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By Standish N

The heterogeneous reactions of carbonaceous materials with oxidising gases are basic to all combustion phenomena and to many gasification processes. The carbon- carbon dioxide reaction at elevated temperatures (Reactivity) plays important roles in many metallurgical operations like iron blast furnace and ferro-alloys smeltings, zinc and lead smelting, alumina reduction, cupola operation and direct reduction processes. The stoichiometry but not the mechanism of the reaction between CO2 and carbon is represented by the equation (Boudouard reaction) CO2 + C 2CO (1) This reaction is more complex than that between carbon monoxide and metal oxides, which involves essentially a transfer of oxygen from the oxide to carbon monoxide to generate carbon dioxide without any change in gas volume, whereas the volume of the product gas of Equation (1) is twice that of the reactant gas. In the present paper an attempt has been made to review critically the reactivity measurements of various carbonaceous materials in carbon dioxide atmosphere. Steps in C-CO2 reactions, surface reaction mechanism, role of mass transfer on reaction kinetics, dynamic oxygen exchange reaction and rate equations and rate controlling steps are discussed. Various methods of reactivity measurements with their pros and cons are also presented. Effects of pertinent process variables on the reactivity of carbon are also described in detail.

Jan 1, 1986

Better quality at lower cost is today's formula for remaining competitive in a world market. For an integrated steel company, high quality low cost steel production must originate before the blast furnace. In 1979, when U.S. Steel initiated a Quality Management Program throughout its steelmaking operations, efforts began at the coal, ore and flux mines. The objective was to improve the quality and reduce the variability of the critical parameters for steelmaking raw materials, to get the blast furnaces, and subsequently the melt shops, under optimum control. The general details of U.S. Steel's Quality Management Program are discussed and how it was used to promote the desired improvements in steelmaking raw materials. Some of the outstanding results obtained by the cooperative efforts between the mines and the steel plants are reported. The lessons learned by U.S. Steel were through upgrading existing operations and facilities. These principles should now be applied to new projects and the benefits of good quality management should commence from the time new projects are Commissioned.

Jan 1, 1986

By Schmidt CG

Parameters affecting gold elution using the AARL process are reviewed and critically analyzed in an attempt to optimise metallurgical efficiency and minimise costs in both current and future carbon adsorption operations. Such factors as acid washing, column geometry, elution temperatures and pretreatment reagents are discussed together with eluant water quality and eluate flowrates. Hot acid washing of carbon prior to gold elution has many benefits. Besides improving elution efficiency when eluting with regional water, a hot acid treatment preheats the carbon without causing any gold leakage. Laboratory data indicated that hot acid washing reduces the mass loss of carbon during thermal regeneration. The eluate going to either zinc precipitation or electrowinning is also relatively free of troublesome impurities (organic contaminants and ferrocyanides in particular). Because of the chromatographic character of the AARL elution where an ionic strength gradient is used to inhibit the readsorption of gold, column geometry plays a significant role. While practical considerations and capital costs may restrain the length of the elution column, high length/diameter ratios are advocated in order to promote the plug flow of column eluate. From both a metallurgical and costing viewpoint, the two significant factors affect- ing the AARL gold elution are temperature and cyanide addition. High temperature and high reagent additions within prescribed limits will improve metallurgical efficiencies, but a balance between energy and reagent costs is required in order to minimise overall elution costs. As pretreatment reagents constitute a considerable portion of the total elution costs, both the addition and consumption of sodium cyanide must be carefully considered. Lower cyanide additions may be effective in certain instances, but the more practical use of 0,6 bed volume of a 2-3 per cent NaCN reagent containing 2 per cent NaOH is advocated. This is equivalent to an addition of 20-30 kg NaCN and 20 kg NaOH per ton carbon Treated.

Jan 1, 1986

Peko Mines, a Division of Peko-Wallsend Operations Limited (PWOL) has operated several small underground mines in the Tennant Creek district of the Northern Territory supplying ore to a central treatment plant. The Argo Mine is the most recently developed by Peko Mines. A magnetic anomaly was identified from low level airborne magnetics in 1960 and drilling, which commenced on the site in 1969, was halted in 1974 and resumed in 1980 following the rise in the price of gold. By mid 1983 a resource of + 200 000 tonnes of 12 g/tonne Au had been outlined and a decision to develop the resource was taken following the drilling of three further diamond drill holes which did not significantly alter the value of the resource. The small size of the orebody could not support the full capital cost of two shafts and a single entry mine plan was developed to extract the ore at a rate of 15 000 tonnes per month and to provide all the safety features, ventilation systems and services of a two shaft mine. In December 1983 a contract was let to Allied Constructions Pty. Limited (Allied) to sink and equip a 4.8m shaft to a depth of 410m and to convert the headframe and winder, which are leased for the life of the mine by PWOL from Allied, from a sinking to a production configuration. Shaft equipment designed by Hardcastle & Richards Pty. Ltd. (H & R) in conjunction with PWOL includes a skip/cage, counter- weight, and an auxiliary cage on rope guides, a sealed ladderway and exhaust air ducts.

Jan 1, 1986

By Baohm C, Barker T

There have been significant changes in the Australian mineral sands industry in recent years due to changing supply and demand conditions, new product opportunities and opportunities for rationalisation of operations. Earnings within the industry have typically been volatile and this has been reflected in the share prices of listed mineral sands companies. Apart from the effects of variations in the state of the economy on the industry, share prices have also reflected the extent to which a company's earnings volatility is due to capital structure, the relative proportion of fixed costs to total costs and the nature of th'- sales mechanism. At the time of writing, the high prevailing share prices for industry participants and the current outlook for the industry would suggest that the time is opportune for raising equity capital. The immediate outlook for the industry and its various product segments appears favourable but beyond this the usual uncertainties remain. The new tax environment will cause most companies in the industry to have to rethink their dividend and capital structure policies. Most shareholders will now be concerned to maximize dividend receipts and minimise exposure to capital gains tax. Companies in the industry that have relied fairly strongly on earnings retention to help finance growth in the past will- need to look to increased equity raisings in the Future.

Jan 1, 1986

This technical note describes a problem with WANG82, a ventilation network analysis programme. The problem was highlighted by Renison Ltd when using the programme on large, complex networks. Under certain circumstances the programme produced incorrect results or failed to converge to a solution.

Jan 1, 1986

Mineralogical analysis of a nickeliferous laterite from the Rockhampton region shows that the nickel is largely associated with the manganese wad and opaline silica. The laterite also contains an appreciable chromite content (about 12 per cent Cr2O,) although this tends to be poorly liberated.Leaching with hydrochloric or sulphuric acid, at atmospheric pressure at the boiling point is non-selective with respect to iron dissolution.The degree of dissolution increases as the acid concentration and retention time are increased; cobalt dissolution requires less aggressive conditions than does the dissolution of an equivalent amount of nickel.Leaching with sulphuric acid at elevated temperatures and pressures leads to a minimum amount of iron dissolution, is rapid, and requires a reduced acid addition rate. Nickel and cobalt recovery from the clarified leachate would be simplified because of the leach selectivity.Pressure leaching appears to be the most practical route for treating the Rockhampton laterite. The economics of processing would be made more attractive by the recovery of a chromium concentrate from the leach residue. This would typically contain about 45 per cent Cr2O, and could be used as a source of chromium chemicals.

Jan 1, 1986

By Blain CF

For all mineral resource-based companies, it is important to reach the right balance of investment between acquisition and exploration to allow the best chance of achieving long-term corporate goals. The Broken Hill Proprietary Company Limited (BHP) provides an excellent example of success from generative exploration and supports the belief that exploration can be justified, not only in terms of investment criteria, but also because it is essential to a company wishing to build a dynamic profitable growth path based on world-class deposits as cheaply as possible. BHP was incorporated in 1885 to mine a lead/zinc/silver discovery at Broken Hill. The Company has since gone through a steel development phase (1911-1965) and is now in a major phase of growth partly based on exploration success. This third phase was marked by decisions taken in the 1950's to search actively for mineral and energy resources above and beyond the requirements of the steel industry. The commercial successes of this period have been Bass Strait oil and gas, Groote Eylandt manganese, Deepdale iron ore, Gregory coal and Carnilya East nickel. In total at least 22 new resource discoveries have been made in the last 25 years, of which 11 have been developed and several are undergoing feasibility studies. A financial analysis shows that the real value of the returns seeded by discovery covers the real exploration cost many times over. Moreover, the major discoveries have had a spectacular impact on the growth and development of the Company. BHP's present exploration effort is directed towards geological targets which most frequently meet attractive financial criteria and also promote diversification from steel-related earnings.

Jan 1, 1986

Within the Mt Whaleback open cut mine the integrity of the final pit wall is achieved through careful rock slope design, use of rock reinforecement technology where marginal stability exists and use of controlled blasting techniques and excavation practices. By reducing the effective density of ANFO explosive within blastholes to around 0.2 glcm', and developing standard blast pattern designs for various rock types, blast damage to pit walls has been minimised. Accurate geological prediction is necessary for optimum blast design. Controlled blasting is undertaken where blasting occurs within 90 m of the designed final batter crest and hole by hole assessment of final limit blast patterns is undertaken before pattern charging. Shovels and trucks remove the bulk of blasted and dozed rock material, but due to the mine's variable pit wall slope configuration, bulldozer excavation of some critical design batters has been successfully Implemented.

Jan 1, 1986

Registrations for the Congress were 393 asdelegates and 200 as accompanying persons.The breakdown of registrations by countries isshown in Table 1.

Jan 1, 1986

The Sydney Coalfield, Nova Scotia contains extensive undersea longwall mining operations which are expected to continue well into the 21st Century. A long term research program has been initiated by the Cape Breton Coal Research Laboratory to investigate the full spectrum of problems associated with undersea mining and develop specific guidelines for use by the mine operator. At present, research is centred on the detailed evaluation of existing undersea sub- sidence guidelines, the identification and development of instrumentation capable of moni- toring seafloor subsidence profiles and the effective sealing of offshore exploration boreholes. In addition, work is also planned to examine in situ strata permeability changes occurring between the mining horizon and seabed and the feasibility of using artificial islands.

Jan 1, 1986

By Fabjanczyk M. W

A limitation to present theoretical roof reinforcement design methods is the inability to derive accurate and quantitative information about the roof rock condition and the action of reinforcement at various excavation stages. To obtain the information required to assess roof rock stability, detailed monitoring of the in-situ behaviour of reinforcement and roof strata is required. Reliable instru- mentation and techniques have been developed for use in underground coal mines to identify the geometry and magnitude of displacements occurring in roof rock and the forces generated in reinforcement. The use of such instrumentation allows an accurate assessment of the in-situ capability of reinforcement and the mode of reinforcing action developed. In-situ monitoring can supply data required for the practical design of reinforce- ment and assess the potential stability of current designs. The use of such data together with mine wide appraisal of rock and stressfield considerations, can allow roof reinforcement to be designed on the basis of a predicted roof Response.

Jan 1, 1986

By Watkins JR

The educational system is a dynamic; a flow resource that can be significantly shaped, changed and - refined by educationists. This paper analyses these various facets of geo- science education in Australia. The Australian educational philosophy is essentially a laissez- faire model, a free market approach without any real government or professional directive or stratagem. Students are therefore free to choose their own educational pathway dependent only upon their ability and the access to courses. Geological education at the tertiary level in Australia is described and critically analysed. There is a real need for a rationalisation of geological education in Australia, and this rationalisation should include not only the number of courses offered but should also aim to fully define both the philosophy and purpose of geological education and the accreditation procedures for the Students.

Jan 1, 1986

There is a link between the requirements of society and the determination of curricula in tertiary educational institutions. Mineral resources exploration provides a strong example of this link. The resources exploration business engages in scientific, engineering, commercial and management activities in an endeavour to discover economically extractable commodities. Most geoscience and geotechnical graduates are employed by the mineral industry for resource exploration and development. This industry comprises a wide range of employer groups which include the Bureau of Mineral Resources, CSIRO, energy authorities, State geological surveys, State water commissions and private companies. Such employers are variously charged with the task of understanding and utilising earth resources to the benefit of society. It follows therefore, that undergraduate education and post-graduate specialization should be directed towards meeting the needs of employer groups in the geoscientific and geotechnical fields. In the past the training of most Australian geologists has emphasised classical science. This type of training remains of primary importance in the early undergraduate years but there is a need for modern educators to recognise the increased desirability for the inclusion of geotechnical subjects in the curriculum. Modern geo-education should address four main sectors when deciding curricula:

Jan 1, 1986

By Reeve JS

Heap leaching is a low capital cost alternative to conventional processing techniques for gold recovery from areas that contain small gold particles in a porous host rock.For successful heap leaching the ores to be leached must maintain good permeability after being stacked into heaps so that the leach solutions can percolate evenly through them.The presence of clays, slimes or excessive amounts of fines can hamper the flow of leach solutions causing channelling and producing dormant or unleached areas within the heaps. This results in unreasonably long leach periods and poor extractions. In extreme cases the clays or fines completely seal ore heaps, causing leach solutions to run off the sides of t'he heaps rather than penetrate the ore.The Northern Queensland Company uses the Agglomeration Heap Leach technique (AHL) to overcome the difficulties associated with clays or fines. This technique involves cementing the fines, by using readily available binders, into a rigid, porous network that greatly enhances uniform flow of cyanide leach solutions through the ore heaps.

Jan 1, 1986

The methods used by the Anglo American Corporation for analysis of long-term metal markets and prices are described. The principal factors affecting the relationships between production costs and metal prices are analysed. These are firstly the type of market, - speculative or consumer commodity, free market or subject to price control; and secondly the rate of growth of demand for the metal. It is shown that virtually all metals will have relatively low rates of demand growth for the foreseeable future, due to market saturation, increased economisation, substitution and product obsolescence. Metal prices have a clear dependance on production costs, however forecasting future costs is by no means simple; amongst other things, account must be taken of changing exchange rates, inflation rates, and the potential for operating more efficiently. The paper concludes by giving brief assessments of the long-term future for aluminium, copper, zinc, nickel and tin.

Jan 1, 1986

By Bellairs P, Stewart JC

On 20 December 1983 at 8.40am blast- hole 57 of Blast RN177 prematurely detonated follwed by a violent deflagration of blast- hole 59 at 10.40am. The blastholes were 380mm diameter drilled in black pyritic Mt McRae shale. The blastholes were loaded with ANFO and primed. Blasthole 57 was stemmed and blasthole 59 was not. A poss- ible mechanism which could lead to such a detonation is described. preliminary tests showed the top 5m of a bench had the highest temperature which could not be influenced by a range of treat -ments. Small scale laboratory tests show- ed that zinc oxide (ZnO) and magnesium carbonate (Mg2CO3) inhibited the reaction. A series of tests using AN with and without inhibitors loaded into the collars of blast -holes drilled in the top 6m of the bench and unstemmed is described. An analysis of the time to reaction of the holes loaded with AN against temperature shows that the decomposition of the AN in contact with the black pyritic shale is probably a sulphuric acid catalysed react- ion. All the inhibitors tested can neut- ralise the sulphuric acid in the shale. 10% ZnO appears to be an effective inhibitor of the reaction providing the AN/ZnO (90/10) is kept out of contact with surface material whose temperature can be as high as 60¦C in summer. It is concluded that ANFO/ZnO (90/ 10) should be now tested in stemmed holes.

Jan 1, 1986

An ongoing research program into surface subsidence over Room and Pillar coal mining is described. A subsidence monitoring network has been established for one Room and Pillar mine in the West Moreton Coal Field of South East Queensland, at which pillar extraction is being conducted. The maximum measured subsidence to 28 January 1986 was 638 mm, with movement continuing. Analysis of the monitoring data with view to application of the subsidence pre- diction theory developed by Kowalczyk (1972) is discussed. The Kowalczyk theory provides predictions of subsidence depression, slope of surface, horizontal displacement, surface curvature and horizontal strain, for both the Partial and Total Settlement cases. The development of subsidence with time is also investigated and a preliminary analysis conducted.

Jan 1, 1986

The original design of the Bougainville Copper Limited (BCL) concentrator took cognisance of the constraints imposed by the topography, the need to minimise capital cost, and the need to allow for plant expansion which, it was known, would be necessary to maintain copper and gold production as head grades declined.At the same time as spare slots have been taken up with additional equipment, technological innovations have been embraced whenever there appeared to be a chance of improving the productivity ofexisting equipment, or replacing it with a more efficient alternative.There are many examples of this in the BCL concentrator in the areas of process control, process design, instrumentation, materials handling, equipment design and wear part technology.Current process developments also pursue the latest technology. The development of the Omnicone crusher, flotation control, tailings water reclamation, and the variable speed gearless drive on the No. 13 mill are prime examples.

Jan 1, 1986

By Nidagal V

This paper discusses the dewatering strategy adopted and the considerations and procedures required to incorporate a dewaterinq scheme into the Mt Whaleback mining operation. It concludes that in pit pre-dewaterinq has successfully allowed mining to progress below the standing water level with the minimum of disruption or radical change to the mining method. It is recognised however, that dewatering is not a static activity and there is a requirement for ongoing investigations and development. Pre-dewatering commenced in October, 1984. Purpose designed pumping trailers have been employed to minimise the loss of pump availability resulting from the frequent. need to remove and reinstall pumps when close vicinity blasts occur. To July, 1986, some 0.5 Mm' of groundwater had been pumped from the unconfined orebody aquifer. Mining has progressed to some 20 m below the standing water level without. any undue water associated problems. Ultimately, it is ,cheduled to extend some 300 in below the original water level in the West Pit. With the development of an increasing area of the mine below the standing water level, the influence of seasonal high intensity rainfall events, which had previously caused little concern, now need to be addressed. Pumping equipment has been designed to evacuate storm water at a rate consistent with mine production Considerations.

Jan 1, 1986