Search Documents

By C. J. Hartley

"Scandium oxide can be recovered as a by-product from process streams in a number of chemical and metallurgical plants including TiO2 sulphate pigment, Ni/Co laterite, zirconium oxychloride and uranium operations. The feed materials available for processing can be either mid or end of process streams containing many species in solution. This paper describes the strategies available to limit coextraction of elements into scandium containing streams from TiO2 pigment production and the removal of these elements to deliver high purity scandium oxide.A critical part of process development is to work within the constraints of the main process in terms of introducing new unit processes and producing minimal additional process intermediates and residues. This requires flexibility in designing flowsheets and plants to find novel process routes that avoid production of intermediates and/or the introduction of reagents that can compromise the main process operations.Bloom Energy has developed novel solvent extraction processes for the extraction and refining of scandium oxide that minimise impacts on core process streams within TiO2 pigment plants. The additional unit processes are designed to have minimal contact with pigment plant process streams to produce a concentrate that is refined to nominal 3N purity scandium oxide in a simple, small scale commercial plant."

Jan 1, 2016

By G. Dodbiba, A. Otsuki, T. Fujita, J. Ponou, A. Shibayama

"The different types of nano to submicron particles, which are well-dispersed nano particles, coagulated nano particles or settled submicron particles, have been measured by the interactive force apparatus (IFA). The information is very useful for mineral processing treatment. The IFA can measure the particle size distribution in low to high concentration of particles in liquids and non-light transparent liquids. Here, mainly the emulsion and bubble size measurements are described.Emulsion (w/o type) is prepared with oil and water mixture. The nano to micro emulsion particle size is usually measured by light scattering method. The particle size distribution of emulsion of light oil measured by IFA agreed well with the one by the dynamic light scattering (DLS) method. The water size distribution in emulsions of gasoline is difficult for the small reflection index and C heavy oil is difficult for the black color by DLS method. The IFA can measure both emulsions.There are many methods to measure fine air bubbles, however, the finer nano size measurement apparatuses are DLS method and IFA. A “ghost” peak appeared in the large particle micron meter size in DLS method. The mean diameter in IFA is similar with DLS for the nano meter size. INTRODUCTIONParticle size distribution measurement of nano to submicron particle, emulsion and bubble size distribution are very useful for ultrafine particle separation and characterization of fine particles by the necessity of recent fine minerals separation (For example, Li et al.2016, Mikhlin et al.2016, Wang et al.2013). As for the size measurement of solid particles in liquids, three different types of nano to submicron particles, that are well-dispersed nano particles, coagulated nano particles or settled submicron particles, have been measured by the interactive force apparatus (IFA). The particle size distributions are compared with the one of dried particles measured by TEM or SEM. The well-dispersed nano particle size distribution by IFA is influenced by the nano size surfactant micelles and becomes smaller, when compared with the TEM result. The size distribution of nano size of magnetite particles in water is influenced by the isoelectric point and the mean diameter of coagulation becomes larger. The particle coagulation in diluted suspension is about 2nm smaller when compared with the higher concentration. The submicron nickel particle size distribution is well agreed the result by SEM. The coagulation effect is small in the submicron size of nickel powder in water (Fujita et al., 2013). In this paper, the emulsion and bubble size measurements are mainly described."

Jan 1, 2016

By K. Forsberg, A. Rasmuson, R. Rodriguez Varela, J. Martinez De La Cruz

"This study analyzes the separation of rare earth elements by means of a supported liquid membrane (SLM) with the final objective of recovering REE from an apatite concentrate (Alemrajabi, Forsberg, & Rasmuson, 2015; Mohammadi, Forsberg, Martinez de la Cruz, & Rasmuson, 2015). In this study, the feed phase consists of an aqueous phase containing REE, the membrane phase contains the organic solvent and carrier (D2EHPA and EHEHPA), and the stripping phase is a hydrochloric acid solution. An evaluation of mass fluxes, separation efficiency, and membrane performance is conducted. In order to analyze the suitability of liquid membranes in the extraction of REE, a deeper insight into the mechanisms causing instability is needed. In this study, surface tension is considered as the key factor of Marangoni instabilities and spontaneous emulsification.INTRODUCTIONThe demand of REE and their compounds has increased considerably due to their special physicochemical features that make them crucial elements for numerous high-tech applications, including wind turbines, hybrid cars, mobile phones, and defense technologies. They are also extensively utilized in traditional industries such as nuclear energy, petroleum, metallurgy, agriculture, and textiles (Xie, Zhang, Dreisinger, & Dyole, 2014; Zhang, Wu, Bian, & Zeng, 2014).Solvent extraction is widely used for the separation of REE (Xie et al., 2014; Zhao, Huo, Pan, Li, & Liu, 2014). Di-(2-ethylhexyl)-phosphoric acid (D2EHPA) and 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (EHEHPA) are two of the most effective extractants for the separation of rare earth elements among organophosphorus extractants (Gupta & Krishnamurthy, 2005). However, the difficulty in stripping loaded D2EHPA extractant, especially for heavy REE, has limited its utilization. Yttrium can be stripped at lower acidities in EHEHPA systems compared to D2EHPA systems (Gupta et al., 2005), but the extraction efficiency is lower. Conventional solvent extraction by mixer-settlers is restricted by its large solvent inventory and loading limits, and suffers from phase disengagement, emulsification, loss of solvent, and flooding problems (Swain, Jeong, Lee, & Lee, 2007). In this context, supported liquid membranes (SLMs) present a potential alternative due to their advantages, being low solvent inventory, process simplicity, low energy and operational costs, great enrichment ratio, and combination of extraction and stripping into one single step. A SLM is a system in which two aqueous phases are separated by an organic liquid membrane suspended in the pores of a porous support by capillary forces. One of the aqueous phases is the feed solution with the solute and the other is the stripping or receiving solution. The solute diffuses through the liquid membrane and then is extracted into the stripping solution (Kislik, 2010)."

Jan 1, 2016

By M. J. Dry, G. B. Harris

"This paper presents basic chemistry and operating conditions for the hydrolysis of ferric chloride into solid hematite and gaseous hydrogen chloride, and shows how this unit operation can be applied in chloride hydrometallurgy to regenerate strong hydrochloric acid and reject iron without also rejecting valuable metals such as nickel, copper and cobalt. Two examples are used to illustrate the hydrolysis technology and compare it to existing technology. The first is the regeneration of spent steel pickling acid, comparing hydrolysis to conventional pyrohydrolysis. The second example is the processing of a hypothetical low grade nickel laterite, comparing the novel chloride hydrolysis route to conventional sulphate HPAL technology.INTRODUCTION Whilst, in many respects, the control and removal of dissolved iron from chloride leach solutions can resemble the manner in which it is done in sulphate systems, chloride chemistry additionally offers the ability to achieve the same objectives in different ways (Harris, 2014). Conventionally, iron is oxidised to its ferric state (if necessary) and then precipitated with a base, usually magnesia where the feed is a laterite and lime where it is a sulphide, since calcium will precipitate sulphate formed during leaching. One method for controlling iron is to form FeOOH, either ß-FeOOH (akaganéite), a-FeOOH (goethite), or a mixture thereof (Fillipou and Choi, 2002). However, if akaganéite is formed, the precipitate will contain a significant chloride component (as high as 7% Cl), leading to chloride losses and difficulty in satisfactorily disposing of the residue. Washing chloride from akaganéite is almost impossible due to the propensity of the solids to undergo peptization. The conventional approach requires the addition of a base, but it is based to some extent on controlled supersaturation precipitation (Demopoulos, 2009), which produces a more uniform and crystalline material and is far more attractive than, for example, the turboaeration process proposed by Great Central Mines in their chloride copper process (Raudsepp & Beattie, 1986)."

Jan 1, 2016

By Ruan Chi, Zhenyue Zhang, Zhengyan He

In order to understand what governs the leaching of exchangeable rare earth (RE) and impurities and enhance the RE leaching process, the effects of the concentration of ammonium sulfate, pH and leaching temperature on the migration of RE and aluminum (Al) during the leaching of weathered crust elution-deposited rare earth ore was studied. The elution curves for ammonium ion (NH4 +) were also studied to reduce the consumption of the leaching agent. It was found that a high concentration of leaching agent can enhance the leaching process of RE and Al, reduce the breakthrough volume of NH4 + and more rapidly obtain the equilibrium of NH4 +. However, excessive leaching agent can both increase the cost and the burden on the environment. There is almost no variation on the elution curves of RE and Al in the pH range of 4-8 and control of the pH of the leaching agent can be omitted. It is better for the leaching work to be done in summer since higher temperatures can enhance the RE leaching process and improve the use ratio of ammonium. Using 0.1 mol/L ammonium sulfate for leaching 250 g RE ore, 95.42% RE extraction can be obtained when the volume of leachate is 102.6 mL. At this moment, only 18.17% of NH4 + is used to exchange RE and 49.22% of NH4 + is left in the leachate that can be reused as leaching agent by replenishing ammonium sulfate. The results of our studies can provide theoretical guidance for high efficiency and low consumption exploitation of RE ores.

Jan 1, 2016

By D. Saramak, T. Gawenda, Z. Naziemiec, A. Saramak

"Crushing and grinding operations are burdensome to the environment due to generating large amounts of dust, noise and waste during course of comminution operations. An indirect negative contribution of industrial crushing processes is an increase of carbon dioxide emissions, which is a byproduct in energy production processes. On the other hand comminution processes in ore enrichment technology are essential due to liberation the useful minerals from the gangue, and producing the demanded particle size fractions of products. The article concerns investigation over negative influence of comminution devices on environment in terms of dust and noise emissions. Several various crushing devices were under investigations, both in laboratory and in industrial scale.The obtained results were analyzed in terms throughput and energy consumption achieved in various crushing devices. The test results allow to conclude that an intensity of dust generation for individual types of crushing devices is varied. An additional aim of this article is to link the aspect of mineral processing with its environmental impact and hence an influence of raw materials beneficiation industry on the quality of life of residents in immediate and close vicinity.INTRODUCTIONMineral raw materials beneficiation processes are an integral part of multi-stage processing of coal, iron ore and non-ferrous metals, production of aggregates, cement, or precious metals and stones. One of the common features of all beneficiation operations is their high energy consumption, which is mainly connected with various operations of feed particle size reduction. Comminution processes in ore enrichment technology are essential to expose and liberate the useful minerals from the gangue, while in aggregate production processes – to obtain the demanded particle size fractions of products. Crushing operations are characterized by a high degree of negative impact to the environment and humans, mainly due to:• High electricity consumption, which indirectly contributes to the increased emissions of carbon dioxide into the atmosphere, since CO2 is often one of the byproducts of energy production;• Relatively rapid wear of device working parts, what forces a production of spare parts and involvement of steel industry;• Intense dust pollution generated during crushing and grinding processes. This is one of the factors affecting the air quality and the consequent deterioration of the living conditions of inhabitants near mines and processing plants; and • Excessive noise emissions."

Jan 1, 2016

By Wengui Su, Qi Zhang, Junce Wang, Zhijun Ma, Xingyuan Weng

"Mesoporous materials with large specific surface area, pore size, and pore volume have been widely used in many fields such as ion exchange, gas separation, adsorption, and catalysis. Mesoporous materials prepared using natural zeolite have the advantages of both acid and alkali resistance. In this work, mesoporous materials were prepared using natural zeolite as the starting material and diethylenetriamine (DETA) as a template. The resulting samples were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD) and N2 adsorption-desorption experiments. The influence of the crystallization temperature and crystallization time on the specific surface area, pore volume, pore size, and morphology of the resulting mesoporous materials are also discussed. Our results show that for an increase in both the crystallization temperature and time, the average pore size first increases then decreases, while the specific surface area first decreases then increases. Based on this work, we concluded that the optimal crystallization temperature was 2003 and the optimal crystallization time was 60 h. These conditions gave an average pore size of 17.93 nm, a pore volume of 0.048 cm3g-1, and a specific surface area of 16.48 m2g-1.INTRODUCTIONMesoporous zeolite, as the name implies, is a highly porous crystalline zeolite. This material is of interest due to its high hydrothermal stability, its adsorption and diffusion properties for macromolecules, and its excellent selectivity and activity as a catalyst. In recent years, it has become a hot spot among research of porous catalytic materials and has been widely used in petroleum and natural gas processing, fine chemical processing, various adsorption and separation tasks, and other uses (Carvalho & Urquieta- Gonzalez, 2015; Teh, Triwahyono, Jalil, Mukti, Aziz, & Shishido, 2015)."

Jan 1, 2016

By S. Steinlechner, S. Wegscheider

"In the past, the metallurgical industry was most of the time dedicated on their main commodity, recovering base metals like zinc, copper or lead but leaving other valuable side elements in the generated residues. As a result, these accompanying minor elements, like gold, silver, indium or also PGMs can be found in the dumps of the corresponding industry. Because of political unrest, strikes, economic reasons or decreasing primary resources leading to a high supply risk, also those mentioned minor elements moved into the focus of the recycling industry. Therefore, beside the base metals, first of all the recovery of those minor metals would be of high interest contributing to the economic viability of recycling processes, although they occur in much smaller quantities in materials. In this context, residues from zinc industry, like leaching residues or precipitation residues show high potential to carry silver as well as indium next to lead and zinc. Therefore, the paper summarizes carried out thermochemical calculations investigating a possible recovery of silver as well as indium by volatilization and the influence of zinc and lead on this process. Based on these theoretical investigations with HSC, trials in lab scale were done verifying the obtained results.INTRODUCTIONHuge amounts of iron precipitate, mainly jarosite get landfilled every year although there is a high content of valuable metals in this residue beside iron. Nevertheless, jarosite has to be dumped due to the presence of contaminating heavy metals. The accumulation of these residues takes up massive land on the one hand but also causes a series of environmental problems in ecosystems on the other. Moreover, some toxic ingredients such as arsenic and cadmium can be dissolved in rain water and are therefore harmful to the health of the aquatic systems. (Erdem & Özverdi, 2011; ÖzverdI & Erdem, 2010) Approximately 0.5 t of dry jarosite accumulate in the production of 1 t of zinc by the hydrometallurgical zinc-winning route (Svens, 2010). Jarosite is a precipitation residue formed during the iron removal. In general, the iron already exists in the zinc ore which is why zinc ferrite builds up during the roasting step of the zinc ore. Zinc ferrite is only soluble in strongly acidic solutions and during the hot acid leaching step it gets dissolved while zinc and iron enter the solution. It is necessary to get rid of the iron because otherwise it would deposit on the cathode first due to its precious character which would be harmful in the zinc-winning electrolysis. Nevertheless successful investigations were done by adding chlorine to the jarosite to recover silver. These findings leads to another residue which occurs in huge amounts – electric arc furnace dust (abbreviated with EAFD) from the iron and steel industry. In 2013 the annual electric steel production reached about 451 million tons. Around 15-20 kg of EAFD is produced per ton of steel in an electric arc furnace (EAF), creating approximately up to 9 million tons of dust per year. (Grabda, Oleszek, Shibata, & Nakamura, 2014; World Steel Association) Next to elements like zinc, lead and iron, chlorine and fluorine are present in this dust. While galvanized steel plates in the scrap act as a source for zinc, casting powders, flame retardants and synthetic coatings are responsible for the chlorine and fluorine contents in the dust."

Jan 1, 2016

By E. Ghali, C. Su, G. Houlachi

"The influence of lead ions on zinc electrowinning process was investigated by means of electrochemical noise measurements (ENMs) and cyclic voltammetry in conjunction with scanning electron microscopy and X-ray diffraction. All electrochemical experiments were performed in sulphuric acid electrolyte containing different lead ion concentrations as impurity. Lead was added in six trace levels between 0.05–0.8 mg/L in the bath. The lead content of the zinc deposits was dependent on the introduced lead concentrations. The overpotential associated with zinc electrodeposition shifted to higher values with the increase of lead concentration in the solution. An appropriate correlation was found between the different concentrations of lead in the electrolyte and the morphology of zinc deposit by ENM. The results showed that the increase of lead ion concentrations is generally accompanied with the decrease of skew and increase of kurtosis values that could be related to the morphology of zinc deposit. Effectively, the morphology changes from well-defined hexagonal platelets to large hexagonal, layered platelets and finally to non-symmetric refined crystalline structure, respectively.INTRODUCTION In commercial zinc electrowinning, zinc oxide is leached from the roasted calcine with an aqueous acid sulfate electrolyte. Then the zinc-rich solution is purified and transferred into an electrolytic cell. During electrolysis, zinc is deposited on aluminum cathode where lead-silver or pure lead is served as anode. Electrodeposition of zinc could be influenced by several parameters such as bath acidity, temperature, current density, the nature and concentration of impurities as well as additives in electrolyte. Metallic impurities play a complex role during zinc electrowinning and they can adversely"

Jan 1, 2016

By M. Ye. Shulgina, M. L. Bolotin, S. A. Prokopev, Ye. S. Prokopev

Iron ores concentration at Russia’s operations is carried out using conventional flow sheets. They comprise the two-four stage grinding followed by one-two stage magnetic separation. This results in the maximum recovery of magnetite to concentrate and the tailings generation. The final concentrate is generated only during the last stage of magnetic separation. Technologically, this flow sheet layout is not effective at recovering the liberated magnetite grains during grinding to the resulting concentrate. Advanced models of magnetic separators do not allow for the selective separation of the tailings and the portion of the resulting iron ore concentrate. Magnetic product which is the ore mixture of the liberated magnetite grains, high grade and low grade intergrowths is directed to the next grinding stage. In this case, regrinding of the liberated magnetite occurs. In addition, the performance of hydrocyclones during classification in closed grinding circuits is poor. Their classification efficiency does not provide the material separation in accordance with the size. In this case, simultaneous separation in accordance with the density occurs. The quartz particles with the size of 300 mm have similar velocity and trajectory like the particles of magnetite with the size of 60 mm. As a result, light and coarser intergrowths report to the overflow and free heavy magnetite grains report to underflow and return to regrinding (“the density effect”). This resulted in a significant increase of a mill circulating load, the decrease in the feed throughput and higher power consumption. In this connection, the development of iron ore concentrate stage recovery with the focus on gradual liberation of the intergrowths is getting much attention. Gravity concentration technique, particularly, spiral separation is effective at solving the problem of stage recovery not only the dump waste product but also high grade magnetite concentrates at the early concentration stages. This can be attributed to a significant difference in magnetite (4.9-5.2 g/cm3) and host minerals (quartz 2.7 g/cm3) densities, which is the principal during gravity concentration. The test work on concentration of various products samples from current operations (the mills discharges, concentrates from various stages of wet magnetic separation and cyclones underflows) was carried out. Spiral separators SV- 500 and ShV-500 manufactured by Spirit LLC were used for the test work. High grade iron ore concentrate (69.05% Fe) was generated during primary wet magnetic separation concentrate concentration using a spiral separator. During the concentration of mills discharges the content of iron in the resulting concentrates and middlings of wet magnetic separation II stage was 64.5% and 64.6%, respectively. The recovery of iron to the concentrates of spiral separation was 33.6-42.0%. The studies presented demonstrate that by using spiral separation for iron-bearing ores concentration, you can separate magnetite liberated grains at the early concentration stages, decrease their regrinding and circulating loads in grinding circuits. This process is able to improve the overall recovery and economics of iron ores concentration process.

Jan 1, 2016

By P. Radziszewski

"The comminution energy curve is a profoundly simple graphical technique that displays detailed operating efficiency information for industrial comminution processes. The database underlying the methodology has recently more than doubled, to now contain a substantial fraction of the international comminution output (1.7 billion tonnes of rock per year) across more than 8 major commodities. This increase has deepened the analytical capabilities and effectiveness for assessing comminution circuit performance in relation to comparable operating mines. This paper will explore how the energy curve methodology can be used to examine the ability of stirred mill technologies to increase efficiency.Specifically, this paper explores how the energy curves methodology can be used to present energy efficiency gains achieved at three mines employing a stirred mill technology under different duties. The first of these cases studies was conducted by Rosa (2014) who compared the performance of two ball mills operating in parallel with a Vertimill in the regrinding circuit at the Samarco Iron project in South East Brazil. The Vertimill was found to achieve the same product specification while consuming 40% less energy. Brissette (2010) investigated the impact of grinding media on the performance of both ball mills and Vertimills. The energy savings achieved varied from 10% to 40% for the ball mills and 30% to 60% for the Vertimills. Lastly, Bergerman (2012) investigated the operating conditions of the Sossego regrind circuit from 2006 to 2011 against design specifications and laboratory testing. The operating work index of this circuit varied from 5.2 kWh/t to 44 kWh/t over this 5 year period. The full suite of energy curves"

Jan 1, 2016

By Tong Guan, Guangqin Fu, Lihong Deng, Yuanlin Chen, Xiaotong Zhou

"In natural world, some kinds of scheelite minerals are rich in molybdenum. Molybdenum exists in the crystal lattice of scheelite in the form of isomorphism, and the content of MoO3 varies from 2% to 10%. As a result, the flotability of seyrigite (scheelite with molybdenum) turns to be weaker. One seyrigite mine, which has been built for 3 years,still could not produce qualified seyrigite concentrate due to the weak flotability of seyrigite (Mo-bearing scheelite) in raw ore. In our experimental research, through adopting new seyrigite collector TA-3 and advanced mineral processing technology, the seyrigite concentrate with a grade of 65.62% WO3 at a recovery of 87.47% was obtained for the raw ore containing 0.19% WO3 and 0.074% Mo. By applying the new technical achievement, for the raw ore containing 0.272% WO3, the seyrigite concentrate assaying 68.03% WO3 with a recovery of 77.56% was obtained in industrial production.INTRODUCTIONIn natural world, some kinds of scheelite minerals are rich in molybdenum. Molybdenum exists in the crystal lattice of scheelite in the form of isomorphism, and the scheelite is changed to be seyrigite (Ca[(W,Mo)O4]) (Ma, Bian, & Wang, 2013). The content of MoO3 in seyrigite varies from 2% to 10% usually, the content of MoO3 in some of the seyrigite even reaches 34%. The flotability of seyrigite is weak (Zhang, 2007), and the seyrigite is difficult to be recovered by flotation with common collectors and regulators. One scheelite mine in Anhui China, which is a skarn type seyrigite mine, has not produced qualified concentrate yet since 3 years it has been built due to the limit of beneficiation technology. Therefore, it is necessary to conduct research on the collectors with high efficiency and developing advanced processing flow for this kind of ore."

Jan 1, 2016

By Yongsheng Song, Yong Chen, Wenjuan Li

"Detailed characterization and improved recovery of a micro-fine, low-grade refractory gold ore from a beneficiation plant in Yunnan Province, China, was investigated. Different analytical techniques, such as videlicet size analysis, scanning electron microscopy, and mineral analysis by a Mineral Liberation Analyser, were used for mineralogical characterization of the ore. This paper describes an experimental study on the effect of the grinding fineness and the use of various flotation reagent regimes involving collectors, depressors, and activators on the flotation behaviour of micro-fine auriferous pyrite. Two-stage flotation resulted in high gold grade (32.71 g/t) and gold recovery (80.02%) of the bulk gold concentrate. This process opens the possibilities of maximizing Au recoveries in a micro-fine low-grade refractory gold ore where low recoveries are common.INTRODUCTIONWith the rapid development of the gold industry, refractory gold ores are becoming increasingly important resources for gold production (O’Connor & Dunne, 1994; Agorhom, Skinner, & Zanin, 2012). Among these refractory gold ores, sulfur and micro-grained native gold ores represent a significant challenge, since they are not amenable to gold recovery by direct cyanidation. The gold contained in this type of ore is very finely disseminated and encapsulated in sulfides, which makes it inaccessible to the cyanide solution during direct cyanidation (Bulatovic, 1997; Allan & Woodcock, 2001). Autoclave pressure oxidation (AC POX) of the sulfide ore and subsequent cyanidation is a common technology used to recover the gold in such types of ore. Flotation is often used as a pre-treatment method to refractory gold ore (Monte Lins, & Oliveira, 1997).As the gold-carrier minerals are usually finely disseminated (sometimes under 10 µm) and intimately associated with gangue minerals, a fine grind is necessary to get a high degree of liberation. At the same time, the fine grind usually causes the production of significant quantities of slimes, which comprise easy-to-float gangue minerals such as mica, dolomite, and calcite. These mineral phases are naturally hydrophobic and float readily, competing with the value minerals in the froth phase and resulting in lower concentrate grades."

Jan 1, 2016

By N. P. Hristov, L. V. Kuzev

"A simulation study of the fill factor of a drum mill was conducted using two types of grinding media: balls and tetraballpebs. Each medium was composed of equal number of grinding bodies having equal weight but different shape. The difference was in the density of the two grinding media.Standard spherical grinding bodies (balls), which were used in practice, and equivalent (by weight) grinding bodies in the shape of spheroidal tetrahedrons (tetraballpebs) were studied. The simulation was conducted in a module of a 1.2 m diameter drum mill, whose length exceeded twice the diameter of the corresponding grinding body. The grinding balls had a few percent (3 to 6) higher fill factor than the grinding tetraballpebs in the same shell.Vertical sections of the grinding medium were taken across the studied shell module along its axis. They showed the location of each grinding body in the fill volume. Defects in the packing of the grinding bodies and the contacts between them and with the inner surface of the shell were also show. Differences in the contact points of the balls and the tetraballpebs were noted. For the tetraballpebs, we observed contacts both between the spherical surfaces and with the edges and vertices of the grinding bodies.The topography of the grinding media is shown visually.INTRODUCTIONThe grinding balls have been studied extensively. It is the traditional grinding medium in ore processing industry. The parameter characterising the grinding medium is its density. It is the mass of the grinding medium per unit of volume. The parameter may have a range of values. It depends on:• The physical properties of the material they are made of;• The shape of the grinding body;• The dimensions of the body;• Size distribution of the grinding bodies in the grinding media.In comminution, the fill factor of the mill shell is the process parameter that is representative of the grinding medium. Some publications have indicated the disadvantages of ball grinding. For example, Wu, Xiang, Glen, and Duan (2008) note in the analysis of the mechanism of grinding that the balls are not the best grinding media and disadvantages include among others:• Easy over-grinding resulting from the point contact between the balls;• Attrition surface is the smallest in the grinding media;• Poor selective exposure of minerals resulting from the accidental and often significantly more powerful impact on the feed;• The grinding efficiency drops as the fineness of grind is increased;In the Handbook of mineral processing, Polkin (1950) noted that the shape of the grinding bodies determines the volume of the void spaces therein and therefore the shape affects the grinding efficiency per unit of volume of the grinding medium."

Jan 1, 2016

By K. Loutet, A. Guenkel, K. Nikolaisen

"The INCO SO2/air process was patented by INCO in 1985. Well over 80 mining operations worldwide are using this process to oxidize cyanides to cyanates in the tailings from gold, silver and copper mining operations. The sulphur dioxide (SO2) for this process can be supplied either as liquid SO2, SO2 gas or as a sulphite-based salt. The majority of SO2/air operations have used sulphite-based salts as the ‘SO2’ equivalent probably due to low capital cost. Liquid SO2 has also been used frequently, but due to concerns with safety and availability, this option is often not preferred. The solid salt sodium meta-bisulphite (SMBS) is commonly employed, but its cost is an order of magnitude higher than that of sulphur. Due to the high cost of SMBS, the increased capital cost for a sulphur-burning SO2 gas plant (green field or retrofit) usually has a pay-back of less than three years. In addition, a SO2 gas plant offers potential for significant heat recovery from the sulphur burning process. In terms of safety, the SO2 gas plant only requires the storage of relatively benign sulphur and the site inventory of SO2 will be limited to the plant gas volume. Therefore, a SO2 gas plant will not trigger the Canadian Environmental Protection Act (CEPA) E2 Regulations or the US Clean Air Act Section 112(r) accident prevention regulations, as may be the case for liquid SO2.Most existing mining operations using ‘SO2’ are gold operations, but in recent years there has been an increased interest in larger sulphur dioxide gas plants for hydrometallurgical facilities that employ leaching of cobalt/manganese minerals or precipitation of manganese/iron (e.g. Tenke Fungurume and El Boleo).This paper focuses on the production of sulphur dioxide gas generated on site and on demand for the use in hydrometallurgical processes. The capital and operational costs of a SO2 gas plant is compared to conventional process alternatives using sulphite-based salts or liquid SO2."

Jan 1, 2016

By Larry G. Twidwell, Corby G. Anderson, Camille M. Fleuriault

"The selective precipitation of iron as ammonium jarosite is a well-established industrial technology in base metals hydrometallurgy. It is a key technology in minimizing iron tenors which would be disruptive to downstream processing. It also provides a more readily filterable iron solid to better facilitate materials handling. This paper elucidates the fundamentals behind industrial iron precipitation. Then, the details of the successful optimization of an industrial ammonium jarosite circuit are presented.HYDROMETALLURGICAL IRON REMOVAL FUNDAMENTALS Iron is the fourth most abundant element in the Earth’s crust (5% by weight) and is often found in complex ores such as sulphide-bearing formations. Iron represents an issue though during leaching, a technology which is widely used for the treatment of this type of ore: •,Iron has the particularity of forming hydroxides when leached under certain conditions. Iron hydroxides form a viscous gel, which is difficult to filter and traps valuable elements such as silver. •,Iron is solubilized along with other metals and interferes with the subsequent extraction steps. As a result, purification of the pregnant leach solutions is required to achieve economical extraction of base metals. In the 1960s, metallurgists developed iron precipitation processes for solution purification (Habashi, 1999). Nowadays, precipitation of iron bearing species, such as goethite, hematite or jarosite, has become one of the most common methods used in the industry to purify leach liquors. To be suitable, the precipitate has to be readily filterable and thus must not be too fine of particle size. Precipitation can take place in autoclaves at medium to high temperatures, under an oxygen or air overpressure (Tourre, 1984, Fleuriault 2016, Fleuriault Anderson Shuey, 2016))."

Jan 1, 2016

By A. Pranowo, G. R. F. Alvear F., N. Aslin, M. S. Moats

"The toxicity of arsenic is well known and documented; however, the presence of arsenic in copper electrorefining anodes and electrolytes is critically necessary to produce high-quality cathode. Arsenic as well as antimony and bismuth concentrations vary relative to their concentration in the anode copper received from the smelter. The behaviour and benefits of arsenic in copper electrorefining and the detrimental effects of antimony and bismuth on cathode quality and tankhouse performance are discussed. This will include the minimization and mitigation of problems associated with arsenic, antimony, and bismuth—including cathode contamination, floating slimes, scaling, and anode passivation.RÉSUMÉ La toxicité de l’arsenic est bien connue et documentée; toutefois, la présence d’arsenic dans les anodes de l’électroaffinage du cuivre et dans les électrolytes est d’une nécessité critique pour produire une cathode de grande qualité. Les concentrations en arsenic, ainsi qu’en antimoine et en bismuth varient selon leur concentration dans l’anode de cuivre reçue de la fonderie. Le comportement et les avantages de l’arsenic dans l’électroaffinage du cuivre et les effets indésirables de l’antimoine et du bismuth sur la qualité de la cathode et le rendement des cuves d’électrolyse sont discutés. On traite aussi de la minimisation et de l’atténuation des problèmes associés à l’arsenic, l’antimoine et le bismuth – incluant la contamination de la cathode, les schlamms flottants, l’entartage et la passivation de l’anode."

Jan 1, 2016

By K. Mayhew, A. Lossin, H. Salomon-de-Friedberg

"The proportion of arsenic-bearing copper concentrates that supply the copper industry is on the increase. The current strategy of miners and smelters to blend feeds to reduce average arsenic levels is rapidly becoming unsustainable as more concentrates with even higher arsenic levels enter the marketplace. In addition, the capability of smelters to manage increasing arsenic levels to more stringent and restrictive environmental standards is limited by available process technologies.CESL Cu-As Technology is a viable technical and economic alternative to traditional smelting. It offers the advantage of simultaneous leaching and precipitation of the arsenic in a single processing step while achieving high copper extractions. The process has been piloted in six separate, fully-integrated pilot campaigns for feeds ranging from ~1% to 12% arsenic in concentration. This paper will focus on the behaviour of arsenic in CESL’s leaching/precipitation step and operational factors that influence it, and on the chemical and physical characteristics of the subsequent iron-arsenic residue that represents today’s best available technology from a long-term sustainable (capital/operating costs, metal recovery, safety, environmental) perspective.The examples provided will demonstrate copper extractions approaching 99% and arsenic deportment to residue of 99%. Instantaneous settling rates of the residue were measured at 15+ m/hr. Data from subsequent short and long-term stability testing of the residue confidently support the view that the scorodite-bearing residues from the process will be stable and provide an acceptable arsenic management practice. The technology offers increased revenue and environmental certainty for miners, smelters & refiners to support the development of metallurgically challenged copper-arsenic deposits. Furthermore, results will be presented demonstrating the technology’s ability to successfully incorporate hazardous arsenic containing smelter by-products such as dust into the process feed and simultaneously extract copper value while fixing the arsenic in a stable residue."

Jan 1, 2016

By A. Mellek, M. Pischtschan, M. Perrucci

ABB has received an order for one of the most challenging mill drive projects in its history. With one SAG mill and one ball mill to be added at an iron ore mine in Sweden, the customer’s plant managers wanted to have the most efficient solution for driving their mills but had the budget limitations typically faced by the majority of mining companies during periods of market downturn. To find the best balance between cost of acquisition and highest performance throughout the lifetime of the plant, ABB was selected to deploy a synchronized bypass solution, in which only one drive system is used for two different mills in series. However, being one of the first grinding mills in the world with such a solution was not the only challenge the ABB team faced: The inclusion of some mill application functions - e.g., frozen charge protection, automatic positioning and creeping mode - brought the demands on the engineers to another level. With only one frequency converter and one mill application controller available, the configuration logic and interlocks had to be meticulously designed and thoroughly tested to ensure a smooth and safe startup. The solution offers a footprint reduction and more operator flexibility at a reduced investment as each mill can be run in both directions, and wear on the mechanical components can be greatly reduced due to ABB’s premium ring-geared mill drive (RMD). This paper will describe the details of the project, the configuration developed and the tests performed to guarantee correct software functionality. Mill startup is scheduled for January 2016.

Jan 1, 2016

By D. K. Sarkar, Jiawei Xiong

"Self-assembled monolayers (SAM) on the aluminum substrates are used as the adhesion promoter between two aluminum substrates when bonded with the adhesive in adhesive bonding technology. Traditional surface analysis tools are not capable of identifying the presence of SAM on a surface; therefore, EIS has been used to determine their presence on the aluminum substrates. In this study SAMs have been deposited on aluminum using the monomer of (3-Glycidyloxypropyl)trimethoxysilane (GPTS) organosilane. AA6061 aluminum alloys substrates were chemically cleaned with NaOH and HNO3 to remove the native oxides, followed by immersion in silane solutions. In a second method, SAMs were prepared by applying a spin coating of silane solution to the samples. The prepared SAM coated aluminum samples were analysed by EIS in the three electrode corrosion cell using a diluted alkaline solution. The impedance of the SAM coated aluminum is found be higher than the as-received aluminum. It has been also observed that the open circuit potential (OCP) of the SAM coated aluminum is higher than the as-received aluminum. Both elevated values of the impedance and OCP confirm the presence of SAM on aluminum.INTRODUCTIONSelf-assembly (Schreiber, 2000) is defined as the spontaneous formation of complex hierarchical structures from pre-designed building blocks, typically involving multiple energy scales and multiple degrees of freedom. Generally speaking, SAMs are created by the chemisorption of ""head groups"" onto a substrate from either the vapor or liquid phase followed by a slow organization of ""tail groups"" of a molecule. Typically, head groups are connected to a molecular chain in which the terminal end can be functionalized with groups such as –OH, –NH2, –COOH, or –SH to vary the wetting and interfacial properties (Chauhan et al., 2007; Ulman, 1996; Vashist, Lam, Hrapovic, Male, & Luong, 2014). Though there exist several methods to prepare SAM (Chauhan et al., 2007; Chen, Yang, & Zhang, 2014; Cho, Park, Jon, & Choi, 2007; Igor Luzinov, 2000; Reis, de Melo, & Costa, 2006; Song, Zhai, Wang, & Jiang, 2006; Sugimura, Hozumi, Kameyama, & Takai, 2002; Vashist et al., 2014), the two methods vapor phase (Song et al., 2006; Sugimura et al., 2002) and solution(Chen et al., 2014; Igor Luzinov, 2000) are commonly used. Recently, many articles have been published on the fabrication of superhydrophobic surfaces with SAM technology (Cho et al., 2007; Pan, Shen, Shang, & Xing, 2012; Siddaramanna, Saleema, & Sarkar, 2014; Song et al., 2006). Brassard, Sarkar, and Perron (2011) successfully obtained a superhydrophobic film by applying fluoroalkylsilane via self-assembly on monodispersive silica. SAMs are also reported as good candidates for anti-corrosion and adhesion promotion (Chen et al., 2014; Saleema, Sarkar, Paynter, Gallant, & Eskandarian, 2012). However, papers on the characterization of SAM properties are rarely seen. The most commonly used substrate for SAM is silicon and the method implemented is scanning probe microscopy (SPM) such as atomic force microscope (AFM) (Igor Luzinov, 2000; Moores, 2011; Zhang, 2003, 2005). Igor Luzinov (2000) analyzed the epoxysilane SAMs’ surface morphology and microstructure properties using scanning probe microscopy (SPM) and ellipsometry on single-crystal silicon wafers. SAMs have been used to improve the adhesion bonding of aluminum or plastics but no characteristic data have been presented yet (Saleema et al., 2012; Telegdi, 2007; Wang, Xu, Luo, Wang, & Wang, 2009). Recently, Reis et al.(Reis et al., 2006) have studied SAM of alkane diphosphonate (Gardobond X4661) on Al 5052 alloy samples by EIS in a naturally aerated sodium sulfate solution."

Jan 1, 2016