Search Documents

By Y. Huang

Corrosion of GaAs in aqueous electrolytes is a major limitation in implementing GaAs-based photoelectrochemical solar energy conversion systems, In this work, the corrosion behavior was investigated by electrochemical methods and surface analysis approaches, in both H2SO4 and NH3?H2O solutions, Open-circuit measurements showed that the cleaned GaAs surface was very sensitive to water/air, Impedance measurements for n-GaAs showed that an inductive loop only appeared at a high corrosion rate because a reaction intermediate is the oxidant for a further decomposition step in combination with chemical reaction with water, The results suggest that the same corrosion/decomposition mechanism occurred on n-GaAs in the two solutions, When the surface-hole concentration was low, the hole injection or generation process was the rate-determining step, At large reverse bias on n-GaAs, with high-hole concentration, the corrosion rate was limited by a Faradaic adsorption process, involving an adsorbed intermediate, The different surface compositions after corrosion in the two solutions can be explained by the dissolution of As(0), Further oxidation of As(0) to As(III) in NH3?H2O solution is still slow, as suggested from X-ray photoelectron spectroscopy (XPS) analysis,

Jan 1, 2005

By Jin Liu, Torstein A. Utigard

At its Copper Cliff Smelter, Vale Inco Limited processes a bulk copper-nickel concentrate in two Inco oxygen flash furnaces. Coke supplies a minor proportion of the process heat requirements, limiting the flash furnace matte grade to the target 45% CuNiCo. Coke addition to the furnace offers a potential means of establishing a reducing barrier on the surface of the molten bath. Such a practice would be conducive to producing sulfur deficient (partially metallized) matte. At the same iron content, the iron activity of sulfur deficient matte is higher than that of regular matte. A supernatant coke barrier could, therefore, be expected to lead to higher nickel and cobalt recoveries, reduction or even elimination of magnetite furnace bottom build-up and increased sulfur elimination as SO2 in the flash furnace. Extensive experiments were conducted in a miniplant flash furnace to investigate the effect on process metallurgy of the suggested modified scheme. The introduction and description of the experimental set up were given in Part 1 of this paper and an early paper published in Yazawa symposium1 together with the results and some in depth discussion on metallurgy. This paper intends to discuss the kinetics of the miniplant flash furnace testwork.

Jan 1, 2015

By P. H. Agson Gani, T. Sitorus, N. P. Widodo

"PT ANTAM UBPE Pongkor underground mine use blasting to develop its tunnels which will cause poisonous and dangerous gases trapped inside mine. To analyze this case, a study of mine ventilation, the dispersion of carbon monoxide (CO) gas concentration and diffusion coefficient is commenced. At the end, the re-entry time formula will be determined. Results indicate that this study is site specific and could only be applied in the place this study executed. The aim of this study is to be further developed by applying Principal Component Analysis (PCA) to find a universal re-entry formula. KEYWORDS Mine Ventilation, Re-Entry, Smoke Clearing, Diffusion Coefficient, Carbon Monoxide Gas, Gas Dispersion INTRODUCTION Pongkor underground mine is using cut and fill as its mining method. Thus, its development and production processes require blasting to develop its tunnel. This process caused poisonous and dangerous gases spread and trapped inside the mine, one of them is carbon monoxide (CO) gas. CO is formed in an unbalanced reaction of explosives detonation and could be the cause of headache, blackout and death to people who inhale CO at certain concentration (McPherson, 2011; Hartman, Mutmansky, Ramani, & Wang, 2012). Mine ventilation system is installed in the mine to resolve this problem. Mine ventilation play an important role to disperse CO gas by absorb the poisonous/dangerous gases and deliver clean air into mine. The important parameter is diffusion coefficient, because diffusion is affecting particulates or gasses spreading from its sources throughout the mine. Diffusion coefficient is the total diffusion in axial direction of turbulent flow mainly by convection of bulk motion, advection and eddy diffusion, while the effect of molecular diffusion is appreciably negligible (Widiatmojo et al, 2015). Taylor (1953, 1954) develops a theory about the dispersion by inducing a slow stream of solvent into a capillary tube. Taylor used Reynolds assumption of radial diffusivity to be analogous with the transfer of the matter in turbulent flow as well as the transfer of momentum and heat. Then, Taylor proposed the formula of diffusion coefficient, D (m2/s), against pipe diameter and turbulent shear velocity are as follow:"

Jan 1, 2019

By B. Hart, J. Marois

"Scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM–EDX), and Time of flight secondary ion mass spectroscopy (TOF-SIMS)were used to analyze pyrochlore grains from Niobec froth flotation plant. Samples from the mill feed, pyrochlore rougher feed, pyrochlore rougher concentrate, and tail were analyzed in order to identify a potential relationship between pyrochlore matrix composition and selective separation. SEM-EDX analyses indicate that pyrochlore grains with high Fe content appear to be less recoverable than those with a lower Fe content and that the flotation response is related to matrix Fe rather than Fe occurring as inclusions. TOF-SIMS was used to analyse the surface of high Fe and low Fe pyrochlore, in order to identify a potential relationship between pyrochlore matrix composition and the related effect on cationic collector adsorption (tallow diamine). Surface analyses of pyrochlore from a conditioning test show that species indicative of the collector favour the surface of Fe poor pyrochlore relative to the Fe rich variety. The results from the conditioning test illustrate a negative relationship between collector loading and the presence of Fe and related oxidation species. This study identifies the link between pyrochlore matrix Fe content and, the presence of surface oxidation products, to collector loading. Poor Fe rich pyrochlore recovery noted in the Niobec froth flotation plant may be partially explained by this mechanism.INTRODUCTIONPyrochlore, the most abundant niobium containing mineral (Perrault and Manker, 1981) is economically recovered in Brazil, China, and Canada (Niobec) (Kouptsidis et al., 2008). Since 1974 Niobec has been extracting niobium from the St-Honorécarbonatite deposit. Niobec is the only operating Nb extraction facility in North American and one of the three major world producers of ferroniobium (Dufresne and Goyette, 2004; Belzile, 2009).Flotation is the preferred and most cost-effective method for pyrochlore recovery (Burks, 1958; Shapolov and Polkin, 1958; Zakharov et al., 1967; Razvozzhaev and Nikiforov, 1972; Bogdanov et al., 1973; Abeidu, 1974; Raby and Desrochers, 1975; Wilson, 1979; Biss and Nadeau, 1982; Biss, 1985). With the aim of optimising the flotation process for the Niobec ore, numerous experiments were performed on the influence of surfactants and type of water to optimise pyrochlore recovery and grade during flotation (Gomez et al., 1987; Rao et al., 1988; Dufresne and Goyette, 2004; Belzile, 2009)."

Jan 1, 2013

By Carlos Antônio de Morais, Renata Dias Abreu

The present work describes a study of the separation of terbium and dysprosium from heavy RE concentrate through a solvent extraction circuit in a counter-current system. As the efficiency of the REE extraction by acid extractants rises with the increase of the atomic number of the element, the aim of this work is to extract the elements with higher atomic number maintaining Tb and Dy in the aqueous phase. Thus, terbium was separated first with subsequent separation of dysprosium. The experiments were carried out by using IONQUEST®801 as the extractant and a REE-hydrochloric liquor as feed solution. The optimum operational circuit in terbium separation was comprised of 37 stages: extraction, scrubbing, stripping, and solvent washing. For the dysprosium separation 39 stages were required. Terbium separation over 92% with over 95% purity and a Dy separation over 97% with over 95% purity were obtained.

Jan 1, 2014

By Jacob Masliyah, Zhiang Zhou, Tshitende Kasongo, Jianjun Liu, Zhenghe Xu, Jeawon Choung

"Slime coating is a recognized challenge in fine particle flotation, not only in decreasing recovery, but also in reducing the selectivity and hence froth quality. In this presentation, a novel method based on electrophoretic mobility distribution measurement to study slime coatings is described. By measuring electrophoretic mobility distribution of individual minerals and their mixtures, the interactions between these minerals can be evaluated.For illustrative purposes, a model system of fine coals, or oil sands with two different types of fine clays was studied. Flotation tests showed a significant decrease in coal (bitumen) flotation recovery with montmorillonite but not with kaolinite clay addition. When electrophoretic mobility distribution of a fine coal/montmorillonite clay mixture was measured, a single modal zeta potential distribution was obtained, in contrast to a bimodal distribution for fine coalkaolinite clay mixture. This finding suggests a stronger adhesion of montmorillonite than kaolinite clays on fine coal surfaces. In the case of bitumen, the bimodal zeta potential distribution was measured for the mixture of bitumen emulsion and kaolinite or montmorillonite, indicating a weak attraction of the clays by bitumen. In the presence of calcium, however, a single modal zeta potential distribution was obtained in the mixture of bitumen emulsion with montmorillonite but not kaolinite clays. These findings are in excellent agreement with bitumen flotation results, demonstrating that the electrophoretic distribution measurement is a powerful tool to study slime coating phenomenon in a complex fine particle flotation system."

Jan 1, 2002

By D. M. Maijer, S. L. Cockcroft, A. B. Phillion, P. Fan, C. Reilly

"A numerical model has been developed to study macrosegregation associated with liquid feeding in the Low Pressure Die Casting of A356 aluminum alloy wheels. The model of the wheel casting process has been implemented within the commercial CFD software package, FLUENT, using a User Defined Function (subroutine) to account for Si rejection based on the Scheil approximation. The model has been validated against temperature and microstructural data taken from a commercially cast wheel. The amount of segregation in the wheel has been shown to be significant in a couple of key areas. The implications of accounting for segregation include an improved ability to predict shrinkage porosity, fatigue performance and potentially also hydrogen porosity.INTRODUCTION The aluminum alloy A356 is widely used in the automotive and aerospace industries for various components. Examples include automotive wheels, automotive suspension components and airframe castings. Focusing on automotive wheels, Low-Pressure Die Cast (LPDC) A356 wheels offer significant design freedom and are far more aesthetically appealing to consumers than conventional stamped steel wheels. A356 wheels now dominate the market, appearing in all but the entry level offerings of the OEM manufacturers. However, they are typically over-designed to allow for the various casting related defects that degrade their mechanical performance. Thus, their potential to save weight has not been fully realized. Wheel manufacturers are under constant pressure to ensure their products meet strict mechanical requirements (ductility, fatigue, vibration), tight geometric tolerances and high aesthetic quality. The mechanical properties of the final product are determined by the microstructure – e.g. SDAS – and the defect population (porosity and oxides). Depending on their size and location, both porosity and oxides, can act as crack initiation sites reducing fatigue life (Caton, 2001; Jordan, 2010; Wu, 2015). There are a number of examples appearing in the literature (Atwood, 2000; Carlson, 2007; Lee, 2001; Yao, 2011) of numerical models that have focused on hydrogen-based pore formation that have demonstrated an ability to predict porosity formation and pore size distributions in geometrically simple castings. These models assume that the local gas species diffusion through the liquid metal to the pores is the rate-controlling factor of pore growth. Another common source of porosity is liquid encapsulation (Dantzig, 2009). As the pressure within the isolated liquid drops, pores form first due to the pressure dropping below the equilibrium partial pressure of hydrogen in solution and then second grow substantially as the pressure continues to drop falling below the vapour pressure of Al. One factor that can affect both mechanisms of pore formation is species macrosegregation, which has received comparatively little attention in die-casting."

Jan 1, 2017

By D. M. Wyslouzil

"This paper was prepared for presentation at the 16th Canadian Mineral Processor's Annual Meeting, Ottawa, Ontario, Jan. 17 to Jan. 19, 1984.This paper gives an account of the development of treatment procedures for the differential flotation of refractory copper-zinc ores. Special references are made to the effectiveness of various zinc depressants and their combinations.Studies carried out on refractory copper-zinc ores demonstrated that conventional zinc depressants such as cyanide and zinc sulphate were not particularly effective when secondary copper minerals were present in the ore; the flotation activity of sphalerite was enhanced in the presence of cyanide.Among the various zinc depressants evaluated, the following depressant combinations were found most effective: Zn(OH) 2-S02 , 802-CaO, Na2S-Na2S03-S02, Na 2 S-S02 and Na 2S-S0rDS22.The practical application of any of these systems depends on the type of ore treated and other conditions such as pH, levels and points of collector and depressant additions.In this paper the effect of each depressant combination on different ores is described with reference to the selection of collectors."

Jan 1, 1984

By Daniel E. Walsh, P. D. Rao

"A four-inch compound water cyclone (CWC) was tested to evaluate its gold recovery characteristics when processing -4.8 mm run-or-pit, placer material. Neutron activated placer gold particles (840 to 37 microns) were used as radiotracers (/98Au) in a closed circuit ewe test loop to determine concentrator recovery; a procedure believed unique to this study. The effect on gold recovery of gold size and shape, feed pulp density, feed pressure, vortex finder clearance (VFC), ewe cone type, top-size of the feed solids, presence or absence of heavy minerals in the feed, and the quantity of-37 micron slimes in the feed was investigated in over 300 tests.CWC concentration ratio and the top-size of the underflow solids were both affected by cone type, VFC, and feed pressure. Gold recovery was significantly affected by gold size, gold shape, and concentration ratio. These effects are complex, because significant size-concentration ratio and size-shape interactions exist. Radiotracer techniques showed gold particles had a residence time within the ewe of approximately one second. This study suggests ewe gold recovery is a concentration. This work suggests ewe gold recovery is a function of particle size and shape, and the flow rate through the cyclone. CWC cone ""bed density"" is considered important only as a thin, protective layer, which shields coarser gold particles from the entraining currents and facilitates their movement through the CWC.IntroductionCompound water cyclones (CWC), or automedium cyclones, are enhanced gravity concentrators for the beneficiation for slurries of sand, coal, and ground ore (Fig. 1). They are called compound water cyclones because of the compound slopes of their basal cones (Fig. 2) and are operated to suppress classification phenomena in favour of gravity concentration effects. The compound water cyclone is not a new wet concentrator. It was developed in the late 1950s by Dr. Jan Visman through research sponsored by Canada's Department of Energy, Mines, and Resources. Since that time, it has become a common unit in coal washeries for cleaning fine coal. CWCs and other versions of concentrating cyclones have also shown promise for heavy minerals and precious metals recovery."

Jan 1, 1988

By B. Stuckert, P. Sheehan, J. Balfour, B. (Manas) Das, D. Fawcett

"With the growth of large scale surface mining operations, waste disposal and stability of waste dumps pose a challenging problem to engineers. Vibrations due to blasting operations proximal to these dumps further complicates dump design. Many dumps which are statically stable may become unstable due to the effects of blasting vibrations.A joint project between CANMET and Smoky River Coal Ltd. has been initiated to study the dynamic stability of waste dumps. The study involves development of an analytical algorithm combined with field monitoring to assess dump performance.Another objective of the study is to provide baseline data for a vibration attentuation relationships for sedimentary rock (coal) environments: most studies to date are for base metal mines. The effect of dump thickness on vibration response is also addressed.The key objective of the study is to present a methodology for assessing the dynamic stability of waste dumps. Implicit in this methodology are a number of assumptions concerning vibration attenuation in sedimentary rock environments, and response of the dump material to induced vibration. Where possible, these assumptions have been compared with monitoring data as a check on their validity."

Jan 1, 1989

By J. Paturaud, A. G. Villemiane, J. Y. Buffiere, D. Fabregue, M. Perrier

In this work, a detailed characterization of the cyclic damage mechanisms on duty in car heat exchangers has been carried out in order to improve their reliability. The material which consists in very thin (<0.3 mm thick) sheets formed of 3 co-rolled aluminum alloys (4045 /3916/ 4045) has been brazed in order to obtain metallurgical and surface conditions representative of those of the real components. Fatigue tests at constant stress amplitude have been performed at room temperature and 120°C in order i) to characterize the cyclic resistance of the studied materials and ii) to study the effect of temperature on the fatigue damage mechanism. The mechanisms leading to failure have been identified from post mortem fractographic analysis. The Wohler curves obtained show that, contrary to common structural Al alloys, this type of thin sheet brazed multi material can be cycled for several hundred thousand cycles at very high stress level (> ~ 80 % of the tensile strength). This behaviour is analysed with respect to the microstructure resulting from the brazing process and the low number of grains present in the sample thickness (around 5 grains).

Jan 1, 2015

By Yihan Liu, Jintao Zhang, Chen Xiao, Xiaomeng Zhao, Guanglei Song

To estimate the performance of the inert anode materials based on NiFe2O4 spinel ceramic during it used for aluminum electrolysis, we investigated the wetting process of cryolite molten salt which is in composition of industrial aluminum electrolysis with carbon anode and NiFe2O4 based cermet materials, by means of determination the interface wetting angle between the molten cryolite electrolyte and the solid anodes interface. The results show that the wetting angle between the electrolyte and carbon anode is larger than 90 angulation, this means that they basically can not wetting; however the nickel ferrate spinel ceramics behaves much better. In regard to the NiFe2O4 matrix materials, their initial wetting angles is 76.9. The initial wetting angles for 1.0wt%MnO2, 2.5wt%TiO2 and 0.5wt%V2O5-doped samples are respectively 56.86°, 52.98° and 51.93°. However, after 50s later, all the wetting angles came down below 15°.

Jan 1, 2015

By C. A. Pickles, K. Mackowiak, D. Gajonera

"Shake-flask oxidation tests were performed on Red Dog mine waste to study the initial dissolution behaviours of lead, zinc, and iron. The conditions for accelerated acid generation in terms of Eh and pH were determined. Each mineral behaved distinctly, with galena dissolving first, followed by sphalerite, then pyrite, although there was some overlap in behaviour. Iron was not detected in solution until approximately day 40 and was present at low concentrations. The experimental conditions and the theoretical model results indicated the formation of iron oxyhydroxides at low weathering times and jarosite at longer times.RÉSUMÉ Des tests d’oxydation par agitation en flacon ont été effectués sur les déchets miniers de l’exploitation Red Dog afin d’étudier les comportements initiaux de dissolution du plomb, du zinc et du fer. Les conditions entraînant la production accélérée d’acide en termes d’eH (potentiel d’oxydoréduction) et de pH (potentiel d’hydrogène) ont été déterminées. Chaque minerai se comportait différemment ; la galène a été la première à se dissoudre, suivie de la sphalérite, puis de la pyrite, mais un certain chevauchement des comportements a été observé. La présence de fer en solution n’a été détectée qu’après environ 40 jours et ce, à de faibles concentrations. Les conditions expérimentales et les résultats du modèle théorique signalaient la formation d’oxyde-hydroxyde de fer sur de courtes périodes d’altération atmosphérique, et de jarosite sur des périodes plus longues."

Jan 1, 2017

By T. Mulpeter, G. Deschênes

Sadiola Gold Mine is an open pit operation located in Mali and owned by Anglogold Ashanti Ltd, Iamgold Corporation and the State of Mali. A conventional cyanidation process (cyanidation/CIP) treats 15,000 tpd (of a mixture of oxide and sulphide ores) at an average grade of 3 g/t Au. In 2002, the increasing tonnage of sulphides caused an increase in production costs and a decrease in gold extraction (from 95% to 70-76%). Because of the short retention time of the leach circuit (18 hours) and the refractory nature of the sulphides, gold leaching kinetics are critical. A laboratory investigation was initiated to evaluate actual plant practice and identify a means of improving the gold leaching rate. The study was conducted on a "soft" sulphide gold sample containing 4.96 g/t Au, 0.4 g/t Ag, 2.5% pyrite, 1.2% arsenopyrite, and 0.2% pyrrhotite with a P80 of 74microns. Pre-leaching significantly influenced the gold leaching rate. A short pre-leach (2 hours) performed at pH 8, a DO of 8 ppm, and with 300 g/t lead nitrate added at the start or the end, produced the preferred conditions. Pre-leaching for more than 2 hours was detrimental to gold extraction. The cyanide concentration had to be maintained at 450 ppm NaCN to reach a maximum gold extraction within the retention time of the circuit. A maximum extraction of 81.3% Au was obtained in 20 hours (leach residue at 0.97 g/t Au). A high level of dissolved oxygen in the pre-leach was not of any benefit. Extension of gold leaching beyond 20 hours indicated that all leachable gold had been extracted by that time. Plant modifications were made to allow leaching of oxides and sulphides in separate circuits. Treatment of oxide ores is now performed at a higher rate. Sulphides are processed at a lower throughput, with 300 g/t lead nitrate, to allow a retention time of 22 hours. Combined throughput remains the same, and total gold recovery has increased from 76% to 80% for an additional gold production of 16,000 ounces per year.

Jan 1, 2005

By D. M. Maijer, S. L. Cockcroft, A. B. Phillion, P. Fan, C. Reilly, H. Khadivinassab

A combined experimental / numerical approach is proposed to investigate the bulk transfer of solute due to liquid metal feeding during shape casting of aluminum alloy A356 (Al-7Si-0.3Mg). A dumbbell-shaped experimental casting geometry has been developed, which promotes solute redistribution due to liquid metal feeding. The redistribution of solute in trial castings is evaluated based on the area fraction of eutectic phases. In the numerical model, silicon species segregation during solidification are calculated assuming the Scheil approximation, and are coupled with macro-scale solute transport due to Darcy flow in the mushy zone and feeding flow. The model has been implemented within the commercial CFD software, FLUENT, which simultaneously solves the thermal, fluid flow fields and species segregation on the macro-scale. The experimental and numerical results are compared and contrasted to examine the effects of liquid metal feeding in this casting.

Jan 1, 2014

By W. Dong

This paper presents the fundamental study of the temperature distribution in a reforming planar solid oxide fuel cell (SOFC) using mathematical modeling and experimental testing approaches at Versa Power Systems (VPS). In order to investigate the on-cell temperature distribution under high rates of Natural Gas direct internal reforming (DIR), both the computer simulation approach and the experimental testing approach have been developed. In this work, comprehensive in-house DIR and SOFC models were developed and employed for the computational fluid dynamics (CFD) based 3D computer simulation. The current SOFC module has been corrected to take into account both the on-cell electrical leaking effect and the stack stage structural resistance. Meanwhile, an instrumented single-cell test jig with multiple thermocouples was built, and a series of experimental tests were performed at various conditions. The numerical results based on the single-cell jigs are in very good agreement with the physical test results.

Jan 1, 2005

By J. Bensabat, B. Figueiredo, A. Niemi, J. Rutqvist, C. F. Tsang

"A hydro-mechanical model was developed to study the interaction between mechanical deformation and fluid flow in the fault zones during CO2 injection and storage at the Heletz site which was chosen as a test site for CO2 injection experiments in the framework of the EU-MUSTANG project. The potential reservoir for CO2 storage at the Heletz site consists of three sand layers separated by lowpermeability shale layers. The potential consequences caused by fault reactivation, focusing on the shortterm integrity of CO2 storage, are evaluated. The difference in the results obtained by considering the three-layer as an equivalent layer storage formation is analyzed.INTRODUCTIONLarge-scale storage of CO2 in deep underground reservoirs may cause considerable pore-pressure perturbation as well as flux migration and concern has been raised over whether shear slip displacements may be induced in nearby faults, as a consequence of their reactivation. A state-of-the-art review can be found in Rutqvist (2012), which describes the various possible effects resulting from CO2 injection into a deep sedimentary basin, including those involved in reservoir stress–strain changes, micro-seismicity, caprock sealing performance, and potential fault reactivation. Moreover, several studies have recently shown how CO2 injection may produce seismic events both on major faults (i.e., large faults with large initial shear offset) (Cappa & Rutqvist, 2011a, b, 2012), and on minor faults that might have gone undetected during the site characterization, e.g., faults less than 1 km long and without detected initial offset (Mazzoldi et al., 2012).The present paper is concerned with the Heletz formation which was chosen as a test site for CO2 injection experiments in the framework of the EU-MUSTANG project. The Heletz site located at the southern Mediterranean coastal plain of Israel and the structure is an anticline fold with a crest of about 4 km by 2 km. The structure is gently dipping to the east, truncated by a pinch-out line to the west and subdivided into a number of blocks by transversal normal faults with small displacements. The water table is located at 300 m below the land surface. An areal sketch of the site with the elevation of the caprock and the location of the borehole that has been chosen for the CO2 injection experiment is presented in Figure 1."

Jan 1, 2015

By Laxman M. Amaratunga, Nuri Hrnidi

"Reactive pyrrhotite tailings were agglomerated using the Cold Bond Tailings Agglomeration (CBTA) process with low cost binders; Portland Cement and fly ash. Various chemical additives, were used to retard acid mine drainage (AMD), including acid neutralizers, surfactants, sealants, and bactericides, which were encapsulated into the agglomerates. The choice of these additives was based on their low cost, low toxicity, and environmental friendliness. The main objective of the study was to examine the long term stability of these reactive tailings agglomerates towards AMD when used as aggregates for disposal in underground paste backfill.A carefully controlled kinetic stability test was carried out using specially designed humidity cells suitable for testing pellets. Using the humidity cell test method a 20-30 year AMD test may be accelerated to 50 weeks. During this period the following parameters were monitored: pH, redox potential, conductivity, sulphate, acidity, and dissolved metals.Results indicated that most of the encapsulated additives were successful in retarding AMD, while the control samples produced significant amounts of acid generation. The water soluble surfactant Enviroseal, and the sodium silicate sealant were very effective as a long term retardant for acid generation reactions in the sulphidic tailings when exposed to oxygen, water and iron-oxidizing bacteria.IntroductionThe sulphidic material discharged from concentrators becomes reactive upon exposure to air and/or water. Pyrrhotite (Fe0 S0_1) and pyrite tailings in particular which are discharged from the beneficiation process in the mining and mineral processing activities consist of finely ground particles. Upon exposure to oxygen and moisture, the tailings become reactive due to the instability of the metal sulphide minerals present which undergo spontaneous oxidation, thereby producing a weak sulphuric acid. Therefore, the long-term behaviour of the tailings can have a significant impact on the environment, due to acid mine drainage (AMD). AMD is created during natural atmospheric weathering when leaching action (natural and bacterial) conditions are present in the process wastes discarded during the mining and milling of sulphur bearing ores, and consequently it plays a major role in surface water chemistry."

Jan 1, 1998

By H. Matsuoka, M. Kawata, K. Mitsuhashi, C. Tokoro, T. Kato

Copper sulfide minerals such as chalcocite, bornite, and chalcopyrite exhibit high floatability, thus they can be recovered as a froth product by adding only a collector in flotation process. However, when their surface is oxidized, the floatability decreases and the simple addition of collectors is no longer effective. In this case, flotation activators are required to improve the floatability. Sodium hydrosulfide (NaHS) acts as an activator for chalcocite and bornite by re-sulfurizing their oxidized surface portions. Nevertheless, the flotation conditions still require optimization in order to achieve a satisfactory recovery of copper minerals. This work addresses the study of the effect of pH and NaHS dosage on the flotation of a complex Chilean copper ore containing chalcocite, bornite, and chalcopyrite. Flotation experiments were conducted using a Denver-type flotation cell and by investigating the effect of two NaHS dosages (50, 100 g/t) and three pH values (8, 9, 10). Following this process, the surface interaction between the minerals and NaHS were analyzed using zeta potential measurements. INTRODUCTION In recent years in the mining area of metal resources, the complexity of ores and the fineness of grind required to liberate minerals have become serious problems. When ores are complex, several valuable minerals may interact with each other and reactions may become more complicated compared with an ore containing only one valuable mineral. Therefore, more processing steps may be required than for a simple ore. When the valuable minerals exist as fine grains, it is difficult to liberate them and more grinding time is required. Furthermore, the probability of collision of fine particles with bubbles in the flotation process declines and it takes much time to recover them. Flotation is one of the most applied methods to separate valuable minerals from unwanted ones using the difference of hydrophobicity (or hydrophilicity). In the flotation method, the air is fed to a cell filled with the pulp of the mineral of interest and agitation is implemented to introduce air and generate bubbles. The hydrophobic particles attach themselves to the bubbles and float along with the bubbles while the hydrophilic particles remain in the pulp. Copper sulfide minerals such as chalcocite (Cu2S), bornite (Cu5FeS4), chalcopyrite (CuFeS2) are widely known abundant copper resources. Generally, flotation is used to recover and concentrate these minerals. Copper sulfide minerals usually have high floatability. However when their surfaces are oxidized, their floatability becomes lower. When the sulfide surfaces are oxidized, activators are added before flotation to modify the surface property of the Copper sulfide minerals so that they can be floated. Sodium hydrosulfide, NaHS, is known as one of the activators. Zhao (2018) reported that NaHS is often used as a sulfurizer for oxidized sulfide minerals (Becker (2014), Clark (2000), Newell (2006), and Newell (2007)). In earlier work, the authors performed flotation tests on a sample of Chilean copper ore which contained chalcocite, bornite, and chalcopyrite using a Denver-type flotation apparatus. The sample was ground to P80 70 µm with a rod mill and ball mill. In these tests, the following conditions were used: natural pH (about pH 8.5), flotation time of 45 min, 60 g/t AP3477 (sodium diisobutyl dithiophosphate) as collector, and MIBC (methyl isobutyl carbinol) at appropriate dosage as frother. NaHS was applied at the dosage of 0, 67, and 120 g/t, respectively at the conditioning. The concentrates were collected at 6, 18, 30, and 45 min. The weights of the concentrates and tailing were measured and they were assayed for copper by ICP-AES (Optima 5300 DV, PerkinElmer Inc.). The flotation recoveries of the copper minerals were calculated from the results of MLA (mineral liberation analyser) (MLA 650, FEI) measurements.

Jan 1, 2019

By M. Dupuis

It has been previously demonstrated [l] that there is no obvious thermal balance related issue limiting the size of a Hall-Héroult cell. Yet, it is well known that a forced-air sidewall cooling system is part of the AP50 cell design [2], In the present study, the authors analyze the impact of thermal loading on the mechanical deformation of high amperage cell potshells. The effect of adding cooling fins or a forced-air sidewall cooling system is then assessed.

Jan 1, 2005