steam, precipitates pure copper(I) chloride. This is used to purify a crude copper chloride sublimate from the chlorination of nickel matte but is applicable to other sources of copper(I) chloride. The pure product can be converted to pure copper(I) oxide, copper(II) oxychloride or pure copper metal directly.

Jan 1, 1980

The copper and zinc contents of herbarium specimens of 11 of the 12 Australian species of Polycarpaea were determined in order to establish background and anomalous values of potential use in biogeochemical prospecting.Cumulative frequency curves were used to establish appropriate threshold concentrations for six species including the "copper plant"' P spirostylis. Collection localities of Polycarpaea specimens with anomalous copper or copper-and-zinc values are under investigation.

Jan 1, 1978

By Belmira Benedita de Lima

Estudos no sistema Nb-B mostram a fase Nb5B6 com formação peritética a partir do líquido, porém sua estabilidade abaixo de 2.000°C não é comprovada experimentalmente. Há também dúvidas sobre a ocorrência da fase Nb2B3 neste binário. Este trabalho tem como objetivo o estudo da estabilidade das fases Nb5B6 e Nb2B3 nas temperaturas de 1.400°C e 1.800°C. Amostras com composições nas estequiometrias Nb5B6 e Nb2B3 foram produzidas através de fusão a arco assim como confeccionadas a partir de misturas de pós de B e NbB. Pastilhas com composição Nb5B6 foram produzidas com e sem adição de semente da fase Nb5B6. Os tratamentos térmicos em 1.400°C foram realizados por até 10h enquanto aqueles em 1800°C por até 1h, todos em atmosfera estática de argônio. As microestruturas das amostras, tanto no estado bruto de fusão como após tratamento térmico, foram caracterizadas por difração de raios X (XRD). Os resultados confirmam a formação fase Nb5B6 a partir do líquido e nas amostras produzidas via metalurgia do pó. A fase Nb2B3 não é observada nas amostras no estado bruto de fusão e nas amostras produzidas via metalurgia do pó tratadas termicamente a 1.800°C, porém, esta fase se estabiliza nas amostras produzidas via metalurgia do pó tratadas a 1.400°C, indicando sua estabilidade com formação peritetóide a partir das fases Nb3B4 e NbB2, abaixo de 1.800°C.

Aug 8, 2018

By F. Stober, D. Wanblad, J. Ndlovu, L. R. Nelson, L. P. S. de Villiers

The single six-in-line furnace of the Polokwane Smelter is the largest installed high-intensity furnace for platinum group metals (PGM) base metals sulphide smelting in the world. The furnace employs state-of-the art technology to deliver a planned throughput of 650 000 t/a dry concentrate at a design 68 MW power input. This furnace, at double the capacity of previously existing PGM furnaces, offers low unit operating and capital cost through the resulting economies of scale. Key features of the design include:

Jan 1, 2005

By Andrew L. Peterson

CATOH Inc. of Weedsport, New York recently completed a very challenging Bored-In Pile project which features unique construction techniques in the installation and load testing of 45 and 100 ton capacity piles. The bored-in piles were installed on a twenty-nine million dollar New York State Department of Transportation project which began in the fall of 1995 and ended in March of 1997. The project included the construction of 5 new bridges to alleviate a very congested traffic network which had come to be known as the "Octopus" in the small city of Ithaca, New York. CATOH Inc. was awarded the piling contract by general contractor Santaro Industries in the fall of 1995. Piling installation work was completed in March of 1997. BACKGROUND The project is located at the southern tip of Cayuga Lake which lies in the heart of Upstate New York's Finger Lakes Region. This region is popular not only for wine making and vacationing, but also for its impressive geological history. The glacial activities that helped to form the deep valleys of this scenic area are also responsible for creating challenging underground conditions for deep foundations work. CATOH developed two pile designs to accommodate differing site conditions on the project. Internally reinforced piles were developed for use in the center of the valley and externally reinforced piles were developed for locations close to the valley wall.

Jan 1, 1997

By G. E. Agar, W. B. Kipkie, R. A. Tenbergen

"This paper describes the successful pilot plant testing of a flowsheet, developed at INCO Ltd.'s J.Roy Gordon Research Laboratory (JRGRL), for improved separation of the constituent minerals in a bulk copper nickel concentrate.The flowsheet utilized the fact that xanthate concentration on the mineral surfaces is the most important variable affecting the high lime separation and that reduction of the xanthate concentration could be effected by an oxidative conditioning stage.When the adsorbed xanthate was reduced to a suitably low level, chalcopyrite and pyrrhotite could be floated to leave a high grade nickel concentrate as the residue. Sodium cyanide was added to the froth product to depress pyrrhotite and any remaining pentlandite. The temporary depression of chalcopyrite by the sodium cyanide was overcome by introducing a conditioning step following cyanide addition. The advantages of the flowsheet; improved copper-nickel separation, operation without heating of the pulp, production of both high grade nickel concentrate ( 29. 5% Ni, . 26% Cu) and copper concentrate ( <O. 5% Ni, 30% Cu) were all realized."

Jan 1, 1984

By Tariq B. Hamid

Deep excavation is commonly associated with construction of different deep below-grade structural elements (e.g., basement walls and slabs, tunnels, retaining walls, tanks, utilities, etc.) Deep Excavation Retaining Systems (DERS) are required when open cuts with safe slopes are not possible. Careful analysis, design, and planning of the DERS are required to provide safe below-grade construction and secure nearby structures from damaging effects that may result from the deep excavation. Selection and design of temporary or permanent DERS (e.g., soldier pile and lagging, sheet piling walls, secant pile walls, tie backs, etc.) can have significant impact on time, cost, and performance. In order to design DERS using conventional methods, it is necessary to obtain shear strength parameters, angle of internal friction (ø), and cohesion (c), of retained soils. Residual shear strength parameters (ø&apos;res, c&apos;res) obtained from drained direct shear tests and triaxial tests on saturated samples have been commonly used in practice for the analysis and design of DERS. However, there are cases where ground water table remains at or below the base of excavation during the design lifetime of DERS. In such cases, the soil above the ground water table is in an unsaturated state. Therefore, it is important to account for the unsaturated conditions of soils in order to optimize the design of DERS. This paper is focused on implementing the basic concepts of unsaturated soils mechanics including matric suction and soils-water characteristic curve (SWCC) to estimate design shear strength parameters of unsaturated soils (i.e., ø°, c&apos;, and ø&apos;) for the design of a cantilever sheet pile walls, a typical case of study of the DERS. The results of this study indicate that the determination of unsaturated soil strength shear strength parameters is simple. In addition, using unsaturated soil mechanics theories has an outstanding impact on the design of retaining systems.

Jan 1, 2006

DESCRIPTION OF OREThe ore consists, in general, of a very finely grained mixture of sphalerite, galena, and pyrite, with a gangue of quartz and schistose material, and contains about one ounce of silver to the unit of lead.Minor minerals are chalcopyrite, tetrahedrite, and ruby silver. The amount of gangue within the ore-bodies themselves is usually less than 20% of the weight of the whole. The ore is banded in a way that corresponds to the structure of the original schists, and is by no means uniform in composition-at one point, for example, blende may predominate, and a few feet farther on the body may become highly pyritic.Owing to the intimate association of the mineral constituents of the ore, it is very difficult to separate them from one another.Although this remark applies to ore from all parts of the field, the difficulty is particularly noticeable with Rosebery ore, the minerals of which are more intimately mixed, and are of smaller grain size than are the minerals of the Hercules ore.To effect a reasonably clean separation, it is necessary to grind the ore so that 90% passes a 200-mesh I.M.M. screen. Microscopic examination of the crushed product shows that 85% of the minus 200-mesh material is less than 30 microns in diameter, or, in terms of screen sizing, is minus 400 mesh. Particles under 30 microns are found to consist, of one mineral only, but in particles over this size separation has not always been effected. For instance, it is known that part of the galena and of the pyrite in the zinc concentrate is associated with sphalerite, and that part of the galena in the mill residue is associated with pyrite. There is only slight association between the minerals in the lead concentrate.

Jan 1, 1927

Techniques have been developed for the dissolution of a wide range of rocks and minerals by a sodium peroxide sinter process. A olarge number of elements are determined by atomic absorption spectroscopy, and other elements such as arsenic and sulphur are determined by chemical analytical methods. The methods adopted to overcome inter-element and ionization effects on the atomic absorption results are discussed.

Jan 1, 1974

By R. K. Rath

Adsorption, electrokinetic and flotation studies were carried out. The maximum density of adsorption of guar gum was obtained at pH 7.5 on sphalerite and at pH 11.5 on galena. Flotation recovery of sphalerite was reduced only marginally by the presence of guar gum in the pH range investigated, whereas recovery of galena was reduced to about 20% at pH 12. Differential flotation tests on binary mixtures indicated that 10 ppm of guar gum can depress galena and separate it from sphalerite at around pH 12.1. Co-precipitation tests confirmed the formation of a metal ion-guar gum complex in the bulk solution, suggesting that this is the precursor to adsorption. The adsorption isotherms for both minerals followed Langmuirian behaviour, but adsorption of guar gum on galena was significantly higher than on sphalerite and dissolution tests indicated that the concentration of Pb ions released from galena was an order of magnitude greater than that of Zn ions dissolved from sphalerite

Jun 21, 1905

By H. William Zeller

The U.S. Bureau of Mines evaluated the effects of two iron-based fuel additives on diesel particulate matter (DPM) emissions. The 5.6-L, six-cylinder test engine is typical of engines used in underground mines. One additive, ferrous picrate, did not measurably affect exhaust emissions. This report is mainly about a ferrocene-based additive that reduced DPM between 4 and 45 pet., depending on engine operating conditions. The report concludes that the DPM reductions were caused by the catalytic oxidation properties of a ferric oxide coating that developed inside the engine&apos;s combustion chamber. The ferric oxide coating also decreased gas-phase hydrocarbons and O2, but it increased CO2 and NOx, The increase in NOx, of about 12 pet, is considered the only adverse effect of the ferrocene-based fuel additive. The results suggest that the effectiveness of ferrocene was partially offset by increased sulfates because of the high-sulfur fuel used. Recommendations for continuing fuel additive research are presented.

Jan 1, 2010

By H. Ipek

Industrial grinding machines used in the mineral processing industries are mostly of the tumbling mill type. These mills exist in various types: ball, rod, pebble, autogenous, and semi-autogenous. Balls and rods are traditionally media shapes used in the tumbling mills. In resent years, as an alternative to balls, grinding charges with various shapes are being used. Cylpebs are slightly tapered cylindrical grinding charges with length equaling diameter, and all the edges being radiused. Cylpebs of equal diameter and length have 50% greater surface area and 45% greater weight than balls of the same material. In addition, they have 9% higher bulk density than steel balls, or 12% higher bulk density than cast balls. An important advantage of cylpebs over balls is that cylpebs produce narrower granulometric distribution due to their shapes. However, some discrepancies were found in the literature regarding the milling performance of cylpebs in comparison with balls (Chi, 2004). In recent studies, Chi (2004) has provided detailed information on cylpebs and has compared these to balls in relation to media mass, size distribution, surface area, and input specific energy. Ipek (2006) has investigated the effects of cylpebs and balls with equal mass and surface area on the breakage rate of quartz, using cylpebs and balls separately. Similarly, Lameck and Moys (2006) have investigated the effects of balls and worn balls on breakage rate of material using worn balls as grinding environment. However, no study has attempted to investigate the effects of grinding environment other than balls on the brekage distribution. As indicated by Prasher (1987), the breakage distribution function is independent of the following variables in ball mills: hold-up (Mika et al., 1967; Kelsall et al. 1969), mill speed and ball load (Herbst and Fuerstenau, 1972), media load and ball density (Kelsall et al., 1973), mill diameter (Malghan and Fuerstenau, 1976), and powder charge (Shoji et al. 1980). The aim of the present paper is to compare the effects of cylpebs and balls on the breakage distribution function of quartz with respect to same mass and same surface area. BACKGROUND Comminution as a rate process is called kinetic approach. Studies on the kinetic approach are reviewed by Oner (2001). Oner states that grinding kinetics are based on studies by Kolmogorov in 1941 and that Robert (1950) is the first to suggest this approach. Later, Melzak, Loeveday, and Reid have improved the grinding kinetics equation; and, Austin and Lynch have conducted two basic studies on the analytical solutions of these equations. Considering the results of studies comparing the size reduction mechanisms, it has been accepted that breakage constitutes of two operations. These two basic operations, first defined by Epstein (1948), are those of selection of material for breakage and the distribution of breakage material to particle sizes smaller than the initial size (Lynch, 1977). Epstein defined the two operations as: ? Pn(y), the probability of breakage of a particle size in the nth step of the breakage process. ? F(x,y), the cumulative distributions by weight of particles of size x<y arising from the breakage of a unit mass of a size y. Probability of breakage is called a selection or a breakage-rate function (Si). Characteristics size distribution after breakage is called a breakage distribution or appearance function (Bi,j). Due to the difficulties in representing particle size distributions mathematically and constantly, the batch equation based on particle size fraction is suggested. Thus, as is the case in breakage distribution and specific rate of breakage, the breakage parameters were defined by batch grinding experiments conducted in laboratories (Oner, 2001). When effective breakage occurs in the mill, the breakage of material with single feed size fraction usually fits first order grinding kinetics and the specific rate of breakage values can be calculated through the slope of semi-log plot. The values of the breakage distributions are deduced from the size distributions at short grinding times where there is mainly size 1 material breaking and only small amount of smaller sizes to rebreak (Austin et. al., 1984). B values can be calculated by using BII. [ ] where j is the top size of the charge, Pi(t) is the cumulative percent undersize of i th size interval at the short grinding time which gives no more than about 30% broken out of the top size interval. Cumulative primary breakage distribution, Bi,j, is also defined in an empirical form by [ ] where xi is the top size and Bi,j is the weight fraction of primary breakage products. The parameters F, ? and ß define the size distribution of the material being ground. On plotting size versus Bi,j on log scale, the slope of the lower portion of the curve gives the value of ?, the slope of the upper portion of the curve gives the value of ß, and F is the intercept as in Fig.1. [ ]

Jan 1, 2009

By A. W. Schlechten, R. P. Abendroth

Jan 1, 1960

By J. R. P. Aguirre

Minerales Monclova, S.A. de C.V. (MIMOSA) is owned by Grupo Acerero Del Norte (GAN). This company has 4 underground coal mines and 1 open pit to feed it?s steelmaking facilities located in the city of Monclova in the North of México in the state of Coahuila. The current underground mines are Mine 3, 5, 6 and 7 and the future projects are Mines 8 and 9. In the last years Mines 2 and 4 have been closed because they finished their coal resources. The remaining mines have bigger production and developments requirements in order to accomplish the goals of the company. The mines have been working in deeper and gassier areas. These conditions have required improvements in the ventilation design and methane control systems for all the mines. In some cases the ventilation of some of the MIMOSA?S mines has been increased 80%, and besides this, an intensive methane drainage program has been applied using horizontal in-seam boreholes and gob wells. The short-term ventilation plan includes the construction of 3 new vertical shafts with 5 and 6 meters diameter for Mines 5, 6 and 7 and the purchasing of bigger new main and backup fans for each one of these mines. One of these vertical shafts and the purchasing of the first 2 fans is already in process. This paper will explain the evolution and results of the ventilation and methane drainage systems in MIMOSA and the ventilation planning for the future years.

Jan 1, 2009

By Willard C. Lacy

INTRODUCTION A program to insure adequate talent for development and management of our mineral resources entails two equally important and interrelated aspects: 1) attracting and retaining promising student talent, and 2) providing a first-rate education for those entering careers in mineral science and engineering. Manpower shortages have eased in many areas of engineering, particularly in those areas dependent directly or indirectly upon government contracts in space and war programs. However, in the minerals industry the needs still remain critical. As increasing concern over preservation of the environment has developed, the political and social reaction was to seek out major offenders, to look for "whipping boys" -- and the mineral industry was, and had been, an offender. It was there for everyone to take pictures, it couldn&apos;t be covered up, and the Department of the Interior lashed away in the beautiful and popular brochures: Quest for Quality, The Third Wave, The Population Challenge, and Surface Mining and Our Environment (Ravaged Land). The Sierra Club, the Field and Stream magazine, TV, and daily news media added their lashes. In the minds of our social-conscious youth the mineral industry took on the image of "exploiters" of natural resources; "polluters" of streams, lakes, and the atmosphere; "despoilers" of wilderness areas and scenic beauty -- a plague to combat, rather than an exciting challenge that entailed exploration of the remote, conquering of the primitive, and developing of the undeveloped. Enrollments declined and many traditional mineral engineering curricula were abolished or Integrated into other stronger engineering departments to meet student-faculty ratio requirements.

Jan 1, 1971

By A. Lyndon

Combined loading tests are described to three 1.2m diameter cast-in-place bored piles, 12m long, formed through cohesionless material into stiff sandy clay. The maximum loading conditions imposed at the pile head were 2400 kN vertical, 160 kN lateral and 3120 kNm in bending, corresponding to twice the working load. Settlements, deflections and rotations of the piles were measured during the tests. An interesting finding which the test results suggest is that, in the short term, vertical movement had apparently no marked effect on lateral performance for piles working at design loadings.

Jan 1, 1989

By Michael Kelly

Inertial navigation technology has, for the first time, allowed the position of a longwall shearer to be mapped in three dimensions. Following the success of the technology in highwall mining and successful trials on a longwall face, the Australian Coal Association Research Program (ACARP) commissioned a three year "Landmark" project that aimed to advance longwall automation to the level of "on-face observation" by the end of 2004. This project has been completed with the following successful technical outcomes: Automatic face alignment was achieved, using an inertial navigation-based sensor on the shearer, to accurately measure face geometry and feedback signals used to move OEM (Original Equipment Manufacturer) roof supports. Operational on-line measurement of creep with creep information incorporated into face alignment corrections. Inertial Navigation System (INS)-based enhanced horizon control was bench-tested. Operational broadband communications system to shearer using wireless Ethernet on a commercial-product basis. Acquisition of located coal-face features for use in thermal infrared-based horizon control. Automated Longwall Information System (LIS) developed which integrates information from multiple systems and sensors and provides high quality visualisation and control interfaces. Automatic roadway and face convergence monitoring tools successfully tested. Condition monitoring tools developed and demonstrated for improved face reliability. This paper summarises the outcomes of the project and describes the work being undertaken for the 2 year Landmark Extension project approved in April 2005. Consistent with the conference theme, the paper focuses on the ground control aspects of the project.

Jan 1, 2005

By G. A. Bala

As part of ongoing research to define mechanisms of microbial enhanced oil recovery (MEOR), this work describes the activity of Bacillus l1chen1formis JF-2 (ATCC 39307) Mosurfactant against crude oils with varying compositions. Surfactant based MEOR improves oil recovery by lowering the oil/brine interfactal tension (IFT) therefore permitting oil to be displaced or solub1lized into the aqueous phase.? MEOR is an Enhanced Oil Recovery (EOR) process which allows for the introduction of chemical and miscible fluids, in the form of microbial metabolic end-products, through the injection of microorganisms into the reservoir or stimulation of indigenous reservoir microbial populations. These microorganisms represent a replenishable in situ source of acid, gas, biopolymer, solvent, or surfactant products which can be. supported and manipulated by the addition of simple and inexpensive nutrients to enhance the recovery of oil. Microbially mediated surfactant production represents one mechanism of MEOR. Bacillus licheniformis JF-2. has been used in a mode 1 MEOR system based on Berea sandstone cores (permeabilly .85 to 400 md) to examine surfactant based MEOR of medium to heavy crude oils (API gravity 38.1° to 17.5°). Enhanced oil recovery was achieved with all oils tested using either cell free culture supernatants or microbial suspensions as injectants with no detrimental effect to the oil. Spatial distribution of cells following mf?crobtal flooding was analyzed with scanning electron microscopy. Data indkate complete distribution of cells with a predominance of organisms located distal to the point of injection. There appears to be no sign:if1cant recovery trend with respect to oil composition.. The biosurfactant produced by Bacillus lichen1form1s JF-2 lowers the interfacial tension of all oils tested equally well.

Jan 1, 1991

By Sherwin F. Kelly

One of the most succinct and illuminating perspectives of the field of geophysical exploration to appear in recent years is an article by E. A. Eckhardt, in the magazine Geophysics for October 1949. Although his review covers the year 1948, many of the data presented are apropos to a review of 1949, and form a pertinent background for a consideration of current progress. He presents charts of the world-wide distribution of gravimeter and seismograph activity in oil exploration, which show that surveys in the United States accounted for practically 68%; of all gravity work and 80%; of all seismic activity. Canada ranked second, with a proportion of roughly 6%, in each case; South America accounted for about the same percentage of seismic work, and double that amount for gravity surveys. Within the United States, Texas and Louisiana were the scenes of the greatest activity, both claiming about 60% of all surveys by each method.

Jan 1, 1950

Size Separation Pretreatment and Alumina Recovery from Bayer Red Mud

Sep 13, 2010