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By T. E. Tietz, J. E. Dorn

Activation energies for creep of copper at intermediate temperatures, where crystal recovery was negligible, were determined by the simple technique of rapidly alternating the test temperature between and T2 (T2 = TI + about 10°K) throughout a constant stress creep test. The activation energy for creep H was found to be 37,000± 3,000 cal per mol, independent of stress and strain. The same creep laws as have been previously established for high temperature creep were found to be valid for creep at intermediate temperatures. But the AH was found to be lower than that for self-diffusion in the intermediate temperature range whereas it is known to be equal to that for self-diffusion at high temperatures. IT is now well established that creep at high temperatures can be correlated by the functional relationship'-" e = f(?) s = constant [I] where E is the total plastic strain, f is the function that depends on the stress, ? = f e -- dt, t is the duration of test, e is the base of natural logarithms, AH is the activation energy for creep, R is the gas constant,T is the absolute temperature, and s is the stress. Thus, identical values of are achieved during creep under a given stress at two alternate temperatures at the same total strain. At the same strain therefore where subscripts refer to the two alternate temperature conditions of test. Consequently, the activation energy for high temperature creep is readily obtained with the aid of Eq. 2. Activation energies so obtained have been observed to be insensitive to the creep strain at which they are evaluated, the applied stress, grain size, minor alloying additions,'-' cold worked state, and the presence of thermally stable dispersions of intermetallic compounds in an a solid solution matrix Furthermore, the activation energy for high temperature creep is very nearly equal to that for self-diffusion in all cases where adequate data are available for comparison." " The apparent identity of the activation energies for high temperature creep and self-diffusion strongly suggest that high temperature creep arises from a dislocation climb process. This hypothesis is further strengthened by the fact that the energy of activation for high temperature creep is insensitive to the applied stress," and by the observations that the correlation suggested by Eq. 1 cannot be ex- tended to temperatures below those for rapid crystal recovery. When using the activation energy for self-diffusion, Eq. 1 fails to give the required correlations between creep curves at various intermediate temperatures.' This suggests that the dislocation climb mechanism for creep might be superseded by some alternate mechanism in the intermediate range of temperatures. This investigation was initiated in a preliminary attempt to ascertain the type of creep law that might be valid in the intermediate range of temperatures. Special consideration, however, was given to the determination of the activation energy for creep in this range because the Becker-Orowan', " and the Mott-Nabarro10 theories for transient creep suggest that the activation energy should increase

Jan 1, 1957

E. O?C. Acker Truman H. Aldrich John H. Allen W. Lawrence Austin W. S. Ayres David Baker Andrew A Blair Walter M. Brodie H.H. Burden Charles Butters

Jan 1, 1936

By William Kent

DURING the discussions at the Philadelphia meeting in February last, † several speakers expressed their doubts of the general accuracy of chemical analyses of steel made by "iron works chemists," and especially of determinations of manganese. Since the meeting,. the discussion of the "practical value of chemical analyses" has been continued at some length in the columns of the Iron Age. †Transactions, vol. ix, p. 529.

Jan 1, 1882

By John R. Weeks, Dan McLachlan, John R. Lewis

DURING the operation of the iron blast furnace, aggregates of hard, infusible, yellow, cubic crystals frequently form in the interstices of the lining and on the hearth of the furnace. These were first examined by Wohler&apos; and were identified by him as a complex cyanonitride of titanium, having a formula Ti(CN)2 • 3Ti3N2, or more simply Ti10C2N8. However, recent investigators have suggested that this complex compound does not exist. Recent work by Hume-Rothery, Raynor, and Little2 on the carbide and nitride particles in titanium steels suggests that a complete series of solid solutions of the general type Ti<0+y>C0Ny exists between titanium carbide (Tic) and titanium nitride (TiN). Assuming this to be true, it seems likely that Wohler&apos;s cyanonitride of titanium is in reality a solid solution of 20 mol pct Tic in 80 mol pct TiN, .the nearly consistent carbide-to-nitride ratio probably resulting from temperature and pressure conditions in the blast furnace. The object of the present work was to investigate thoroughly this possibility of a solid solution by using the single-crystal methods of X-ray analysis. A spectrographic qualitative analysis of a sample of the yellow crystals furnished by the Geneva Steel Co. sh&apos;owed, in addition to the titanium, strong lines of vanadium and moderate to weak lines of iron, magnesium, silicon, aluminum, and calcium. The last five were probably slag impurities, but the vanadium was possibly included in the yellow crystals, owing to a great structural similarity of its carbide (VC) and its nitride (VN) to the titanium compounds, Table 11. A chemical analysis was made

Jan 1, 1952

By Courtenay DeKalb

Revision of the United States mining law is needed chiefly because of the following reasons: 1. The conceptions as to the characteristics of orebodies that were held at the time the statute of 1872 was enacted have since proved to be in many respects erroneous. 2. The operation of the existing law has been found to work unnecessary hardship upon many claimants to mineral land. 3. The existing statute fails in large degree to encourage development of mineral resources. 4. The existing law often produces conflict between placer and lode-claim rights, working unnecessary injustice to placer claimants. 5. The methods of establishing the rights of locators on United States mineral land are defective, and are not uniform throughout the States within which such lands exist. Law of the Apex The objections to the so-called "law of the apex" are so well known as to require no detailed statement. It is sufficient to point out that the apex rule was based upon the notion that ore deposits consisted of well-formed veins included between definite walls, like the slice of ham in a sandwich. The fact is that veins conforming to that simple type are rare. Irregularity is the rule, and the chief metal production of the United States comes from mass? which bear no resemblance to the tabular form of vein. Manifestly the law of the apex fails completely in such cases. Moreover, the tendency is constantly toward the exploitation of ores of lower grade than could formerly be worked, and such deposits exist mainly in the form of large irregular impregnated zones and masses, so that the future development of our mineral resources would be continuously embarrassed by shadowy claims to extra-lateral rights by the locators of so-called apexes.

Jan 1, 1915

By Tell Ertl

THE term oil shale is defined. Foreign oil-shale developments are outlined briefly, The richest and most extensive oil-shale deposits in the United States lie in Western Colorado. The Bureau of Mines is opening two adjacent areas for underground mining in Western Colorado. From the first area the oil shale is mined selectively as required by the retorting plant. The second area is being developed as a unit of a full scale oil-shale mine to ascertain the most practical methods of mining oil shale and to determine costs. In both of these mining areas, research will be carried on to develop new and improved practices for mining oil shale.

Jan 1, 1947

Jan 1, 1881

The Second Pan-American Scientific Congress will be held under the auspices of the United States Government in Washington, D. C., Dec. 27, 1915, to Jan. 8, 1916. The organization officers are John Barrett, LL. D., Director General of the Pan-American Union, Secretary General; Glen Levin Swiggett, Ph. D., Assistant Secretary General; the headquarters of the Congress are the Pan-American Union, Washington, D. C. The program of the Congress is divided into nine main Sections, which are given below with the name of the Chairman of each Section: 1. Anthropology, William H. Holmes, B. S., Smithsonian Institution, Washington. 2. Astronomy, Meteorology, and Seismology, Robert S. Woodward, Ph. D., Carnegie Institution, Washington, D. C. 3. Conservation of National Resources, Agriculture, Irrigation and Forestry, George M. Rommel, B. S., Bureau of Animal Industry, Department of Agriculture, Washington, D. C. 4. Education, P. P. Claxton, LL. D., Bureau of Education, Washington, D. C.

Jan 12, 1915

An experiment substituting pneumatic crawler drills for large-diameter rotary rigs in overburden stripping operations has indicated significant bit cost savings for Perry and Hylton Coal Co., Beckley, W. Va. The test was conducted in the Egeria Mountains (part of the Appalachian Range), where about 30 m (100 ft) of overburden consisting of hard, seamy sandstone and shale must be removed to recover a 560-mm (22-in.) vein. Perry and Hylton operates ten surface mines and is presently developing three more for start-up in the near future. The company follows a progressive policy toward ecological concerns, incorporating a self-imposed systematic mining and reclamation program for mined lands which leaves the landscape in a suitable condition for further development by local communities.

Jan 6, 1976

By Robert M. Dreyer

Although lateritic ore deposits are relatively flat-lying, surficial ore bodies, the evaluation of lateritic bauxite and nickel deposits is among the most difficult problems confronting an economic geologist. Laterite is a soil formed under tropical conditions resulting in the concentration, within the soil zone, of certain trivalent metals - principally iron and aluminum, but also, locally, nickel and manganese. The soil zone is divided into two parts: (a) the true soil or lateritic zone and (b) the zone of partially altered bed rock or saprolite. Whereas bauxite generally is confined to the lateritic zone, some nickel deposits occur in both the laterite and saprolite zones. The evaluation of bauxite and lateritic nickel deposits thus has both similarities and differences. These ores have been formed by supergene, soil-forming solutions moving downward through zones of widely varying permeability within the weathering rock. Because the permeability varies widely, both vertically and laterally. the extent of weathering may vary greatly within short distances. Because the weathering process varies widely, the degree of metal concentration may also vary widely. It is not at all uncommon for a laterite to change, within a few centimeters, from a virtually valueless rock to a high grade ore. Moreover, the depth of weathering, and hence the depth and form of the ore profile, vary greatly. Obviously, for this type of deposit, a few grab samples or a few drill holes are virtually worthless. The evaluation of such a deposit requires a sophisticated statistical study based on thousands of carefully selected samples. As a rule of thumb, the cost of evaluating a large bauxite or lateritic nickel deposit will be about one cent per ton of ore in the ground. Thus, the cost of evaluating a several hundred million ton deposit may be considerable. The following factors must be considered during the evaluation: Type of Sampling: The best and most reliable samples for the evaluation of lateritic ores are taken along large, vertical channels in hand-dug pits. Where labor costs are high, some form of drilling may be used in place of pitting, but it is always wise to choose a drilling procedure after checking drilling results against a series of pit channel samples. The drilling may not reproduce exactly the results from pit channel samples, but it may be possible to derive a constant correction factor. If the physical character of the laterite varies within the deposit, it may, of course, be necessary to change the type of drilling, the correction factor or both. In some areas, it has been found empirically that augers, chum drills, vacuum drills, rotary drills, or core drills yield satisfactory results. The problem is to find which drilling technique gives results most similar to channel samples through the heterogeneous sequence characterizing the laterite in a given area. In lateritic nickel deposits, the drilling characteristics of the lateritic and saprolitic portions of the deposit are very different. Within the saprolite, the major nickel values are commonly found in weathered zones within less altered boulders - a type of occurrence which makes sampling very difficult.

Jan 1, 1979

(Members are urged to send in for this column any notes of interest concerning themselves or their fellow-members.) Members and guests who registered at Institute headquarters during the period July 10 to Aug. 10, 1915: William H. Rettie, Yonkers, N. Y. Paul S. King, Wilmington, Del. A. J. Eveland, Pachuca, Mexico. E. E. R. Tratman, Chicago, 111. Chang Fu Wang, Shanghai, China. Courtenay Dekalb, Tucson, Ariz. F. H. Fovargue, Terlingua, Tex. Emil Gathmann, Baltimore, Md. W. W. Elmer, Tuttletown, Cal. Henry S. Drinker, E. M., LL. D., has just completed 10 years&apos; service as President of Lehigh University. A notable gathering of alumni, with their wives and daughters, numbering more than 1,000 persons, met in South Bethlehem on June 5. In accordance with the request of Dr. Drinker, no formal celebration was held, but, nevertheless, a spontaneous and enthusiastic expression- of appreciation and affection was voiced by alumni, students and faculty, testifying to the regard felt for Dr. Drinker and extolling the progress made by the University under his guidance.

Jan 9, 1915

By William C. Buell

As used in connection with open-hearth or other high-temperature operations, "insulation" refers to a multitude of substances, natural or manufactured, that have the one principal property of preventing the flow of heat by conduction to a greater degree than refractories can prevent it, the principal properties of the latter being resistance to temperature and/or chemical action. The term "control" as commonly applied to the mechanization of management functions is inappropriate without qualification, for without some degree of control of every operation we could produce no steel worthy of the name. Although grouped together in this paper, insulation and control in open-hearth furnaces have little, if any, interrelationship, therefore the paper is made up of two distinct parts. INSULATION OF OPEN-HEARTH FURNACES More than ten years ago the writer proposed the insulation of an acid open-hearth furnace system below the charging floor, and it was accomplished, with gratifying results. Possibly that was the first time the insulation of regenerators and slag pockets of any open-hearth furnace was undertaken, but shortly thereafter such insulation became general, and when the six groups of 150-ton furnaces1 were built in 1929-1930, they were completely insulated below the charging floor. While the practice was accepted at least five years ago, it was not well understood, however, as indicated by the following incident which occurred in connection with an installation made in 1929. After the

Jan 1, 1935

By R. Gibala

Internal-friction measurements on hydrogen-charged iron over the temperature range 4° to 300°K are reported. Two relaxation peaks, the hydrogen Snoek peak at 48 °K and the hydrogen cold-work peak in the range 145" to 2200K, are observed at 80 kc per sec. The effects of hydrogen-charging, aging, and deformation on the internal-friction results are determined and are used to show evidence of partitioning of hydrogen between solid solution and dislocations. The hydrogen-dislocation binding energy is estimated from the behaviors of the relaxation tiwzes and relaxation strengths of the Snoek peak and the cold-work peak. Its value is approxi,mately 6400 cal per mole. MANY investigators have demonstrated the usefulness of internal-friction measurements in determining the manner in which interstitial impurities interact with dislocations in bcc metals. Part of this success has resulted from the existence in bcc interstitial alloys of two anelastic relaxation peaks—the Snoek peak&apos; and the cold-work or Koster peak2 (designated hereafter by SP and CWP, respectively). The SP has its origin in the redistribution of interstitials in solid solution among sites made energetically nonequivalent by an applied stress. The rate at which the redistribution occurs, measured by the relaxation time for the process, is related in a simple way to the diffusion rate of the interstitial in the free solution. The relaxation strength is proportional to the concentration of interstitial in solid solution. The CWP appears to have its origin in the relaxation of an interstitial-dislocation complex for which the relaxation time at a given temperature is much longer than that for the SP. The relaxation strength depends strongly on the concentration of interstitial and the amount of deformation at relatively low concentrations and deformations.2-8 From the dependence of the relaxation strength on interstitial concentration, the SP and CWP may serve as measures of the concentrations of interstitials in free solution and bound at dislocations, respectively. Thus their behaviors have been used to investigate interstitial-dislocation interactions in Fe-C, Fe-N, and several refractory metal systems.&apos;-&apos; However, the Fe-H system has not been studied extensively,? even though disputes in recent years over the mechanism of hydrogen embrittlement in steels involve argument over the extent to which lattice hydrogen and hydrogen-dislocation interactions play an important role.?-&apos;&apos; Previous work on Fe-H indicates the internal-friction behavior to be qualitatively consistent with that for other systems. Apparently, both a SP and a CWP are observed in the temperature ranges 30" to 50°K and 100°to 140°K, respectively (at 1 cps). However, there is neither sufficient nor accurate enough information to identify convincingly these peaks with their supposed counterparts in other systems. Nor have there been any attempts to make quantitative use of these peaks to study hydrogen diffusion, aging, or interaction processes. In this paper, an attempt is made to obtain more complete information on internal friction of hydrogen in iron than presently available. Internal-friction measurements in the range 4° to 300°K on hydrogen-charged iron show that the two peaks discussed above are in fact the hydrogen SP and CWP. Several effects of hydrogen charging, aging, and deformation on these peaks are observed and are used to determine the partitioning of hydrogen between solid solution and dislocation sites in iron. EXPERIMENTAL Materials. The starting material for this investigation was a high-purity iron supplied by National Research Corp. as a 1-in.-diam rod. The following analysis was given (inwt pct): C, 0.004; N, 0.0003; 0, 0.007; P, 0.002; S, 0.005; Si, 0.006; Mn, 0.001; Cu, 0.002; Ni, 0.005; Cr, 0.001; Mo, 0.001. After an initial vacuum anneal (-5 XTorr) at 700°C, the rod was cold-

Jan 1, 1968

By Paul Gemmill

Production was first recorded from the Pioche district in 1864, and it has continued to show an inherent ability to take on new life after periods of depression in the metal markets. Production from replacement leadsilver- zinc sulfide ore bodies in limestones of Cambrian age now accounts for several times the gross value of silver production from rich fissures in Lower Cambrian Quartzite. Aggregate production of some 6 million tons represents a gross value over $100-million. Future output is expected mostly to be from limestone replacement deposits of which the most productive are "channels" of ore up to several hundred feet wide and several thousand feet long with thicknesses from a few feet up to 50 feet. Such channels are restricted to the lowermost limestone bed of the district, about 250 feet above the basement quartzite. The "blotter-like" characteristic of this highly productive Jimesto~e bed in absorbing mineralization is believed to be, at least in part, due to lithology, including free carbon in the bed, which has created a unique set of conditions for delicately balanced mineralizing solutions that rejected any tendency to replace siliceous wall rock and were properly constituted for replacement of Limestone. All recognizable orogenic history is considered to be related to the Basin and Range faulting that created the mountain ranges. The faults developed after mid-Tertiary time and after widespread extrusives that are themselves involved in the faulting. Flat faults, formerly believed to be part of regional thrust faulting, are now interpreted as gravity slide faulting that can be shown to be large in magnitude and not simply local landslides. Large slide faults generally have concealed the great magnitude of mountain-bordering faults. Mineralization that accounts for ore is later than the faulting. Most faults are pre-mineral since they influence the shape of ore bodies, and some clearly have been offset by fault fissures containing ore. Post-mineral movement probably has been an important component of some large, initially pre-mineral faults. A single period of mineralization was begun by the introduction of large quantities of ironmanganese carbonate, and, in places, carbonate manganese with minor values in sulfides. Closely following the carbonate invasion, massive sulfides were brought in, usually replacing part of the carbonate body though in some places the massive sulfides replaced limestone that was not previously mineralized. Manganese mineralization is not a "halo" but leaks of manganese to higher formations and to the surface are the most significant exploration guides. The Pioche district is expected to be long lived with technological developments in ore treatment being important to the exploitation of low-grade manganiferous ores, while aggressive exploration is expected to find important quantities of bedded lead-silver-zinc ores of the massive sulfide type.

Jan 1, 1968

By Charles Allen

THE Athens mine is in the city of Negaunee, Mich. It is one of the larger producers of soft hematite ore on the Marquette iron range. The property is held under lease by the Athens Iron Mining Co., and is operated by the Cleveland-Cliffs Iron Co., which is a partner with Pickands, Mather & Co. in the Athens company. The mine was opened in 1913, and shipments of ore commenced in 1918, the total reaching 3,063,711 tons up to Jan. 1, 1932. Diamond-drilling from surface, together with a knowledge of geological conditions in neighboring properties, gave a comprehensive picture of the location, size and shape of the orebody before shaft-sinking started. Striking east and west, the orebody entered the east boundary of the property at a depth of about 1500 ft. below surface. A pitch of 15° to the west carried it down to about 2500 ft. on the west boundary, about double the depth of that of any soft-ore property heretofore worked on the Marquette Range. The width of ore averaged close to 500 ft., and the thickness 300 feet. The depth of the deposit and its size, together with an overburden of quicksand, which in places reached a thickness of 150 ft., presented unusual mining problems. The use of a caving system made surface drainage into the orebody inevitable, because the north boundary of the deposit was a vertical diorite dike 200 ft. wide, and the south boundary a northward-dipping impervious slate. S. R. Elliott, manager of the mining department of the Cleveland-Cliffs Iron Co., who was super-intendent of the mine at that time, conceived the idea of starting at the bottom of the orebody and working upward, reversing the usual mining procedure. This innovation divided the Athens orebody into a series of steps, or blocks, the first of which was adjacent to the western boundary, and therefore in the lowest portion of the deposit. Top-slicing was to start under the capping in this first block by raising from the bottom level, and development and mining were to progress upward in successive blocks to the east. A complete description of the Athens system of mining was

Jan 1, 1933

By G. A. Koenig, Moritz Stockder

Locality and Geological Occurrence. The Alpine region of Southwest Colorado, comprising the San Juan and Uncompaghre Mountains, is composed of a deeply eroded sheet of acid eruptive rocks, overlying in part gneissic sehists, and in part limestones and sandstones, including portions of the Silurian, Devonian, and Carboniferous systems. The section is clearly and beautifully exposed along the Uncompaghre River from its headwaters to its exit from the mountains. The river&apos;s course from the town of Ouray towards the Los Pinos agency is due north, and four miles from Ouray, in this direction, the Uncompaghre receives from the east the Red Cafion Creek. Following up the narrow caftan we find the section through white.. sandstone in strata dipping to the north and west, and belonging either to the lower or middle Devonian system. Presently the steep cafion-liko character of the ravine gives place to more gentle slopes, and we have entered crystalline rock-porphyry. The contact is well marked, for the sandstone, to a depth of from six to ten feet, resembles quartzite, i. e., is semifused. Ascending still higher, a small

Jan 1, 1881

By Albert Ledoux

SEVERAL years ago my firm was representing the Mt. Lyell Co. of Australia, which was shipping its blister copper to a refining works in the United States. After the contract had been running for many months, the superintendent of these works discovered that if water was poured upon the surface of the bars much of it would disappear into the interior through blow holes. -Some experiments made by him showed that this could be a considerable amount, so that copper which had been rained on before it was weighed, although the surface appeared dry, nevertheless would contain water. It had frequently occurred in our experience-as samp-lers that the drillings from a lot taken by boring would come out quite wet, and in some cases, indeed, water would drip into the sample pan placed below the bars, due to the fact that the drill had penetrated a cavity or cavities containing water, which presumably got into the cavities at the time the copper was water-cooled after casting, there being, perhaps, no outlet to the surface. So far as I know, until this discovery at the refining works, no. one had thought that rain could penetrate into the interior of blister copper; at least in any quantity sufficient to be considered.

Jan 10, 1922

By H. E. Stauss, G. Sandoz

THE purpose of this note is to draw attention to the possibility that a melt may be contaminated by a material not in direct contact with it by means of gaseous intermediate agents. In recent years silicon has assumed a position of importance because of its use in rectifiers and transistors and close attention has been required to control of both purification and contamination during all stages of preparation.&apos; This note reports the observation that a graphite heater may have contaminated silicon ingots without direct physical contact through reactions that developed gaseous products. Several ingots made with the equipment of Hino and Stauss,2 using a graphite heater in a dried helium atmosphere, were found to have a small amount of a very hard substance on the free surface. X-ray analysis by F. W. von Batchelder showed the sub- stance to be Sic. Similar contamination was not found when the heater was tantalum, indicating that the carbon had not come from an original impurity in the silicon powder. One source of the carbon could have been volatile matter released from the graphite heater. This heater had been used about ten times at the time of the observations. A second source of carbon could have been a direct reaction between the quartz crucible and the graphite heater to form CO, or an indirect reaction involving a crucible-melt interaction and volatile SiO as an intermediate product. Such reactions should have developed Sic on the heater; and in fact a yellow powder did form on the inside of the graphite heater although its composition could not be determined. References &apos;H. C. Torrey and C. A. Whitmer: Crystal Rectifiers (1948) Chapter 10. New York. McGraw-Hill Book Co. 2 J. Hino and H. E. Stauss: Trans. AIME (1952) 194, p. 656; Journal of Metals (June 1952).

Jan 1, 1954

By C. V. O. Hughes

Florida phosphate operations are unique in the ways standard mining equipment is made to meet specialized problems. Hydraulic mining and transportation has evolved in meeting three such special problems: 1) surface mining of a shallow, poorly consolidated but wet material; 2) high pro¬duction rates, necessary because of low prices for phosphate rock in a highly competitive market; and 3) preparation of the value-bearing rock, or matrix, for washing and flotation. The magnitude of the problems is better appreciated if the reader understands the size of operations in the area. The Florida phosphate field produces and ships about 10 million tons per year of phosphate rock. All of this has to be concentrated to its shipping grade, either by scrubbing and screening or by flotation.

Jan 1, 1956

There&apos;s a right way and a wrong way to store diesel electric systems and similar equipment for generating on-site power, according to James Frankow, service manager for Allis-Chalmers Corp&apos;s Engine Division. In any event, the less storage the better. Many generating sets are stored before installation, especially when new construction is underway. Improper storage, or mothballing, can create initial reliability problems. Therefore; arrange for inside storage with no drastic extremes in temperature or humidity. If engines and alternators are stored in areas other than inside a dirt-free and temperature-controlled building, the unit or engine should be completely covered and protected against the environment. Before covering it with a canvas or with plastic, the unit should first be sealed at the following critical engine openings:

Jan 3, 1978