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By Amauri Garcia, Rodrigo Valenzuela Reyes, Noé Cheung, José Eduardo Spinelli, Leonardo Fernandes Gomes, Rafael Kakitani

"The present research work deals with directional solidification (DS) of both Al-15wt.%Si and Al-15wt.%Si-1.5wt.%Mg alloys and further characterization of the related microstructures. The growth of refined primary Si and refined eutectic is well-known as positive in order to improve mechanical properties of the Al-Si based alloys. Alloying is also an effective method to strengthen the Al-Si based alloys, in which Mg is considered an important alloying element. However, lack of investigation regarding the effects of Mg on microstructure of these alloys is noted. So, in the present research work emphasis is given on both dendritic and eutectic growth being affected by solidification kinetics (V-growth rate and G-thermal gradient) during transient directional solidification. Experimental evolutions of microstructural spacing of both alloys have been determined which becomes possible to understand the effects of Mg coupled with the effects of growth rate on the final microstructural arrangements. A direct comparison of the tensile mechanical properties obtained for the alloys is also performed. It is shown by these correlations that the addition of Mg generally improves the tensile mechanical resistance with a minor decrease in ductility. Furthermore, the Scheil solidification path of the ternary Al-Si-Mg alloy was determined using the computational thermodynamics software Thermo-Calc, resulting in the following sequence of precipitation: Liquid-Si-a (Al)+Si- a(Al)+Si+Mg2Si. This sequence is compared with the experimental microstructure findings.INTRODUCTION Al-Si alloys containing from 4wt.% to 22wt.% Si comprise more than 90% of all Al-based castings. Parts manufactured with these alloys have a wide range of industrial applications due to their excellent castability, crack resistance, good corrosion resistance, good weldability, low density and high strength (Bray, 1976; Zolotorevsky, 2007; Reyes, 2017). Hypereutectic Al-Si alloys are widely used and researched in the automotive and aerospace sectors due to the low coefficient of thermal expansion, resistance at high temperatures, good wear resistance and high strength (Reyes, 2017; Tebib, 2013). Above the equilibrium eutectic composition (~12.5wt.%Si) the amount of primary Si particles becomes significant (Lasa, 2003). In the place of conventional hypoeutectic Al–Si, there is growing interest in hypereutectic Al–Si alloys as a candidate material for the high-quality engines because a higher volume fraction of silicon may bring about superior properties (Matsuura, 2003)"

Jan 1, 2017

By L. A. Jameson, J. Awmack, P. J. Lind

"Peñasquito is a polymetallic deposit containing gold, silver, lead, and zinc. The operation is currently the largest producer of gold in Mexico. Over the next few years, the process flowsheet will be expanded beyond the flotation of lead and zinc to include flotation of pyrite from zinc tails and subsequent leaching of the pyrite concentrate. This paper outlines mineralogical leach characterization that has been carried out to improve the understanding of the complex hosting of gold and silver minerals in the ore. Organic carbon that is present in the ore can have an impact on flotation and leaching. Mineralogical techniques used to characterize this deleterious component of the ore are introduced.INTRODUCTION Goldcorp’s Peñasquito operation is located in the Mexican state of Zacatecas, approximately 200 km from the city of Zacatecas as shown in Figure 1. Peñasquito has been in operation since 2009 and is currently Mexico’s largest gold mine. Mining is carried out by open-pit methods, with oxide ore proceeding to a heap leach facility and sulfide ore treated in the sulfide processing plant.The processing capacity of the sulfide plant is 130,000 tonnes of ore per day and in 2016 production amounted to 450,000 ounces of gold, 17.6 million ounces of silver, 109 million lb of contained lead, and 263 million lb of contained zinc in lead and zinc concentrates. GEOLOGY The Peñasquito deposit is hosted in and adjacent to two breccia pipes; Peñasco and Breccia Azul. The two breccia pipes are branches of a larger intrusive-related complex, which is hosted in the sedimentary Caracol formation as illustrated in Figure 2. The regional geology is dominated by Mesozoic sedimentary rocks which comprise a thick series of marine sediments deposited during the Jurassic and Cretaceous periods. A 2 km thick sequence of carbonaceous and calcareous siltstones and interbedded sandstones is underlain by a 1.5 to 2 km thick limestone sequence (Goldcorp Inc., 2015)."

Jan 1, 2017

The Curtin University Gold Technology Group has been involved in surveying, modelling and optimisation of batch centrifugal concentrator type gravity circuits and CIP/CIL circuits for nearly two decades. The most commonly asked question regarding gravity recovery is, “What is the benefit of a gravity circuit”, which can be hard, if not impossible, to quantify. With the help of the AMIRA P420 Project’s Integrated Liberation Leach Model (ILLM) it is now possible to evaluate the effect of gravity recovery on total gold recovery when changes are made to the grind size, gravity and/or leach/adsorption circuits. This paper demonstrates how the ILLM can be used to determine the net benefit of introducing or modifying a gravity circuit and assess the effect of operating conditions (grind size, coarse gold size distribution, leach residence time, carbon activity, etc.) on plant performance.

Jan 1, 2017

"Mineral separation by exploiting the differences in mineral or metal specific gravities (sg) has been used since antiquity. In the modern era, this is most commonly seen in the recovery of gold by the use of centrifugal concentrators and the separation of coal (low sg) from waste rock (high sg) using heavy media cyclones and jigs. Other metals, notably oxides of tin and tungsten, are successfully recovered using some combination of jigs, spirals and shaking tables. However, many conventional gravity separation systems are limited to fairly coarse (>1 mm) to medium (>100 micron) particle separations due to the limitations of the gravitational separation forces in conventional equipment.Many of the high specific gravity minerals of interest are friable (e.g. cassiterite, wolframite, etc.) and excessive fines are generated in the grinding/comminution circuits which cannot be recovered with conventional equipment and may be lost directly to the tailings stream. Recent developments in centrifugal gravity separation equipment specifically designed for fine or ultra-fine particle separation and recovery have resulted in heavy mineral particle recoveries as fine as 10-20 microns. Ongoing research work has also identified the benefit of closed-circuit, multi-stage gravity recovery circuits using some combination of centrifugal concentrators and conventional equipment (tables, spirals, flotation, etc.) which can substantially increase overall plant recovery and final concentrate grade.This paper will provide details of the evolution of non-fluidized bed gravity concentrators for high sg mineral recoveries, correlate laboratory scale development work with plant results to confirm scale-up, and show how recent flowsheet developments have contributed to significantly improved plant performance.IntroductionGravity concentration is one of the oldest and most cost effective metal and/or mineral recovery systems, ranging from the classic hand panning of alluvial gold, through to the large scale production of a wide range of metals and minerals, including gold, silver, PGMs, black sands, coal and iron oxides. Conventional gravity recovery systems, comprised of some combination of sluices, spirals, jigs and shaking tables have limited application in fine particle (i.e. <100 microns) recovery, or where there are limited differences in particle specific gravities (sg), e.g. the separation of high sg, high value metal oxides (e.g. those of tin, tantalum or tungsten), from medium sg, lower value metal sulfides such as pyrite and pyrrhotite. These unit operations tend to have limited capacity, and while double and triple turn spirals and multi-deck tables have been developed, extensive floor space is often required in order to process the tonnages incorporated in the modern mineral processing plant."

Jan 1, 2017

By Quenton Johnson, W. A. Gough, David Carr

"This paper describes the application of the BrainWave Model Predictive Controller (MPC) and Advanced Control Expert (ACE) Advanced Supervisory Control System on the SAG Mill, Ball Mill, and Rougher Flotation cells for a new gold processing line at the Oceana Gold - Haile Gold mine in Kershaw, South Carolina. For this project, ANDRITZ supplied the control system design and programming, operator-training simulator and advanced control. The advanced control was tested against the IDEAS™ dynamic simulator, and commissioned during the startup of the processing plant to help achieve target production as quickly as possible. Operators were able to run the equipment in a consistent and optimized manner from an early stage of the plant operation, increasing efficiency and profitability. MPC is able to reduce process variability beyond the best performance that can be obtained with conventional Proportional Integral Derivative (PID) control methods. MPC is able to optimize the control of processes that exhibit an integrating type response in combination with transport delays or variable interaction, which are characteristic of many gold processes including SAG mill weight control and Flotation cell froth level control. The experience and benefits of applying MPC during the startup of a new gold processing plant are presented in this paper.INTRODUCTION Mineral processing operations present many challenges for automatic process control due to variations in unmeasured ore properties, material transport delays, and non-linear response characteristics. Advanced process control technologies such as expert systems and multi-variable model predictive controllers are often used to improve the control of these processes to increase productivity and recovery efficiency. Typically these systems are applied after the mine has been in operation for a period of time. For this project, a complete dynamic process simulator was developed using the IDEAS platform for the purpose of training operators before the plant was constructed. Operators were able to become familiar with the process and the control system in order to become proficient in the use of the controls before the plant was ready to start. They were able to practice abnormal condition management including startup and shutdown of the process using the simulator and develop complete Standard Operating Procedures (SOPs) for these situations. The simulator was also used to test the control system functionality and operator Human Machine Interface (HMI) configuration to reduce errors and improve the performance of the control system during plant start-up."

Jan 1, 2017

By J. R. Tickner

"Gold is conventionally analyzed using fire-assay or other destructive chemical methods that impose significant sample preparation, OH&S, and skilled labour requirements. Developed over the past 15 years by the CSIRO, PhotonAssay provides a new approach. A high intensity, high-energy x-ray source is used to activate atoms of gold and other elements in bulk mineral samples. The resulting activity is counted to automatically, accurately and rapidly determine metal grade. Samples weighing 0.5–1.0 kg can be measured in a few minutes with minimal preparation. As the method is matrix-agnostic, traditionally hard-to-assay materials such as highly refractory ores, carbon pulps and copper concentrates require no special treatment. We present the status of commercial PhotonAssay systems being developed by Chrysos Corporation. The first unit with a throughput of up to 80 samples per hour is to be deployed in an Australian assay laboratory in late 2017; smaller systems suitable for providing real-time assay directly at the mine-site will be progressively rolled out from mid-2018. Performance results from extensive testing using both mine-sourced and standard reference materials are presented, demonstrating the sensitivity and accuracy of the method. Implications for replacing conventional gold assay in exploration, mining and processing operations are discussed.INTRODUCTION Accurate methods for assaying ore grade are essential throughout the exploration, mining and mineral processing value chain. The discovery and evaluation of new ore deposits, reserve and resource definition, mine operations planning, ore processing, metal accounting and product quality evaluation all rely on accurate measurement of the valuable metal content of bulk materials. The analysis of gold presents particular challenges, stemming from the very low concentrations at which commercial operations run (often part-per-million (ppm), or equivalently one gram-per-tonne levels or below), and the highly heterogeneous nature of many gold deposits. These challenges mean that any analytical method must have high sensitivity and be capable of measuring large-mass samples. The most widely used quantitative analytical method for gold is fire-assay (Hoffman, Clark and Yeager 1998). An initial ore sample typically weighing several kilograms is dried, crushed and pulverized to allow a small sub-sample (10–50 g is common) to be representatively drawn. The sub-sample is mixed with flux, litharge (lead oxide), a reducing compound and other reagents. The mixture is fired at a temperature of 1000–1200°C until molten. After cooling, the slag is removed and the lead button containing any gold present in the sample is remelted in a porous cupel. The lead is absorbed into the cupel, leaving a gold prill which is either weighed directly, or dissolved in acid and analysed via atomic absorption spectroscopy (AAS) or inductively coupled plasma spectroscopy (ICP or ICP/MS)."

Jan 1, 2017

By Kevin P. Plucknett, Z. Memarrashidi

"In the current work, factors influencing the corrosion mechanisms of TiC and Ti(C,N) based cermets are reviewed. Cermets were typically prepared with 30 vol.% of metal binder, in the form of various in-situ reaction-formed Ni3Al alloys. Commercial WC-Co hardmetals were also examined as baseline materials. The assessment of corrosion involved a variety of electrochemical measurements, including open circuit potential and potentiodynamic polarisation. The corrosion potential and current density were determined, following Tafel extrapolation, allowing estimation of the corrosion rates. Post-corrosion characterisation involved scanning electron microscopy analysis and associated energy dispersive X-ray spectroscopy of the sample surfaces. It is demonstrated that the primary corrosion mechanism for this type of cermet is dissolution of the metallic phase during oxidation attack, and thus this response can be expected to increase with the amount of binder in the cermet, although degradation can be subtly affected by composition (i.e. alloy composition, C:N ratio, impurities in the ceramic phase, etc.) and test procedure (i.e. aerated vs. de-aerated electrolytes). It was observed that addition of N content into the ceramic phase is beneficial to the corrosion characteristics of TiC based cermets, through significant refinement in the grain size of the hard phase. Similarly, elimination of impurities, such as W in selected TiC powders, also improves the corrosion resistance.INTRODUCTION Cermets are prepared using the combination of a hard, high elastic modulus ceramic phase with a ductile, high toughness metallic binder. This pairing of hard and ductile components ensures wide application of cermets in demanding wear environments. These materials are consequently used industrially in both bulk and coating form. The most common example of such a composite system is based on the use of tungsten carbide with a cobalt-based binder (WC-Co), which has been widely examined over the past 80 years. However, while WC-Co has been shown to exhibit an excellent combination of high strength and wear resistance, the corrosion and high temperature properties of this material are relatively poor. In addition, WC-Co possesses a high density (~13–14 g/cm3), which makes it a less desirable option when the component mass is a design factor (i.e. use in aerospace). In particular, the aqueous corrosion response of WC-Co limits its use in wear environments where combined corrosive degradation may occur (i.e. tribo-corrosion scenarios). Alternate cermet systems are therefore being actively developed due to these performance limitations."

Jan 1, 2017

By Pingchao Ke, Zhihong Liu

"To overcome the problem that scoroditeis not stable in neutral and alkaline solutions, we proposed and investigated a synthesis method of scorodite coated in-situ with hydrated ferric oxide in the Fe(II)-As(V)-H2O system at the initial Fe(III)/As(V) molar ratios larger than 1.0.The synthesis was carried out at 90?,pH 1.5 under atmospheric pressure. During the synthesis, oxygen gas was conducted and bubbled into the system to oxidize Fe(II) ions into Fe(III)ions, and Na2CO3aqueous solution as neutralizing agent was added controllably into the system for keeping the pH constant at 1.5. In this study, three samples of scorodite were synthesized at the controlled initial Fe(II)/As(V) molar ratios of 1.0, 2.0 and 3.0, respectively. The characterizations of the samples by HRTEM, TEM/EDX, and chemical composition indicated that the particle surfaces of scorodite synthesized at the initial Fe(II)/As(V) molar ratio of 2.0 and 3.0 were coated in situ by a film of hydrated ferric oxide with the thickness of several nanometers, while the sample synthesized at the initial Fe(II)/As(V) molar ratio of 1.0 was uncoated scorodite. The TCLP and long-term leaching for the toxicity characteristic of the samples showed that scorodite coated in situ with hydrated ferric oxide was stable in a wide pH range from 3.0 to 10.0, with the arsenic concentrations in the leaching solutions less than 1.0mg/L. Nevertheless, uncoated scorodite was unstable under the conditions from weak acidity to alkalinity, with the arsenic concentrations in the leaching solutions larger than 5.0 mg/L.INTRODUCTIONArsenic pollution is a challenge for environment and health and has been an important issue for scientists (Hopkin, 1989).Arsenicis commonly associated with ores or concentrates of nonferrous metals, mainly as independent arsenic bearing minerals such as arsenopyrite (FeAsS), tennantite(Cu12As4S13), enargite (Cu3AsS4), cobaltite (CoAsS), and gersdorffite (NiAsS), realgar (As2S2), orpiment(As2S3), etc.(Matschullat, 2000; Mandal & Suzuki, 2002; Long & Peng, 2012). In the nonferrous metallurgical processes, arsenic is enriched mainly in such arsenic bearing materials as various flue dusts, residues, and anode slimes, which results in the accumulation of arsenic in the system owing to the circulation of those arsenic-bearing materials back to the system and the pollution to the environment (Harris, et al, 2003).In addition, the utilization of arsenic is limited and has been decreasing owing to its toxicity and carcinogenicity. Therefore, arsenic has to be removed from those arsenic-bearing materials and discarded safely (Dutrizac & Jambor, 1988; Monhemius & Swash, 1999; Drahota & Fillippi, 2009).In this case, how to immobilize arsenic has become a difficult problem which must be solved. Among the methods of immobilizing arsenic which have been proposed and investigated, immobilizing arsenic into a stable mineral to fix it, has been realized as a promising method and becomes a research focus(Dutrizac et al, 1987; Dutrizac & Jambor, 1988; Demopoulos et al, 1995; Fujita et al, 2008a; 2008b).Scorodite has been known as one of the best minerals for immobilizing arsenic, owing to its high stability under weak acidic condition, the arsenic content as high as 32wt%,and good crystallinity benefiting the separation of solid to liquid(Daivid et al, 1999; Zhu & Merkel, 2001). Scorodite can be synthesized from arsenic containing solutions under both hydrothermal and atmospheric conditions, and a lot of work has been done on the synthesis of scorodite and its leaching stability characterization (Filippou & Demopoulos, 1999; Gomez et al, 2011).Two plants for the immobilization of arsenic as scorodite have been putin to operation in Chile and Japan, respectively (Filippou & Demopoulos, 1999; Amir et al, 2016)."

Jan 1, 2017

By Roberto Pena, Cristhian Morales, Darwin Morales, Veronica Cambiaso

"This article makes evident the shortcomings of the current operation of oxygen pipes as well as the damages they cause and why they cause them. When focusing on the causes and effects of these drawbacks, it was possible to develop a new family of thermal lances that could pierce a taphole with the precision of a drill but with the capacity to complete the whole operation. Although efforts have been made to replace oxygen pipes since they are annoying, dangerous and inefficient, nobody had worked to improve the way the traditional oxygen pipe taps/perforates the furnaces and reactors tapholes. In fact, developments made in drills and robotic arms, have failed to replace the oxygen pipe, which despite their negative side effects have been used for more than a century. Observation and theory were key to radically transform this humble tool into a dependable and efficient support in the operation. A good news that it is worthwhile to share for the benefit of all of us, passionate about the world of pyro metallurgy.INTRODUCTION Normally, reports and papers prepared for conventions, symposia or other technical events related to metallurgy aim to relevant topics in the operational field, probably because in them lay the scale economies every company pursues. We intend to give relevance to a matter normally disregarded in operations, but that unmistakably vital: if the furnace or reactor cannot be bled, the pyrometallurgical process will not be completed. Besides, if the tapping task is difficult or is long delayed, the availability of the furnace will be reduced. Consequently, there will be a waste of energy and workers will be exposed to dangerous levels of radiation as well as to work overload and physical injuries Apart from these basic effects, in tapping operations where oxygen pipes are used, we can see serious damages in the smelting furnace, especially in the taphole components such as refractory bricks, taphole jackets and water cooled plates. This paper intends to show that taking care of the tapping task can significantly upgrade not only to the tapping operation itself, but also the whole plant productivity."

Jan 1, 2017

By Claude Bazin, Jalna Lamontagne

"The operators of mineral processing plants collect daily samples from strategic process streams with a view to prepare production balances to assess plant performances. The rules to minimize the risk of systematic sampling errors are known and applied in many mineral processing plants. The mass of the sample to be collected is calculated to yield a target measurement reproducibility considering the fundamental error associated to the sampling of heterogeneous material. This paper demonstrates that this practice is partly valid if one does not account for the time variation of the ore composition during the day. The concept is demonstrated using samples collected on a 30 minute basis from different streams of a gold ore concentrator. Results show that depending of the natural variability of the stream characteristics the mass of the daily samples may not be the critical variable to obtain reproducible measurements. On the other hand the number of cuts taken during the day could impact on the variance of the measurements obtained from daily samples.IntroductionMineral processing plants may treat several thousand tons of ore every day to produce concentrate or impure gold ingots. The operation and performances of these plants are monitored on a daily basis through the collection of ore samples from various streams of the processing circuit. The samples are prepared and assayed to obtain the concentrations of target elements that are subsequently used to calculate the mass flowrates in the streams of the circuit and ultimately the distribution of the target metals for the estimation of the plant performances (Morrison, 2009; Lachance and Leroux, 2016).The acquisition of representative and reproducible samples is therefore the first step in the characterization of plant performances. The term representative sample is used here to indicate an unbiased sample, i.e. a sampling procedure that does not introduce a systematic error. Rules for the collection of unbiased samples are reviewed in the literature by different authors (e.g. Morrison, 2009) and are not discussed in this paper. The term reproducible indicates the dispersion of the measurements around the average value of a characteristic of a stream meets an acceptable level of variance. The reproducibility of a measurement process (sampling and analysis) is assessed by the relative standard deviation or coefficient of variation of the measurement that is a function of the sampling and assaying errors (Morrison. 2009; Gy, 1979). Usually the focus is put on the fundamental error of sampling whose variance can be controlled by the choice of the primary sample mass or adequate particle size reduction during the preparation of secondary or tertiary samples extracted for the chemical analysis. When a sample is taken from a stream that exhibits a time varying characteristic, the obtained measurement exhibits a variability that is not only a function of the sample mass but also of the natural variability of the ore in the sampled stream. This paper examines this aspect of the sampling of a time varying process on the reproducibility of composite samples for a day of production."

Jan 1, 2017

By Ahmad Ghahreman, Lin Li

"In this study, the Fe(II)/Fe(III) redox reaction kinetics on the surface of pyrite, have been investigated in a 0.5 mol L-1 sulfuric acid solution for a temperature range of 22 to 65°C. Based on mixed potential theory, chronoamperometry is introduced to study the Fe(II)/Fe(III) kinetics by subtracting the current density of pyrite oxidation in an iron-free acidic solution from that in an iron-containing solution at the same applied polarized potential. Tafel behavior was established by this method to analyze the kinetics of the Fe(II)/Fe(III) redox reactions. The results showed that exchange current densities increased slightly with temperature, however remained on the order of 10-5 A cm-2. The activation energy for Fe(II) oxidation and Fe(III) reduction on the pyrite surfaces was calculated to be 102.0 and 32.7 kJ mol-1, respectively. Anodic transfer coefficients also increased, from 0.24 to 0.39, with increasing temperature, which indicates a weakened n-type semiconductor property at higher temperatures. Electrochemical impedance spectroscopy measurements have indicated that at lower anodic over potentials the charge transfer is the rate determining step of pyrite oxidative dissolution in sulfuric acid solution. In the presence of Fe ions, the major contribution of the total current density comes from the Fe(II)/Fe(III) redox reaction. INTRODUCTION Pyrite, an abundant sulfides mineral in the nature, is commonly considered a valueless gangue mineral frequently associated with other valuable sulfide minerals such as chalcopyrite, or metals such as gold, or coal (Lin & Say, 1999). Pyrite oxidation has been the subject of extensive research in view of gold metallurgy, as oxidation of pyrite is the initial step to break down the pyrite lattice and expose the encapsulated fine gold particles (Gasparrini, 1983). Fe(III) ion and dissolved oxygen (DO) have generally been considered as the two most important oxidants with respect to pyrite oxidation, having been studied extensively in previous research (Zheng, Allen, & Bautista, 1986; King Jr & Lewis, 1980). The process of pyrite oxidation can be viewed as a series of reactions amongst pyrite, ferrous, ferric and oxygen in which pyrite is initially oxidized by the dissolved oxygen in water forming ferrous (Eq. 1), and then the ferrous also is oxidized by he dissolved oxygen to form ferric (Eq. 2). The ferric, produced by reaction 2, then could potentially oxidize pyrite (Eq. 3) and convert to ferrous."

Jan 1, 2017

By M. Cousineau, S. Gariepy

"Current business and corporate environments push for improving metal accounting practices in smelters. The ensuing projects commonly proceed along a bottom-up approach. As such, efforts are first put on reviewing the measurement system and then on remedying the identified weaknesses. The focus is thus moved to mass/metal balance only after the measurements upgrade process has been completed. However, practice has shown that assessing the high variances related to suboptimal measurement processes is complicated without the help of statistical data reconciliation. This bottom-up approach leads to a to-do list that can not only exceed available resources but also lack prioritization in view of achieving the targeted end use. This paper describes an upgrade project done differently where all the three dimensions of the metal accounting system: hardware, software, and people were instead involved at the onset. Personnel was thus trained on data reconciliation software at the beginning of the project to make the reconciled mass balance benefits available earlier in the upgrading project. This has pinpointed the most critical measurements where accuracy and reproducibility should be improved. Overall, not only the instrumentation retrofitting process has been streamlined, but the global risk for the whole upgrading project has been significantly lowered.INTRODUCTION Mining companies are pressured to improve their production accounting practices in response to the strengthening of corporate requirements for timely and accurate production reporting (Gaylard, Randolph, & Wortley, 2014). Smelters are not spared from these changes. However, their unique situation in the mining value chain set them as strategic targets for upgrading projects. They usually have a longer lifespan than concentrators thereby offering an extended lifecycle to justify investments. Furthermore, numerous smelters have toll agreements with third parties. Accurate cost and production accounting is, therefore, a vital piece of information to fix acceptable contract conditions. Mining companies are ultimately aiming at a clearer view of the operating performance of each business unit to improve their business decisions in a competitive environment. This sought for increase in visibility through plant performance can only be achieved through an upgrade of the metal accounting system. Figure 1 shows the different components of a state of the art system (Gaylard, Morrison, Randolph, Wortley, & Beck, 2009)."

Jan 1, 2017

By K. Morin, C. -Y. Hon, G. Lachapelle

"Air-sampling results suggest drill operators working inside environmental drilling cabs at an open-pit gold mine in Nunavut, Canada, are at risk of exposure to asbestos and silica (quartz). The authors installed RESPA® CF Vortex HyperFLOW® units, which showed promising results under laboratory conditions. The goal was to evaluate the effectiveness of these units under actual working conditions. Personal and area air sampling was conducted in drilling cabs with and without the unit and a Wilcoxon rank-sum test was performed to compare the results. Particulate concentrations were significantly lower in drill cabs with a unit installed than in those without.RÉSUMÉ Selon les résultats d’une campagne d’échantillonnage de l’air, les foreurs travaillant dans des cabines de forage environnemental dans une mine d’or à ciel ouvert du Nunavut, au Canada, risquent d’être exposés à l’amiante et la silice (sous forme de quartz). Les auteurs ont installé des unités RESPA® CF Vortex HyperFLOW®, lesquelles of frent des résultats prometteurs en laboratoire. L’objectif est d’évaluer l’efficacité de ces unités dans des conditions de travail réelles. Des échantillons de l’air inhalé par le personnel et dans les aires de travail ont été évalués dans des cabines de foreuses équipées ou non de cette unité ; un test de Wilcoxon (également appelé test de la somme des rangs de Wilcoxon) a été mené afin de comparer les résultats. Les concentrations particulaires étaient considérablement plus faibles dans les cabines de foreuses équipées d’une unité que dans celles en étant dépourvues.INTRODUCTIONGenerally, mining operations are associated with a variety of occupational hazards. In an open-pit gold mine in Nunavut, Canada, drill operators are routinely exposed to asbestos (primarily amosite) and silica (quartz)—two naturally occurring substances in the ore that is to be drilled (Table 1). Inhalation is the primary route of exposure for these two hazards, which are associated with respiratory health effects such as asbestosis and silicosis, respectively. In addition, asbestos and silica are classified as human carcinogens by the International Agency for Research in Cancer (2001, 2011). Given the toxicity of these two agents, it is imperative that precautions be taken to minimize the risk of exposure of the mine’s workforce. To address this matter, the mine has an exposure-control plan, which includes the provision of personal protective equipment, personal hygiene facilities, training, and a medical surveillance program. Furthermore, the mine performs occupational exposure assessments or air sampling on a regular basis because the morphology of the ore changes rapidly with respect to asbestos and silica content."

Jan 1, 2017

By F. McCarthy, W. Zhang, R. McDonald

"The processing of nickel laterites has been a topic of major interest at CSIRO for almost twenty years. During this period CSIRO has collaborated with other researchers and industry in developing a better understanding of existing processes and been actively involved in testing/developing new beneficiation and process options for these ores. The current paper summarises the results of selected studies and highlights improvements that have been achieved. Key topics to be discussed include enhancements in the mineralogical characterisation, beneficiation approaches, improvements in the understanding and application of leaching technologies, the development of synergistic solvent extraction (SSX) for the recovery of nickel/cobalt from laterite leach liquors and the collaborative development of the Direct Nickel process. Future opportunities and key research questions will be briefly examined.INTRODUCTION Nickel laterite ores comprise a significant resource in Australia and according to United States Geological Survey data nearly a quarter of world reserves are located there (USGS, 2016). More specifically, around 95% of Australian nickel resources (laterite and sulfide) are located in Western Australia (Australian Government, 2017). Given the recent closure of Queensland Nickel, essentially all of Australian nickel production occurs in Western Australia and the primary producers of processed nickel products include Nickel West (Kwinana) with ~84,000 t saleable nickel metal in 2016 (BHP Billiton, 2017), Minara Resources (Murrin Murrin) with 46,700 t nickel metal produced in 2015 (Glencore Australia, 2017), and First Quantum Minerals Ltd (Ravensthorpe) who sold 25,882 t nickel as mixed hydroxide product in 2016 (First Quantum Minerals, 2017). The total sales of nickel from Western Australia in the 2015-16 financial year were 175,722 t. The study of nickel laterites at CSIRO recommenced at the time second generation High Pressure Acid Leaching (HPAL) plants were being commissioned at Bulong, Cawse and Murrin Murrin in the late 1990’s. A combination of technical and engineering issues meant that the ramp-up times at these operations were slower than expected and the outcomes resulting from the attendant problems are well documented (e.g. Griffin & Becker, 2000; Reid & Barnett, 2002; O’Callaghan, 2003) while the issues faced at the BHP-Billiton-built Ravensthorpe plant have been addressed by the current owners of this project, First Quantum Minerals Ltd (Piper, 2012)."

Jan 1, 2017

By Gae On Kim, Ki Baik Kim, Suk Hoon Kang, Tae Kyu Kim, Sanghoon Noh

"Advanced radiation resistant oxide dispersion strengthened steel (ARROS) is being developed as a fuel cladding tube material for future nuclear reactor system applications. The research activities consist of advanced radiation resistant ODS steel development and fabrication technology development of ODS steel structural components. One candidate material with a chemical composition of (in wt%) Fe-10Cr-1Mo-0.5Mn-0.1V-0.25Ti-0.35Y2O3and was selected as representative materials, and this material was named as the advanced radiation resistant ODS steel (ARROSTM).On the basis of this ODS steel composition, an optimized fabrication process of structural components such as plates, sheets and tubes has been established through various process conditions in mechanical alloying, hot/cold working, and heat treatment processes. These R&D activities are expected to contribute to the realization of ODS materials in the future.INTRODUCTIONA sodium-cooled fast reactor (SFR) is being developed at the Korea Atomic Energy Research Institute (KAERI) with a view to economics, safety, reliability, and sustainability. The prototype Gen-IV SFR with a capacity of 150 MWe is under design, and this prototype reactor is scheduled to operate from 2028. For a commercial SFR system application, it is necessary to develop an advanced structural material having both high creep strength and irradiation resistance at high temperatures (Jeong, 2014). Oxide dispersion strengthened (ODS)steel is one of the most promising structural materials because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density, which is extremely stable at high temperatures under a neutron irradiation environment for a prolonged operating period(Kim, 2016). As the first step, several batches of ODS steel were designed and the candidate samples with a 2 kg scale each were fabricated by mechanical alloying, hot isostatic pressing and hot rolling processes. The mechanical properties of these samples were evaluated. Up to now, two candidate materials with chemical compositions of (in wt%) Fe-10Cr-1Mo-0.5Mn-0.1V-0.25Ti-0.35Y2O3 was selected as representative materials, and these materials were named as the advanced radiation resistant ODS steel (ARROSTM).The next step was to optimize the fabrication process of the ARROS compositions for in-core structural components such as the fuel cladding tubes of a SFR. An optimized fabrication process of fuel cladding tube with a composition of ARROS has been established through various process conditions in mechanical alloying, hot consolidation, hot/cold working and heat treatment processes. Joining technologies of the ODS steel tubes is being developed using solid-state welding such as magnetic pulse welding, friction stir welding and diffusion boding. It is expected that the development of ARROS will contribute to the realization of a commercial SFR with high economics and sufficient safety in the future. In this paper, the study of fabrication process of ARROS structural components is introduced."

Jan 1, 2017

By K. L. Boyd

"Can the increasing tonnages of ore and waste mined today be accommodated simply by using bigger and better crushers? This paper reviews the latest primary crushing and large cone crusher designs. It highlights how—in addition to using the larger crushers now available—maximizing the utilization percentages in each stage of the rock size reduction circuit will assist in meeting the larger production requirements of existing and new mining operations. Its goal is to help consultants and operators select the optimal equipment and custom-designed items in material handling from the mine to the mill, maximizing operating hours per year.RÉSUMÉ Le recours à des concasseurs plus grands et plus performants suffit-il à gérer l’augmentation du tonnage du minerai et des déchets que l’on extrait de nos jours ? Cet article examine les tous derniers modèles de concassage primaire et de grands concasseurs à cône. Il montre que, pour satisfaire aux exigences de production plus conséquente des exploitations minières existantes et nouvelles, il est important d’optimiser les taux d’utilisation à chacune des étapes du circuit de réduction de la taille des roches, en plus d’utiliser les concasseurs plus grands actuellement disponibles. L’objectif de cet article est d’aider les sociétés d’experts-conseils et les exploitants à sélectionner le meilleur équipement ainsi que des articles fabriqués sur mesure pour la manutention de la mine au concentrateur, en optimisant les heures d’exploitation par année.INTRODUCTIONAre larger crushers the answer to meeting the demands of existing or new mining projects for increased tonnage? Boyd (2002) predicted that larger crushers for primary and fine crushing would be beneficial and contribute to the further development of mineral processing. Larger crushers for primary and fine crushing applications have since become available.The rock size reduction process from the mine to the selected milling process facility has not changed since a person first broke a rock to get at the interesting mineralization within. The rock size reduction process circuit from the mine to the mill can be summarized in four stages:• stage 1: mining (rock breakage and fragmentation);• stage 2: prescreening (scalping);• stage 3: primary crushing; and• stage 4: fine crushing (secondary, tertiary, and quaternary).Plant throughput and ore delivery schedule will form the basis for flowsheet design and equipment selection. Once the project design criteria and the mine plan have been established, the circuit’s utilization percentage (percentage of hours when the circuit is being utilized) can be optimized for each of the four stages. The mining and process departments play a key role in the selection of the final comminution circuit, and both departments should be familiar with and contribute to the design of the circuit."

Jan 1, 2017

By Neri Roux, Chris Budgell, Allan Cramm, Leo Cheung

"Anaconda Mining Inc. is investigating potential improvements and expansions to their operating plant located on the Baie Verte Peninsula in Newfoundland. An extensive batch and continuous bench scale testing program was launched to investigate the efficiency of cyanide destruction under different conditions in order to improve tailings handling. The primary objective of the cyanide destruction study was to apply new technologies to develop a novel cyanide destruction system.Effluent and slurry from Anaconda Mining Inc.’s Point Rousse Project was received at RPC where test work was conducted. Various sodium metabisulfite (MBS) dosages were evaluated and the use of utilizing ozone and ultra violet (UV) light to oxidize cyanide was investigated. All the data was evaluated and mass balances were compiled to develop several flowsheets. Overall encouraging results were found using a combination of ozone and MBS.IntroductionAnaconda Mining Inc.’s Point Rousse project includes an operating gold processing plant located on the Baie Verte Peninsula in Newfoundland which is in the process of improving and expanding. This plant comprises of milling and flotation followed by cyanide leaching in order to extract the gold. The residue from cyanide leaching is filtered by drum filters prior to being clarified for the Merrill-Crowe process. Once the gold has been recovered by the Merrill-Crowe process the effluent is filtered by filter presses and the resulting filtrate as well as the solids from the drum filters are detoxified prior to being pumped to the tailings pond along with the flotation tailings.The entire process is very dependent upon the efficient destruction of cyanide in the effluents and successful tailings handling. Substantial amounts of effluent are delivered to tailings ponds after gold extraction which could create environmental problems if the regulations are not met. Environmental regulations stipulate that final effluents contain no more than 1 mg/L Total CN.The detoxified tailings of the Point Rousse project are produced by the INCO SO2-Air circuit depicted in Figure 1. These detox tailings contain 10 mg/L Total CN at that point of the circuit and this was selected as the target to be matched while reducing overall MBS consumption rates from 3.2 g/L per minute. Prior to detoxification, the filter press tailings contain 520 mg/L Total CN while the drum tailings contain 29 mg/L Total CN."

Jan 1, 2017

By J. Dennett, M. Faris, M. Antonio, M. Collins, N. Tuffrey, R. Ellenwood, V. Reddy

"In January 2012, AngloGold Ashanti Córrego do Sítio Mineração, with assistance from Sherritt International Corporation, commissioned a new autoclave for pressure oxidation of refractory gold concentrate at the Córrego do Sítio operation in Brazil. Start-up of the plant occurred in a few weeks and enhanced gold recovery was realized almost immediately, with 94% gold extraction achieved in carbon in leach (CIL), compared to less than 70% without pressure oxidation. This paper describes start-up and commissioning of the plant and provides an overview of plant performance over the last five years.INTRODUCTION In 2008, AngloGold Ashanti purchased the former São Bento property from Eldorado Gold, which, along with AngloGold Ashanti’s existing Córrego do Sítio mine, was renamed AngloGold Ashanti Córrego do Sítio Mineração (AGA Mineração). Later that year, the Sherritt Technologies division of Sherritt International Corporation (Sherritt) was contacted to begin batch and continuous pilot plant tests to determine the amenability of the AGA Mineração refractory gold concentrates to the pressure oxidation process. Based on the results of the batch and pilot plant tests, AGA Mineração requested basic and detailed engineering studies to be conducted by Sherritt, eventually leading to commissioning of the plant in January 2012. AGA Mineração’s plant is located in southeastern Brazil in the state of Minas Gerais, near the city of Belo Horizonte. AGA Mineração`s Phase 1 mine plan covers three sites in the Laranjeiras, Carvoaria Velha and Cachorro Bravo ore bodies, and is designed to process 60,000 tonnes of refractory gold concentrate per year to produce 140,000 ounces of gold per year with an 11 year life of mine (AngloGold Annual Financial Statements, 2010). Recovery of gold at AGA Mineração is based on Sherritt`s pressure oxidation technology for refractory gold concentrates (Berezowsky et al., 1991; Collins et al., 2011a; Collins et al., 2011b). This process had previously been applied to the recovery of gold at the São Bento site (Carvalho et al., 1988; de Silva et al., 1989), in a plant that was operational between 1986 and 2007 (Silva et al., 2004)."

Jan 1, 2017

By E. Engelbrecht

"A pressure non-oxidative leach is employed at Anglo American Platinum Base Metal Refiners to extract nickel from a slow cooled matte. The design base requires two 80 m3 autoclaves in parallel to achieve a nickel extraction of 60% at the nameplate capacity of 32.4 ktpa nickel plated. Isothermal modelling of mineralogical and chemical concentration profiles, through a reactive mass balance, permitted rate constant parameter estimation and selection of the most probable reaction pathway. The model was validated with plant data up to a capacity of 26 ktpa Ni plated and suggested by extrapolation that nameplate capacity may be viable through one 80 m3 autoclave.INTRODUCTION Anglo American Platinum Base Metal Refiners is situated on the outskirts of Rustenburg in the North-West province of South-Africa. The refinery produces nickel cathode, copper cathode, cobalt sulphate powder, covellite rich copper pressure leach residue and bulk sodium sulphate through an integrated circuit that refines slow cooled converter matte. The converter matte is milled, non-magnetics are separated as solid nickel copper matte (NCM), and the magnetics are leached yielding a pressure vessel liquor (PVL). The remaining solid platinum group metals (PGM) concentrate after leaching is sent for downstream processing in the Precious Metals Refinery (Hofirek & Kerfoot, 1992). The work presented here is applicable to the base metals refinery which receives the two base metals feed stocks NCM and PVL. In 2009 the capacity of the refinery was upgraded from 21 ktpa nickel cathode plated to 32.4 ktpa. This paper deals with evaluating the capacity of the pressurised non-oxidative nickel leach (NOX) process which accounts for at least 28% of the nickel leached from NCM by design. The NOX design base requires two 80 m3 autoclaves divided into four compartments operated in parallel at 155°C and 600kPa(g). Elevated temperature is required to speed up the leach kinetics of particularly nickel and iron which are trapped in slow leaching mineralogical phases namely millerite and bornite, (Dinham, 2006). The stated equivalent capacity for the NOX configuration was 32.9 ktpa nickel plated at first pass nickel and iron leach efficiencies of 60% and above 80% respectively and is a key step for the selective removal of iron (Bryson, Hofirek, Collins, Stiksma, & Bereaowsky, 2008)."

Jan 1, 2017

By J. R. Kadambi, E. Kucukal, J. Furlan

"Hydrocyclones are used in various industrial applications, including mineral processing and tailings management, to separate or classify solid particles and/or liquid droplets from multiphase feed. The fluid flow in a hydrocyclone (used in mineral processing) was investigated numerically and experimentally using particle-image velocimetry (PIV) and refractive index matching techniques. Two turbulence models were used in the calculations: the k–? model and the Reynolds stress model. Particle image velocimetry measurements were taken at various spatial locations along the cyclone. Computational results were validated globally using pressure and flow-rate readings at the boundaries, and locally by comparing the PIV velocity-vector maps and profiles.RÉSUMÉ On utilise les hydrocyclones dans diverses applications industrielles, dont la minéralurgie et la gestion des résidus, pour séparer les particules solides et/ou les gouttelettes liquides de l’alimentation polyphasée, ou pour les classifier. Une étude numérique et expérimentale sur l’écoulement des fluides dans un hydrocyclone (dont on se sert en minéralurgie) a été menée à l’aide des techniques de vélocimétrie par images de particules (PIV, de l’anglais particle image velocimetry) et d’appariement des indices de réfraction. Deux modèles de turbulence ont été utilisés dans ces calculs, à savoir le modèle de turbulence k–? et le modèle aux tensions de Reynolds (RSM, de l’anglais Reynolds stress model). La valeur de la PIV a été mesurée à diverses positions spatiales le long du cyclone. Les résultats de ces calculs ont été validés globalement à l’aide de relevés des pressions et du coefficient d’écoulement d’une extrémité à l’autre de l’hydrocyclone, et localement à des coordonnées spatiales spécifiques en comparant les cartes et les profils du vecteur vitesse PIV."

Jan 1, 2017