Search Documents

By Falbo A, Quarestima S, Cozza C, Barbaro M

A new synthetic reagent of the mercaptobenzoxazole class, 5- methyl-2-mercaptobenzoxazole, has been studied. This reagent exhibits powerful selective collecting action towards copper sulphides present in several complex ores, as demonstrated both by laboratory and pilot plant tests. Industrial production is expected to start in the near future. The way this reagent reacts with pure chalcocite has been studied utilising in situ FTIR techniques, adsorption tests, electrokinetic potential measurements and Hallimond cell flotation tests. The FTIR studies have indicated the nature of the surface phase. Adsorption isotherms obtained by the rest method have revealed the quantitative evolution of surface products, permitting the determination of surface coverage at various reagent concentrations. The electrokinetic potential has been utilised to verify the stability of individual species in diverse concentration ranges. Correlation of the results obtained has provided indications on the chemical interaction of this reagent with the surface and on the surface Arrangement.

Jan 1, 1993

By G J JAMESON

The flotation cell has undergone a number of changes since the process was first introduced in Broken Hill in the early years of this century. The development of the mechanical flotation cell is reviewed, followed by a discussion of more recent developments such as the flotation column, the air-sparged hydrocyclone, the Wemco-Leeds cell, the Bahr and Deister columns and the Jameson cell.

Jan 1, 1992

By Grady B. V O, Cavell K. J, Ault A. R, Newman O. M G, Malcolm J. McPhersqn

Cyclic voltammetry (CV) has been evaluated as a technique for monitoring the quality of an industrial zinc sulphate electrolyte. The basis of the method involves measuring a change in the polarisation of the zinc nucleation reaction at an aluminium surface and relating this to the impurity content and/or the overall quality of the electrolyte. Specifically, the technique aims to be able to indicate and quantify detrimental synergism between impurity elements, something which traditional analytical techniques are incapable of providing. The technique has found some success with regard to monitoring glue additions in a range of metal electrolytes. It has been found that investigations by a number of workers over the past 15 years have produced variable and often misleading results due to the inadvertent use of commercial purity aluminium working electrodes. It has been shown that impurity elements in the working electrode can give rise to a range of responses that are not obtained when pure aluminium is used and that the response is variable due to the lack of surface homogeneity of commercial purity aluminium electrodes. Furthermore, it was demonstrated that previous detection limits reported in the literature were based on the presence of additional peaks in the cathodic scan and not polarisation effects. The results of this study have shown that when a pure aluminium working electrode was used, the method was incapable of detecting any change in polarisation for an electrolyte containing three common impurities (Co, Ni and Ge), at concentrations that would significantly reduce optimum electrolytic performance. A range of methods was tried to sensitise the technique, including raising the temperature and acidity, and adding antimony in order to induce some synergism. In all cases the polarisation response was unchanged. Consequently, apart from the commercialised application for monitoring additions of antimony and levelling agents such as glue, CV has very limited application as an electrolyte screening technique.

Jan 1, 1993

By van der Walt TJ, van Deventer JSJ, Reuter MA

Owing to their complexity, many metallurgical processes are difficult to model fundamentally, and as a result more attention has been focused on the use of artificial intelligence techniques to simulate these processes. In this paper recent advances in the use of neural nets to model processes not amenable to conventional methods are discussed. These include the application of a new modelling methodology based on the use of neural nets for the dynamic simulation of metallurgical processes, the use of conventional techniques in conjunction with neural nets to simulate gravity separation circuits, as well as the detection of gross errors in variable measurements by means of a neural net representation of the relation between measurement and constraint residuals.

Jan 1, 1993

By Griffin PT, Espinosa-Gomez R, Jameson GJ

Two major issues are to be addressed in the Copper Concentrator of Mount Isa Mines Limited. The first of these is the need to increase concentrator flotation capacity to increase copper recovery, while the second is the need to reduce the iron sulphide dilution to meet future smelting requirements. Extra capacity in the cleaner and retreatment sections of the concentrator have been identified as key target areas, with additional copper recovery of at least one per cent identified from plant trials. Extensive pilot plant tests have been undertaken to evaluate the performance of the Jameson cell compared to conventional mechanical cell and column circuits. This work has shown that Jameson cells present an opportunity to achieve the desired grade and capacity specifications at lower capital cost than available alternatives. This paper outlines metallurgical results of work undertaken in the Copper Concentrator, together with a summary of pertinent Jameson cell operating parameters investigated during the period.

Jan 1, 1993

By Bruington T, Perkins J, Hutton R

Natural resource developments are among the largest and most challenging projects taking place in the world. They involve capital intensive investment with long lead times and the management of geological, market, technical, operational and financial issues. A clear strategy is required to manage these projects and this strategy is underpinned by a development Philosophy.

Jan 1, 1997

By T GRAHAM-TAYLOR

A trend towards mining more complex and economically marginal orebodies, often combined with increasingly tight product specifications, increases the number of variables which need to be considered in production scheduling. Linear programming incorporating integer constraints can be used to create production schedules which are practical as well as mathematically optimum. Factors which can be taken into account include variability in product stockpiles, targets for head or product grades, production of different material types, production from different areas, production targets for loaders, and dependencies between mining blocks. For each schedule an appropriate objective for optimisation must be chosen. Examples of objectives are: to minimise or maximise grade variation; to minimise waste movement; and to minimise movement by front end loaders. A staged approach to the implementation of computer systems based on linear programming optimisation is Proposed.

Jan 1, 1992

By Sataev IS, Malinovskaja ND, Otrozdenova LA, Knodov NV, Maximov II, Kuznetzou OK

The technology of flotation recovery of silver from the residue of a zinc plant is described. The peculiarity of this technology is a preliminary pulp conditioning in sodium chloride solution in the presence of aluminum metal under high temperature. In this process the silver is converted to the metallic phase and then floated with the usual sulphydryl collectors. A variant using a combined technology is also described, in which before flotation is performed about 50 per cent of silver is leached. The total silver recovery with the combined technology comes up to 90 - 94 per cent.

Jan 1, 1993

By Szwedzicki T

In recent years substantial advances have been made in the field of geomechanics. Staff at the Western Australian School of Mines (WASM) are keen to see that such advances continue and that the mining industry in Australia can take full advantage of such developments in a timely manner. WASM views mining geomechanics in its broadest sense, as being concerned with the characterisation of the physical properties and the behaviour of earth materials (soil, rock and water) and openings as mining proceeds. Aspects such as, soil and rock improvement techniques for difficult site conditions and the rock breaking processes, are also considered to be an integral part of mining geomechanics. This paper indicates the inter-relationships between the various areas within the field of geomechanics and the strong reliance of all of these areas on site specific engineering geology.

Jan 1, 1992

A variety of algorithms and methods are being used by the mining industry today to map mineral resource for reserve estimation. The traditional methods including Polygonal, Sectional and Inverse Distance methods are relatively easy to understand and implement. They have served industry well for several decades and should continue to do so for the large bulk mineable deposits with very regular geometries with relatively small variation in grade.

Jan 1, 1992

By Kwitko G

Exploration for coal has been on-going in South Australia for the past 100 years. During this period substantial resources of low rank coal have been delineated throughout the State. These deposits are of variable quality often with high moisture, sodium, chlorine, sulphur and ash content and although generally regarded as suitable for use in conventional pulverised fuel boilers, many are difficult to utilise. The only operating coal mine in South Australia is at Leigh Creek where coal bearing shale was discovered by chance in 1888 during excavation of a railway dam near the township of Copley. Leigh Creek has had a very diverse mining history from the initial small scale underground mining through to open-cut mining utilising draglines and more recently large shovels and trucks.

Jan 1, 1992

By Lewis RW, Tullemans FJ, Gallo JB

Gold mineralization at Kidston occurs in a semicontinuous zone near the margin of a large, late Palaeozoic breccia pipe. The pipe is ovoid in plan, funnel-shaped in cross section and straddles a contact between Proterozoic metamorphic and granitoid rocks which are intruded by a swarm of late Palaeozoic acid dykes. Rock fragments within the breccia pipe reflect the enclosing country rocks and mix in various proportions to form gradational lithological domains. Most of the gold is free and is located in the breccia matrix and in a set of inwardly dipping sheeted quartz veins which kink around the pipe margin. Sulphide minerals, dominantly pyrite, occur as disseminations in the breccia matrix and as aggregates in the cores of quartz veins. Hydrothermal altLration is pervasive within the breccia and is most intense in areas with the highest percentage of acid dyke fragments. Sericite and carbonate are the main alteration minerals. An empirically developed genetic theory for the formation of the breccia pipe and attendant mineralization involves magmatic and post-magmatic processes associated with the intrusion of a granitoid body to a shallow level in the crust. Economic evaluation of the deposit relied heavily on the results of diamond drilling. Both polygonal and geostatistical reserves were calculated and found to be in close agreement. Geostatistical reserves are considered to more closely reflect the tonnes and grade achievable during mining. Daily geological mine routine is strongly biased towards grade control allied with the practical aspects of open-pit mining. Tonnage/ grade correlations between ore blocks geostat- istically generated from exploration diamond core results and ore blocks generated from high

Jan 1, 1986

By Morsky P, Kalapudas R, Natunen H, Virtanen M

The development of autogenous grinding modification in Outokumpu, known with the name 'Outogenius Comminution', was 'reversed'. At first the metallurgists studied and tested tens of years autogenous grinding in detail in full scale circuits at the concentrators of the company. After the final solution already had been found, also a pilot plant was built and now finally, research work is under way to develop a special laboratory method for testing the suitability of ores for 'Outogenius Comminution'.

Jan 1, 1993

By Holmes RJ, Sowerby BD, Watt JS

Major improvements have taken place in mineral and coal processing in the last decade. The development of nuclear on-line sensors that continuously analyse the material being processed has led to better control of metalliferous mineral processing and increased recovery of valuable minerals. The recent development of on-line techniques for analysis of coal is expected to be of similar Importance. Australian developments in on-line nuclear gauges are reviewed. These include systems for in-stream analysis of mineral slurries with comments on plant operating experience; on-line determination of ash in coal using low energy Y-ray transmission and pair production techniques; in-stream determination of solids weight fraction and ash content of coal in slurries with variable voidage; and on-line determination of moisture in coal, iron in high grade iron ores and sulphur in lead sinter.

Jan 1, 1986

By MJ SMITH

For the past 150 years, drilling and blasting has been an integral part of the underground mining industry in Australia. Ever since Busby's Bore was developed using black powder to supply Sydney with water, miners have been drilling holes, filling them with explosives and blasting the rock into a manageable size. The drilling was fairly straight forward but the explosives were always a mysterious commodity. It worked, but how and why? The explosives industry is now working much closer to the mining industry to dispel these mysteries and also to aid the advancement of explosive technology. This paper looks at the results of these advances in the form of explosives, accessories and blasting systems.

Jan 1, 1992

By JSrvinen A, Yll÷ E

At Cominco's Zinc Refinery at Trail, British Columbia impurities are removed from zinc sulphate electrolyte by a two-stage purification process using zinc dust. Copper, cadmium and thallium are removed in the first stage whereas cobalt is removed in the second stage. Cobalt removal kinetics are affected by soluble antimony and copper additions to the electrolyte. This study was focused on the kinetics of cobalt removal by zinc powder cementation. Experimental variables included copper and antimony concentrations, pH and temperature. Common organic additives employed in zinc plants were studied to determine potential interactions with the cobalt removal process. Cementation products obtained from laboratory experiments and plant practice were studied using SEM. A number of significant results were obtained: 1. Copper and antimony ions were sustantially removed from solution during the early stages of the cementation reaction (within the first 15 minutes). Cobalt cementation kinetics are slow and follow a first order kinetic regime. 2. A drop in the cobalt removal rates can be correlated with a rise in the Eh of the slurry. 3. Ligninsulphonate, Percol 351 and animal glue at levels of 2 mg/L significantly impede cobalt cementation.

Jan 1, 1993

By Rashchenko AF, Voiloshnikov GI, Elshin VV, Khomutov VV

The sorption method for the precious metals recovery fromsolutions and pulps are a perspective trend of modernhydrometallurgy. Russian gold mining industry uses thesemethods, anion-exchange resins being applied as sorbents. Theanion exchange resins allow effective recovery of preciousmetals, however, they have several drawbacks as compared withactivated carbons: high cost of sorbents; difficulties arisingduring treatment of pulps with complex ion composition;necessity of using titanic equipment and thiourea for gold elutionfrom loaded anion-exchange resin and its regeneration.

Jan 1, 1993

By Lawson E, Purkiss S. A R, Van Ashwegen p C

It is only in the past decade or so that industrial exploitation of biological resources and techniques has become regarded as a distinct discipline. Commonly referred to as Biotechnology, it embraces biochemistry, microbiology and the engineering sciences and is mainly aimed at the biological conversion of suitable raw materials into desired end products. The catalytic agents are more often than not bacteria although other micro-organisms such as fungi are used. The range of micro-organisms used is wide and the choice depends upon the desired end product, which in turn depends upon the metabolic attributes, genetically engineered or otherwise, of the cells. The metabolic diversity of micro-organisms has been applied to processes such as antibiotic production, food processing, brewing and chemical production, and of course extraction of metals from ores. Metabolic diversity is, to a certain extent, based on nutrition, which, in its simplest form, can be divided into energy source, carbon requirements and nature of the electron donor producing reducing power to the cells. The source of energy may be light, in which case the organisms are phototrophic (eg green plants, algae). The carbon requirements and reducing power may come from organic sources. These organisms are then called heterotrophic (eg man and most bacteria, including the well known Escherichia colt). However, there is a group of bacteria whose energy metabolism depends upon chemical redox reactions, use inorganic carbon (CO2) and obtain their reducing power from reduced chemicals such as metal sulphides. These are known as chemolithotrophs. They play an important role in mineral recycling in nature and are also ideal for extraction of metals from ores. This is because they are extremeophiles being acidophilic (grow at very low pH) and sometimes also thermophilic (grow at very high temperatures). These bacteria operate in such hostile environments that competition, or contamination, by other organisms does not occur. Extraction of metals from ores by chemolithotrophic bacteria is commonly referred to as biohydrometallurgy. Other related areas are bioadsorption of metals from dilute solution,- microbial treatment of metal contaminated wastes and removal of toxic chemicals produced or used during mineral processing. This paper basically reviews the work that Gencor has undertaken in the field of biohydrometallurgy and the advancements it has made in commercialising the technology, but also touches on certain long-term areas of research that are currently under investigation.

Jan 1, 1995

By Cloutier JY, Quinn P, LeClerc A, Dube G, Agar GE

Gold dissolution by cyanide requires the presence of oxygen which is usually supplied by sparging compressed air into the gold containing slurry. For those ores that contain certain obnoxious substances that consume oxygen, maintaining the required minimum level of dissolved oxygen can be troublesome. One of the most economical solutions to the problem of low dissolved oxygen, especially in plants that have air compressors installed, is to enhance the rate of oxygen mass transfer. The oxygen mass transfer rate was measured in a two phase system using two different sparger arrangements, and with addition of a frother that is known to reduce the bubble size produced by the sparger. The common sparger system was shown to be inefficient compared with a readily available but under utilised method of gas dispersion which introduces air directly below the reactor turbine. Transfer of this technology to an operating plant confirmed the beneficial effect of the improved sparger system. The addition of the frother did decrease the bubble size, but it also reduced the oxygen mass transfer rate.

Jan 1, 1993

The importance of proper planning, preparation, and execution of a steady state sampling campaign for metallurgical plant assessment must not be underestimated. Careful planning can increase the amount and reliability of information from an optimum number of samples and fully utilize available plant data. It requires specification of the data required, determination of run duration sampling frequency, the selection, modification and testing of sample points and cutters, as well as organisation and briefing of plant and sampling personnel. Preparation immediately prior to sampling, the conduct of the sampling campaign itself and procedures to handle the collected samples and information are discussed. Cutter design, fabrication and use are described in detail, and typical sampling situations, for ball mills, classifiers, pipes, launders, flotation cells and thickeners are considered individually. Measurement of pulp flow rate can often resolve difficult mass balance problems, and discussion of convenient techniques is included.

Jan 1, 1976