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By Gale D. C, Giles D. E, James Parker A

A zinc-lead-iron sulphide concentrate from McArthur River can be leached at atmospheric pressure in aqueous solutions with HCI, FeCl3, CuCI2, HCl/02 HC1/02/ CuCI2, Cl2, and CI2/CuCI2 to extract >98 per cent zinc, >90 per cent silver, and <15 per cent iron in 1-7 h at 95°. Galena is more reactive than sphalerite and is converted to lead chloride. Except for leaching with HCI, elemental sulphur is the the main by-product of the leach with little or no sulphate ion detected. The rates and products of these reactions are compared. It is recommended that aqueous slurries of the concentrate (50 per cent w/v) are leached at atmospheric pressure with Cl2 in the presence of copper(II) chloride, which accelerates the extraction of zinc. Hydrochloric acid is a by-product which is consumed bYJeaction with fresh concentrate in air at 60°. Copper is subsequently stripped from the leach solution and recycled by reaction with fresh concentrate at 100°. The separation, recovery, and electrolysis of zinc and lead chloride is outlined since this process would produce Cl2 gas which can be recycled and used directly in the leaching stage.

Jan 1, 1976

Operation of the tankhouse at the Electro lytic Refining and Smelting Company's works has been improved, but further automation is re- quired to cut the labour intensive nature of the routine tasks. Anode quality, both chemical and physical, plays an important role in efficient refinery practice, and impurities such as lead, antimony and nickel have required careful monitoring for smooth operation. The gradual replacement of copper blanks by titanium has markedly improved the quality of starting sheets, but problems have been ex- perienced with surface preconditioning of the titanium blanks. Polishing with emery paper proved to be a successful technique.

Jan 1, 1976

By Sheard SN, Tucker DH

Sampling procedures are an important aspect of geophysical exploration survey design. It is good practice that the selection of survey parameters ensures that the signal to noise ratio is optimised, while minimising survey cost.Sampling considerations for any geophysical method include the size of the target, scale of observation, aliasing associated with station and line spacing, nature and extent of overburden, and the presentation of data.As a guide to survey design, the specifics are discussed for three geophysical techniques in common use in mineral exploration; these include the magnetic method, transient electromagnetics and induced polarisation.

Jan 1, 1976

By Gadsden R. W

Physical and chemical requirements are defined for coke and ferrous materials used in modern high productivity blast furnaces operating in Australian conditions. Recent developments in the type of equipment required to be installed at the steelworks to ensure these requirements are described with illustrations from current plant practice provided.

Jan 1, 1976

By Warren R. P

When the original Mount Gunson joint venture, between CSR and United Uranium ceased operations in December 1971, an intensive ex- ploration campaign was launched to prospect for more ore in the Mount Gunson region. This campaign resulted in the discovery of the Cattle Grid deposit. A comprehensive sampling programme proved the existence of 4.6 million tonnes of ore, at a mean grade of 2.4% Cu, calculated at a 1.0% Cu cut-off. The planning and development programme that followed this discovery included not only the mining and metallurgical aspects of the exploration of the deposit, but also the en- vironmental aspects. Preliminary work included data collection with respect to meteorology, soil types, and existing flora and fauna.

Jan 1, 1976

Most mineral products exported from Australia to Japan, with the notable exception of coal, are purchased with weight and quality determined on discharge. Sampling of imported minerals for purpose of payment is done at facilities owned and operated by the purchaser. The selling shipper is represented at the weighing, sampling and testing by an independent inspection group who supervises the whole procedure. Sampling and testing are done within the provisions of the contract between the two parties, and normally in accordance with the relevant Japanese Industrial Standards (JIS). These JIS specify such things as the number and mass of increments to be taken; the practice of taking these increments; the method of determination of moisture, size distribution and quality. The JIS concerned with sampling however, are meant to be basic guides rather than rigid rules. Hence sampling and testing practice varies from plant to plant. In general Japanese sampling facilities and methods are elaborate and efficient. Opportunity is given for the discussion of varying technical viewpoints between consumer and shipper. However the resolution of differences and the implementation of changes normally takes a long time. Such discussions seem best reduced by prior contract agreement on reasonable specifications and detailed testing methods. The independent inspectors

Jan 1, 1976

Erosion of unprotected batters, spoil banks, slopes, and stockpiled material creates a multitude of environmental problems. Winds blowing across these denuded surfaces can generate dust clouds capable of depositing un- desirable particulate material a considerable distance from the source. Water eroding these areas continually exposes new surfaces which may be oxidized. Iron pyrites can be dissolved in the flowing water, resulting in the addition of pollutants to streams and water sources. Silting of water sources can also occur as a result of this erosion. Valuable topsoil can be blown or washed away. In addition, the after-effects of erosion leave a visual pollution which is more difficult and expensive to correct than to prevent.

Jan 1, 1976

This paper describes thick seam mining as practised at Westfalen Colliery, Redbank via Ipswich,in South Queensland. The author describes the develop- ment of the mine from conception to the time of successful operation and compares the two systems of mining adopted at the colliery.

Jan 1, 1976

By Greenwood-Smith R, Ellis W. K

A bulk analyser based on the gamma-ray resonance scattering process can be used to give a rapid and accurate measure of the percentage by weight of copper or nickel averaged over a large mass of sample, typi- cally 20 kg. It is shown that for a bulk sample containing about 3 wt.% Cu, crushing to -25 mm is the only sample preparation requited for analysis to within an error of about 0.06 wt.% Cu (errors quoted are one standard deviation). A comparison of bulk analyser and con- ventional assays on the same bulk samples can be used to estimate the sample preparation errors in the conventional methods. The squared deviations between bulk analyser and conventional assays are approximated by the sum of variances in sample preparation, conventional analysis, and bulk sample analy- sis. The sample preparation error was esti- mated as 0.26 wt.% Cu for samples crushed to -2 mm before splitting, 0.08 wt.% Cu for samples crushed to -0.35 mm before splitting, and 0.04 wt.% Cu for the average of 15 grab samples from bulk samples which had been crushed to -2 mm. The average copper grade for each group of samples was about 1.7 wt.%. Results are presented which show that

Jan 1, 1976

By A L. Withy

This paper is intended as a review from a planner's viewpoint, of the relationship between town and country planning, a primarily government activity, and the minerals industry, which, with the exception of coal, is a largely private enterprise activity. The paper first considers the nature of the system of planning in New Zealand, and the objectives sought by planners in relation to minerals are discussed. The reasons why these objectives are not generally being achieved are investigated. A final section deals with the gap between objectives and achievement, and suggests a number of ways in which this gap may be narrowed.

Jan 1, 1976

The major heavy industrial consumers of limestone are the cement, lime'and steel ind- ustries. Each of these requires large quantities of cheap raw material. Other ind- ustries such as glass and chemical manufactur- ing are significant consumers and agricultur- al and constructional activities provide additional demand which is usually more local in its occurrence. Limestone is widely dis- tributed throughout Australia but location in relation to major markets, and transport con- siderations render most deposits of no economic value. Among deposits which are sufficiently close to the major metropolitan markets many must be rejected as being unsuitable on grounds of quality, inadequate size for major.develop- ment, or other reasons such as environmental considerations. The major producing locations are sit- uated in a variety of geological environments. Most have limited reserves and require partic- ular attention to quality control. Planned extraction programmes based on detailed geo- logical investigations enable not only satis- factory grade control but also permit, by the adoption of appropriate quarry procedures, the use of sub-grade material, thus optimis- ing utilisation of the available reserves.

Jan 1, 1976

The thick coal seams of the South Maitland field are the only ones in New South Wales which have been worked extensively to heights beyond 3.8 m (nominal "thin" seam height). Under shallow cover only minor difficulties were experienced in developing first workings but later the widespread occurrence of incidents of spontaneous combustion and the growth of "creeps" extending over large areas gave the field its own peculiar problems. As the mines have driven under deeper cover extreme difficulties in forming development roadways have been experi- enced. Various methods have been adopted in an attempt to overcome the problems of the field.

Jan 1, 1976

By Hocking G

For some underground structures, the use of the plane strain assumption in stress analyses may not be justified. The finite element method and photoelasticity have been used to obtain complete 3-D solutions, but, for various reasons, neither method has found universal use. The boundary integral equation method (B.I.E.M.) can be more efficient and economical than the finite element method for 3-D problems involving large volume to surface area ratios. A B.I.E.M. program developed for calculating stresses and deformations in infinite elastic media has been used to determine the 3-D distributions of stress around T- and Y- junctions of circular tunnels in stress fields in which the ratios of horizontal to vertical stress are 0, 0.33, 1.0 and 2.0. For the T- junction considered,stress concentrations at the intersection are approximately twice the plane strain values. Except where horizontal field stresses are high, the stresses in both tunnels approximate the plane strain values at about two tunnel diameters from the point of intersection of the tunnel centre lines. The stresses in the two branches reach those for the corresponding plane strain, two parallel tunnel case two diameters from the point of intersection of thq inner tunnel walls. Very high stress concentra- tions occur in the pillar of rock between the inner tunnel walls near the point of intersection.

Jan 1, 1976

Differences in the assay results of replicate samples engender doubts on the reliability of ore sampling and of assaying procedures. An analysis of variance is a technique to estimate the variability at each level of the procedures. In an example, the variability of one-metre core samples was far greater than that of the assaying technique.

Jan 1, 1976

In the consideration of coal resources in this country one of the most neglected aspects and perhaps one of the most important is that of the geologic controls on coal formation. The composition, properties, thickness and distribution of the coal are all determined by geological factors. The extent and amounts of coal to be found in the South Auckland area have great economic significance, and are in the main considered here. Upheaval of the New Zealand geosyncline during the Rangitata Orogeny produced a system of parallel, north-south trending basement ridges and basins in the South Auckland area. A subtropical climate and relative tectonic stability allowed deep weathering of these mesozoic greywackes in the late Cretaceous and early Tertiary. Such weathering, markedly reduced the landscape relief, and provided vast supplied of very fine detritus for later sedimentation as the Waikato Coal Measures. This coal measure phase marked the beginnings of Tertiary  sedimentation in this region and represented a change from a sub-aerial weathering regime to a fresh water swamp environment.

Jan 1, 1976

The refractory industry in New Zealand is small, consisting of two main manufacturers - one at Huntly and the other at Kamo. Together these would have an annual refractory production of about 30 000 tonnes. The industries which use refractories include two steelworks, NewZealand Steel Limited and Pacific Steel Limited, the former is involved in continuous casting from sponge, iron and scrap steel and the latter is involved in ingot teaming from scrap steel and steel billets; One aluminium smelter, cement works, dairy companies, small foundries producing engineering requirements and many other small users. The New Zealand manufacturers produce refractories in thefire brick range, that is up to 50 per cent alumina content (ignited basis), based on indigenous raw materials and in the high alumina range up to 85 per cent alumina content (ignited basis) based on imported bauxites. All of the basic refractories high purity silica and high alumina low alkali refractories and many of the higher grade acid resisting refractories are imported.

Jan 1, 1976

Victorian brown coals occur in massive deposits, the quality of which is determined in the first instance by means of samples taken from exploratory bores. As a number of important utilisation characteristics are connected, not with the relatively homogeneous organic mass of the coal, but with minor components such as the ash content and particular constituents of the ash, it is necessary to know how bore samples relate to coal finally used in the process concerned. Tests are described in which the statistical parameters associated with bore sampling, operational sampling and sample reduction and laboratory procedures including a range of coal analytical methods were determined. These indicated properties where analytical errors were relatively high and where sample reduction procedures contributed substantially to imprecision in results. They also showed the effects of the non-homogeneity of brown coals with higher than normal ash contents. A further experiment explored the relationship between samples taken at various stages in the course of test boring, digging, and burning a defined 'block' of coal, and demonstrated an apparent increase in the proportions of adventitious mineral constituents as the 'intensity' of sampling Increased.

Jan 1, 1976

By Veal FL

Technological changes in Portland cement manufacturing during past years have reflected changes in the economics and availability of various types of fuel such as coal, fuel oil and natural gas. The industry consumes a sig- nificant quantity of both thermal and electric- al energy. The nature of the process and its chemical constraints does however permit the use of comparatively low grade fuels such as high ash coal and high sulphur oil. In striving for increased daily kiln outputs and conservation of energy, there is a worldwide trend towards the use of dry process plants. Wet process kilns of about 2 500 tonnes per day assume massive component sizes which present difficulties in manufacture, and transport to plant sites. Large capacity dry process units in excess of 8 000 tonnes per day are now in operation using precalcination techniques in which part of the fuel is introduced in the static preheater section ahead of the kiln while the balance is added to the kiln in a conventional manner. This technique has virtually doubled the potential output of any given single kiln.

Jan 1, 1976

The implementation of the Mining Further Amendment) Act, 1970, and later the Coal Mining Act, 1973, placed a requirement on the Department of Mines to accept an initiative in relation to coal exploration and coal mine development which does not apply in the case of other minerals. It is necessary to consider the exploration of the total coal resources of the State when considering exploration rather than one individual basin or deposit. If the level of knowledge of the coal resources in these basins is considered in relation to their potential for development it is possible to allocate broad scale priorities to their assessment. Due to the enormity of the task which involves a conservative estimate of in excess of 400 000 m of drilling to reach a broad reconnaissance level of understanding the involvement of industry with the Department in the exploration programme is necessary. The development of the coal deposits by mining operations must give consideration to a number of constraints apart from the simple availability of the resources. Principal among these are aspects

Jan 1, 1976

The three main types of iron ore deposits in Australia are bedded, massive and residual. Some character- istics of iron ore, important in its process behaviour, are related to its mineralogy which is a result of its geological history. World iron ore resources are extremely large but there are problems in quantifying re- serves, defined as that part of re- sources from which a useable commodity can be extracted economically. The relationship between the discovery and exploitation of iron ore resources and the process of industrialization is examined in historical and present day contexts.

Jan 1, 1976