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By Y. Wang, J. D. Miller, C. L. Lin, Virginia Tech

Conventional flotation machines are typically limited to a particle topsize of 150-200 microns due to inherent constraints created by the pulp and froth phases. To overcome these limitations, a novel fluidized-bed flotation system called the HydroFloatTM Separator has been developed specifically for the purpose of floating coarse particles containing only small amounts of exposed hydrophobic minerals. Over the last decade, this technology has been successfully applied to industrial minerals with several full-scale units installed to recover particles up to and exceeding 3,000 microns diameter. More recently, sulfidebased test work has shown that this novel device is also capable of recovering metalliferous values at a grind size that is much coarser than currently used in industrial concentrators. In the current study, high resolution X-ray microtomography (HRXMT) was used to experimentally compare the degree of exposed grain surface area necessary to recover coarse particles using the HydroFloatTM technology to that attainable using a traditional mechanical flotation cell. The data indicate that exposed grain surface area is a critical factor for coarse particle flotation. For the gold-bearing sulfide ore examined in this study, the HRXMT data suggest that near complete recoveries of coarse (850x500 µm) multiphase particles containing as little as 1% exposed grain surface area were realistically attainable using the HydroFloatTM technology. As such, this new technology may offer a unique opportunity for increasing concentrator capacity by increasing the primary grind size needed for rougher/scavenger separations.

Jan 1, 2016

By W G. Brese

The attention of the world is being focused on the spectacular rise of elemental sulphur production in Alberta. In the short space of a decade, production has increased from less than 10,000 long tons, in 1952, to al-most 1,000,000 long tons in 1962. Moreover, 1963 sulphur production is expected to rise by 50 per cent to approximately 1,500,000 long tons, and further increases are forecast for ensuing years. The reason for this dramatic in-crease in elemental sulphur production, particularly in the last year or two, is that Alberta elemental sulphur is recovered in association with the production of sour natural gas. When very large volumes of natural gas began moving to U.S. markets in the latter part of 1961, the resultant increase in sour gas production led to a marked increase in the production of sulphur. Consequently, Canada, mainly on the strength of sulphur produced in Alberta, will soon become the second largest producer of sulphur in the Free World

Jan 1, 1963

By J. E. Nesset

"I had been requested earlier this year by MetSoc, our sister society of CIM, to contribute a chapter on technical developments in Canadian mineral processing over the past 50 years to their 50th Anniversary volume. Accepting the challenge of assembling such a chapter seemed at first a reasonably straightforward task, until one realises that the list of contributions by Canadians to mineral processing over this period has been more than just significant. It turns out to have been an extraordinarily fertile time for innovation and impact for Canadian-based technology. The list is necessarily a subjective one, however I had no trouble identifying twenty technology developments that are clearly outstanding, and there are undoubtedly others. As much as possible, I approached the individuals themselves who played key roles in each technology and asked that they tell the “story”. Without exception, all who were invited accepted eagerly and delivered more than I had hoped for. The technologies have been grouped into those that are truly Canadian innovations, such as the Knelson gravity concentrator and the McGill gas dispersion sensors in flotation, and technologies where Canadians and Canada played a very significant role in their success and implementation, such as AG/SAG grinding and ion-beam surface analysis. Also included are what may be termed technology transfer initiatives and institutions that have risen to a world class level, such as SGS Lakefield and the Canadian Mineral Processors Society of CIM. The challenge is now for the coming generation to continue this record of innovation and contribution to the industry, and that includes the (mostly) Canadian mining and metallurgical companies who have taken the longer term view and supported many of these initiatives, through their critical early years, with both financing and project sites for these ideas. Let us hope that the current trend of mining company globalization will not dampen their enthusiasm to participate. This plenary presentation will highlight many of these technologies, the individuals behind them, and their significance to the mineral processing industry."

Jan 1, 2012

By W. B. Dingle

"IntroductionMANY PAPERS presented on developments in the Canadian Petroleum Industry •during the past few years have commenced with this general sentence: ""The past year has been a record •one for the oil industry in Canada, with new records being set in nearly all phases •of exploration and development ,activity"". This sentence applies equally well to 1951. It is not possible to outline all the details of the broken records in exploration, development, and production but general comparisons can be made. There are several significant developments that have stolen the spotlight during 1951, some of which were foreseen in 1950 and some which were not. Among the high-lights were the following:(1) The greatly •expanded activity in the search for gas, which was touched off by the new Alberta regulations covering gas leases and reservations.(2) The discovery of commercial oil production in the Williston basin of North Dakota and Manitoba, which will have far reaching effects on Canadian oil.(3) The greatly increased activity in northern Alberta, northwestern British Columbia, the southern Northwest Territories, Saskatchewan, and Manitoba.(4) The new discoveries in the general central Alberta area.(5) The granting •of a permit for an oil pipeline to the Pacific coast.(6) The arrival of Western Canadian crude in central Ontario.(7) The number of new refineries completed, commenced, or proposed.(8) The present •and proposed expansion in the petrochemical industry.Most of the remarks made on various exploration and development •activities will refer to Western Canada operations, primarily because the greatest •activity and the most significant developments have been there. Eastern Canada exploration and development operations were at a slightly higher level than in 1950."

Jan 1, 1952

By Jon R. Maki

"EVTAC, an iron ore mine in Minnesota, had trouble meeting the customer’s pellet silica requirements. In addition, the mine plan was moving towards a lower grade ore and funding was not available for plant improvements to compensate for the change in ore or improving quality. Small changes to optimize various processing equipment resulted in significant improvements in both quality and productivity; for example, productivity on one mill line increased by 10% while producing lower silica concentrate. This paper will provide the methodology that allowed EVTAC to improve quality and productivity through process optimization with little capital investment.INTRODUCTION EVTAC, an iron ore mine in Minnesota, had trouble meeting the customer pellet silica requirements. In addition, the short-term mine plan was changing to a lower ore grade. Because of limited funds, EVTAC did not have the capital for investing in the plant to compensate for the ore change or to make improvements to lower product silica levels. Small changes to optimize process equipment resulted in significant improvements in quality and productivity; for example, one mill line feed rates increased by 10% while also producing a higher quality concentrate. These changes were sufficient enough to allow the mine to lower the target ore grade beyond their initial goal. At one time, a $3M flotation facility was considered as a way to meet quality with the new ore grade. However, the process changes were able to accomplish the same silica reduction with roughly a $50,000 investment in VFDs for sump controls. This paper will discuss some of the modifications that allowed EVTAC to meet the quality and production objectives with little capital investment. It also discusses the methodology used to make these process improvements."

Jan 1, 2014

This paper details a brief history of the Australian gold industry from the 1980s gold boom to the present day, highlighting an industry characterised by innovation in plant design and junior companies prepared to "have a go", in contrast to the conservatism of many larger mining companies. Design flexibility, the innovation of new processes, the preparedness to exchange "process know how" and technology singularly differentiated the gold industry from other sectors during the 1980s to the present. The introduction of two stage crushing, semi autogenous (SAG) milling, and pebble crushing, mill innovations, carbon in pulp (CIP) and carbon in leach (CIL) and the North Kalgoorlie screen etc were all exciting changes in the industry.

Jan 1, 2011

By P. Hajiani

"It has been shown that the economics of the hydrometallurgy of a rare earth process depend upon the amount of acid needed to extract the metal per unit mass of the ore. In this paper, we show how to save a significant amount of acid treating a low grade ferrocarbonatite and extracting +99% constituent REEs. In order to save the acid, the alkali earth metals, originated from gangue minerals were removed prior to REE leaching. Moreover, the operating conditions of leaching reactor are optimized to leave iron behind and to leach REE selectively and effectively. Consequently, the hydrochloric acid consumption per ton of ore drops significantly compared to other processes.INTRODUCTIONThe viability of an extractive metallurgy process of rare earth elements (REEs) to produce an intermediate mixed concentrate depends upon a low-cost simple flowsheet (Bogner, 2014). It has been known that regardless of the mineral, the acid consumption is intimately associated with the operational cost (OPEX) of any REE project, particularly when the initial REE grade is low. Besides acid, the other reagents consumed in the process impact the OPEX. This makes minimizing acid consumption in an REE method a critical priority. The acid consumption in different projects has been reported to be equivalent of 100 kg to 1000 kg HCl (100%) per tonne of ore (Average: 500 kg/t HCl 100%) (Bogner, 2014). This value is strongly correlated with the grade of REE in the ore and therefore in the pre-concentrate.Previously, it has been stated that the Montviel flotation concentrate requires about 300 kg HCl (100%)/t ore to attain +99% REE recoveries using direct leaching (Yu, Verbaan, Pearse and Britt 2013). Hence, for an ore feed rate of 2500 t/d ROM, a large acid production plant (744 t/d HCl 100%) would be required for acid leaching of such concentrate. The equivalent Chlor-alkali plant is estimated to cost M$ 150 (CAPEX) and may require 100 MW power. Therefore, there is a necessity to improve the extractive hydrometallurgy and to reduce the acid consumption significantly."

Jan 1, 2016

By I. M. London, G. P. Hatch

The Canadian Rare Earth Elements Network (CREEN) was formally launched at the Rare Earth Symposium at The Metallurgy and Materials Society of CIM (MetSoc) Conference of Metallurgists in October 2013. CREEN is an industry-led, multi-stakeholder network focused on providing collaborative solutions that will advance Canada’s REE sector to produce a significant proportion of the global production of separated critical rare earth products by 2018. The Network is industry driven by companies with REE projects under development and supported by universities, engineering firms, national and commercial laboratories, and government. CREEN aims to accelerate the development and delivery of timely solutions to technical and economic issues specifically facing Canada’s emerging rare earth sector. It will facilitate partnerships with other national and international organizations to leverage existing research initiatives. It will also support training and education to ensure that the needed qualified human resources are available to achieve the sector’s goals. CREEN membership spans the full rare earth supply chain and technical support organizations, from prospective producers, advanced project developers, national and commercial laboratories, engineering consultants, university researchers, and other innovators. This paper provides an update on CREEN's developing networking and project develop

Jan 1, 2014

By B. H. Weber

"Industry generally has become noise-conscious and is realizing that damage to the human ear is expected to become more costly than any other compensation. Noise control has been recognized as a necessity and, fifteen years ago, in co-operation among different countries, inter-national organizations were set up to co-ordinate measures against dangerous noise and the development of silencing devices began. Rock drills for underground operations were particularly scrutinized because of the explosive nature of the noise developing from air escaping from exhaust. This paper describes the results and the present stage of development in the reduction and control of noise on rock drills, with special application to their use in mines."

Jan 1, 1970

By H. Miki, S. Wheatley

The addition of precipitated silica greatly enhances chalcopyrite leaching in the presence of sodium chloride at moderate temperatures (65-90°C) in acid media with ferric ions as the oxidant. The beneficial effect increases with the increase in chloride concentration and temperature. The addition of sodium silicate and silica sand has no significant influence. The analysis of solubility data in acid/salt solutions indicates that the solubility of silica as Si(OH)4 as the dissolved species is controlled by the activity of water, as expected from the hydration theory. Kinetic analysis shows the trends that copper dissolution from chalcopyrite in the presence of precipitated silica with sodium chloride follows a shrinking sphere model indicating a chemically controlled surface reaction. The effect of temperature on copper dissolution in the presence of both precipitated silica and sodium chloride was also larger compared to the results in sodium chloride alone. The SEM analysis shows that chloride and silica facilitates the precipitation of sulfur on the surface of the silica particles rather than the chalcopyrite particles which avoids the blockage of the mineral surface and thus improves the leaching kinetics.

Jan 1, 2014

By Rob Assabgui

Presentation Overview ? Stobie Mine Sublevel Cave Background ? Elevated Silica Levels ? Silica Control ? Challenges and Issues ? Conclusions

Oct 1, 2010

By G. Major-Marothy

"INTRODUCTIONA beneficiation plant to upgrade earthy iron ores is being installed by the Iron Ore Company of Canada in Sept-Iles, Quebec.The crude ore for the plant will come from the Knob Lake area, located in Northern Quebec, where mining has been in progress since 1954.Some 170 million tons of ""direct 11 ores have been mined and shipped in the past eighteen years, with an overall silica content of 7 to 8 percent. No beneficiation - except the reduction of the top size to about 2 inches - took place during this period, but extensive research work has been carried out, in order to find a feasible process.Since “washing"", gravity separation, roasting and magnetic separation experiments did not indicate positive enough results, flotation was tried and found to be feasible.The beneficiation complex being installed will consist of grinding, flotation, dewatering - i.e.: thickening, filtering and drying - balling feed preparation, and agglomeration - i.e.: balling and induration.This process will result in a product superior to the ""direct shipping"" ores and will also expand the ore reserves by allowing material with a higher silica content to be utilized.THE OREThe Knob Lake ores are grouped by mineralogical composition and by grade.BLUE ORES, representing roughly two thirds of the reserves, carry their iron content mostly in the form of massive, blue hematite and martite.YELLOW ORES, about one sixth of the reserves, have predominantly hydrated iron oxides as the iron bearing minerals.RED ORES, the other sixth of the reserves, carry the iron mostly in the form of red hematite.The gangue in all ores is mainly quartz, but aluminum oxides and hydroxides are also present, particularly in the red ores."

Jan 1, 1972

By M. Behrouz

Thermal power plants convert thermal energy due to nuclear reactions or the combustion of coal, gas, heavy oil, or some other hydrocarbon to electrical energy. They consist of a variety of equipment, such as boilers, turbines, generators, cooling towers, and auxiliary equipment. Any factor that affects the equipment efficiency affects the overall efficiency. Analysis of the cooling tower and raw water using the Langlier Saturation and Ryznar Stability Indices showed that the cooling water at Sarchesmeh was slightly scaling with respect to silica. Cold lime softening was found to be a cost-effective method to produce cooling water with adequate properties to reduce the cooling water make up from 85 to 70 m3/h and blow down rate from 35 to 20 m3/h.

Jan 1, 2007

By B. Dyck, L. Verhelst

"Colloidal silica in Key Lake’s Solvent Extraction (SX) feed solutions has presented an operational problem for the mill throughout its history. The colloidal silica stabilizes aqueous continuous emulsions, resulting in elevated solvent losses and operational downtime. Through the years, many attempts have been made to solve this problem, but no viable solutions were found. By revisiting an idea dating back to the 1979 feasibility study and re-evaluating it under current operating conditions, a practical solution was achieved. This paper discusses Key Lake’s history around colloidal silica removal, starting with coagulation using a polyethylene oxide polymer (PEO), and ending with coagulation using a polyethylene glycol (PEG) polymer. The results of a mill trial using POLYSIL® RM1250 introduced at doses up to 300 ppm into the counter current decantation (CCD) circuit to clarify SX feed solutions are discussed with a focus on the benefits to SX.INTRODUCTION Colloidal silica has historically been a significant operational problem in the Key Lake mill. Silica originates from clays in the ore as well as concrete backfill intermixed with the ore resulting from the mining method used at Key Lake’s ore source, the McArthur River mine. The silica is dissolved as silicic acid into solution in the mill’s sulphuric acid leaching circuit. Once in solution, silicic acid polymerizes (Hearn, Smethurst, & Boskovic, 2016) forming a fine suspension of stable colloidal particles. These silica colloids are unaffected by flocculants and sand filtration reporting to the pregnant leach solution (PLS) as a fine turbidity in solution. Silica concentrations typically ranged from 700 to 1200 mg/L Si in the PLS fed to SX. Throughout Key Lake’s history, silica interactions in the Solvent Extraction (SX) process have made SX a mill bottleneck and a source of significant reagent costs."

Jan 1, 2018

By W. L. Stuewe

The Dominion Steel and Coal Corporation requires enormous quantities of bricks each year for its Sydney steel plant operations. Clay brick of all types are purchased, while silica brick is made in the Company's plant at Sydney. A description of this plant was given in a paper presented by H. B. Gillis and F. C. Morrison at the 1938 Annual General Meeting of the Institute. The rock used to make silica brick was for years obtained from a quarry at Leitches Creek, about eighteen miles from Sydney. Due to the gradual deterioration of this deposit, the Corporation was forced to look for other sources of supply. In 1945, the problem was presented to the Nova Scotia Department of Mines and, through the efforts of Dr. A. E. Cameron and Mr. J. P. Messervey, an examination was made of a silica-rock deposit some six miles northwest of Yarmouth, N.S. Preliminary samples proved satisfactory, and arrangements were made with the Department of Mines to ship to the steel plant at Sydney a fifty-ton car load for the purpose of further testing. Brick made from this sample shipment stood up very well in the furnaces. At the same time, two hundred and fifty tons of silica rock from a deposit at Lac Bouchette, Que., were purchased from the Industrial Silica Corporation, and brick made from this rock also was found suitable for our requirements. Comparative transportation costs, however, led to a decision to open the Yarmouth deposit. The silica rock, or quartzite, of this deposit outcrops at Chegoggin point along what is known as the 'Pembroke shore', a northerly trending section of the coast-line at the extreme southwest of the Province, in Yarmouth county. The country here is fairly flat, with elevation averaging about twenty feet above high tide, and is for the most part mantled by a growth of brush and some scrub trees, chiefly small fir. Bed-rock is generally concealed beneath three to four feet of clayey soil, but scattered outcrops of the quartzite indicated that a band of this rock, some 260 feet wide, extended inland in a northeasterly direction from Chegoggin point at least to Utleys lake, a distance of about three miles.

Jan 1, 1947

By D. E. Smith, M. K. Murthy

"The commercial potential of a silica-kaolin deposit that occurs on the banks of and close to the Missinaibi River in the District of Cochrane, Ontario, is under evaluation by Algocen Mines Limited. The geological features of the deposit, as well as its probable origin, are described. Mineralogical analysis of the deposit samples indicates that the principal minerals are quartz and kaolinite clay; it is estimated that about 20 per cent of the deposit is kaolin clay. The impurity minerals present are: a slightly magnetic Fe-Ti oxide mineral, goethite, muscovite mica, tour-maline, staurolite, anatase and zircon. Laboratory research studies are in progress to develop and evaluate suit-able methods for the separation of silica sand from kaolin. Results to date indicate that good-quality silica sand with an Fe,03 content in the range of 0.012 to 0.025 per cent can be produced. It appears that the clay portion can also be beneficiated to yield products meeting commercial requirements. It has been possible to beneficiate a portion of theetlay to obtain the particle size distribution now specified by industry. However, research is continuing to develop suitable separation and beneficiation methods which can produce kaolin clay meeting all the commercial requirements."

Jan 1, 1970

By Kostas Fytas

Acid mine drainage (AMD) is a serious environmental problem that preoccupies the Canadian Mining Industry. Considerable amounts of money are spent every year in an effort to prevent or reduce the acid mine drainage phenomenon. AMD occurs when sulphide minerals (ex. pyrite) contained in rock are exposed to air and water and subsequently oxidize to produce low pH water. This acid effluent has the potential to mobilize any heavy metals contained in the rock. Coating the sulphide minerals with silicates is a new promising technology to reduce AMD. Pyrite is treated with a solution containing H2O2, sodium silicate and a buffering agent. H2O2 oxidizes a small part of pyrite producing ferric iron (Fe3+) ions. These ions subsequently react with the silicate ions to produce ferric hydroxide-silica that precipitates on the pyrite surface producing a passive coating. This silicate coating can protect the grains of pyrite from oxidation. This paper presents a series of experiments that confirm that silicate coating can considerably reduce AMD.

May 1, 2001

By P. Bousquet

Acid mine drainage (AMD) is a serious environmental problem that preoccupies the Canadian mining industry. Considerable amounts of money are spent every year in an effort to prevent or reduce the acid mine drainage phenomenon. AMD occurs when sulphide minerals (e.g., pyrite) contained in rock are exposed to air and water and subsequently oxidize to produce low pH water. This acid effluent has the potential to mobilize any heavy metals contained in the rock. Coating the sulphide minerals with silicates is a new promising technology to reduce AMD. Pyrite is treated with a solution containing H2O2, sodium silicate and a buffering agent. H2O2 oxidizes a small part of pyrite producing ferric iron (Fe3+) ions. These ions subsequently react with the silicate ions to produce ferric hydroxide-silica that precipitates on the pyrite surface producing a passive coating. This silicate coating can protect the grains of pyrite from oxidation. This paper presents a series of experiments that confirm that silicate coating can considerably reduce AMD.

Jan 1, 2002

By Gulshan Kumar Pradhan, Yogendra Pratap Singh, Dhawanm Nikhil

"Potassium (K) is one of the essential elements for the growth of plants and thereby for humans. In fertilizers, potash demand has been steadily increasing at ~3.5% annually. Water soluble potash deposits are rare and highly localized. India is neither present on the world potash production map nor it has adequate potash rich rocks. The K-bearing minerals are recovered either by using conventional underground mining methods or though solution mining methods. India possesses a vast resource of silicate rocks such as glauconitic sandstone and Feldspar. These rocks are basically a group of alumino silicate of potassium, sodium and calcium (K2O%: 5-12, Na2O%: 3-10%, SiO2%: 52-65, Al2O3%: 15-20, Fe2O3%:, 5-7 and MgO%: 2-3.5).The K extraction from silicate rocks has received little attention probably due to the slow release, the locked structure of alumina-silicate minerals, and the unavailability of appropriate economic processes & their know-how. In fact due to this India imports all of its potash demand (about 3.5 million tons per annum) from different countries.In the present work, an attempt has been made to identify the structural and chemical alteration of desired K mineral phase in silicate rock (~K2O%: 10.5, Na2O%: 2%, SiO2%: 55, Al2O3%: 19, Fe2O3%, 5-6, MgO%: 2.5) under different conditions such as acid leaching, thermal treatment and chemical processing. Different treatments are aimed to increase K availability which is related to the modifications in mineralogical composition. The modifications in the feed sample and treated samples are studied through SEM-EDAX, XRD, EPMA and optical microscope. With the combination of treatments, it is possible to extract more than 90% K and the formation of sylvite phase (water soluble) confirms the dissolution of potash values."

Jan 1, 2016

By Kari Niiranen, Andreas Boehm

LKAB (Luossavaara-Kiirunavaara AB) is operating underground iron ore mine, with three beneficiation and pelletizing plants in Kiruna, Northern Sweden. The wet low intensity magnetic separation (WLIMS) is regarded as the crucial part of silicate mineral separation from the ore. The Kiirunavaara iron ore deposit shows a rather low content of silica (ca. 2.3 to 3.3 % SiO2) but the silica grade is expected to increase in the deeper parts of the deposit. This can be problematic in the case of DR pellet quality with an average silica grade under 0.75 % SiO2. A laboratory scale methodology was developed for the systematic characterization of the ore for mineral processing with the focus on silicates at the Institute of Mineral Processing, University of Leoben. This methodology is combining mineralogical, geochemical and process mineralogical characteristics. Automated mineralogy (QEMSCAN) was used to study the modal mineralogy, the distribution of silicate minerals in different particle size classes after comminution, the deportment of silicon (Si) between various silicates and degree of liberation and intergrowth of magnetite and silicates. Based on the mineralogical investigations, actinolite, phlogopite and even quartz and albite are the predominating SiO2 bearing minerals in the ore. The important result of the investigations was the discovery of two separate subtypes within the high silica ore type B2 based on their mineralogy and mineral processing characteristics. The crucial part of the investigations of intergrowths and liberation of magnetite results was the magnetic separation tests carried out with the Davis magnetic tube. The binary intergrowths of magnetite and the silicate minerals (mostly actinolite) are the most common type of mineral association discovered. The significant characteristics in the intergrowths of magnetite and actinolite are the fine-grained magnetite inclusions in actinolite which may end up increasing the SiO2 grade in the magnetite concentrate despite magnetic separation.

Jan 1, 2016