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By M. L. Free

Laboratory scale extraction of metals from heterogeneous materials such as copper ores is often performed using fine material to increase kinetics and reduce sample size requirements and costs. In contrast, commercial extraction is usually accomplished using much larger material sizes than are used in laboratory settings. The large size difference between laboratory testing and commercial application materials makes it difficult to use laboratory test data to accurately predict performance for commercial material. One solution adopted widely in industry is the use of large test columns. Large test columns cost considerably more to set up and run and take much longer periods of time to evaluate than laboratory scale tests with small particles. Consequently, from a cost and data collection efficiency perspective, the development of accurate scale up methods offers significant potential for saving both time and money. This paper provides details for a new approach to correct for scale-up phenomena in heterogeneous material processing.

Jan 1, 2007

By Zetti Gavelán

Globalization and the search for new ore deposits inevitably lead to investment in foreign markets. Investors need to be aware of the effect of their venture on regional, social and economic issues when they invest. Decades of detailed statistics from various sources can be integrated and analyzed to predict the social-economic impact of investment, thereby mitigating risk. To this end, the correlation among variables such as foreign direct investment into mining (FDIM), reserves, and socio-economic indexes is examined. The investigation focuses on South America from 1992 to 2000. Throughout the past decade, South America has benefited from capital investment from more developed countries. This huge investment by the mining industry has impacted the South American economies and can be measured directly using the FDIM. Other economic variables investigated include mining gross domestic product, direct employment, and human development indexes. The correlation is based on data compiled from the World Bank, international risk assessment agencies, the United States Geological Survey (USGS), and the information agencies of various South American countries. Initial analysis of the economic data suggests various expected outcomes. For example, foreign investors may disregard a measured, highly negative country risk in deference to the quality of its mineral resources. It is important to note that the standard measures of country risk published by investment analysts are not industry or investor-specific. In the case of the investor, the level of accepted risk is based on their managed investment portfolio. It is noted that arguments for level-playing fields may be the antithesis of globalization. The discovery and exploitation of ore bodies in a globalized environment necessitates the development of economic measures that standardize mining-specific risk variables and trends. The latest published information on the security of mineral investments in South America is investigated by integrating databases of economic, geologic, production, human indexes, and risk ranking.

May 1, 2003

By A. Banerjee, J. P. Weiler, J. Jekl, J. T. Wood, R. Berkmortel

"The work presented here is part of an ongoing project designed to develop predictive capabilities of the local mechanical properties, and thus, structural behaviour of a thin-walled high-pressure die-cast AM60B magnesium alloy component. This work focuses on developing correlations between process parameters and local microstructure. Numerical simulations of the die filling and solidification behaviour of the AM60B component were used to estimate local process parameters such as solidification rate, temperature gradient, filling velocity, etc. These estimated parameters were used to establish semiempirical correlations with measured VALUES (of the local microstructure measured in regions throughout the component of different solidification conditions. INTRODUCTIONHigh-pressure die-cast magnesium alloys are experiencing increasing use in structural automotive components. A strength-to-weight ratio comparable to steels and its ease of castability allow for these alloys to be utilized in such capacities as instrument panel beams, seat and door frames, and engine cradles, among others (Gjestland and Westengen, 2007). However, the current use of these alloys is limited due to variations in local mechanical properties. These local property variations restrict part designers to assume lower than actual properties, resulting in larger sections, thus diminishing the light-weighting advantages of magnesium alloys. If these local property variations could be predicted, part designers would be able to optimize die-cast magnesium alloy components and fully take advantage of the light-weighting capacity of these materials.The work presented here is part of an ongoing project aimed at developing predictive capabilities of the local mechanical properties, and bulk mechanical performance, from variations in local microstructure, and ultimately from local process parameters in die-cast magnesium alloys. This project, unique in its nature, is based upon the results determined from fifty sequentially cast AM60B magnesium alloy instrument panel beams provided by Meridian Lightweight Technologies (shown in Figure 1)."

Jan 1, 2012

By C. Blawert

In spite of various corrosion studies on HPDC AZ91, there is no clear indication which microstructure gives the best corrosion performance. The skin with its fine microstructure is sometimes reported to have the best corrosion resistance, but there is no clear definition of the skin. If the skin is the outermost part of the casting and nothing is removed from it, then it is contaminated and the corrosion resistance is low. If the outermost skin is removed (about 25 µm) then a better corrosion resistance can be obtained. However this does not automatically mean that there is no other region in the bulk of the casting which could have a similar or even better corrosion resistance. Indeed, the corrosion measurements including potentiodynamic polarization and long term electrochemical impedance spectroscopy (EIS) revealed a lower corrosion resistance of the original as-cast skin about 100 pm thick. The thickness of this region is more or less independent from the thickness of the casting section. The surface region is free from any dendritic grain growth which influences the amount and distribution of the 13-phase and therefore the distribution of the most important alloying element Al. This could explain the different corrosion behavior. Further reason can be found in the enrichment of some impurities such as Fe in the near surface.

Jan 1, 2006

By D. A. Beattie

Talc is a commonly encountered gangue mineral in metal sulfide flotation. Talc is naturally hydrophobic, resulting in high recoveries if polymeric depressants are not used to specifically reject this MgO containing mineral. We have studied the adsorption of a selection of polymers onto talc using a variety of techniques. Adsorption isotherms have been determined using ex situ depletion techniques and in situ ATR-FTIR spectroscopy has been used to determine adsorption kinetics. Adsorbed layer thicknesses have been determined for the polymers on cleaved talc surfaces using the AFM. The effect of the adsorbed polymer layer on the properties of the talc surface has been quantified through contact angle measurements and single mineral flotation tests. Distinct correlations are observed between the adsorbed layer properties and the flotation performance of the polymers. These observations are discussed with reference to the bubble-particle attachment process and the molecular structure of the polymers.

Jan 1, 2006

By K. Dinh

The Ground Penetrating Radar (GPR) has been studied for a long time as a non-destructive evaluation (NDE) technology for inspection of concrete structures. Currently, the most widely used technique for interpreting GPR data of concrete bridge decks is the one that based on the amplitudes measured at various interfaces such as asphalt-concrete, top rebar, or slab bottom. The assumption behind this technique is that a sound concrete deck should have the same reflection amplitude at these interfaces while any low number would indicate some sign of deterioration. Unfortunately, this assumption is not completely valid in most cases. As a consequence, the reported test results usually do not reflect real condition of concrete bridge decks in question. The main goal of this paper is therefore twofold: (1) to discuss the limitations of the amplitude analysis method, and (2) to propose a new model that interprets GPR data of concrete bridge decks. The model methodology is based on the comparison of GPR A-scans between two inspections, using the so-called correlation analysis. The results, indicated by the correlation coefficients, are then employed to develop a contour map that estimates different levels of deterioration. The model is then implemented to a case study in order to illustrate its methodology.

Aug 1, 2013

By John Shirokoff, Ladan Khaksar

"Cyclic polarization technique and also potentiodynamic measurements were applied to study corrosion behavior of 13% chromium steels in chloride containing environment. Potentiodynamic measurements were performed at 25 and 75 °C with 0, 10 and 20 g/l NaCl in 0.01 M hydrochloric acid solution. At the same time, the significant pitting parameters such as corrosion potential (Ecorr), pitting potential (Epit), protection potential (Epro) and passive current (Ipass) of cyclic polarization curves with various NaCl concentration were analyzed and compared to describe the corrosion behavior of 13% chromium stainless steel. Surface measurement techniques such as SEM and EDS were used for morphology and analysis of corrosion products. The results showed that both temperature and Cl- concentration had significant effects on corrosion behavior of 13% chromium stainless steel in acidic solution.INTRODUCTION Of all the corrosion resistant alloys (CRA) used in oil and gas developments, martensitic stainless steels (MSS) are some of the most common ones these days. These steels not only have the advantages of normal steels: high strength, cost-effective, easy to manufacture, available in a wide variety of product forms, but they also have good CO2 corrosion resistance at higher temperatures as a result of their 11% minimum chromium content. One of the most common types of MSS used in the oil and gas industry is 13% chromium steel. NACE and API standards both reference several different varieties of 13% chromium steels for use in oil and gas projects(“Corrosion Resistant High Cr Steel for Oil and Gas Wells,” 2013). All types of 13% chromium steels have about 12 to 14% chromium and other minor alloying additions, and can be placed into two general groups: conventional and modified. Conventional 13% Cr steels (13Cr) are those most common in oil and gas, some of which are CA6NM (UNS J91150), AISI 410(UNS S41000), and AISI 420 (UNS S42000). These alloys have excellent corrosion resistance when compared to carbon steels up to about 300°F (150°C) and are used for a variety of wellhead, tubular, and downhole components however they have very limited resistance to cracking in H2S (Vallourec Group, 2015). Modified 13% Cr (M13Cr) steels came from the need for increased corrosion resistance at higher temperatures, increased H2S cracking resistance, and increased yield strength above 85 ksi (586 Mpa) primarily for tubular goods and other downhole equipment. These features were developed by taking a conventional 13Cr steel and adding nickel (Ni), molybdenum (Mo), copper (Cu), and other alloying elements. M13Cr provides better corrosion resistance than 13Cr up to about 350°F (177°C), yield strengths up to 110 ksi (758 Mpa), and also improved H2S cracking resistance(“Corrosion Resistant High Cr Steel for Oil and Gas Wells,” 2013)."

Jan 1, 2017

By P. Gautier

Current feedstock in the aluminum hot forging processes can be used in the cast or extruded forms. The microstructural variation between as-cast and extruded materials could result in different mechanical properties and corrosion resistance for hot-forged products. Corrosion performances were examined for forged parts produced by two AA6082 feedstocks at different conditions using the following corrosion tests: open circuit potential, anodic polarization, salt spray exposure and corrosion fatigue. With the help of optical and scanning electron microscopes, metallographical investigations were carried out on cast-forged and extruded-forged materials before and after corrosion. The corrosion behavior of both materials was compared in both as-forged and aged tempers. Results show that there is no significant difference in the corrosion performance for final cast-forged and extruded-forged products.

Jan 1, 2011

By K. S. Raja, B. Pesic, S. Kshetri

"We investigated the electrochemical corrosion behavior of commercial permanent magnetic material (NdFeB alloy) in 0.1 M NaH2PO4 solution (pH:4.75) containing 0 – 1000 ppm of chloride at room temperature (298 K). The material was evaluated in magnetized and demagnetized condition with different surface preparations such as: Ni-Cu-Ni coated, uncoated (bare), and anodized (in fluoride containing ethylene glycol at 60 V for 15 minutes to form a thick nanoporous oxide surface). The nickel coated magnetic sample showed reasonable pitting corrosion resistance up to 100 ppm chloride addition. The uncoated samples showed passivity in chloride free phosphate solution. Chloride additions caused pitting and the pitting protection potential was equal to the corrosion potential with 100 ppm chloride addition. Demagnetization did not alter the electrochemical polarization. However, the passive film formed on the magnetic sample showed higher charge carrier density than the film formed on the demagnetized sample. INTRODUCTIONSintered NdFeB permanent magnets exhibit excellent magnetic properties such as large energy product [(BH)max > 450 kJ/m3], high saturation magnetization (1.6 Tesla), and high coercivity (1.2 – 2.08 x 106 A/m) (Sugimoto, 2011). However, the NdFeB magnets are prone to corrosion attack because of the presence of Nd-rich intermetallic phases, such as Nd4Fe (Jurczyk & Jakubowicz, 2000). Nd-rich and B-rich intermetallic phases are distributed in a matrix of Nd2Fe14B tetragonal ferromagnetic compound in a permanent magnet. Generally, several types of Nd-rich phases are present in the magnet with Fe:Nd ratios ranging from 1:1.2 to 1:7. The volume fractions of Nd-rich and B-rich (Nd1+xFe4B4 type) phases are about 10% and 7% respectively (Li, Ma, Li, & Wang, 2011) . Among these intermetallic phases, Nd-rich phase has the most active electrochemical potential. Therefore, dissolution of this phase occurs in preference to other phases by galvanic corrosion when exposed to moisture. Since Nd-rich phases are present at the grain boundaries of the Nd2Fe14B matrix, corrosion leads to disintegration of the magnet."

Jan 1, 2012

By C. Liu

Corrosion behavior of the stir zone in a friction stir weld of dissimilar A12024/AZ31 alloys was investigated in the immersion test in distilled water (pH=6) for different times. Microstructures and the distribution of chemical elements were analyzed by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). Due to the difference in the corrosion potentials between A12024 and AZ31, the AZ31 alloy constituent in the stir zone was susceptible to the corrosion attack in the distilled water. The corrosion attack was found to occur in the narrow region of the AZ31 alloy adjoining the A12024 region, where there was a low ratio of anode-to-cathode surface area. The corrosion attack became more severe in the AZ31 alloy regions with increasing immersion time. The A12024 alloy region in the stir zone of the weld was protected by cathodic reactivity due to sacrificial anode AZ31 alloy.

Jan 1, 2007

By Ham. Y. M.

The corrosion behaviour of Al-B4C metal matrix composites immersed in 2500 ppm boron-containing H3B03, 0.5 M K2SO4, and 3.5% NaC1 solutions was investigated. Effects of B4C particle volume fraction on the corrosion behaviour of composites were studied using potentiodynamic polarization and electrochemical impedance spectroscopy techniques. Scanning electron microscopy was employed to study the surface morphology of the material before and after corrosion. Results show that all materials investigated are more corrosion resistant in 2500 ppm boron-containing H3B03 than in other solutions. No appreciable corrosion was observed in boric acid and sulfate solutions in contrast to an obvious pitting in NaC1 solution for both base alloy and composites. The preferential pitting sites are the interfaces of Al/Fe intermetallics for the base alloy, and the A1/B4C interfaces for the composites. Increasing the volume fraction of B4C particles in the composite decreases its corrosion resistance of Al-B4C composites.

Jan 1, 2011

By F. Charette

The paper reviews recent investigations of the impact of corrosion on the performance of both plain and coated Swellex rock bolts. It addresses the problems associated with estimating and predicting corrosion rates of friction bolts, and based on field data it suggests an empirical relationship to predict corrosion rates. A review of the necessary qualities for a protective coating leads to recent experience with coated Swellex bolts that suggest that they can contribute to extending the useful life of Swellex bolts in potentially corrosive environments.

May 1, 2004

By W. Dingley, G. R. Hoey

"AbstractWear of six types of grinding balls was compared with and without corrosion inhibition in grinding Ni-Cu sulphide and hematite ores in laboratory ball mills. Forged steel balls (Rc 60 to 65) and three types of white cast iron balls (Rc 50 to 65) were susceptible to corrosive wear and two types of stainless steel balls [AISI Type 440C (Rc 65) and AISI Type 302 is; 35)] were relatively immune. The relative wear rates of the five types of hard balls (Rc 50 to 65) were dependent on the corrosivity of the ore. Ranking of the hard balls with respect to wear resistance was consistent for the sulphide and hematite ores in the presence of corrosion inhibition, whereas their ranking was different for the two ores in the absence of inhibition.The electrochemical potential of the grinding balls was measured during grinding and was found to be a useful measurement for assessing the susceptibility of an alloy to corrosive wear. Reduction of ball wear for forged steel and white cast irons with corrosion inhibition was concomitant with a shift of ball potential to less active values. Ball potentials in the presence of inhibition were indicative of non-corroding metal surfaces.IntroductionA PREVIOUS STUDY by the authors (1) showed that corrosion inhibitors - sodium nitrite, sodium chromate and sodium metasilicate - reduced wear of forged steel grinding balls by up to 49% in grinding Ni-Cu sulphide ore. Although the mechanism of wear reduction was not elucidated, it was concluded that corrosion must play a significant role in the wear of grinding media. Remark and Wick (2) of Battelle Pacific Northwest Laboratories have also evaluated corrosion inhibitors for the reduction of metal wear using abrasive and n on- abrasive te sting procedures. Their research was sponsored by 16 companies throughout the world. Preliminary results indicated that anodic inhibitors prevent from one-fourth to one-half of the loss due to corrosion."

Jan 1, 1977

By K. R. Nichol

The author points out that corrosion works 24 hours a day, every day. It is an economic reality that the cost of corrosion is inevitable and that its cost should be incurred in the least expensive way. An economic evaluation technique to properly assess its relative impact is the Discounted Cash Flow Method. Various remedial and corrosion control measures are available and these, when coupled with a planned corrosion control program, help reduce the cost of corrosion.

Jan 1, 1973

By W. Dingley, G. R. Hoey

"Thirteen Canadian sulphide ore mines were surveyed for corrosion control. The mines visited were a small, yet representative, proportion of this segment of the Canadian mining and metallurgical industry. Information on metallic corrosion and methods used to control it in underground workings and mills was gathered (a) by discussing corrosion problems with company personnel, (b) by examining equipment and structures during under-ground and mill tours, (c) by photographing corrosion sites, and (d) by collecting and analyzing mine water samples.The corrosion survey, which is summarized in the re-port, leads to the following general conclusions. Mine environments are corrosive, particularly when the mine w1a-ter is acidic. Because of a lack of good corrosion control measures, excessive deterioration of equipment due to corrosion occurs in mines. Mill environments are also corrosive, but in some cases good preventive measures are being taken to effectively control corrosion losses.Ways to reduce corrosion losses in sulphide ore mines and mills are discussed. The main areas for more corrosion research and development are selection of materials of construction, protective coatings, cathodic protection, inhibitors, equipment design, and mining and milling practices."

Jan 1, 1971

By R. B. McIntosh, S Ramanchuk

A brief description is given of the process used by Sherritt Gordon Mines Limited to recover cobalt metal from nickel-cobalt sulphides. A description of the equipment with the operating conditions is presented with an evaluation of the corrosion test results for various stainless steels and other acid resistant materials for the part of the process involving the sulphuric acid leaching of nickel-cobalt sulphide slurry under air pressure. SINCE 1954 the Sherritt Gordon ammonia leach process has been used at Fort Saskatchewan to recover nickel metal, copper sulphides and cobalt-nickel sulphides from nickel concentrate produced at Lynn Lake, Manitoba. 'To develop a process for recovering cobalt and nickel from the cobalt-nickel sulphides, studies were carried out in the Sherritt Gordon laboratory and pilot plant and, late in 1957, continuous acid leaching of sulphides was started in the refinery. In September 1958 the present equipment

Jan 1, 1961

By V. S. Sastri, G. R. Doey, R. W. Revie

"Different forms of corrosion, the various corrosive environments encountered, the mining equipment subject to corrosion and the methods to control corrosion in the mining industry are briefly reviewed along with the savings that could be achieved by corrosion control. IntroductionCorrosive conditions in mines and metallurgical plants, lead to deterioration and wastage of equipment and of materials. The cost of corrosion in the mining industry can be significant, and measures to minimize corrosion must be taken to reduce this cost(l-3). Although the data in Table I are twenty years old they indicate the significance of corrosion costs in four industrialized countries. The costs of corrosion in the U.S. metallic ores sector and in the Canadian mining industry are presented in Tables 2 and 3, respectively. Significant savings in the mining industry can be achieved by using corrosion control methods. For example, corrosion in the Canadian mining industry in 1991 cost $1460 million of which $97 million was avoidable. Indirect costs of corrosion associated with plant shutdown, lowered efficiency of equipment and overdesign are additional to the direct costs cited here."

Jan 1, 1994

By A. Rahimi

The smelting plant at Sarcheshmeh Copper complex commenced working with two reverbatory furnaces, four pierce smith converters, two anode furnace and one holding furnace having a known capacity of 420 metric tons of anodic copper according to the initial design in 1982 (1361 Iranian calendar). During the period from the commencement date up until now, the smelting plant has undergone changes for improvement and enhanced production by substituting holding furnace with another anode furnace, installing the fifth converter and utilizing oxyfuel burners on the ceiling of the reverberatory furnaces. According to the different operational processes in reverberatory, converter and anode furnaces different types of corrosion mechanisms and degradation can be observed in the refractories of copper smelting furnaces. In the case of reverberatory furnaces, the corrosion and degradation of refractories may be factors such as hot corrosion by melt, corrosion attack by the constituents of burning fuel, degradation of sidewalk exposed to mechanical stresses of the feed charge and the hydrostatic pressure exerted by the melt inside the furnace, all of which are due to the unique operational condition governing the reverberatory furnaces environment, i.e. burning fuel atmosphere, charge concentration and combination, furnace temperature, calm melt condition, etc. In the case of converter furnaces, the most likely corrosion and degradation of refractories may be due to the chemical reaction between the melt and degradation of tuyere zones due to sever movement of the melt and mechanical strikes of the punch rod. Also the most essential corrosion reaction occurs around the mouth of the converter because of the mechanical strikes by the cleaning device and thermal heat shock. Other parts inside the furnace are corroded due to the reactions between the fayalite slag and the furnace refractory. In anode furnaces the degradation mechanism is mostly related to the gaseous corrosion (penetration of natural gas or liquid gas inside the refractory structure due to the long period of reduction processes and refining stages. Finally another important factor responsible for destruction of refractories in these furnaces is the copper oxide slag together with the fume constituents of burning fuels.

Jan 1, 2004

By P. Hubert, J. P. Ildefonse, F. Qafssaoui, J. Poirier

Corrosion tests by corrosive alumina-lime slags were carried out on commercial high alumina bricks used in steel ladle linings and model refractories (with different raw materials : bauxite, andalusite, and different microstructures). Using (SEM) scanning electron microscope and (EDS) energy dispersive spectroscopy, microstructures of slag-corroded refractory interfaces were studied in detail. The monomineral and glassy phases, the composition of reaction products and chemical profiles were determined. A thermochemical analysis based on phase equilibrium diagrams has permitted to estimate the proportion and the composition of the high temperature intergranular liquid phase. These data were compared to the experimental microanalysis results. The viscosity of the high temperature liquids were calculated according to Urbain 's model and the relationship between the viscosity and the penetration of liquid phases were discussed. These theorical and experimental results were used to understand the complex phenomena of slag penetration and corrosion of andalusite and bauxite refractories at high temperature and to propose new ways of improvements for the formulation of high alumina refractories.

Jan 1, 2004

By I. Murray, N. Geoffroy

"Buried pipelines, tanks and other similar equipment are almost always present on large scale industrial sites, including in the oil and gas fields. However, as the proverb “out of sight, out of mind” suggests, it is easy to overlook proper maintenance procedures and simply assume that corrosion protection measures in place are working correctly. Unfortunately, this is not always the case, leading to significant environmental damage and loss of production. This paper describes several cases from various industries where buried equipment failed because of corrosion, sometimes with catastrophic results. It also presents various strategies, based on experience and new research, to help predict and prevent damage to underground metallic structures.INTRODUCTION Metallic underground structures are extremely common in industrial and commercial settings for numerous reasons. Burying pipes, tanks, wires and other similar equipment has numerous advantages: it provides significant protection from mechanical damage, frees up ground space that can be used for other purposes, requires little to no support structure and is generally more esthetically pleasing. However, this last benefit can also be considered the most significant disadvantage of underground equipment: becoming invisible and forgotten. While every engineer is aware of the importance of preventive maintenance, it is also human nature to somewhat forget about equipment that is hard to inspect and assume that everything is fine. This is unfortunately not always the case and failures in industrial settings can have extremely serious consequences. While economic aspects immediately come to mind (loss of production, cleanup cost, etc.), failure of underground equipment also results in an environmental and therefore public relations nightmare, especially in the oil and gas field. Leaks that would have been considered negligible in the past can now make national headlines and perfect reliability, while probably impossible to achieve, is now the goal of most companies. While environmental damage (real or perceived) is most often associated with leaks in the oil and gas industry, it can also affect the mining world. For example, the authors have worked on a project where a buried slurry pipeline had ruptured in the ground, causing a release of perfectly inert tailings. While the economic loss was low, the leak was reported in local media and caused a public relations problem."

Jan 1, 2017