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By E Christodoulou, L Zoumpoulakis

The kinetics of the thermal decomposition of MgCO3 was investigated using isothermal experiments performed in a thermogravimetric analyzer under a nitrogen atmosphere at 380¦, 400¦, 450¦ and 480¦C. The weight loss data as a function of time were modified to give the fraction that reacted (ß) and the rate of reaction (dß/dt) vs. time (t). Kinetic analysis of the experimental results, using three different methods, showed that diffusion predominates the MgCO3 decomposition over the investigated temperature range, with the data being best fitted by JanderÆs equation ([1−(1−ß)1/3]2=kt). The activation energy was estimated by Arrhenius plots using both the initial reaction rates and rate constants from fitting the above equation. The values estimated were 27.1 and 171.4 kJ/mol respectively.

Jan 1, 2001

Kinetic Study on the Leaching of Vanadium from LD Converter Slag Using Sulfuric Acid In order to reduce the environmental impact due to land disposal of LD (Linz-Donawitz) converter slag from steelmaking plant and to valorise this waste material, an acid leaching study was carried out to assess the effect of several parameters on the kinetics of vanadium dissolution. The characterisation and morphology of the feed investigated using XRD, XRF. The factors influencing leaching vanadium such as particle size, temperature, slurry density and the concentration of sulfuric acid were investigated and optimised. The maximum vanadium recovery about 95 per cent achieved at 70¦C, S/L: 1/15, acid concentration: 3M and for 150 minutes of leaching time. The dissolution of vanadium in sulfuric acid shows that there are two stages in the kinetics of leaching. At the first 15 minutes, there is a sharp increase in the amount of vanadium extracted and at longer leaching time, the extraction increase slightly. In the present work, the shrinking core model (SCM) was used to describe the acid leaching of vanadium compounds. A summary of the controlling regimes in the SCM are examined below for short time (less than 12 min.) and long time (more than 30 min.) stages. So, it was found that the kinetics of leaching in both stages is controlled by solid product diffusion regime.

Sep 13, 2010

A composite iron ore-reductant pellet is a mixture of fine iron ore and fines of coal/char/coke, bonded at essentially room temperature with sufficient green strength for subsequent handling. In ironmaking, these pellets offer the advantage of fast reduction, utilisation of fines, non-coking coal and coke breeze. The composite pellet-based alternative ironmaking processes constitute a promising route for ironmaking in future. The present paper is a brief review of kinetics and mechanism of reduction of iron oxides into iron and other associated reactions, when these pellets are heated to high temperature. It would draw significantly from investigations conducted by the author and his co-workers.

Jan 1, 1999

By Glastonbury J. R

The kinetics of the direct chlorination of, zircon in the presence of carbon was studied at temperatures between 9000C and 12000 C. From the experimental data it is prop- osed that the most likely mechanism for metal oxide (MeO2) chlorination is as follows: At I Surfaceon zMeO2+ZMeCl - MeOC12 (1) At Carbon MeOC12+C+Cl MeC14+CO (2) Surface It.is envisaged that this type of mechan- ism would occur for both the zirconium and, silicon. constituents of the ore. In the above mechanism; the surface re- actions appear to be fast and not rate controll- ing. In a carbon surface deficient bed the diff- usion of oxychloride intermediate through the boundary layer to the carbon surface becomes the rate controlling step. In a zircon surface deficient bed the diffusion of oxychloride away from the zircon surface controls the reaction. This postulated mechanism can be used to ex-, plain the observed experimental effects.

Jan 1, 1973

By Zhou A, Cadogan J. M

Direct reduction of iron ore (DR) is one of the promising technology emerging in the world's steel industry. Kinetics and Mossbauer studies of DR with hydrogen have been carried out at two temperatures of 600¦C and 800¦C in this investigation. The results show that different controlling steps govern the reduction rate at different temperatures. The mechanism was also found to vary during the reduction. The Mossbauer spectra of the samples reduced in various time intervals were studied to determine the phase changes during reduction.

Jan 1, 1997

By Happ J. V

Factors affecting the rate of arsenic removal from lead bullion during softening processes were studied. Very high rates of removal could be obtained under conditions of intense agitation and ready availability of oxidant. Reaction mechanisms were proposed to explain the sequences observed. Selective removal of arsenic with minimal loss of antimony from bullion was favoured by a low temperature Harris process and oxidizing via a caustic soda medium.

Jan 1, 1987

Kinetics of bubble-particle interaction, surface hydrophobicity and interfacial phenomena in sulfide mineral flotation are discussed in this paper. Results of the measurements of a bubble and mineral induction time (IT) and detachment force (DF), vacuum of bubble evolution (VE) and mineral floatability are discussed for pyrite, galena, chalcocite and chalcopyrite. Natural wetting and wetting induced by xanthates with different lengths of alkyl chains are examined. Experiments show the existence of several maxima of hydrophobicity on dependences of pH and electrochemical potential. These maxima are attributed as the reflection of mineral surface heterogeneity due to xanthate adsorption and the presence of cationic and anionic centres with uncompensated positive and negative charges. These charges can be neutralised by both regulation pH and applied potential. The aim of this paper is to evaluate a thickness of the rupturing film and to estimate how long the bubble-mineral interactions are according to the experimental values of IT, in order to develop a procedure for comparing of the results of DF and atomic force measurements in the same dimensionality, and to compare the results of the experimental studies on the wettability of sulfides with those predicted by the models of physics of capillarity.

Jan 1, 2005

By A Holmgren, W Forsling

In the present study infrared attenuated total reflection (IR-ATR) was used to monitor the rate of in situ adsorption of heptyl xanthate on a layer of zinc sulfide synthesised on a germanium ATR crystal. The zinc sulfide surface was characterised using x-ray photoelectron spectroscopy (XPS). The absorbance of heptyl xanthate measured increased with increasing bulk concentration of the adsorbate up to an equilibrium plateau value corresponding to a fractional coverage of the surface sites of the substrate. For the adsorption from solutions of concentrations between 10-3 and 10-5 M, the rate of adsorption increased with increasing bulk concentration. At higher concentrations the measured absorbance should be corrected for the absorbance due to the concentration of xanthate in bulk solution. The present work provides a discussion of this correction. Assuming the adsorption stage to be rate-controlling and proportional both to the concentration of the adsorbing species in solution and unreacted surface area, a rate law governing this type of transient adsorption kinetics was derived. By means of absorbance data for the concentrations 0.1 and 0.01 mM, the rate constant of adsorption was calculated. From the initial part of a Langmuir adsorption isotherm, the absorbance at monolayer coverage and the equilibrium constant of adsorption could be estimated.

Jan 1, 2005

By Boontanjai C, Boyapati ER

Reagents used for batch flotation tests were Aeroxanthate-343 & 350, Dow Z-6, & reagent-4037 (from Benambra) as copper collectors; Na2SiO3 & Na2S2O3as gangue depressants; lime & HCl as pH regulators; and pine oil & MIBC (methyl isobutyl carbinol) as flotation frothers. A Denver Sub A flotation cell of capacity 250 gms was used for the batch flotation experiments. Atomic absorption spectrophotometer was used for copper assays and microscopy for selectivity and liberation studies. Melbourne tap water was used throughout the experiments. Unless otherwise stated, the following parameters apply to the flotation experiments: flotation impeller speed - 1300 rpm, pulp density during flotation- 22%, reagents addition - in 4 stages, total conditioning time for collectors - 8 minutes, total flotation time- 9 minutes. A variable quantity of copper mineral collector according to the test in question was added, then conditioned the pulp for 2 minutes. The froth was removed by hand, scraping the full length of the cell at constant depth every 10 seconds. No frother is required for this copper tailing flotation. Four concentrates were collected after addition of collector and conditioning at 2,4,6 and 9 minutes. The pulp volume was maintained at a constant level to yield a constant froth depth.

Jan 1, 1990

By Wright G. A

The objective of refining in steelmaking is to reduce the concentration of impurity atoms, e.g. sulphur, phosphorus, from an initially high level to a specified low concentration. A two-film theory of refining is presented in which the rate of

Jan 1, 1980

Kinetics of Reclamation of E-Waste by a Bioleaching Route

Sep 13, 2010

By Lawson F

The Australasian Institute of Mining and Metallurgy is a society of engineers and scientists formed in 1893 (incorporated by Royal Charter in 1955) to advance science and engineering in the mineral industries, and to facilitate the exchange of information and ideas to enhance the professional excellence of its members. The Institute has several grades of members. The professional members are linked with Student and Company Members, as well as an Affiliate grade covering other professionals and non-professionals with experience in the mineral industry. The diverse group covers all sections of the mineral industry, from exploration through production to marketing of minerals and petroleum. Corporate (professional) membership also covers science and engineering professionals from specialisms other than the "traditional" ones in geosciences, mining and petroleum engineering and metallurgy. The Institute has Branches throughout Australia, New Zealand, Papua New Guinea and Oceania, whose activities complement the corporate occasions arranged for the benefit of all members by Headquarters in Melbourne. Members are drawn from all sections of the industry - private enterprise, government, research, education, and the support sector, including consultancies, manufacturers and suppliers. Membership of The Institute allows professionals to contribute to their profession through participation in The Institute's seminars and conferences, its many committees and Branch meetings, and through contribution to its many high standard publications. The Institute is the main body for the accreditation of professionals in the minerals industry. The activities of The Institute are directed towards the achievement of professional excellence. It provides opportunitites for contact with, and professional support from, colleagues, and the interchange of information on the latest industry developments.

Jan 1, 1989

The widely accepted kinetic model for the gaseous reduction of hematite is critically examined. The formation of the wustite layer during internal reduction cannot be explained in terms of solid-state diffusion. Present evidence indicates the existence of a micropore system in the wustite adjacent to the magnetite with the gas/solid type of reaction occurring not only at the iron/wustite interface but also at the wustite/magnetite interface. During the partial reduction of dense hematite pellets, in a controlled atmosphere, porous magnetite and wustite are formed as products. The mean pore size, as measured by mercury injection, increases with time at constant temperature and with temperature increase over the range 6500C to 950°C. The sizes of the pores indicate that Knudsen diffusion is the principal gaseous transport mechanism across thick layers of magnetite or wustite.The kinetics of the gaseous reduction to iron are consistent with a mixed control mechanism involving the interaction of gaseous diffusion effects with a first order reversible chemical reaction at the iron/wustite interface. Because of the larger pore sizes in the iron layers, ordinary molecular gaseous diffusion must be the principal transport mechanism. The usual experimental methods used for establishing the validity of chemical rate ~ontrol are incapable of differentiating between the mixed control- mechanism and exclusive chemical control.Some implications of mixed control kinetics are developed, including a predicted independence of rate on reducing gas pressure at higher pressures.INTRODUCTIONAn extensive literature review of the reduction of iron oxides has been compiled recently by Themelis and Gauvin (1962). From the large number of papers published and the widely divergent opinions of workers in this field, it appears that a simple unified quantitative analysis of reduction kinetics is not possible. The aim of the present paper is to show that a major cause of confusion is due to the attempts of many workers to interpret experimentally observed reaction rates in terms of a single rate controlling mechanism without due regard to other rate processes which must occur simultaneously.Some of the differences in behaviour reported for particles...

Jan 1, 1964

The difficulty in creating and obtaining a competitive edge in the mineral industry is rapidly increasing. The Kiruna Iron Ore Mine in the far north of Sweden is currently thriving on the world market through firm managerial strategy. LKAB believes in upgrading its raw material to produce a high quality iron ore product for sale to steelworks throughout the world. It is vital that this product is also of uniform quality and quantity to provide quality assurance to customers. The first link in meeting these product requirements starts in the underground workings. Mining methods and operations are of large-scale. Automation and continuous production streamline operations and reduce operating costs. These factors have built Kiruna Iron Ore Mine into the world's biggest, most modern, underground iron ore mine. To remain competitive on the world market, LKAB relies heavily on research and development. The mine is currently in a phase of upgrading its operations. A 25-tonne Toro electric loader is being tested to improve the rate of output of ore from the mine. Long hole drills are being improved to increase accuracy and efficiency. An electronic detonating system will improve detonator delay precision. Projects are underway to better understand ore flow mechanisms from a caving orebody. Benefits include improved ore recovery along with better rock quality control at the caving front. The continued updating of mining operations at Kiruna will enable LKAB to continue to maintain its competitive advantage on the world market in the production of high quality iron ore products.

Jan 1, 1997

By X-F Zhao, J-W Li, L-P Zeng

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The formation of Kiruna-type deposits has been ascribed to either immiscible iron phosphate melt separated from silicic magma or precipitation from magmatic-hydrothermal fluids. The early Cretaceous Ningwu volcanic basin in Eastern China contains tens of Kiruna-type iron deposits. The orebodies are mainly hosted within the top zones of subvolcanic dioritic intrusions and along the contacts between these intrusions and adjacent volcanic rocks/strata.The orebodies are commonly associated with widespread brecciation and wall rock replacement. Magnetite formation was closely associated with extensive hydrothermal alteration that may extend kilometres, with both vertical and horizontal zonation. Field and textural data indicate that magnetite formed slightly later than albitisation but coeval with apatite and actinolite. Elemental analysis of magnetite and apatite from ores shows distinct features to those as igneous accessary minerals in the host dioritic intrusions, suggesting a genetic relationship to magmatic-hydrothermal processes. Magnetites have elevated TiO2 (up to 5 wt per cent) and V2O3 (up to 0.7 wt per cent), which implies that they are derived from incipient high-temperature magmatic fluids. It is concluded that the Kiruna-type deposits in the Ningwu basin most likely formed from high-temperature magmatic-hydrothermal fluids. The emplacement of dioritic intrusions into a subvolcanic setting likely plays a critical role in the development of Kiruna-type deposits.CITATION:Zhao, X-F, Zeng, L-P and Li, J-W, 2015. Kiruna-type iron deposits in the Mesozoic Ningwu volcanic basin, Eastern China – origin and relationship to subvolcanic dioritic intrusions, in Proceedings PACRIM 2015 Congress, pp 657–662 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By B Vietnieks, N Widmer, L White, E Tata, J Natukunda, D C. Ilouga, J P. Tyler

The Republic of Uganda aims to exploit its’ significant, un-developed iron ore resources to supply the required raw material for developing its’ iron and steel industry across all the stages of the supply chain. Large prospects of iron ore exists in Uganda in the eastern (Tororo) regions and southwestern (Kisoro-Kabale) regions of the country. The Kisoro-Kabale iron ore projects covers mineralisation in hematitic banded iron formation (itabirite) in the north-eastern Congo-Tanzania Craton; covering ten Iron ore prospects. The prospects include Kamena, Karukara, Nyamiringa, Kyanyamuzinda, Rugando, Katagata, Rwengongo, Kijuguta, Kihumuro and Katuna. High-grade hematite ore prospects in south-western Uganda have known grades ranging from 55 per cent to 68 per cent iron ore content with an exploration target estimated at over 500 million tonne (Mt). Small scale production of iron ore from the south-western regions provide raw material to existing steelmaking and direct reduction iron ore plants located in the Jinja and Iganga districts of eastern Uganda. Large quantities of iron ore and other steelmaking raw material, however, are required to be imported into Uganda due to the limited exploration and development of their own iron ore mining operations. A joint collaboration between the European Union (EU), the Department of the Geological Survey and Mines (DGSM), Ugandan Ministry of Mines in partnership with Australian drilling and mining consultancies, ADT Africa and Kalem Group as a EU funded project was undertaken during November 2022 and September 2023. Exploration and evaluation of the ten iron ore prospects in south-western Uganda was undertaken through geological mapping, drilling, assaying, and technical studies with the view to attract investment for the development of Uganda iron ore mining and steelmaking industry. The collaboration developed mineral exploration policy, guidelines and standards, an iron ore exploration manual, a geological data management policy, and to support the sustainable development of iron ore mining in Uganda through building the capacity of local Ugandan geology and mining personnel through the transfer of knowledge and expertise from experienced iron ore experts. The quantification of these resources is an important first step in assessing their economic potential and attracting mining investors. This paper presents an overview of the investigation program and the preliminary results as an important first step in attracting mining investors to this exciting new iron ore province.

Sep 18, 2023

The concept of Extreme Gravity is the latest in a series of innovations that has seen a re-introduction of gravity recovery systems into the milling operations of most gold mines. Traditionally, most gold milling circuits are designed around flotation and cyanidation requirements, with the gravity circuit being fit in where possible. Extreme Gravity takes the novel approach of optimising the circuit, in order to maximise recovery by gravity. In some cases gravity systems can achieve high enough recoveries to eliminate the need for chemical systems such as cyanidation or flotation. There are many advantages of such a system including low capital cost, reduced permitting, improved cash flows and much reduced environmental issues. There are a number of plants currently in operation which utilise this new methodology. The Muzhievo project has been an example of a recent turn key success achieving recoveries from 85 - 90 per cent. The details of this project are examined as a case study.

Jan 1, 2000

By I Grewal, B Klein

The Knelson Continuous Variable Discharge (CVD) is a continuous centrifugal gravity concentrator for high-mass yield recovery applications. It has four operating variables that enable control of mass yield, product grade and recovery namely: fluidisation water, bowl speed, pinch valve open time and pinch valve closed time. Plant testing of a pilot scale Knelson CVD6 was conducted to evaluate the effects of operating variables on mineral separation. The analysis of operating variable effects has provided a framework for the development of operating guidelines for the CVD.

Jan 1, 2001

By Perring CS, Barnes SJ

The nickel exploration boom of the late-1960s and early-1970s led to the discovery of numerous komatiite-hosted nickel sulphide deposits, associated with variably serpentinised bodies of olivine-rich cumulates. Subsequent research has shown the importance of volcanological processes to understanding the genesis of these deposits. Crucial developments have come through consideration of the fluid dynamics of magmas and magma-crystal mixtures, through observation of the dynamics and geometry of modern day basaltic lava flows, through application of theory and experimentation on the kinetics of crystal growth from magmas, and most importantly from extensive detailed field mapping of komatiitic sequences in the Yilgarn Block and elsewhere. From these studies has emerged a new integrated view of the volcanological setting of komatiite-hosted deposits, and a recognition that a complete continuum of deposit types exists. Nevertheless, komatiite associated magmatic nickel deposits generally fall into two overall types based on the nature of the sulphide ore. In the first type the bulk of the ore is either massive Fe-Ni-Cu sulphide or a variable mixture of massive sulphide and an ore characterised by olivine crystals in a continuous matrix of sulphide occupying between 30 and 75 per cent by volume of the rock (called Matrix Ore). Nickel grades of massive sulphide ore range from 2 - 20 wt% and those of the matrix ore generally fall in the range 1 - 5 wt% (average 2.5 wt%) Ni/Cu ratios of the sulphide fraction are generally >10.

Jan 1, 1996

By Woodhouse M, Drew GJ, Andrews DL

The Honeymoon nickel sulphide deposits are located 45 km south of Wiluna in the 2.7 Ga old Agnew-Wiluna greenstone belt in the NE of the Yilgarn Craton (Figure 1). Both disseminated and massive nickel sulphide deposits are present within the deformed and metamorphosed Honeymoon Well ultramafic complex and are hosted by distinctly different komatiitic lithologies (Gole et al, 1996). The deposit styles and host rock lithologies reflect formation in markedly different volcanic settings. Metasomatism has affected parts of the ultramafic complex, including sections of the sulphide deposits, and has had a marked impact on mineralogy and bulk sulphide compositions. The present indicated resource is 158 Mt at 0.71 per cent Ni in four deposits (0.4 per cent Ni cut-off, resources above 300 m depth, December 1995). This includes a massive sulphide resource of 2.5 Mt at 3.36 per cent Ni.

Jan 1, 1996