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By Messenger A. J, Miles J. G

A thermal neutron irradiation technique using a mCf neutron source has been developed and applied to thp.simultaneous determination of iron and aluminium (expressed as AI2O3) in iron ore fines (-6 mm particle size) on a moving rubber conveyor belt.While the determination of iron with this technique is based on the use of a NaI(TI) detector to monitor the characteristic prompt gamma rays (7.64 MeV) emitted by thermal neutron capture reactions in the iron, the etermination of AI2O3 is based on the use of a second Nal(Tl) detector to monitor the characteristic gamma rays (1.78 MeV) emitted after thermal neutron activation of the aluminium. The second detector is located downstream from the first. Although the speed of the conveyor belt has no direct effect on the iron measurements, it must not exceed about 3 m/min if good accuracy is required for the AI2O3 measurements. Consequently an auxiliary conveyor belt is required in order to avoid interference with normal ore processing.Dynamic trials of the technique, using 1500 kg samples of ore on a 460 mm-wide rubber conveyor belt moving at 1.7 m/min, have demonstrated that the method can achieve accuracies of 0.7% Fe and 0.1% AI2O3. At the present stage of development, it is recommended that lump ore be crushed to a particle size of 6 mm before analysis.In addition to iron and AI2O3 determinations, measurements of total moisture content and bulk density are possible. The determination of Si02 is also feasible, but a separate fast neutron source (e.g., Am-Be) and a separate gamma ray detector are required.

Jan 1, 1980

By Kajioka H, Nakamura Y

Na2CO3 is a powerful flux for both dephosphorization and desulphurization in oxidizing atmospheres. In order to study refining with Na2CO3 and the nature of the Na2CO3 slag itself, hot metal (4Kg) was melted in Al203 crucibles in a high frequency induction furnace and oxidised with oxygen under Na2CO3 slag. The behaviour of Na2CO3 at high temperature was observed by thermobalance. It was found that dephosphorization ceases in a few minutes and [,P] after refining is easily lowered to less than 0.010%. [%P] after refining is affected by [Si], [P] of hot metal, the refining temperature and the consumption of Na2CO3. Desulphurization also ceases in a few minutes but it shows curious behaviour, increase of [S], decrease of (S) and increase in sulphur lost, during the latter half of run. [%S] after refining is also affected by [P] of hot metal, the refining temperature and the consumption of Na2C03o

Jan 1, 1980

By G C. Bolton

Experiments were conducted to access the feasibility of removing zinc from lead slag by sulfation or chlorination or both. Gaseous sulfation with sulfur dioxide and oxygen released only 50 per cent of zinc even under the most severe conditions. Sulfation with concentrated sulfuric acid by a fast-leach process released 95 per cent of zinc while pug-roasting released a maximum of 78 per cent of zinc. Chloridization with NaCl in the presence of sulfating gas released 50 per cent of zinc, while direct chlorination with chlorine gas and oxygen released 85 per cent of zinc and 100 per cent of lead in a chloride condensate containing little impurities.

Jan 1, 1980

By Tsuchiya N, Takada Y, Okabe K

Alkalis in the blast furnace are removed mainly by the slag, Alkali removal by the slag was studied as a rate process of alkali vapor- ization from the slag flowing through the dropping zone in the blast furnace. The vapor-, ization rate of I:20 from CaO-Si02-A1203 IZ20 slag was- measured under various experimental conditions. An empirical formula for the vaporization rate was obtained as a function of slag basicity, temperature and surface area per unit mass of slag. A simulation model of IC20 vaporization in the dropping zone was evaluated using the rate equation when the true velocity and surface area of the slag was de- termined from a flow dynamic model of counter- current gas-liquid flow through packed beds. The influence of the dynamic conditions of flow, as well as the slag basicity and temperature, on alkali removal by the slag was estimated.

Jan 1, 1980

A mineral exploration manager's prime function is to provide a frame- work within which new mine production can be achieved. As part of this framework, the manager should know his employerb future requirements, and should direct exploration towards those particular mineral commodities which indicate satisfactory growth in consumption and price. Selection of these commodities can be assisted by studies of world reserves, and long term trends in price and consumption. Exploration planning is most efficient with an assured and reasonably uniform supply of funds.

Jan 1, 1980

Recovery of tin and copper from concen trates containing cassiterite, stannite and chalcopyrite was studied in laboratory-scale tests designed to simulate continuous operation of the matte fuming process in which tin is recovered as SnS fume while copper accumulates in the matte. Charges made up of 300g of mixtures of the concentrate and siliceous flux were added at a uniform rate in pelletized form to crucibles containing 300g of matte and 50g of slag (both of which were recovered from previous tests), while blowing through the matte with air or oxygen-nitrogen mixtures at a rate of 3 to 5 1/min. Accurate material balances enabled the effects of process operating conditions on tin recovery and sulfur utilization to be deter- mined. When operated correctly, the matte fuming process gave tin recoveries exceeding 90 percent in spite of wide variations in the copper content of the matte and in the operat- ing conditions. Deterioration of tin recovery was associated with undersaturation of the slag with respect to silica, and with high partial pressure of sulfur dioxide (greater than approx- imately 0.2) brought about by oxygen enrichment of the blowing air. The utilization of sulfur varied widely in low grade mattes. Copper in excess of approx- imately 10% promoted formation of SO2 by the commonly accepted reaction: FeS + 1-120 2= FeO + S02 while in copper-free and lower grade mattes a substantial fraction of the oxygen was consumed in the alternative reaction FeS + i 02 = FeO + z S2.

Jan 1, 1980

By Yanagase T, Nakamura T, Ueda Y

The possibility of removing the phos phorus and sulphur contained in steelmaking slag has been studied by observing directly through the microscope melts heated on Pt- filaments. After a CaO crystal was placed in the molten slag, distributions of P, S and other elements formed around the CaO crystal were determined with the aid of EPMA. The results indicated that a layer of 2CaO SiO2 is formed on solid CaO in CaO-Si02 melts. Then between CaO and the newly formed compound the molten slag tends to migrate through cracks. For higher Fe 2 03 contents, the layers of the compounds 2CaO.Si02 and 3CaO SiO2 formed around the CaO crystal are not continuous but look more like particles, which promotes the dissolution of CaO. Phosphorus in slag was found to be enriched in the 2CaOòSi02 layer. Phosphorus in the 2CaO SiO2 phase is not related to the primary slag composition, being about 5-7% P205.. Sulphur in slag,as well as the phos- phorus,was concentrated in the 2CaO.Si02 phase. Disintegration due to weathering observed for slags produced in these investigations appeared to be due principally to hydration of lime.

Jan 1, 1980

Lower Silesia Coal Basin/SW Poland/ is adjacent to highly gas saturated igneous massiv and since the beginning of this century more than 1500 outbursts have occurred in four existing mines, including 1295 in the most hazardous mine Nowa Ruda. Prevailing part of these are carbon dioxide/coal outbursts of ejected masses 50-5000 tonnes/av.200/t and gas volume released from 200 m3 to 800,000 m3 Magnitude of these phenomena is growing with the depth and for present extraction levels/ 375-753 m/ may be expressed by a formula: M = 4.25/H-400/, where M-masses ejected, t and H - depth of extraction, m. Regulations obligatory hitherto call for gas pressure measurements to be made in 3 m long and 42 mm dia. boreholes spaces not more than 25 m along the longwall face and taking sample of drillings for desorption testing. Criteria of a hazard are following: pressure higher than 30 kPa /for C02/ or 80 kPa /for CH4/ and desorption more than 1,44 cm3/g. These criteria are not satisfactory because many outbursts occurred in spite of low values of parameters measured and for several times no hazard was evident after very high values were obtained. Moreover, observations show that a huge majority of case outbursts occurred in coal weakened by local geological distortion.

Jan 1, 1980

The role played by lawyers in business has, in the course of the last 15 to 20 years, changed perceptively. This development has coincided with, and indeed has been a reflection of, the changing nature of Australian business, especially as the mining industry established its predominance in the Australian economy. The nature and extent of governmental regulation of business, too, has changed markedly. As a consequence, there has been a qualitative'change in the nature of commercial law practice. For the needs of business to be met, lawyers have had to develop specialist skills in new areas. Furthermore, there has been the emergence of the "in-house" lawyer, who increasingly plays a primary rather than a subordinate role in corporate law practice. There is no evidence to suggest that this trend, which is by now so well established, will prove to be ephemeral. Instead, with all indications pointing towards even greater governmental regulation of business activities, the intimate role of the lawyer in business seems entrenched.

Jan 1, 1980

By Sparrow G. J

The effect of polyelectrolyte flocculants on the de-watering of a tailing suspension of very fine clay was investigated.Sedimentation and filtration experiments were carried out in the labqratory to characterise the de-watering properties of the tailing. The results were used to calculate the effect of flocculant additions on the drainage and vaporation components of the de-watering of a clay suspension ponded on to a sand drainage bed.A flocculant increased the drainage rate, but decreased the volume of water that could be removed by drainage leaving more water to be lost by evaporation.The sorptivity values measured in the laboratory were used in the de-watering equation previously established for the tailing to estimate the effect of flocculant additions on the time required to de-water the suspension from 18.2 to 60 per cent solids w/w. The calculated de-watering times were found to increase or decrease depending on the volume of water removed by drainage and the prevailing evaporation rate.

Jan 1, 1980

By Stokes WPC

The capital requirements to develop a new mining venture are becoming very large; amounts of the order of US$1,000 million are not now unusual among estimates to bring new mining complexes into production. At the same time prevailing political and economic conditions are making it increasingly difficult to determine whether or not a project is likely to be viable. These factors emphasise the need to carry out thorough evaluation studies of all mineral prospects before making major investment. Additionally with the rapidly changing economic climate existing at the present time, it is becoming more and more necessary to carry out reappraisals of existing mines. An important function of both initial evaluations and reappraisals is to provide the operators of the mine with effective mining plans to ensure that the operation will meet its required economic targets. P, p M. tl p b, c v, s c 1 n 1 f r d c e c e u w Modern computers are well equipped to store and manipulate large amounts of data with speed and reliability. Their use in the mining field r is increasing and this trend serves to free f technical staff from much of the time consuming m and error prone hand calculations which were o formerly required in determining reserves and w carrying out all forms of mine planning. r Nevertheless, computers are not a universal

Jan 1, 1980

The Wongawilli system of mining has been in use for over 30 years and has enabled high production rates and acceptable extraction ratios to be achieved in seams less than 4 m in thickness. A modification of the Wongawilli system has been developed to permit the use of a continuous miner and mobile equipment to extract a coal seam 6 m thick. Following physical and mathematical model studies the new mining method is now undergoing field trials at Collinsville, Queensland. Progress of the field trials to date has achieved 99 per cent extraction of the upper slice by remote control operation of the continuous miner and established the feasibility of installing resin grouted wooden dowels in the coal floor to reinforce the coal septum. The method is explained in the text. Monitoring of the goaf gases as an early indication of spontaneous combustion has been incorporated in the mining cycle by placement of tubes in the goaf as the face retreats and continuous analysis of the goaf gases made at the surface by the National Coal Board tube bundle monitoring system.

Jan 1, 1980

By Goto T, Sato K, Mori N

A field investigation by making use of the seismic method has been carried out in order to comprehend the mechanism of rockburst and gas outburst and their predictive measures. The seismometers were so arranged both on the surface and underground as to enclose a mining panel. Seismic signals detected by the array were recorded and processed by the 32-kwords computer system. At present the system is available for analysing the source location and Richter's scale of each event and for visualizing the distribution of seismic foci and released energy at any mining stage. The magnitude distribution of events can be regarded as a comparable index of the seismic activities among mining panels. An analysis of the spatial density distribution of seismic energy in the mining panel can be useful to distinguish a highly stressed zone from stress released areas. The energy released curve or the rate of energy release determined from seismic data is also a good indication of the seismicity.

Jan 1, 1980

By Svensson J

The nickel segregation process is one of the methods for treating nickel oxide ores. In this process nickel oxide ores are heated together with a small amount of the carbonaceous reductants and halides to about 800-950¦C. The reduced nickel segregates onto the surface of the carbonaceous reductants in the form of metallic particles which are recovered by magnetic separation or flotation. Pilot plant tests for the extraction of nickel from nickel oxide ores have been made using nickel segregation process by means of a new roasting installation which is called the "Mechanical Kiln" (2.5m~ x 3m,') with autogenous heating. Nickel oxide ores containing about 2.5%Ni were mixed with 2.5%CaC12 and 2.7%coal, and continuously charged into this installation at the rate of 60kg/h in continuous operation for 30 days per trial.

Jan 1, 1980

The technological advancement in computing power and the increasing demand for information processing systems spread throughout many aspects of a corporation's business activities has revolutionised management information systems departments. This revolution is manifest in the proliferation of mini-computers and micro-processors as well as the planned or unplanned migration from centralised processing to distributed processing. The total data processing investment in people, hardware, software and telecommunications has reached a high level in many organisations. Therefore, the cost of inadequate planning or ad hoc growth of systems can be considerable. The concept of MIS systems planning has gained adherence in recent years; however, there appears to be a wide diversity in the effectiveness and quality of corporate systems plans. To be effective a systems plan must have the support and concurrence of executive management of an organisation. A disciplined planning approach to systems together ,with the involvement of senior user management as well as MIS management is necessary to develop a satisfactory systems plan that forms the basis of a corporation's data processing strategy.

Jan 1, 1980

By Carter A. C

The increasing need for alternative energy sources as well as the less clearly perceived but equally increasing demand for non-fuel minerals has resulted in extensive exploitation of near surface deposits. Many such deposits have depleted reserves and mining corporations are increasingly turning their attention to deposits, with thicker overburden, less competent materials, steeper dips and more complex structure. These deposits pose mine layout, geotechnical and equipment problems as well as the need for large outputs to achieve economies of scale. The paper describes the major problems and operational solutions for such deposits using continuous excavation and transport equipment.

Jan 1, 1980

By Cripps-Clark CJ, Deague TK

In order to study conditions under which SiO(g) may be formed in a blast furnace, equilibrium phase diagrams were constructed for the combustion of high and low ash cokes with oxygen-enriched blast and oil injection under conditions of high and low raceway pressures. Free energy minimisation techniques were used to calculate the composition of gaseous and condensed phases. Where coke ash is assumed, for simplicity, to comprise Si02 only, the coke can be comple- tely gasified, mainly to SiO and CO, under restricted conditions of coke to blast ratio and at temperatures greater than 1600 - 1650¦C, depending on system pressure. The formation of SiO(g) is partially suppressed by the introduction of alumina into the ash, because of the formation of solid and liquid alumino- silicate compounds. The minimum temperature for complete silicon gasification is raised to about 1700¦C. The results of the equilibrium calcula- tions are related-to actual raceway conditions. It is proposed that virtually all silicon in the coke ash is gasified such that, on condensation, it affects hot metal chemistry and slag properties and secondly, that the effects will be greater with higher ash cokes.

Jan 1, 1980

By Jimbo I, Ogawa O

A series of experiments was carried out to investigate the solubilities of copper, arsenic, antimony and bismuth in silica-saturated iron silicate slags under controlled oxygen partial pressures at 1200 and 1250¦C. Molten copper containing each of the above elements was kept in contact with a slag in a silica crucible for 24 or 48 hours to attain equilibrium. No me- chanical entrapment of metal into the slag was observed. The appearance of the magnetite phase in the slag was avoided by holding oxygen potentials at substantially lower values than that evaluated from available data on iron silicate slags. Solubilities of copper, arsenic, antimony and bismuth in slags were plotted against oxy- gen potentials and both oxidic and atomic types of dissolution were found, except in the case of arsenic, from the dependencies of the solubili- ties on the oxygen potential and from positive intercepts of regression lines when extra- polated to zero oxygen potential. The dissolu- tion of arsenic seemed mostly oxidic. Distri- bution coefficients of arseò,ic, antimony and bismuth between copper and slag are also Discussed.

Jan 1, 1980

Close spatial relationships between the deposits of the Etheridge Goldfield (23,000 kg of bullion) and various regional geological and geophysical features suggest that genesis of the ore deposits was a multi-stage process that started with magmatic and metamorphic stages in the mid-Proterozoic, climaxed with structural and hydrothermal stages in the late Palaeozoic and terminated with an oxidation enrichment stage in the Cainozoic. Acceptance of this hypothesis permits classification of the Georgetown region into areas likely to contain deposits of the Etheridge type and those unlikely to do so. Consequently there is little scop- for the discovery of extensions of this field. However, the stratigraphic interval between the source rocks of the Etheridge field and stratigraphically higher host rocks of the Croydon field may contain disseminated replacement gold deposits of the Carlin type. The potential host (pyritic carbonaceous, and locally dolomitic siltstone of the Candlow Formation) is locally faulted and cut by granitoids and the extension of a mineralised, long-standing zone of structural weakness.

Jan 1, 1980

By Robinson B, Ham B

Outbursts have occurred irregularly in the Collinsville Coal field since 1954 when an incident claimed seven lives. Further significant outbursts occurred in 1960, 1961, 1972 and more recently in the No. 2 mine in 1978. From the information collected over 25 years a comprehensive program to minimize the hazard of outbursts has evolved. Further developments of techniques to combat outbursts are being developed.

Jan 1, 1980