Search Documents

By K S. Park, J K. Kim, J H. Park, Y Su

The present study investigates the possibility of the direct removal of oxygen from the Ti-30Ni (wt per cent) alloy melt through the thermodynamic equilibrium reactions at 1623 K in the vertical tube furnace. The deoxidation efficiency of Ti-Ni alloy melt by adding different contents of metallic calcium (Ca) as a deoxidant was evaluated with the binary CaF2-MgCl2 flux. The thermodynamic equilibrium experiments showed that the total oxygen content in the alloy decreased from about 650 ppm to 350 ppm when 3.5 wt per cent Ca was added to the Ti-30Ni (wt per cent) alloy. Alternatively, the effect of flux composition in the CaF2-MgCl2 flux on the oxygen content was also investigated at 1623 K. Therefore, the effect of binary flux systems on the deoxidation ability was compared at 1623 K. According to the results, the flux system with 80 per centCaF2– 20 per centMgCl2 exhibited the best deoxidation capability, ie total oxygen content in the alloy reduced from 1450 to 550 ppm.

Aug 21, 2024

No paper available.

Jan 1, 1996

By J Zhao, C E. Loo

The flame front is a narrow region in the iron ore sintering bed where coke particles combust. The maximum flame front temperature is as high as 1400°C. At high temperatures, the sinter mix components react to form melts, which facilitates material coalescence and the formation of dense sinter particles. It is well-established that flame front speed is an important factor influencing sinter productivity, sinter quality and fuel rate. In this work, the effect of suction, coke addition and mix moisture on flame front speed was studied in a pilot-scale sinter pot and also using the outputs of a recently developed theoretical model, which takes into account most of the significant physicochemical processes in sintering. Airflow through the bed has a large influence on flame front speed. A power law relationship between these two parameters means that increasing sintering airflow rate will lead to increased flame front speed, but the increases become smaller at higher airflow rates. Sinter pot test results showed that increasing coke addition decreased green bed permeability and increased flame front temperature, which resulted in increased flame front resistance and decreased flame front speed. Studies also showed that green bed properties are sensitive to sinter mix moisture level. The changes in green bed properties further influence the flame front speed and temperature.CITATION:Zhao, J and Loo, C E, 2015. Dependence of flame front speed on iron ore sintering conditions, in Proceedings Iron Ore 2015, pp 83–90 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By P Minkkinen

"Pierre Gy showed in his early works that the results in estimating the variance of the mean value of continuous lots depends on sampling mode (random, stratified or systematic), except in the theoretical case that the measurand is randomly distributed in the lot. The experimental variance estimate calculated from samples taken from the lot is independent of sampling mode but depends on sample size and the type of the lot heterogeneity. Variography can be used to estimate the variance of the lot mean for different sampling modes.Gy also defined weighting error, which is made if a simple average is calculated from the assays of samples taken from a continuous object (eg from a process stream) where the flow rate varies with time and is correlated with the concentration of the analyte in the stream.The effect on sampling uncertainty of the three sampling modes and their interaction with the following factors in estimating the uncertainty of the mean concentration is studied using simulated lots, and lots having heterogeneity patterns similar to those of real data sets, including the effect of: the type of heterogeneity (random, grading and clustered heterogeneity patterns) increment size and number employing composite sampling weighting error. CITATION:Minkkinen, P, 2017. Dependence of the variance of lot average on the sampling mode and heterogeneity type of the lot, in Proceedings Eighth World Conference on Sampling and Blending, pp 319–330 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

May 9, 2017

By Matsushita Y, Maeda M, Sano N

The present study was carried out to explore the possible separate recovery of iron and phosphorus (as gas) from BOF slag using graphite crucibles or graphite powders in the presence of a tin bath. The last is consider- ed to enhance the activity of phosphorus in iron reduced from slag or not to absorb the phosphorus vapour readily. When the slag was reduced in a graphite crucible in contact with a tin bath, the phosphorus reduced from the slag was carried away in CO explosively generated by the reduc- tion of iron oxide. When graphite powder was used as the reductant instead, 78% of the phosphorus was removed from slag, only 3% of which was absorb- ed into the tin bath. The rest left the system as gas. Gaseous dephosphorization depends on the area of contact between slag and reductant as cll n.u the amount of the latter. the reduction behaviour was directly observed, using an X ray transmission technique, to conlirm the reaction mechanism.

Jan 1, 1980

By K Ionkov

The oolitic iron ore reserves in Lisakovsky, North Kazakhstan represent quite a challenging deposit both from a technological and from a resource point of view. The difficulties in processing such types of ore are connected with the extremely fine dissemination of phosphorus and gangue minerals inside the oolitic formations. The goethite crystals are cemented in their structure by aluminosilicates with quartz and other gangue minerals and dissemination is so fine that they are not separable by physical methods. The laboratory tests performed for dephosphorisation show that the combination of alkaline roasting followed by low intensity magnetic separation and acid leaching enables the obtaining of high grade iron concentrate. The magnetic separation performed ahead of leaching is effi cient as a means of buffering the high pH by washing out the soluble salts and the excess of base and after leaching facilitates the removal of secondary liberated gangue minerals in the non-magnetic fraction. As a consequence, phosphorous content is dropped to a more acceptable level for the ferrous metallurgy and iron grade and recovery reach 61.6 and 80.8 per cent respectively.

Jul 11, 2011

By Vilela A. C F

In the present work, the process of dephosphorisation of stainless steel was developed in laboratory scale by adopting a high frequence induction furnace, using BaCO3 base flux. By using BaCO3 - CaO - BaC12 - Fe2O3 Flux of about 110 g/Kg-metal, 30 per cent dephosphorisation degree was obtained a stainless steel containing 18,8 per cent Cr and carbon between 0,08 and 2,0 per cent. In addition, a dessulfurisation degree of 89 per cent was achieved too.

Jan 1, 1991

Detailed investigation was carried out on the dephosphorization of a number of phosphorus-rich manganese or samples of India by leaching with dilute sulphuric acid. Various process parameters like concentration of acid, liquid-solid ratio, temperature of leaching, time of leaching, and particle size of the ore were studied in detail for the three samples of manganese ore from central India, and optimum values were worked out on a laboratory scale. Preliminary studies show that certain ores which are not easily amemlible to appreciable dephosphorization by leaching with dilute sulphuric acid can be made amenable by :roasting to 700-900°C before leaching.

Jan 1, 1974

By Baafi EY, Sun Y, Tague I

Field trials at three New South Wales and one Queensland coal mines were carried out to gather data on oxygen "run out" times of Self-Contained Self Rescuers (SCSRs), time taken to escape from the mine, distances travelled and the average heart rate of subjects wearing SCSRs. The study has led to a method of predicting the duration of oxygen supply from a SCSR as a function of the wearer's body weight, physical fitness and the prevailing environmental conditions. Escapeway design, planning for emergencies, familiarity with SCSRs and experiential escape training are critical to control panic and maximise the likelihood of survival of a person attempting to escape in an emergency involving fire or explosion.

Jan 1, 1998

By J Zhou

Gold in sulfide ores is associated predominantly with sulfide minerals and occurs as both microscopic and submicroscopic particles. In non-refractory sulfide ores, gold occurs mainly as coarse- and medium-grained particles. Minute inclusions and submicroscopic gold usually account for a minor portion. In contrast, gold in refractory sulfide ores occurs mainly as minute particles and submicroscopic gold, and microscopic gold usually accounts for an insignificant portion. In gold ores containing carbonaceous material, the preg-robbing nature of carbonaceous material may impose challenges on gold extraction and cause gold losses. To extract gold from refractory sulfide ores, the ore needs to be finely ground and preoxidation is often required. Sulfide host minerals must first be oxidised to create a porous structure through which the cyanide leach solution can penetrate to reach the colloidal gold particles. The oxidation is traditionally achieved by roasting, autoclaving or bacterial oxidation. In carbonaceous sulfide ores exhibiting a preg-robbing nature, the carbonaceous material needs to be treated by roasting, autoclaving or other means to minimise the preg-robbing effect. As a predictive and troubleshooting tool, the gold deportment study plays an important role in gold metallurgy. It determines the deportment of gold in an ore or mill product and identifies the mineralogical issues that may affect or may have affected gold extraction. The information acquired from a gold deportment study can be used to assist in process selection, flow sheet development, recovery improvement and reagent optimisation.CITATION:Zhou, J, 2013. Deportment of gold in sulfide ores and implications for gold extraction, in Proceedings World Gold 2013 , pp 433-442 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

A rotating disc of precipitant zinc in a single stage flow reactor was used to study the effects of deposit mass on the reaction kinetics of copper cementing on to zinc from dilute aqueous solutions.The reaction rate is controlled by external mass transport and the mass transfer coefficient (relative to the original precipitant area) is dependent on the quantity of deposit present. For deposit masses up to about 0·3 mg/cm2 the mass transfer coefficient (first order rate constant) is that expected for the counter-diffusion of reactant and product cations through a laminar boundary layer to a smooth rotating disc. For depositmasses from 0·3 mg/cm2 to about 5 mg/cm2, the mass transfer coefficient increases significantly with deposit mass. For deposit masses greater than 5 mg/cm2 and at least up to 12 mg/cm2, the mass transfer coefficient has again a constant value which is some four to seven times the initial ("deposit free") value. The rate constant for the entire range of deposit masses studied (0 to 12 mg/cm2 ) can be expressed empirically as a cumulative normal distribution of the logarithm of the deposit mass.The enhancement in the mass transfer coefficient for deposit masses greater than 5 mg/cm2 relative to the initial mass transfer coefficient depends on the local operating conditions and increases with increasing disc rotational speed. This enhancement is, however, independent of the previous history of reaction rates.

Jan 1, 1973

By Pollard D, Meadows N

The presence of impurities which are electropositive to zinc in acid zinc electro- lyte causes changes to deposit morphology and reduced current efficiency. Glue may be added to control some impurity effects, but assaying for animal glue concentration is difficult and seldom done. Measurement of the activation overpotential for zinc deposition by cyclic voltammetry is used in some plants to monitor electrolyte quality and control glue additions. The deposit morphology and current efficiency of zinc deposition from commercial electrolyte were investigated for various glue additions in the presence of increased levels of antimony. Cyclic voltammetry was invest- i,ated as a method of optimizing glue additions in the presence of antimony. Scanning electron microscopy showed deposits characteristic of the impurity element present and the glue addition rate. Cyclic voltammetry measurements showed some correlation between current efficiency and activation polarization potential. The importance of using tankhouse electrolytes where results are to be related to tankhouse operation was noted.

Jan 1, 1984

By A B. Christie

Known epithermal deposits in the Coromandel region belong to the low-sulphidation type, represented by three subtypes: (1) andesite-hosted epithermal Au-Ag, (2) rhyolite-hosted epithermal Au-Ag, and (3) andesite-hosted polymetallic veins. Paleo-depths for a range ofdeposits are estimated using various features including: paleo-surface indicators (e.g. sinters), hydrostatic pressures estimated from homogenisation temperature measurements on fluid inclusions, and alteration mineralogy. Paleo-depth estimates to the base of the ore zone for the rhyolite-hosted Coromandel deposits are in the range 200 to 500 m. Andesite-hosted Au-Ag deposits have more variable paleo-depths, and are deeper (up to 950 m) in those deposits with base metals at depth. The majority of Coromandel Au-Ag deposits have limited depth extents (<200 m) of economic grade mineralisation, although Waihi and Karangahake are notable exceptions with depth extents of 575 m and 700 m respectively. Limited depth extents of economic ore are a feature of epithermal systems worldwide and are commonly attributed to gold deposition from boiling fluids. Under hydrostatic conditions in epithermal/geothermal systems, boiling in an up-flowing hydrothermal fluid is controlled by the boiling point for depth (BPD) curve. From fluid inclusion studies of many low-sulphidation epithermal systems, deposition of electrum in economic concentrations appears to be confined to a temperature window of 260 to 180¦C. This means that for dilute, gas-poor fluids that follow the BPD curve, gold deposition is limited to a vertical depth zone of about 400 m, with its upper boundary at about 100 m below the ground surface. The greater depth extent at Waihi and Karangahake, can be explained by mixing of/a deep, hot (300¦C) fluid with cooler (c. 200¦C) heated ground waters. This has the effect of lowering the 260¦C isotherm by up to 300 m, thereby increasing the depth range of economic grade gold deposition within the 260 to 180¦Cwindow of electrum deposition.

Jan 1, 2000

Coal washery wastes comprise tailings, finer than 0.5 to 0.1 mm depending on the sophistication of the washery, and coarse reject, typically finer than 50 mm. Subaerial disposal of coal tailings slurry at about 30 per cent solids by mass results in the formation of a delta with an average slope of about 1 in 100, representing one extreme. The ravelling of coarse reject on loose-dumping, results in an angle of repose slope with an angle of about 37o (1 in 1.3), representing the other extreme. The pumped co-disposal of coal tailings and coarse reject results in the formation of an upper delta with an average slope of about to one in ten, between the two extremes. The depositional behaviour of these three waste streams is discussed and compared in this paper. The important depositional and material parameters, and a theoretical description of the processes involved, are also presented. Comparisons are made between the depositional behaviour of the various coal washery waste streams, and natural depositional systems, such as rivers, alluvial fans, and scree slopes.

Jan 1, 1998

By D J Williams

Coal washery wastes comprise tailings, finer than 0.5 to 0.1 inn depending on the sophistication of the washery, and coarse reject, typically finer than 50 mm. Subaerial disposal of coal tailings slurry at about 30 per cent solids by mass results in the formation of a delta with an average slope of about 1 in 100, representing one extreme. The ravelling of coarse reject on loose-dumping, results in an angle of repose slope with an angle of about 37" (1 in 1.3), representing the other extreme. The pumped co-disposal of coal tailings and coarse reject results in the formation of an upper delta with an average slope of about to one in ten, between the two extremes. The depositional behaviour of these three waste streams is discussed and compared in this paper. The important depositional and material parameters, and a theoretical description of the processes involved, are also presented. Comparisons are made between the depositional behaviour of the various coal washery waste streams, and natural depositional systems, such as rivers, alluvial fans, and scree slopes.

Jan 1, 1998

By Draper J. J, Jell J. S

The Burdekin Basin in the Townsville hinterland is an intracratonic extensional basin which contains up to 4500 m of marine and continental siliciclastics and carbonates. The basin sequence is recognised as having accumulated during five major episodes of deposition. Facies analyses of these show that each consists of one or more transgressive or regressive phases. Each episode led to the accumulation of thick sequences in several half-grabens in a transtensional back-arc setting. The depositional episodes can be recognised in comparable sequences in the Broken River Province to the west and Drummond Basin to the south.An Early Devonian episode resulted in the deposi-tion of dominantly marine facies, currently mapped as Fanning River Group, in the northern part of the Burdekin Basin. Two transgressive phases are recorded there, firstly in the Pragian, then later in the late Emsian to early Eifelian. A Middle Devonian episode is represented by dominantly marine facies of the Fanning River Group, representing the peak of a widespread late Eifelian to Givetian transgressive phase. A Late Devonian episode is characterised by continental facies of the Dotswood Group. Deposition occurred during a major regressive phase in response to regional uplift of surrounding areas, and the onset of acid-intermediate volcanism to the south. A Late Devonian to Early Carboniferous episode followed, which was a period of alternating marine transgressions and non-marine regressions that resulted in the deposition of the Keelbottom Group. A final Early Carboniferous episode, marked by the deposition of calc-alkaline volcanics and non-marine faciesòof the Glenrock Group, was a direct outcome of Early Carboniferous subduction further to the east. Compression of the basin followed in the Late Carboniferous, resulting in folding and reactivation of basement faults.

Jan 1, 1990

By Hochwimmer B, Baxter JL

Heavy minerals are mined from two fossil strandlines on the southern Swan Coastal Plain. The Capel shoreline, 7 km inland, and the Yoganup shoreline, 15 km inland are arcuate, northwest-facing, and remote from the modern coast. Based on foraminiferal and molluscan assemblages, the shorelines are probably of Pliocene age. The Yoganup shoreline is adjacent to the Whicher Scarp, which is cut into the Leederville Formation (Lower Cretaceous) at the southern boundary of the Swan Coastal Plain. Stratigraphic relations and detailed sedimentology have been studied from temporary exposures in the Yoganup Extended and Yoganup North mines, within a strandline complex at 27 m and 18-33 m above sea level respectively. Heavy minerals were deposited in thin, shallowing-upward sequences along a wave-dominated clastic shoreline cut into pre-Cainozoic sediments. Lithofacies units deposited in eolian, foreshore, shoreface and lagoonal environments are the most significant sites of heavy mineral accumulation. The data collected provide a basis for further exploration.

Jan 1, 1986

The Proterozoic Pb-Zn deposits of the Gulf of Carpentaria, Australia, include HYC (McArthur River), Mt. Isa, Dugald River, Lady Loretta and Hilton. Two seamingly incom- patible depositional models have been proposed to account for their origin. Finlow-Bates (1980), Large (1983) and Russell(1983) classify these-deposits as sediment-hosted submarine exhalative deposits. This class includes Rammelsberg, Meggen, Silvermines, Sullivan and others. In contrast, a lacus- trine, shallow-water origin has been advocated by Williams and Logan (1981), Logan and Williams (1984), Muir (1983) and Eugster (1985). The discrepancies between these two models can be removed by creating a separate class, that of continental sediment-hosted exhalative deposits.. HYC., Mt. Isa and Dugald belong to this class and their sediments were deposited in shallow, alkaline lakes. Metal- rich, hot, Na-Ca-Cl brines entered the basins along boundary faults and interacted with pore fluids and sediments, depositing-Cu-Zn-Pb sul- fides. Similar brines entered the Lady Loretta basin after marine flooding, depositing sulfi- des and barite, placing Lady Loretta into the class of marine Sedex deposits.

Jan 1, 1987

By Shinnosuke U, Zhang HE, Qian X

In this paper it is recommended that pyrite is to be separated as froth from arsenopyrite by selective depression of arsenopyrite in strong alkaline medium (1), by oxidation with chlorinated lime (II), by co-use of chlorinated lime with sodium carbonate (III), and by modification with `L' reagent (know-how) without filtering to get rid of residual copper ions after Cu activation (IV). The corresponding principles of these (new) effective methods were briefly discussed. The artificial mixture (1:1) of pyrite and arsenopyrite could be successfully separated, and concentrates of pyrite containing 2.12 per cent (I), 7.00 per cent (II), 2.60 per cent (III) and 3.16 per cent (IV) arsenic with recovery of 90.9 per cent (1), 89.5 per cent (II), 89.0 per cent (III) and 81.4 per cent (IV) respectively can be obtained by only one flotation. Some effective precautions were suggested to improve the separation of arsenopyrite and pyrite (or other sulphides) by flotation.

Jan 1, 1993

By N Kreutzman, A Moilanen, V Palosaari

Carboxymethyl cellulose, CMC, is widely used in mineral processing as a flotation depressant, mainly for the depression of carbonate and talcaceous gangue in the flotation of Cu-Ni sulfide and PGM ores. Although CMC is a common depressant that can be used in the flotation of different ores, understanding of the interaction mechanisms between CMC and mineral particles in different flotation circuits and different pulp conditions is still limited. Electrokinetic measurements, microflotation and laboratory-scale flotation tests were carried out to optimise the action of CMC depressants in the flotation of a PGM ore. Standard and new CMC brands produced and characterised by Noviant were used in the study. Pure talc and chlorite minerals and a low-grade PGM ore composite were used as test materials. A laboratory flotation test evaluation was performed using the recovery-grade relationship and double value index (DVI) calculation to estimate the effects of both valuable and harmful components on the product value. Solution conditions play an important role in the depression of gangue minerals such as talc. The most favourable conditions for MgO depression were found to be mildly acidic in which conditions the electrostatic repulsion between the CMC molecule and talc is minimised. Similar effects were obtained with electrolytes that affect the conformation of the CMC molecule and the mineral surfaces. In addition to the control of chemical conditions in the pulp, CMC molecules were modified to optimise structural variables. The new CMC brands developed in this work showed significant potential to improve flotation performance, particularly when pulp conditions are controlled.

Jan 1, 2005