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By Binbin Luo, Northeastern University, Chuanyao Sun, Jie Liu, Yimin Zhu, Yanjun Li

"A series of new type collectors a-bromo-saturated fatty acids, CH3(CH2)5CHBrCOOH (a-BHA), CH3(CH2)7CHBrCOOH (a-BDA), CH3(CH2)9CHBrCOOH (a-BLA), CH3(CH2)11CHBrCOOH (a-BMA) were synthesized from saturated fatty acids and bromine by solvent-free method (Hell-Volhard-Zelinski reaction) in laboratory. The micro-flotation tests of quartz mineral were conducted at a relatively low temperature of 15 °C. The adsorption mechanism of such collectors on quartz mineral surface were established by zeta potential measurements, in conjunction with the results of quartz micro-flotation tests. The flotation results showed that the collecting ability is in the order of a-BMA > a-BLA > a-BDA > a-BHA for the flotation of quartz mineral, which also demonstrating that the a-bromo-saturated fatty acids (a-BFAs) are new selective collectors for reverse flotation to remove quartz mineral from iron ores at a relatively low temperature.INTRODUCTIONThe requirement of higher pulp temperature to maintain the activity of fatty acid anionic collectors which have been widely applied in technological process of iron ores reverse flotation lead to a great deal of energy consumption.The purpose of this paper is to synthesize a new modified collector with carbon chains from eight to fourteen atoms, with strong electronegativity bromine atom introduced into a-carbon position to improve the activity and solubility of the reagent so that it can be adopted at a comparatively low pulp temperature. The collecting performances of these new collectors on quartz surface were studied, and the structure - properties were discussed in light of zeta potential measurements and quantum chemistry calculations."

Jan 1, 2016

By Leopoldo Gutierrez, Sergio Castro, Lina M. Uribe, Janusz S. Laskowski

"The effect of sulfite and metabisulfite ions on the amyl xanthate flotation of copper-activated pyrite, in distilled water and seawater, has been studied by micro-flotation tests and redox potential measurements. The activation of pyrite was carried out varying copper ions concentration. It was found that in the presence of copper ions in solution, sulfite and metabisulfite are able to depress copper-activated pyrite at neutral or slightly acid pH. After the addition of sulfite or metabisulfite ions the resulting pH is more acidic with metabisulfite ions. A significant increase of the redox potential of the solution was observed as copper ions concentration increased. Then, the initial reducing conditions brought about by sulfite and metabisulfite ions, change abruptly to oxidizing conditions in the presence of copper ions. Under these oxidizing conditions, the metabisulfite showed to be an effective depressant for pyrite mainly in seawater. However, sulfite was a pyrite depressant in both distilled water and seawater. Based on these results, the pyrite depression by sulfoxy-depressants during the flotation of Cu/Mo ores in distilled water and seawater is discussed.INTRODUCTIONDepression of pyrite by sulfoxy-depressants (sulfite and metabisulfite) in the presence of copper ions is an important issue. This is particularly true when pyrite depression in the flotation of Cu/Mo sulfide ores is carried out in seawater. The use of lime in seawater must be avoided because the formation of magnesium hydroxy-complexes and precipitating magnesium hydroxide strongly depresses molybdenite flotation (Castro et al., 2014). In order to solve this problem, one large plant in Chile uses sodium metabisulfite (MBS) instead of lime to depress pyrite in seawater. In plant practice, this also improves molybdenite flotation since with the use of MBS the pyrite depression is carried out at pH 6-7, instead the pH 11-12 usually employed with lime.From a general point of view, pyrite exhibits some natural floatability over acidic pH ranges and may be partially floated without thiol collectors (a coating of sulfur/polysulfides has been claimed). Therefore, pyrite flotation with xanthates is usually high in the acidic pH region, but decreases greatly at alkaline pH (Leppinen, 1990; Fornasiero and Ralston, 1992; Zhang et al., 1997)."

Jan 1, 2016

By T. Hadley, Northern Minerals Ltd, C. S. Griffith, T. A. Safinski, K. H. Soldenhoff, M. Fainerman-Melnikova, A. Manis

"ANSTO Minerals and Northern Minerals have been working together since 2012 on the process flowsheet development for the Browns Range project for the recovery of the heavy rare earths (Dy – Lu, + Y). Initial efforts were directed toward defining the most efficient and direct flowsheet for the Preliminary Feasibility Study (PFS), issued in June 2014, then towards the Definitive Feasibility Study (DFS), issued in February 2015. These goals were achieved by undertaking comprehensive laboratory and continuous piloting programs. Further improvements to the flowsheet following the DFS have been made. This publication provides an overview of the evolution of the process flowsheet based on these laboratory and piloting programs from the PFS through the DFS and beyond.INTRODUCTIONNorthern Minerals Ltd (Northern) has been working on developing their flagship project at Browns Range for the recovery of the heavy rare earth elements (HRE, Dy – Lu, + Y). The project is located in the north of Western Australia as shown in Figure 1. The Total Mineral Resource at the project is currently estimated at 8.98 Mt @ 0.63% total rare earth oxides (TREO) comprising 56,663 t of contained TREO using a cut-off grade of 0.15% TREO. Of the Total Mineral Resource, 58% is classified as Indicated Resource, with the remainder in the Inferred Resource category.The deposit is characterised by breccia-hosted, hydrothermal, HRE-rich, xenotime mineralisation. The main gangue mineral associated with the xenotime is quartz. The distribution of rare earths (RE) observed for the xenotime mineralisation at Browns Range is presented in Figure 2. Extensive test work has shown that the xenotime can be readily beneficiated to between 20 – 40% rare earth oxide (REO) using a process consisting of crushing and grinding, followed by magnetic separation and flotation steps. Continuous piloting of this process was conducted on ~80 t of trench-sourced ore in late 2013 at SGS Perth, to produce ~2 t of ~20% REO mineral concentrate (MC) for hydrometallurgical testing. The composition of the MC produced during piloting is presented in Table 1."

Jan 1, 2016

By G. Bimpilas, G. N. Anastassakis

"Today, one of the most intense problems in mineral processing systems is referred to the treatment of fine (–100 µm), and even smaller size, particles. Fine mineral particles possess specific properties (small mass, high specific surface area, and high surface energy per unit area) that render their separation inefficient with conventional methods (physical, physicochemical) and equipment. As a result, it is not feasible to obtain a concentrate both of high grade and recovery in mineral value and a considerable amount of mineral fine particles is lost to the tailings. As evidence, we could cite numerous examples from industrial practice with considerable loss of mineral values to the tailings because of the fine particles size, e.g. phosphate, tungsten, tin, etc.The objective of the current paper is to investigate the possibility to separate magnetic gangue minerals and rocks (serpentine, ilmenite, and olivine) from magnesite by co-agglomerating all the gangue components and subsequent magnetic separation of the agglomerates.To meet the target, hydrophobic agglomeration tests were initially carried out on single minerals to define the favorable conditions for selective hydrophobic co-agglomeration of the gangue minerals. In this respect, the effect of the following factors was examined: pH, collector dose, conditioning time, and settling time of the agglomerates. Among the combinations examined, the most favorable proved that with amine in the basic pH region. The use of non-polar oil proved beneficial. The preliminary results were confirmed by tests on mineral mixtures. The application of magnetic separation resulted in the removal of gangue minerals and the recovery of magnesite concentrates of commercial grade (magnesite content 95% approximately) and high yield.The current paper contributes to the development of mineral processing, since it successfully copes with a very important problem of mineral processing, such as the efficient separation of fine particles."

Jan 1, 2016

By David Stephenson, Hugo Granados, Steven Klohn

"HudBay’s Constancia project is a copper molybdenum concentrator located in southern Peru. In 2010 Ausenco was contracted to perform a feasibility study optimization review which resulted in an improved design with significantly increased throughput capacity at a minimal increase in capital cost. Construction began in 2012 with commercial operation commencing in May 2015. This paper outlines the process plant design as well as describing the plant’s major equipment selections, start-up and early operations experiences.IntroductionHudBay Mineral’s Constancia project is located at 4200 meters above sea level (masl) in southern Peru, approximately 630 km south-east of Lima, Peru. The property can be accessed by road from Cusco, Peru, (approximately 110 km to the north), or from Arequipa, Peru (approximately 215 km to the south). Matarani, accessed via Arequipa, is the closest port.Constancia is located within the Yauri-Andahuaylas metallogenic belt. The region contains several large copper-gold-molybdenum porphyry deposits such as Antapaccay (by Glencore) and Los Chancas (by Grupo Mexico), and copper skarn deposits such as Tintaya (by Glencore) and Las Bambas (by MMG). Constancia’s ore reserves contain copper and molybdenum with trace amounts of gold and silver.Ore is mined by an open-pit operation. The process plant recovers copper and molybdenum concentrates, storing tailings in a conventional tailings management facility. Infrastructure at the site includes a grid power supply (via a 70 km overhead transmission line from Tintaya), water supply, workshops and an accommodation camp. Mine life is 22 years.Site construction works began in 2012 with first copper concentrate produced in late 2014. The project was executed for approximately 1.75B$USD.Ausenco’s design approach focussed on developing a capital efficient copper molybdenum concentrator. This paper outlines key features incorporated in the concentrator design, plant layout and equipment selection, as well as start-up experiences and early operational results."

Jan 1, 2016

By Kari Niiranen, Andreas Boehm

LKAB (Luossavaara-Kiirunavaara AB) is operating underground iron ore mine, with three beneficiation and pelletizing plants in Kiruna, Northern Sweden. The wet low intensity magnetic separation (WLIMS) is regarded as the crucial part of silicate mineral separation from the ore. The Kiirunavaara iron ore deposit shows a rather low content of silica (ca. 2.3 to 3.3 % SiO2) but the silica grade is expected to increase in the deeper parts of the deposit. This can be problematic in the case of DR pellet quality with an average silica grade under 0.75 % SiO2. A laboratory scale methodology was developed for the systematic characterization of the ore for mineral processing with the focus on silicates at the Institute of Mineral Processing, University of Leoben. This methodology is combining mineralogical, geochemical and process mineralogical characteristics. Automated mineralogy (QEMSCAN) was used to study the modal mineralogy, the distribution of silicate minerals in different particle size classes after comminution, the deportment of silicon (Si) between various silicates and degree of liberation and intergrowth of magnetite and silicates. Based on the mineralogical investigations, actinolite, phlogopite and even quartz and albite are the predominating SiO2 bearing minerals in the ore. The important result of the investigations was the discovery of two separate subtypes within the high silica ore type B2 based on their mineralogy and mineral processing characteristics. The crucial part of the investigations of intergrowths and liberation of magnetite results was the magnetic separation tests carried out with the Davis magnetic tube. The binary intergrowths of magnetite and the silicate minerals (mostly actinolite) are the most common type of mineral association discovered. The significant characteristics in the intergrowths of magnetite and actinolite are the fine-grained magnetite inclusions in actinolite which may end up increasing the SiO2 grade in the magnetite concentrate despite magnetic separation.

Jan 1, 2016

By Frederik H. Kriel, John Ralston, Craig Priest

"Stream-based microfluidic solvent extraction offers a novel alternative to bulk-scale mixer-settler operations. However present maximum throughputs are restrictive and there are engineering challenges that need to be overcome before the technology is robust. This is especially the case for mineral processing, where circuits must be able to handle variable feed streams with long retention times and where maintenance should be minimized. This paper highlights research directed at investigating and evaluating these challenges for actual mineral leach solutions of metal ions. Molecular and particulate channel fouling is discussed. Most extraction systems studied to date show no effects that would preclude use of the technology. For rare earth elements (REE) with fast extraction rates, scale-up of volumetric throughput to 100 L/h using suitable arrays of channels, microfluidic chips and modules is shown to be achievable using a small contactor (approx. 2 m3) platform. This requires only 2–3 % of the typical aqueous phase inventory and residence time used in an equivalent mixer-settler. For a circuit with 100 contactors, the overall residence time would be less than 1 h, using an aqueous inventory of 40 L.INTRODUCTIONHydrometallurgy is of pivotal importance in many mineral processing circuits around the world, with liquid-liquid solvent extraction (SX) a key step in the separation of many base metals (e.g. Cu and Ni), radioisotopes, precious metals, and the ‘technology’ metals, such as rare earth elements (REEs) (Ritcey & Ashbrook, 1979). The standard equipment for SX in mineral processing is the mixer-settler, in which liquid dispersions are created, by agitation, to increase the surface-to-bulk ratio and, thus increase the mass transfer rate between the liquid phases. In stream-based microfluidic SX (microSX), these high surface-to-volume ratios are achieved by contacting microscopic streams (Ciceri, Perera, & Stevens, 2014), rather than forming small droplets, so that phase disengagement can be accelerated (essentially instantaneous via branching of the two streams of liquid at a channel junction). MicroSX is profoundly different from bulk mixer-settler SX operations and offers exciting opportunities for processing hydrometallurgy solutions (Kriel, Holzner, Grant, Ash, Woollam, Ralston, & Priest, 2015; Priest, Zhou, Klink, Sedev, & Ralston, 2012). Nonetheless, the advantages of using microfluidic environments are presently balanced by very significant challenges relating to throughput, process control, coupling of stages, flow stability, and fouling. If these challenges can be met using smart chip designs, process control and clever engineering, high-value/low-volume SX processes stand to benefit greatly."

Jan 1, 2016

By K. C. Corin, Z. G. Song, J. G. Wiese

In the present investigation flotation was used as a diagnostic to understand the effects of changes to the media during the grinding stage. The observations from flotation for different media are discussed in terms of particle size distribution, water recovery, solid recovery and valuable mineral recovery. The chemical parameters; pH, redox potential (Eh) and dissolved oxygen (DO) levels were measured. A Base Metal Sulphide (BMS) ore was ground under media of different shapes and compositions to determine the effect of different rod/ball material on the flotation performance of the ore. For a given grind (D80 = 75 µm), media shape had no effect on flotation performance of a BMS ore. Different grinding media had significant effect on slurry chemical properties and flotation performance. Mild steel rods (RMMS) produced the highest solids recovery, nickel and pyrrhotite (Po) recovery, with the highest ethylenediaminetetraacetic acid (EDTA) extractable iron and the lowest DO level. Chrome steel balls and stainless steel rods produced the lowest metal recovery, EDTA extractable iron and the highest DO level. A complementary study was conducted to investigate the effect of using different grinding media compositions, viz, ceramic, forged steel, 15% chrome steel, stainless steel and a mixture of stainless steel and 15% chrome steel (50:50) balls were investigated using a Platinum Group Mineral (PGM), UG2 ore. Grinding products of five different media produced the same solids and water recovery, but the grades and recoveries of Platinum Group Elements (PGE) and chromite were different. Grinding products of ceramic media showed the best flotation performance, with the highest PGE recovery and the lowest Cr2O3 recovery. While grinding products of stainless steel balls (SS) produced the lowest PGE recovery and highest Cr2O3 grade and recovery in the concentrates.

Jan 1, 2016

By Francisco Tamargo

"This paper refers to a new process for the full recovery (above 98%) of zinc and other valuable metals (Pb, Ag, Au) accompanying zinc in its concentrates while iron is separated as a marketable product free of any harmful impurities and suitable for sale to the cement industry. The process has been especially designed to achieve the following goals: maximizing the recovery of zinc and those valuable metals that are present in most zinc concentrates (lead, silver, gold); allowing the recovery of other valuable metals such as indium or germanium that could be present in some zinc concentrates; avoiding or minimizing the need for residue disposal in safe areas as it is the common practice nowadays in the zinc industry. Finally, the process achieves the previously related goals at a competitive cost, in line with the existing more efficient operations while using conventional equipment working under atmospheric conditions. The new process can be easily implemented in those smelters using the jarosite or goethite processes as well as in those smelters using direct leaching as a part of the processing facilities. A study has already been conducted on the use of jarosite in the cement manufacturing process, in the raw mix preparation as well as for a set controller. It shows that use of clean jarosite in the manufacture of ordinary Portland cement can result in improved quality of the clinker. Jarosite showed compatibility to influence the burning characteristics of the cement raw mixes. The presence of SO3 bearing mineral phases such as natrojarosite showed the suitability of clean jarosite for use as a set controller in cement production.INTRODUCTION Iron is by far the most abundant impurity accompanying zinc in its concentrates, and consequently, iron residue disposal is a major environmental concern for many zinc smelters in the world. This is especially true during the last 30 years when environmental restrictions became more and more strict. Much research work has been carried out during the last 30 years to try to find a solution for this important issue, but with little success. Only the jarofix process represents a partial solution to this problem as jarofix is stored nearby the smelters with certain limitations as a non-contaminant residue. However, it does not avoid the need to dispose of an important amount of residues every year, representing an environmental liability. Meanwhile, the number of countries limiting or banning the disposal of iron residues generated by the zinc smelters is growing, so that the solution to this problem is becoming an urgent matter right now. At the same time, the lack of appropriate available land for iron disposal is also a major concern in many cases."

Jan 1, 2016

By McGill Metals Processing Centre, S. Chang, L. Calzado, X. K. Cao, C. H. Hsin, M. Isac

"Due to the increasingly stringent cleanliness requirements for final steel products, there has been a growing interest in the possible use of micro-bubbles for the removal of inclusions with diameters smaller than ~50µm, present within the steel passing through a steelmaking tundish. However, several technological barriers have prevented the adoption of this technique in industry. These are related to a) the generation of micro-bubbles in liquid steel, b) the measurement of bubble size distributions, and c) the optimization of bubble injection conditions to create micro-bubbles. In the present study, a novel Aqueous Particle Sensor (APS) system was developed for the in-situ, on-line, detection of micro-bubbles in water, generated by a newly designed full-scale ladle shroud, located at McGill Metal Processing Centre (MMPC). Measurement results from the sensor were validated against bubble size data collected through a high speed camera and post-processed through the commercial software, Image J.Control variables and orthogonal experiments were designed to assess the dependence of average micro-bubble sizes and bubble size distributions on key experimental parameters. Those chosen were the air inlet flowrate, the distance of the gas injection port from the slide gate, and the number of injection ports used. The investigation demonstrated that the APS system can be successfully adapted to detect micro-bubbles up to ~800 micron diameters. Using this novel sensor, it was shown that multi-port injection using low air inlet flowrates, closer to the slide gate, were useful in forming small micro-bubbles within the flow through the ladle shroud. The results from the APS system were compared and validated against data resulting from an optical technique. INTRODUCTIONModern industry expects increasingly stringent cleanliness requirements for final cast products. Therefore, the numbers and sizes of inclusions need to be strictly controlled in steelmaking operations. Thus, the cleanliness of steel products depends on the amount, morphology and size distributions of nonmetallic inclusions in steel (Zhang L. & Thomas B., 2003). Since large, deep, tundishes provide longer nominal residence times for liquid steel passing through it to the exit SEN’s, this can provide the ideal place to separate inclusions, and bubbles can assist by removing help attach inclusions and float them to the top surface."

Jan 1, 2016

By P. Hickey, G. Hubert, P. Healy

"J. S. Redpath Limited, an underground contractor with a worldwide presence, has implemented innovative techniques in various projects in Canada to shorten the development cycle. Conventional methods currently used for installing primary ground support are compared with the Australian technique of bolting and meshing with jumbos equipped with twin telescopic booms, in-cycle shotcreting, and the use of two jumbos and two scissor bolters set up side by side in wide headings. Recommendations and lessons learned are presented with the aim of providing realistic expectations with regard to development advance rates in a mining environment.RÉSUMÉ J. S. Redpath Limitée, un entrepreneur minier souterrain d’envergure mondiale, a complété plusieurs projets au Canada où des techniques novatrices ont été mises en oeuvre pour raccourcir le cycle de développement. Cet article présente une comparaison entre les méthodes conventionnelles fréquemment utilisées pour le support de terrain, la technique australienne de boulonnage et d’installation de grillage au moyen de jumbos équipés de flèches télescopiques doubles, du béton projeté appliqué durant le cycle de développement et de l’utilisation de deux jumbos et deux boulonneuses côtes-à-côtes dans des galeries de grandes dimensions. Les recommandations et les leçons apprises sont présentées dans le but de fournir au lecteur des attentes réalistes quant aux taux d’avancement du développement dans un environnement minier."

Jan 1, 2016

By Q. Ricoux, F. Goettmann, A. Maihatchi

"Electrodeposition processes are widely used in the metallurgical industry to produce, extract and refine metals from various feed materials. However, raw materials used to provide non-ferrous metals often contain high amounts of iron. In the presence of iron, while metals are plated at the cathode, electrowinning processes produce corrosive and highly oxidative ferric ions at the anode that are harmful for the process sustainability. In fact, these ferric ions cause dramatic current efficiency loss, induce high maintenance expenditures to limit the corrosion of devices and it results in the formation of impure and dendritic deposits on the cathode. Consequently, the management of iron in electrodeposition process became a major issue in non-ferrous metals production. Actually, numerous methods have been developed to limit the ferric ion concentration in the electrolyte or, at least, to limit its harmful effect. Many methods aim to limit the iron(III) concentration in the electrolyte, generally by coupling electrowinning to extraction process such as solvent extraction (SX) (Bender & Emmerich, 2015), ion exchange (IX) (Gula, Dreisinger, & Horwitz, 1996) or cementation (Kust, 1979) processes to remove ferric ions. Other routes consist of (i) using the ferric ions oxidant properties to leach raw materials, either directly in the electrolytic cell (Fanta & Tributsch, 1975) or through a secondary circuit (Cain, 1950), or (ii) reducing ferric ions through periodic reversal of direct current to enhance the formation of Fe2+ (Loutfy & Bharucha, 1980). On the other side of the spectrum, papers discuss methods to valorize the iron from by-products of the non-ferrous metal industry, that generates vast quantities of iron containing wastes (A. Agrawal, Sahu, & Pandey, 2004). Many studies on iron electroplating and electrolytic iron production from ores have been carried out (Cain, 1950; Mostad, Rolseth, & Thonstad, 2008), but very few have been conducted on waste or by-products. Therefore, we propose to build on the previous literature review to develop a process for the production of electrolytic iron from by-products.INTRODUCTIONNon-ferrous metals and their alloys are used in a large variety of applications. Aluminum and titanium are used for their strength, light weight and corrosion resistant properties in structural applications. Copper has been used in various applications requiring high thermal and electrical conductivity, as kitchen products and electrical wires. Nickel and zinc are commonly used as plating materials; nickel offers a wide range of working temperature and zinc is used for steel plating. Gold, silver, and platinum group metals are used in electrical/electronic applications, jewelry and chemistry as catalysts."

Jan 1, 2016

By P. Erskine

"Hyperaccumulator plants can be utilized as ‘metal crops’ in agromining operations. This emerging technology produces ‘bio-ore’ by growing ‘metal crops’ on sub-economic ore materials, such as natural ultramafic soils. In a typical application plant material is periodically harvested, followed by air-drying and incineration to produce the bio-ore intermediate. The bio-ore is of very high grade (>15 wt. % nickel), and of high purity, and may be processed into a number of different products (including nickel metal, nickelbased catalysts and pure nickel salts). Current research efforts from our team focus on Mediterranean climate field trials (Albania, Spain) and tropical climate field trials (Malaysia, Indonesia). Field-scale demonstrations are required to provide evidence of real-life performance and of economic viability. If the trials are successful, agromining may in the near future support local livelihoods with income opportunities as an alternative type of agriculture: to farm nickel.INTRODUCTION AND BACKGROUNDHyperaccumulators, plants with the exceptional ability to uptake and concentrate trace elements in their shoots, can be utilized as ‘metal crops’ in agromining operations (Van der Ent et al., 2013a; Chaney et al., 1998; 2007; Baker et al., 2010). Agromining produces ‘bio-ore’ from harvested ‘metal crops’ grown on unconventional resources such as natural ultramafic soils (Van der Ent et al., 2015a). The bio-ore is a high purity and very high-grade (>15 wt. % nickel) product intermediate that may be turned into a range of different nickel products (nickel metal, nickel-based catalysts and pure nickel salts). The potential for agromining is greatest in tropical regions (Asia-Pacific Region: Indonesia, Malaysia, Philippines, Papua New Guinea and New Caledonia) where very large expanses of ultramafic soils exist (Van der Ent et al., 2013b). Agromine operations may replace existing marginal agriculture on poor ultramafic soils, for example oil palm plantations that require high fertilizer inputs to be profitable, or take place under a cocropping regime. The ability of ‘metal crops’ to achieve high nickel concentrations in biomass (and hence in harvested bio-ore) from soils with just <0.5 wt. % nickel, makes it possible to access non-conventional resources, not accessible by traditional mining techniques. For example, agromining could be implemented both on the large ‘halo’ around the mine leases, and as part of the progressive rehabilitation process after conventional resource extraction. As with all methods for resource extraction, agromining will be finite due to the diminishing concentrations of nickel in the zone accessible by plant roots (Chaney et al., 2014). Nevertheless, considering soil materials with 0.2 wt. % nickel and ‘metal crops’ with a yield of 100 kg nickel ha-1 the agromining venture may be sustainable for decades (Van der Ent et al., 2015a)."

Jan 1, 2016

By T. Wajima

"A novel carbonaceous adsorbent for recovery of nickel from nickel plating waste solution was prepared from rice straw using sulfur impregnation. The rice straws were cut to 1 cm pieces, and then immersed in 0.01 - 3 M K2S solution to prepare sulfur-immersed materials. The immersed-materials were heated at 100-700 ºC in nitrogen gas to produce the sulfur-impregnated carbonaceous adsorbent by pyrolysis. The contents of carbon and sulfur in the adsorbent and abilities of adsorbent to recovery nickel from aqueous solution were examined. The contents of carbon and sulfur in sulfur-immersed materials are almost same as those in raw material. In pyrolysis, with increasing the heating temperature to 200 ºC, the contents of carbon and sulfur are almost constant, and then above 300 ºC those increase. The recovery for nickel using raw material, sulfur-immersed material and the product pyrolyzed at 100 - 200 ºC are almost same, and with increasing the heating temperature to 400 ºC, that of the product increases, and above 500 ºC that of the product decreases. In immerse step, with increasing K2S concentration, the carbon content of the product at 400 ºC gradually decreases, the sulfur content of the product increases, and the recovery for nickel using the product gradually increases and then above 1 M K2S decrease. The product prepared from material immersed in 1 M K2S solution at 400 ºC indicates a maximum recovery for nickel ion. The product can adsorb nickel ion in nickel plating waste solution coexisting with phosphate ion, and adsorbed nickel ion in the product was deposited as nickel metal after heating at 1000 ºC under N2 atmosphere.INTRODUCTIONRice is the second world’s largest cereal crop after wheat, but produces large amount of straw residues, of about 330 million metric tonnes. Rice is a widely grown crop in Asia, and rice straw is produced as a by-product of rice production. In most parts of rice fields, open-field burning of rice straw is commonly practiced in the region when there is limited time to prepare a field for the next crop. However, open-field burning of crop residues is an uncontrolled combustion process during which air pollutants are emitted into atmosphere. These air pollutants have significant toxicological properties and are potential carcinogens (Gadede et al., 2009). Although wildfires are prohibited in cultivation fields of most countries, farmers usually keep on burning their crop by-products. Biomass burning is an important source of aerosol particles which may affect local and regional air quality (Gao et al., 2011), and also contribute to global climate changes."

Jan 1, 2016

By J. T. Liu, G. H. Han, W. C. Chai, Y. F. Huang

"In beneficiation process, metal ions could adsorb onto clay mineral surfaces or interact with flotation chemicals, and then result in the flotation behavior changing of desired minerals. Al(III) is the dominating ion existing in the bauxite flotation system. In this research, the adsorption behaviors of Al(III) on two silicate clay minerals (including bentonite and kaolin) were investigated by means of UV-Vis spectra, zeta potential testing and scanning electron micrograph analysis. The adsorption experiment results show that the adsorption capacity of clays for Al(III) ions increases with the initial Al(III) concentration, contact time and solution pH. There are some different adsorption behaviours for two clays. Increasing the clay concentration decreases the adsorption capacity of bentonite, while increases first then decreases for kaolin. Higher temperature favours the adsorption of Al(III) on bentonite but goes against for kaolin. The adsorption capacities of bentonite and kaolin for Al(III) respectively reach 12.48 and 0.875 mg/g at initial solution pH 5. Zeta potential results show that the adsorption of Al(III) on two clays is characterized by electrostatic attraction mechanism.INTRODUCTIONIn beneficiation process, there is inevitably a wide variety of metal ions generated from mineral crushing, mineral dissolution and water chemistry conditions. Metal ions adsorb on the mineral surfaces or interact with the beneficiation agents, affecting the flotation efficiency of desired minerals (DiFeo et al., 2001; Parolis et al., 2008; Shackleton et al., 2012; Shengo et al., 2014). Therefore, it is necessary to have a detailed investigation on the adsorption behaviour of metal ions on clay minerals.Having good ion exchange capacity and negative surface charge, the clay minerals could take up various metal ions from the mineral-water system. Bentonite and kaolin are very common aluminosilicate clays in the mineral processing system. These two clays both hold a permanent negative charge, =X- on the basal surfaces, and a smaller variable charge, =SiOH on the mineral edges (Gu & Evans, 2008; (Gu et al., 2010). Adsorption experiments are usually used to study the adsorption affinity of metal ions for clay minerals (Sen & Bhattacharyya, 2012). The adsorption of Zn(II), Cu(II) and Pb(II) onto natural bentonite showed that the adsorption amounts of metal ions increase with contact time, solution pH and metal ion concentration, but decreases with adsorbent concentration and system temperature (Sen & Gomez, 2011; Melichova & Hromada, 2013). Cr(III) adsorption on bentonite was significantly pH dependent. The adsorption process followed pseudo-second-order model and the equilibrium adsorption was consistent with Freundlich isotherm (Lollino et al., 2015). The adsorption behaviours of Pb(II), Cd(II), Ni(II) and Cu(II) onto kaolin indicated that increasing pH favoured the adsorption of metal ions (Jiang et al., 2010). The adsorption of Cd(II), Cu(II), Pb(II) and Zn(II) onto kaolin showed that an ion-exchange reaction occurred at pH<7.0 and inner-sphere surface complexes were prone to form at higher pH (Srivastava et al., 2005)."

Jan 1, 2016

By C Jincheng, L. Liang, L. Wenjun

"Considering overgrinding in a grinding process, the grinding characteristics of comminuted hematite products using a HPGR and a conventional CC were comparatively studied. The major properties including particle size, grinding kinetics and grinding technical efficiency (Et) were investigated. Individual size distributions (ISDs) of -2.0mm in a HPGR product showed a more significant “double-peak” characteristic than a CC product. As a result, HPGR products were finer and had a wider full-size distribution because of the greater proportion of fines. The parameters m and zi in m-th order grinding kinetics were analyzed by the partial-derivative method and the critical time tc(tc = exp (1/ zi)) was obtained. zi mainly affected the breakage rate when t < tc; otherwise, m mainly affected the breakage rate. In these tests, tc was considerably higher than the grinding times, and HPGR products yielded a higher zi-value than the CC product for the same sieve size. This indicated that HPGR products had a higher breakage rate and needed a shorter grinding time for a certain grinding fineness. Et was calculated by simulating the size distributions of batch grinding products. HPGR products gave a lower Et at a decreasing rate than the CC products for -2.0 mm feed and -0.5mm feed, and then showed a slightly higher Et for -2.0+0.5 mm feed. This indicated that overginding in HPGR full-size products was more serious under the condition of coarse grinding, whereas the efficiency was higher and overgrinding weakened significantly in HPGR coarse products because of screening-out fines. Based on the above research, a new process of “ultra-crushing in HPGR – classified grinding” was advanced, reducing ores tonnage into first stage ball mill significantly, improving grinding efficient and weakening overgrinding in the whole grinding process.INTRODUCTIONIn mineral processing, comminution accounts for a substantial portion (approximately 60~70%) of the energy consumed in plants. As an ultra-fine crushing equipment,the application of the HPGR for industrial comminution has been paid close attention because of its low specific energy, low steel consumption, high capacity and high ratio of reduction, among others (Schonert, 1998; Norgate & Weller, 1994; Fuerstenau & Kapur, 1995). HPGRs comprise two counter-rotating rolls that draw feed material into the roll gap. One roll is fixed to the mainframe, while the other movable roll is mounted on slides and positioned by hydraulic rams. The specific pressing force (SPF) (i.e., total force divided by projected roller area) is typically in the range of 3~9 N/mm2 depending on the application, while pressures of up to 1000 N/mm2 have been measured within the operating gap (Maxton , Morley, & Bearman , 2003)."

Jan 1, 2016

By M. Maccagni, J. Nielsen

"Engitec developed the EZINEX® Technology some years ago to recover zinc from oxidized secondary sources. This process works at neutral pH and can take into solution any kind of metal, but iron is rejected and remains in the leach residue. Engitec has also developed the FLUOBORATE System, which is able to recover lead and copper from relevant concentrates. Some iron is leached into solution, but it is controlled through a solution purification bleed treatment. In this paper, we present the two above mentioned technologies. They are very different with regards to the chemical environments and the methods used to control the build-up of iron in solution, but both systems are suitable to treat iron bearing feeds.INTRODUCTIONIn the design of hydrometallurgical processes, the most important issues are the water balance, the filtration and the control of impurities. This is particularly important when the process includes an electrowinning unit. Iron has been one of the most problematic elements to remove, especially in acidic environments.Engitec Technologies has developed several hydrometallurgical processes divided in two different electrolyte lines: the Fluoborate Technology for the recovery of lead and copper from primary and secondary sources and the Ammonium Chloride System based on a chloride electrolyte for the recovery of different non-ferrous metals, among which zinc and lead are the most important. In both cases, iron is present in the feed and needs to be eliminated from the solution. It is not a problem for the quality of the metal produced, but when present in solution, it consumes the basic electrolyte reducing its free concentration which is very important both for both the leaching and electrowinning unit operations. Both process systems are very peculiar, the fluoborate case being much more intriguing."

Jan 1, 2016

By L. J. Bryson, C. A. Biley

"Anglo American Platinum’s Rustenburg Base Metals Refiners (RBMR) produces Ni and Cu cathode from slow cooled converter matte after Platinum Group Metals (PGMs) are magnetically separated for further processing. In 2010, execution of the RBMR expansion project was commenced to increase the production capacity to 33 ktpa Ni. The expansion, which is currently still in a ramp-up stage, brought about several fundamental changes to the circuit chemistry, including the installation of a dedicated Pressure Iron Removal (PIR) autoclave. This provided an independent outlet for iron from the refinery, which previously deported to the residue from the leach circuit and was toll refined. At the same time as changes in the circuit associated with the RBMR expansion were being made, the plant experienced a significant increase in iron and copper units per nickel unit in the feed. The decoupling of the leaching and iron removal process steps has had significant advantages for the robustness and control of the overall circuit, in particular pertaining to the preparation of a nickel electrolyte of sufficient purity to produce LME grade nickel. This paper details the primary changes to the RBMR circuit chemistry with a particular focus on iron deportment and the benefits derived from the installation of the PIR autoclave.INTRODUCTIONAnglo American Platinum mines and refines Platinum Group Metals (PGMs) through a complex processing pipeline in its South African operations. Mined ore is first treated through several mineral processing stages, geared to the recovery of base metals and associated PGMs, followed by smelting and refining operations that aim to separate base metals from PGMs and recover the value components to purified, saleable products. The focus of this paper is the Rustenburg Base Metals Refiners (RBMR) complex which receives a PGM-containing converter matte, then physically separates PGMs and base metals, and recovers nickel and copper to cathode by utilising leaching, precipitation and electrowinning processes.With new mining operations coming online and the continued increase in PGM ore arisings, it was necessary to undertake an expansion project at the Base Metal Refinery (BMR) to increase production capacity from 21 ktpa to 33 ktpa Ni. Complicating the expansion project was the requirement of continued production through all stages of design, construction and implementation and, due to stringent capital constraints, the utilisation of all existing equipment installed during a previous expansion in 1981. Against this backdrop, the expanded BMR flow sheet involved significant changes to the chemistry, especially iron management. These changes in iron management allowed for the separation of iron and copper residues and significantly increased the robustness of the plant to changes in feed mineralogy as well as the potential to increase production duties of the existing equipment."

Jan 1, 2016

By Elbasher M. E. Ahmed, Indresan Govender

"A mechanistic model of axial charge segregation in rotating drums is presented. We show that granular material composed of different frictional properties diffuse into axial bands as a consequence of concentration fluctuations in the free surface layer that is caused by friction-limited mobility. A Bagnoldian stress assumption ensures an asymmetric free surface profile thereby providing the essential ingredients for the evolution of axial bands and the subsequent band coarsening observed in the literature. The formulation is sensitive to the boundary conditions of tumbling mills, including particle size and density, mill speed, inter-particle bulk friction, end wall friction and drum geometry (length and diameter).INTRODUCTIONA mechanism to fully describe the axial segregation of charge in a rotating drum remains elusive to the mineral processing industry. With regard to low aspect ratio mills (like ball mills), current thinking favours the use of closed circuit mills with correspondingly low residence times to offset the completely random contact probabilities between particles and balls (Wills & Napier-Munn, 2006). Conical end caps are argued to exploit the centrifugal force to achieve a regular gradation of ball size along the mill with larger sizes at the feed end and smaller ones closer to the discharge. However; segregation along the length has been observed in the absence of conical end caps (Oyama, 1939; Levine, 1999): In these investigations, sufficient differences in the particle’s mechanical properties (particle size, density, shape, surface roughness) was enough to successfully achieve axial segregation. Figure 1 shows the segregation of a bimodal distribution (by size) into bands of larger (darker colour) and smaller (lighter colour) particles."

Jan 1, 2016

By C. Dodds, R. S. Ferrari-John, The University of Nottingham, G. Dimitrakis, J. Katrib, A. R. Batchelor

"Sorting technologies have the potential to reduce energy use in comminution by rejecting uneconomic ore before feed material enters the mill. However, a major challenge for sorting porphyry copper ores is providing a basis of discrimination between valuable and non-valuable fragments, due to their complex mineralogies and textural features. Microwave heating in combination with infra-red detection (MW-IR) has been shown to provide upgraded feedstock for certain ores at bench scale. Selective heating of copper sulphide minerals compared to the gangue leads to an increased thermal response for valuable fragments, providing the basis for sorting.Rapid scale up of MW-IR from bench scale to a 100 t/h continuous pilot plant facility has been facilitated by the design of microwave choking structures to allow continuous operation at industrially meaningful throughputs, whilst meeting health and safety and electromagnetic compliance standards, and the integration of materials handling with electromagnetic systems.Laboratory batch testing on a pilot scale microwave system has been undertaken to investigate the thermal response of copper ores under industrial conditions, at microwave energy inputs up to 1 kWh/t. These results provided the operating window and recommended test conditions for the continuous pilot plant. Sortability curves predicted in the laboratory are in good agreement with separations achieved during continuous pilot plant operations. The potential microwave sortability of a number of ores has been studied, allowing informed decisions to be made about potential ore candidates based on mineralogy. Future development of the technology will be underpinned by the creation and validation of scale up concepts for 1000 t/h operations. Understanding the value proposition for individual sites/applications will be central to unlocking the potential economic and environmental benefits of microwave sorting."

Jan 1, 2016