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By S Romanchuk, V N. Macvkiw, D. J. I. Evans

The paper describes the processes developed and piloted by Sherritt Gordon Mines Limited for recovering copper, in the form of specification copper powders, from Lynn Lake sulphidic copper concentrates and Fort Saskatchewan Refinery by-product copper sulphides. The process includes ammonia pressure leaching and hydrogen reduction from solution. Nickel and cobalt present in the con-centrates dissolve in the leach solution and a method was developed for separating these metals from the cop-per. Methods are described for con-trolling the physical properties of the copper powder produced in the reduction vessel. The chemistry of the process is briefly discussed and the effects of some of the more important process variables are described. SHERRITT Gordon Mines Limited have developed and proven on a pilot plant scale, a process (I) for the production of copper powder

Jan 1, 1961

By D. C. Fraser

Copper occurs invisibly in a geo-logical environment characterized by swampy conditions and an accumulation of forest peat. This swamp, located in southeastern New Brunswick, contains up to ten per cent cop-per (dry weight), in the organic sediments. This occurrence appears unique in that the metal is apparently organically combined in a chelate compound. Unlike the acidic nature of most peat bogs, the pH of the cup-riferous peat is nearly neutral. Analyses of the peat and associated soils have indicated that the bulk of the copper is contained in the organic sediments. It appears that the cop-per distribution is affected by capillarity, evaporation and the growth of frost crystals, and that the copper fixation is effected by organic sequestration resulting in the metal being bound to the nitrogen or oxygen components of the forest peat. While such a fixation mechanism is not definitely established as responsible for the immobilization of the metal, the facts at hand are compatible with

Jan 1, 1961

By Roorda H. J, R. R. Saddington, Curlook W

THE copper-nickel sulfide ore deposits of the International Nickel Company of Canada, Limited contain the minerals pyrrhotite, pentlandite, and chalcopyrite. In the extraction of the nickel, copper, and iron, much of the processing involves oxidation of the metals as well as sulfur. Roasting plays a predominant role at several stages in the operations which prepare the constituent metals for refining. Copper, nickel and iron concentrates of various grades, ranging from low-grade nickeliferous pyrrhotite to high-grade nickel sulfide, must be partially or completely oxidized. Figure 1 shows the main points at which roasting is conducted at INCO. Roasting experience at INCO dates back to the time when lump ore was partially roasted in heaps. It has progressed through single hearth roasters, sinter machines, multiple-hearth roasters, flash roasters, and more recently has centered on the development and utilization of fluid bed roasters. The primitive, slow, and inefficient method of heap

Jan 1, 1961

By Christopher Riley

A relatively unexplored lead zinc deposit lies about 12 miles northwest of Revelstoke, B.C., in the highly metamorphosed Monashee Group of rocks of the Shuswap Terrane, Precambrian in age. Host rocks are of sedimentary origin and consist of gneisses, schists, marbles and quartzites with intermediary types. The marbles and quartzites provide good horizon markers. Using these it is possible to interpret the controlling structure which is a syncline overturned to the north, dipping south at about 45°, and plunging east at about 12°. The syncline is truncated at about halfway of its length on a peak on the west side of which a partial cross section together with superimposed minor folds may be seen. The quartzites and the two marble beds may be traced over much of the structure. There are two lodes, above the marble and below the quartzite, which converge eastward and which are the exposed edges of the same host bed -an impure limestone.

Jan 1, 1961

By R. L. Bailey

"The Acheson D-3 Pool was discovered in August 1950, and contains 88 producing oil wells on 40 acre spacing. Initial oil-in-place was 118 million stock tank barrels and initial well potentials averaged 2,000 barrels per day.In early 1956 studies of hydraulic interference between the Acheson and Leduc D-3 Pools were conducted on the Carter Petroleum Reservoir Analyzer. These studies indicated that the natural water drive to Acheson would be incapable of replacing reasonable withdrawal rates over the life of the pool. To avoid shrinkage losses a scheme of pressure maintenance by water• injection was therefore instituted in March 1957.This pressure maintenance scheme is notable because pressure is being effectively maintained by high volume injection through one well located on the flank of the pool. Close control on reservoir behaviour is maintained by regular bottom-hole pres-sure surveys and observation of water cuts on producing wells. No evidence of pressure gradients or channelling of the injected water has been observed to date, and the water-oil contact has remained level over the whole field. It is possible to control the average reservoir pressure within very close limits by varying the rate of fresh water injection.Ultimate recovery estimated from the rise of the oil-water contact and calculated water influx to December 31, 1958, is 335 barrels per acre foot, or a total of 91.4 million barrels from the pool. This compares to 217 barrels Per acre foot or a total of 59.4 million barrels indicated from laboratory test data."

Jan 1, 1961

By P. G. Thornhill

EARLY in 1951, Falconbridge undertook a research program aimed at the development of a sulphate roasting process for the recovery of the non-ferrous rnetals from the nickeliferous pyrrhotite fraction of Falconbridge ore, in order to reduce the tonnage of iron entering the srnelter. Such a method, it was hoped, would permit a high recovery of the nickel from pyrrhotite otherwise entering the smelter feed, thus not only raising the grade of the latter and reducing its iron content, but also providing an iron oxide residue useful as a source of by-product iron ore. At an early stage in the exploratory laboratory test work it was found that the degree to which the nickel could be solubilized by the sulphating roasting treatment was limited by particle size and the ex-tent to which the pyrrhotite concentrates were freed of the nickel occurring as physically separable pentlandite, a mineral relatively difficult to roast. ( 1) Thus the program

Jan 1, 1961

By D. J. Hains

IN this paper we shall examine the Why, Where and How concerning the agglomeration of iron ores and concentrates. Fig. l answers the questions @f why there is so much interest at the present time in the art of agglomeration. The use of sinter or pellets in the blast furnace has materially increased their rated •capacity. ':'President Hains Company Ltd. Engineering J. S. McMahon ( 1) reports an increase from 653 tons of .pig iron per day to 1140 tons of pig iron per day with the use of a 100 per cent sinter burden on one of his blast furnaces. In the United States the use of 100 per cent pellets has increased pig iron production from approximately 1800 tons per day to over 3000 tons pig iron per day (2). In our economic system the general objective is to produce more and better commodities cheaper. Fig. 2 shows the decrease in coke consumption with increased tonnages from the furnaces when using -

Jan 1, 1961

By H. D. B. Wilson, W C. Brisbin

The Thompson-Moak Lake nickel belt lies along the root of a Precambrian mountain range of the island-arc or alpine type. This range coin-. cides with the boundary between the Superior and Churchill blocks of the Canadian Precambrian shield. The nickeliferous peridotites and nickel ores occur along a negative gravity strip, which also coincides with strong thrust faulting and the axis of greatest deformation of the mountain range. Similar structures and highly nickeliferous peridotites occur in present-day island arcs. Much of the belt is covered by Paleozoic rocks, but a length of 270 miles may be explored by present-day methods. Nickel deposits have been located along 60 miles of the belt. The length of the favorable structure and the size of the known deposits suggest that this will be one of the world's major nickel regions. The regional gravity anomalies, which consist of a branching negative strip bordered by two positive strips, are best explained by major warps of a crust consisting of a granitic and basaltic layer. The ore deposit

Jan 1, 1961

By R. A. Kipp

THE dry concentration of ores and minerals is a subject on which there is very little engineering literature available. With the advent of flotation, practically all milling research was turned to this development as it held the answer to large-scale economic operations. However, there are many concentration problems that can be more adequately and economically handled by the dry methods that have been developed, and, consequently, I believe it is very advisable for mining men to become fully 'conversant with just what can be done in the dry state. Therefore, today, I should like to give a brief summary of the processes that are available and, in a general way, how they can be a p-p lied. I shall confine my remarks mainly to two dry processes: THE Am FLOTA'l'ION TABLE AND THE ELECTROSTATIC SEPARATOR Dry Magnetic Separators should probably also be included, but I am

Jan 1, 1961

By R. H. Pemberton

"THE Mattagami district of Quebec has, during the past few years, experienced intense exploration by virtually every mining company operating in Canada. As a result of this activity, a number of well-mineralized zinc-copper bearing bodies have been found, some of which will almost certainly go into production. Much of the area has undergone what is now termed ""Saturation Prospecting"" or intense and detailed geological and geophysical surveying, followed by the drilling of nearly all possible bets. Considering only the airborne geophysical surveying, some blocks of ground have been flown by virtually every geophysical instrument which has to date been installed in an aircraft. A list of these different geophysical instruments would include: l. Fluxgate-type total field magnetometers 2. Vertical field magnetometer ,3. Nuclear-precession magnetometers 4. Single-frequency out-of-phase electromagnetometers 5. Dual-frequency out-of-phase electromagnetometers 6. Horizontal component measuring electromagnetometers 7. In-phase and out-of-phase electromagnetometers8. Dip-angle measuring electromagnetometers."

Jan 1, 1961

By Nathaniel S. Scott

Caland Ore Company Limited, a subsidiary of Inland Steel Company of Chicago, Illinois, leased an iron ore deposit from Steep Rock Iron Mines Limited on January 1, 1953.. This deposit lay underneath a lake and was covered with 161,000,000 cubic yards of Jake bottom material, mainly silt. Removal of this material was done on a contract dredging basis. This contract was divided into a plant phase and an operating phase. The plant phase consisted of supplying two cutter-type suction dredges, each with two booster pumps in the discharge lines. All six pumps were centrifugal, had 36" discharges and were powered by 10,000 horsepower electric motors. Peak demand was 59,157 kilowatts. One hundred and forty miles of steel tower line were built to bring power to the site. The balance of the plant consisted of tugs, 12 miles of discharge line, varying from 36" diameter to 42" diameter and attendant land-based equipment. A number of interesting dams were constructed

Jan 1, 1961

By Kenneth M. Haley

THE development of Reserve Mining Company's pelletizing practices began in 1949 in a pilot plant located at Ashland, Kentucky. Three years later the participating companies -Armco Steel Corporation, Cleveland Cliffs Iron Mining Company and Republic Steel Corporation concluded the work and the small plant was shut down. Oglebay Norton and Company was the operating manager and Armco Steel Corporation furnished labor and services. Arthur G. McKee and Company were the designers and constructors. The equipment flow sheet that was employed in that pilot operation is shown in Figure 1. This was Reserve's first step from the laboratory work per-formed by the Mines Experiment Station of the University of Minnesota in developing a commercial operation. The plant used New York state concentrate, purchased from Jones and Laughlin Steel Corporation's Benson Mine. This concentrate, minus 14 mesh, 64.3 per cent Fe, 5.7 per cent Si02, was processed at Ashland to 80 per cent minus 325 mesh in conventional ball mill, classifier, thickener, filtering

Jan 1, 1961

By Lionel A. York

THE first application of the cementation process took place in the year 1864, according to H. Standish Ball, when a break in the brickwork lining at a depth of 270', in one of the Rhine Preussen pits near Homburg, was sealed by running in milk of cement from the surface by means of a small hand pump. At about the same time Monsieur Portier adopted the method in France for repairing breaks in shaft lining. Figure 1 is descriptive of the Portier system and is of interest when compared with modern practice. During the next thirty years numerous attempts were made to improve the process; the general method used in sinking being to put clown bore holes outside the perimeter of the shaft for the purposes of injection. The cementation process was first recognized as an important as-set to mining in 1896 when Monsieur A. Francois developed his method of boring and injecting inside the shaft below the permanent water level. The Francois cementation process rapidly attained fame on the Continent and many shafts were sunk by its use in France, Belgium and

Jan 1, 1961

By C. H. G. Bushell, G. Brown, C. J. Krauss

1N FLOTATION, copper sulphate is used universally for the activation of sphalerite and marmatite and, to some extent, for the activation of other minerals. The copper activated surface readily adsorbs standard collectors such as the xanthates and dialkyl dithiophosphates whereas untreated zir~ sulphide does not. With the host of reagents available, making a mineral float is seldom difficult. The problem is to achieve selective flotation. In zinc flotation, the great value of copper sulphate results from its ability to activate zinc sulphide preferentially to gangue minerals. At the Sullivan Concentrator of The Consolidated Mining and Smelting Company of Canada Limited, the most abundant gangue mineral in the lead-zinc ore is pyrrhotite, and the zinc mineral is marmatite of somewhat variable zinc to iron ratio. For this Cominco study, selectivity between marmatite and pyrrhotite was therefore the most interesting aspect of copper sulphate activation.

Jan 1, 1961

By G. A. Gross

DURING the past 5 years a large amount of money and effort has been expended in exploration of iron-formations and in testing their suitability for beneficiation. Beds of ferruginous material are numerous and widely distributed in the Precambrian rocks of Canada and practically all of the known iron ranges or belts have been examined to a limited degree at least in an effort to evaluate their potential as sources of iron ore. A number of favorable beds have been selected for mining on completion of surface sampling, diamond drilling, extensive metallurgical testing and economic studies, and many other ranges are being studied. There are still a great many iron-formations that have not been evaluated by modern concentration methods and their regional extent is not fully known. The iron-formations are easily located by airborne or ground magnetic surveys but the main task in finding a mineable ore-body of this type amounts to locating a bed sufficiently large for mining which consists of material that can be concentrated economically by modern beneficiating methods. The ease with which an iron-formation can be concentrated to give a marketable ore depends primarily

Jan 1, 1961

By H. W. Fleming

In 1955, the results of a regional, geological interpretation of the northern portion of New Brunswick were used as a basis for selecting, for intensive exploration, three areas in which structural and stratigraphic conditions were believed to be favourable. Airborne electromagnetic work, in one of these areas, provided the justification for acquiring the Murray group. Even though the initial results were discouraging, this geological interpretation, combined with the fortuitous discovery of cop• per-bearing float, was sufficient reason for carrying out further work using geochemical methods. This work finally resulted in the discovery of the Murray massive-sulphide deposit, after about eighteen months of coordinated exploration on the property. While this deposit is a typical New Brunswick-type base-metal occurrence, extensive leaching has produced a fossil gossan that rendered it an elusive target for exploration techniques of limited penetration Full credit for localizing the target area is given to the geochemical techniques, but geophysical surveys were needed to provide the necessary

Jan 1, 1961

By R M. Ennis, J. C. Botham

This paper is one of a series pre-pared to study the role of fuels and reductants in metallurgical processes, especially from the viewpoint of Canadian requirements. The object of these studies is to provide a reason-ably authoritative interpretation on the interrelation of fuels in light of the considerable changes that have taken place in the Canadian energy field during the past few years. Previous papers in this group have dealt with the problem generally, and specifically in terms of the development of the iron and steel industry of Western Canada. These latter papers, presented at the Symposium on Iron and Steel in Western Canada held in Edmonton, Alberta, on September 8-9, 1959, surveyed the ferrous processes of interest for use in Wes tern Canada, especially with regard to solid fuel requirements. At that time it was evident that there was a need for a similar study of the fuels aspect of the non-ferrous metals industry.

Jan 1, 1961

By R. M. Porter

PILLAR extraction at the Sullivan Mine bas been in progress for over twenty-five years and bas .involved progressively larger pillars. The largest pillar blasted to date exceeds one million tons and is described in this paper. This blast is believed to be one of the largest to take place entirely under-ground. The Sullivan Mine, owned by The Consolidated Mining and Smelting Company of Canada Limited, is located in the southeastern corner of British Columbia on the east flank of the Purcell range overlooking the twenty-mile wide Rocky Mountain Trench (Figure 1). The orebody is a bedded replacement deposit in argillites, varying in thickness up to 300 feet, but averaging about 80 feet. Above the 3900 Level, the dip varies from nearly horizontal to 40 degrees; be-low the 3900 Level it varies from 45 to 20 degrees (Figure 2). Pillar extraction follows a plan of retreating outward from caved areas. The size of each blast is determined by the effect which the removal of support

Jan 1, 1961

By M. H. Cullender

THE determination of the flow characteristics of gas wells depends upon the analysis of pressure data obtained under shut-in conditions and under one or more known flow conditions. These data are commonly referred to as back-pres-sure test data, and I know you are all familiar with the back-pressure equation where, Q rate of flow, Mcfd @ standard conditions C coefficient of the back-pres-sure curve P 1 formation pressure, psia P • sand face flowing pressure, psia P2 (psia)2/1000 n exponent of the back-pres-sure curve Figure 1 is a graphical presentation of the back-pressure equation; the coefficient is the rate of flow at a difference in squared pressures of 1, in this case 2250 Mcfd, and the exponent defines the manner in which the rate of flow changes with a change in the difference in squared pressures. In Figure 1, the exponent of the back-pressure curve is 0.554 which means that for a 10-fold change in the difference in squared pressures, there will be a 3.58-fold (10 raised to the 0.554 power) change in the rate of flow.

Jan 1, 1961

By J. S. Kirkaldy, W. J. Slater, G. R. Mason

Activation analysis for copper and manganese in 10 mg samples machined from aluminum-base diffusion couples has been used in the study of ternary diffusion in the Al-Cu-Mn system. The accuracy, economy and convenience of the method are considered to be very competitive with other methods for analysis of such small samples. Neutron-activated aluminum-zinc alloys in the range from 10 per cent to 100 per cent zinc have been equilibrated with a known volume and the vapors subsequently condensed and collected. The vapor pressures relative to pure zinc (the thermodynamic activities) have been determined at 550°C' by recording the relative count of /'-rays from zn65 in the collected samples. The method is a sensitive one, although subject to serious obstacles to experimental accuracy.

Jan 1, 1961