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By C. T. Wiliams, John B. Bush, John Lamb

"THE TOWN OF HEDLEY is in the valley of the Similkameen River, about 200 miles east of Vancouver and 25 miles north of the International Boundary between British Columbia and the State of Washington. The main ore deposits are located on Nickel Plate Mountain, northeast of the town.The outcrop of the Nickel Plate system of orebodies is at an elevation of 5,900 feet. It was discovered in 1898 by prospectors and sold in the following year to the Marcus Daly interests of Butte, Montana. Production commenced in 1904 under the name of Daly Reduction Company. In 1909 control passed into the hands of the Hedley Gold Mining Company. Operation of the mine continued until 1930, when exhaustion of known ore reserves forced it to close. Upon the recommendation of Paul Billingsley (3) the mine was optioned by the 1. W. Mercer Exploration Company in 1932. Production began once more in 1934 under the name of Kelowna Exploration Company Limited, and was practically continuous until August 1955, when the mine was again shut down. The name of the latter company was changed in 1951 to Kelowna Mines Hedley Limited.The Mascot Fraction, a small wedge-shaped claim lying astride the Nickel Plate orebodies, was mined by Hedley Mascot Gold Mines Limited between 1935 and 1949. The geological setting and structural control of ore are essentially the same as in the adjoining Nickel Plate Mine.Total production from all operations on Nickel Plate Mountain to the end of 1954 was approximately 3,800,000 tons of gold ore, with a gross value in excess of $48,000,000.General GeologyNickel Plate Mountain occupies the gentle westerly dipping limb of an asymmetrical anticline, the axis of which trends northeasterly. The rocks are composed of a thick pile of Triassic limestone, limy argillite, and quartzite, -resting on a flattish floor of granodiorite near the base of the mountain. Associated with these sediments is a host of porphyritic sills and dykes of gabbro-diorite composition. In the mine area east-west brown soda-rhyolite dykes and north-south black andesite dykes crosscut all the other formations and the ore, probably following steep later fractures."

Jan 1, 1949

By R. A. Bergman

"Process descriptions are provided for the following ten plants that treat high-magnesia lateritic nickel ores (saprolite) by pyrometallurgical means: PT Aneka Tambang; Cerro Matoso S.A.; Falconbridge Dominicana C. por A.; Hyuga Smelting Company Ltd.; Larco (Societé Minière & Métallurgique de Larymna); Loma de Niquel; Le Nickel, SLN-Eramet; Nippon Yakin Kogyo Company Ltd.; Pacific Metals Company Ltd.; and PT Inco Indonesia.Flowsheets, equipment information,chemistry and production data have been compiledfor plants based on both information providedby the companies and on calculated massand energy balances.IntroductionNickel is of vital importance to modern society. Without it, we would not be able to enjoy many of the things that we take for granted, such as computers, airplanes and stainless steel appliances in our homes and workplaces, to mention a few.Nickel occurs in nature both as sulphide and oxide ores. Approximately 36% of the nickel reserves in the Western World occur as sulphide and 64% as oxide ores. Sulphide ores respond to concentration processes, whereas, oxide ores do not. Sulphide ores mined at 1% nickel can be readily concentrated to 10% nickel, whereas, oxide ores cannot be concentrated and therefore have to be processed as mined.Laterite ores are normally classified intotwo groups:1. The high-magnesia ores, saprolites or serpentines, are, as a rule, processed by smelting. The main reason for this is that the nickel replaces magnesium in the magnesium-silicate lattice. To be able to recover nickel, the lattice has to be destroyed. This can be achieved by smelting under reducing conditions.Acid leaching is also possible, but in this case, large amounts of MgSO4 or MgCl2 will be produced making it costly to regenerate the acid.2. The high-iron, low-magnesia ores are known as limonite. The nickel is relatively loosely bonded to goethite and hence can be recovered by selective reduction followed by ammonium-ammonium carbonate leaching. In recently developed processes, these ores are also being extracted by acid pressure leaching, with high Ni and Co recoveries.This paper focusses on the production of ferronickel and nickel matte from the highmagnesia ores."

Jan 1, 2003

By S. C. Livanou, S. P. Tampouris, E. N. Zevgolis

In ferronickel (Fe-Ni) production from oxidized nickeliferous ores, mechanical losses of ferronickel in the slag are reduced by magnetic separation. Slag from the electric furnaces (E/Fs) contains 0.16% Ni. Its magnetic separation gave a pre-concentrate with 0.76% Ni, weighing approximately 6.5% of the feed. Nickel recovery was 29.7%. This pre-concentrate was then treated in a second (concentration) plant. Concentration treatment involves screening, crushing and magnetic separation. A pre-concentrate with 0.76% Ni gave a magnetic concentrate with 2.58% Ni and a non¬magnetic part with 0.35% Ni. Smelting of the non-magnetic part without the addition of a reduction agent in a laboratory electric arc furnace, gave a ferronickel alloy with approximately 20% Ni and a slag with 0.16% Ni.

Jan 1, 2005

By Toivo Toivanen

The paper begins with a brief history of the nickel industry in Finland, and then deals with the introduction of the flash smelting process. The main part of the paper is devoted to nickel refining, which is studied under four main headings -grinding, leaching, electrolyte precipitation, and nickel electrowinning. Flowsheets are illustrated, and the equipment used is described. Analyses of the material in the various stages, from concentrate to high-grade nickel matte, are also presented. N ICKEL made its appearance in the Finnish mining industry forty years ago, when a nickel deposit was discovered at Petsamo in Lapland. Mond Nickel Co. received the concession for this deposit from the Finnish Government, and the Petsamon Nikkeli Company constructed a mine and a nickel smelter (1), the completion of which was prevented by the 1939 Winter War. The mine and smelter were, however, completed soon afterwards in spite of World War II,

Jan 1, 1964

By Rick Collins

Presentation Agenda 1.Sudbury Basin 2.Diamond Drilling 3.Planned Production 4.Safety 5.Timeline 6.Sustainable Development 7.Scope Elements 8.Progress 9.Delivery Approach 10.Owners and EPCM Roles 11.Contract Styles 12.Mine Systems & Technologies 13.Q & A

May 1, 2009

By J. W. Matousek

Since the late 1800s, copper-nickel ores have been mined and smelted in the Sudbury area. The Canadian Copper Company, the Copper Cliff ancestor of Inco Limited, commenced operations with a blast furnace smelter in 1888. Coal-fired reverberatory furnaces were added in 1911 and multihearth roasters in 1914. The blast and reverberatory furnaces smelted, respectively, coppernickel ores and ore fines until 1930, when a milling process and plant began operating to concentrate and separate the minerals of these two metals. Two reasons for this delay were: (1) the availability of high grade ores suitable for direct smelting; and (2) the difficulties in making the copper-nickel separation. The Mond Nickel Company, however, practiced flotation at its Coniston Smelter site from 1914 to 1930. A bulk concentrate containing six per cent copper and five per cent nickel was recovered from ore of 1.6 per cent each of copper and nickel. Gravity (table) and magnetic concentrates were also produced. Inco Limited (then The International Nickel Company) began laboratory-scale flotation tests on its ores in 1918. This work led, ultimately (in 1930), to the construction of the 7500 tonne-per-day Copper Cliff Mill, designed to recover separate copper and nickel concentrates. Its capacity was expanded to 11000 tpd in 1936, to 18 000 in 1940, and to 27 000 in 1942. Since 1971 it has operated to process only the bulk flotation products from other mills to yield individual nickel and copper concentrates.

Jan 1, 1999

By K. M. Mayhew, G. D. Barr, T. M. McCoy, C. T. Knilans

"Teck Resources Limited (“Teck”) has developed and extensively tested on a continuous basis the CESL Technology hydrometallurgical process for treating copper and nickel sulphide concentrates, including bulk copper-nickel concentrates. Copper, nickel and cobalt are leached efficiently into solution, utilizing CESL process conditions. Total precious metals including gold, silver, platinum and palladium are recovered from the residue stream via sulphur flotation. This paper describes the CESL Technology testwork on a bulk copper-nickel concentrate derived from Twin Metals Minnesota?s (TMM) deposits within the Duluth complex and evaluates the economic benefits (increased cash flow, increased revenue certainty) and investment criteria (capital cost, payback and cash flow) of incorporating CESL Technology into the staged development of TMM?s deposits.INTRODUCTION Mineral Processing and the Role of Hydromet in the Duluth Complex The Duluth Complex in northern Minnesota, United States (US), represents one of the largest undeveloped accumulations of copper, nickel, gold, and platinum group metals (PGMs) in the world, ranking second in copper and PMs and third in accumulation of nickel. The figure below identifies some of the larger known deposits within the Complex (see Figure 1). Copper, nickel, PM and PGM mineralization within the Duluth Complex is hosted by mafic to ultramafic intrusive rocks that are part of the overall intrusive complex.One of the mineral processing challenges of Cu-Ni-PM-PGM deposits in this Complex is the complicated, polymetallic nature of the mineralization1: copper occurs primarily as chalcopyrite and cubanite with minor occurrence of talnakhite; nickel occurs as pentlandite and refractory nickel oxide/silicates; iron sulphides are present as both pyrrhotite and troilite; and PMs/PGMs occur in both the sulphide matrix as well as discrete minerals. An additional challenge for the Duluth Complex is the ratio between copper and nickel; in most of the identified deposits, copper grade is three to four times greater than the nickel grade, which precludes the production of a simple bulk concentrate due to the lack of a traditional smelting market for a bulk concentrate of this character."

Jan 1, 2017

By C. Nikolic

A process utilizing ozone for the precipitation of cobalt from nickel sulphate liquors containing ammonium sulphate has been developed. Best results were obtained using nickel carbonate to maintain solution pH at 5.0 to 5.5. Work was performed both in column and stirred-tank reactors. Variables studied included neutralizer type and concentration, NH4+ concentration, temperature, Ni++ and Co++ concentration, per cent O3 in the O2 carrier gas, O3 input rate and agitation. The over-all rate of cobalt rejection increased sharply with increasing agitation and ozone concentration in the gas phase, reflecting relatively slow transfer of ozone from the gas to the liquid phase.

Jan 1, 1978

By J. R. Gill

Introduction The property and plant of the Falconbridge Nickel Mines, Limited, is situated about 13 miles northeast from Sudbury, in Falconbridge township, near the eastern extremity of the southern Nickel Range. As early as 1899 or 1900 some work was clone on this property by the late Thos. A. Edison, when a shaft was sunk through 80 feet of overburden to within a few feet of the ore-body. At this point quicksand was encountered, which made it impossible to continue with the equipment at hand. As a result, the activities of the Edison party ceased in this section. There was no further progress until 1915 and 1916, when an extensive diamond-drilling campaign, carried out by the E. J. Longyear Company, located the ore-body that is now being worked. The property was acquired by the present operators in 1928, and in September of that year active mining development was commenced. Features Influencing Design Of Plant Early in 1929 plans were prepared for a smelter and the necessary crushing and sorting plant. In spite of the general trend towards the reverberatory furnace as a smelting unit, it was decided to erect a blast-furnace plant. The limited tonnage to be treated, of course, influenced this decision to a great extent. However, it was known that, with the proper procedure, extremely favourable results, both economic and metallurgical, could be obtained in blast furnace smelting. The possibility of very low slag losses, the simplicity of operation by the elimination of roasting plant, fuel plant, etc., the ability to handle coarse feed, and the lower initial cost, were considered factors in favour of the blast furnace. Notwithstanding the fact that we might be called on to treat a certain amount of concentrate, it appeared that the blast furnace was the proper unit for the contemplated operation.

Jan 1, 1932

By Robert C. Stanley

The prominence of her mineral resources makes Canada a most fitting place in which to hold the Second Empire Mining and Metallurgical Congress, since in all probability the Dominion has more diversified mineral wealth than any other part of the British Empire. This paper is concerned with nickel, an important factor of Canada's mineral production. The richness and quantity of her nickel ores have made Canada the world's most important source of supply of the metal. Its history and diversified uses are, therefore, particularly interesting at this meeting. Early History Probably the first use of nickel by man was in the fashioning of implements, and later swords, from nickel-bearing meteorites, masses of metal that have fallen from time to time at many points on the earth's surface and which consist normally of iron carrying substantial amounts of nickel. Meteorites were perhaps the first metal known to man. The falling star, sought out with fear overborne by curiosity, was found to be a better stone than the earth-given, truly a boon from the gods. Archaeologists tell us there is good evidence that the ancient oriental peoples learned at an early date to make these stones into useful implements. The invincible blades of the great warriors of old, in China, Persia, and in northern Europe, were Heaven-sent, a fable which sounds significant of meteoric iron. Probably some of the ancient swords of Khorassan and of Damascus were of meteoric nickel-bearing iron.

Jan 1, 1927

By Robert C. Stanley

Early History Probably the first use of nickel by man was in the fashioning of implements, and later swords, from nickel-bearing meteorites, masses of metal that have fallen from time to time at many points on the earth's surface and which consist normally of iron carrying substantial amounts of nickel. Meteorites were perhaps the first metal known to man. The falling star, sought out with fear overborne by curiosity, was found to be a better stone than the earth-given, truly a boon from the gods. Archeologists tell us there is good evidence that the ancient oriental peoples learned at an early date to make these stones into useful implements. The invincible blades of the great warriors of old in China, Persia, and in northern Europe, were Heaven-sent, a fable which sounds significant of meteoric iron. Probably some of the ancient swords of Khorassan and of Damascus were of meteoric nickel-bearing iron (1). Fifty centuries were to pass before men learned to isolate nickel and add it to iron to produce the same alloy for much the same purpose. Meanwhile, man had found another natural alloy of nickel, known first to the Chinese as paktong, or 'white copper.' It was obtained from complex copper-nickel sulphide ores of Yunnan in southern China. This metal was brought by caravan through India into Bactria, a country north of the Hindu-Kush mountains, in what is now known as Russian Turkestan. The earliest specimen extant is a Bactrian coin attributed to 235 B.C. The rough reddish-white metal was also sent in the form of triangular rings to Canton, where zinc ores were added and the whole smelted to a more malleable alloy, also known later as paktong. This alloy was the forerunner of German-or nickel-silver. Specimens of this alloy, wrought into ornamental candlesticks and boxes, were brought from Canton to Europe by the East India Company in the early days of the China trade. Paktong was highly prized for its beauty as well as its eastern origin in far-away China. By 1760 the unwrought metal was imported into England for domestic manufacture.

Jan 1, 1935

By L. A. Melis, A. R. Marchbank, S. A. Webster

"Certain northern Saskatchewan uranium ores have a high content of nickel and cobalt which offer the potential for recovery as a by-product to uranium. A nickel/cobalt recovery process has been developed as a viable method of recovering a marketable concentrate from typical uranium raffinate solution.Impurities are first removed from the raffinate and the pure solution is then treated with sodium carbonate to recover a bulk nickel/cobalt carbonate precipitate for sale to a primary nickel producer. All contaminants of concern are removed to very low levels and the product is free of radioactive contamination with gamma emissions significantly below natural background. Cost estimates have shown that installation of a nickel/cobalt recovery circuit within a uranium process plant is economically feasible.The testwork that led up to the selected process is described along with recommendations for further investigations such as additional testing of hydroxide precipitation as a possible viable alternative to carbonate. The selected process is described and project economics are briefly reviewed.PROCESS TEST PROGRAMBackgroundExtensive metallurgical research has been performed over the years to develop a process for recovering uranium from the Midwest deposit in northern Saskatchewan. During the course of this research, a certain amount of information became available which suggested that recovery of nickel and cobalt from uranium raffinate could be economically feasible. It was decided to undertake a test program which would investigate methods of separating nickel and cobalt from radioactive and other metal contamination to permit production of a saleable product.Available technology suggested that three general approaches could be taken to recover nickel and cobalt. The first and simplest approach would be to selectively precipitate the impurities of concern, primarily arsenic, iron and radium, and then recover a bulk concentrate from the purified raffinate. The second approach would be to purify the raffinate and then remove cobalt from solution by solvent extraction producing pure nickel and cobalt solutions for further treatment. The third approach would be to precipitate all metals from solution and then selectively re-dissolve nickel and cobalt in ammoniac solution which would be further treated by solvent extraction for nickel recovery, leaving cobalt for further treatment."

Jan 1, 1993

By P. E. Weidmark

"CANMET InformationPART 1-Published PapersAsmis, H. W., ""The dynamic response of caverns in discontinuous rock""; Proc 22nd U.S. Symposium on Rock Mechanics, Cambridge, Mass, June 1981, 272-277; 1981.Austin , M.W., Bray, J.W. and Crawford, A.M., ""A comparison of two indirect boundary element formulations incorporating planes of weakness"" ; Technical Note; Int J Rock Mech Min Sci Geomech Abstr; 19:339-344; 1982.Barrett, J. R., ""Applying geotechnical theory to underground metalliferous mining""; Proc 1st Intnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of AIMMPE; 210-222; 1983.Barron, K., Wright, P.L. and Smales, T., ""Guideline s for the design of coal pillars in the No .4 seam at Mclntyre Mines Ltd ., Grande Cache, Alberta""; Proc 1st Intnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of A IMMPE; 559-578; 1983.Bauer, A., ""Wall control blasting in open pit mines""; Mining Engng; 34:155-158; 1982.Bieniawski, Z.T., "" Improved design o f room-and-pillar coal mines for U.S. conditions""; Proc 1st Intnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of AIMMPE; 19-51; 1982.Blackwell, G.H. and Calder, P.N., ""Practical aspects of wall stability at Brenda Mines Ltd., Peachland, BC""; 3rd Intnl Conf on Stability in Surface Mining; Vancouver, BC, June 1981; SME-A1ME; 3:573-608; 1982.Blake, W., ""Microseismic monitoring for underground stability "" ; Proc 1st Intnl Cont on Stability in Underground Mining; Vancouver , BC, August 1982; SME of AIMMPE; 272-294; 1983.Brawner, C.O., ""Stabilization of rock slopes"" ; 3rd Intnl Conf on Stability in Surface Mining; Vancouver, BC, June 1981; SME-AIME; 3:289-310; 1982.Bridges, M.C., ""Review of open stope mining in Australia""; Proc 1st lntnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of AIMMPE; 813-828: 1983."

Jan 1, 1983

By Christopher Andreae

Years before iron and steel works were established at Sydney, several thriving although short-lived iron works operated in Nova Scotia. These furnaces reflected the general nineteenth-century North American experience with iron works. At the beginning of the century, small furnaces struggled to supply local needs. Charcoal was the principal fuel and water powered most furnace equipment. By the end of the century, a few huge primary iron and steel works dominated production for Nova Scotia and the rest of Canada. Two sites achieved prominence in the nineteenthcentury Nova Scotia iron industry: Londonderry and Ferrona (Fig. 1). Londonderry, the larger and longerlasting of the two sites, is today a small village on the south flank of the Cobequid Mountains, about 30 km west of Truro. Prior to the establishment of an iron works in 1849, no community existed. At the peak of operation in the 1880s, however, over 2600 people were located there. The second site, Ferrona, today is a mere crossroads on the map, about 10 km south of New Glasgow. Following the construction of a blast furnace there in 1892, a small village grew up around the furnace. But once the furnace was blown out in 1904, the population gradually drifted away.

Jan 1, 1999

By Christopher Andreae

"Years before the present iron and steel works were established at Sydney, several thriving although short-lived iron work s operated in Nova Scotia. These furnaces reflected the general nineteenth-century North American experience with iron work s. At the beginning of the century, small furnaces struggled to supply local needs. Charcoal was the principle fuel and water powered most furnace equipment. By the end of the century, a few huge primary iron and steel work s dominated production for Nova Scotia and the rest of Canada.Two sites achieved prominence in the nineteenth-century Nova Scotia iron industry: Londonderry and Ferrona. Londonderry, the larger and longer-lasting of the two sites, is today a small village on the south flank of the Cobequid Mountains, about 30 km west of Truro. Prior to the establishment of an iron works in 1849, no community existed. At the peak of operation in the 1880s, however, over 2,600 people were located there. The second site, Ferrona, today is a mere crossroads on the map, about 10 km south of New Glasgow. Following the construction of a blast furnace there in 1892, a small village grew up around the furnace, but once the furnace was blown out in 1904, the population gradually drifted away.Early HistoryThe history of Nova Scotia's iron industry began in 1604 when Samuel Champlain became the first European to identify iron ore in the future province. Despite this early acknowledgment, iron was not smelted commercially in Nova Scotia for another two hundred years. Although primitive smelters of the period produced more iron than could be used locally, early settlers depended on imports of iron from Britain and the United States."

Jan 1, 1983

"In 1989, improved milling and recoveries resulted in a record production of 7 722 200 Ib Nb2P5 at the Niobec Mine. At the beginning of 1990, proven and probable reserves stood at 11 952 000 tons grading 0.65% Nb205. This year, the world steel market has slowed and as a result, niobium consumption is down. Consequently, production at the mine dropped 14% for the second quarter.IntroductionThe Niobec Mine is located approximately nine miles northwest of Chicoutimi, Quebec, (Fig. I). After ten years of production, the Niobec Mine is the only operating niobium mine in North America and the second largest producer of niobium in the world after Brazil.The Niobec Mine is a joint venture held equally by Teck Corporation and Carnbior. Teck Corporation operates the mine while Cambior is responsible for marketing and selling the niobium pentoxide concentrate (Nb2P5).The deposit was discovered in 1964 following an airborne radiometric survey in search of uranium. However, mining of the deposit did not begin until 1976. The initial production capacity of 1500 tons per day was increased several times to the present capacity of 2450 tons . The deposit is considered as an ample source of pyrochlore concentrate for at least 15 years at the present production rate.Niobium, also known as columbium, is a greyish-white metal used primarily as an alloy in various steels and other metals. The use of niobium in alloys heightens tensile strength and improves corrosion resistance while at the same time reducing the weight of the alloy. Niobium is also used in the fabrication of steel for the aerospace, automobile, and oil and gas pipeline industries. Although substitutes for niobium exist, their use often results in diminished performance and net cost increases."

Jan 1, 1990

By Sarah Belair, Gauthier Deblonde, Valerie Weigel, Alexandre Chagnes, Gerard Cote

"Niobium and tantalum are strategic metals for electronic and alloys industries. They are produced by pyrometallurgy and hydrometallurgy but most of the niobium and tantalum production processes are not environmentally friendly. For instance, in the hydrometallurgical route, niobium and tantalum separation can only be achieved by liquid-liquid extraction in the presence of hydrofluoric acid by taking advantage of the difference in niobium(V) and tantalum(V) speciation in fluoride-based media. Therefore, the environmental footprint of hydrometallurgical processes for the production of niobium and tantalum could be clearly lowered by replacing HF or NH4F by greener media such as alkaline solutions in which high solubility of niobium(V) and tantalum(V) can be achieved.The development of such new efficient and environmentally friendly hydrometallurgical processes requires a fine description of the physicochemistry of niobium(V) and tantalum(V) in alkaline solutions. Unfortunately, literature data show a huge discrepancy on niobium(V) and tantalum(V) speciation in such media. This paper gives a brief overview of the niobium(V)-tantalum(V) production processes and paves the way to the development of alternative processes in alkaline media by presenting and discussing recent advances in the physicochemistry of niobium(V) and tantalum(V) in these media.INTRODUCTIONNiobium and tantalum are strategic metals since they are used for the production of alloys and super alloys, capacitors and magnets in strategic industries such as electronic, aeronautics and automobile. The main sources of niobium and tantalum are given in Table 1."

Jan 1, 2016

By F. N. Smith

The carbon steel casings of Heat Recovery Steam Generators (HRSGs) in a co¬generation plant were found to have developed cracks that originated on the inside surfaces. The HRSGs receive hot exhaust gases from the primary Gas Turbines (GTs), which are fuelled with pipeline natural gas. The GTs was initially operating without any suppression of nitrogen oxides (NOx). After being in service for about two years, some of the cracks were found to have penetrated right through the 1/4 in. thick casings. The casings are fitted with insulation on the inside (hot gas side). Examination of steel samples cut from the casing walls revealed (i) fine cracks propagating through the steel from the inside surfaces, and (ii) the presence of relatively large amounts of nitrate ion on the inside surfaces. It was concluded that the nitrate ions originated from nitric acid that was condensing on the relatively cool walls of the casings behind the insulation. Nitric acid was formed in the GT exhaust gases by the combination of water vapour (formed from combustion of the hydrocarbon fuel and from moisture in the combustion air) and nitrogen oxides (formed from nitrogen and oxygen in the combustion air).

Jan 1, 2005

By Liangtian Liu, Tie Ou, Guangqiang Li, Chenghuan Yu

For stabilizing the production of containing nitrogen steels, a study on nitrogen absorption behavior of killed molten steel has been carried out by means of the RH vacuum device in which nitrogen was used as a driving gas. The results showed that there was an increase of nitrogen content in molten steel under vacuum processing but the rate of nitrogen absorption was slowed down by the surface active elements. Therefore, a kinetic equation for nitrogen absorption of molten steel with apparent first order reaction was derived by constructing a modified model in which the adsorption of closed surface site was taken into account. The experimental results confiimed that the calculated values agreed with the observed ones. This model is suitable for the prediction of nitrogen adsorption operation for containing nitrogen steels.

Jan 1, 2004

By B. Stettner, J. Asante, S. Abraham

The levels of nitrogen in steel produced in various metallurgical vessels vary significantly. For example, the tap nitrogen levels in steel produced in the BOF are around 4Oppm, as compared to 70-100ppm in both DC and AC electric arc furnaces. Given the pressing need to reduce nitrogen levels in steel to satisfy customer demand, IPSCO Inc. has gained considerable experience in controlling nitrogen levels in steel over the course of the last three years. Hence, a cost effective process has been developed through an intensive nitrogen control program from steel melting in the EAF through to the continuous slab casting stage. This paper describes the practices employed at each stage of the steelmaking process that have enabled IPSCO Inc. to reduce and control nitrogen levels in steel.

Jan 1, 2004