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By R. Peter King, Claudio L. Schneider, Reiner Neumann

Predicting the liberation spectra that is produced from breakage of two-phase ores under the random fracture assumption can be accomplished by measuring the conditional, on length, linear grade distribution directly from images obtained from a representative sample of the unbroken texture. The technique tremendously simplifies the prediction problem by avoiding the multiple convolutions that arise from the traditional method based on a description of texture from a measurement of the chord length distributions associated with each phase in the unbroken texture. For a 3-phase system, the phase transition probabilities associated with the textural information make the traditional calculation an almost insurmountable mathematical problem. The direct measurement procedure on the other hand can be expanded to three phases comparatively easily.

Jan 1, 2003

By Claudio L. Schneider, Peter R. King, Reiner Neumann

"Predicting the liberation spectra that are produced from breakage of two-phase ores under the random fracture assumption can be accomplished by measuring the conditional, on length, linear grade distribution directly from images obtained from a representative sample of the unbroken texture. The technique tremendously simplifies the prediction problem by avoiding the multiple convolutions that arise from the traditional method based on a description of texture from a measurement of the chord length distributions associated with each phase in the unbroken texture. For a 3-phase system, the phase transition probabilities associated with the textural information make the traditional calculation an almost insurmountable mathematical problem. The direct measurement procedure on the other hand can be expanded to three phases comparatively easily.A coal sample is used here to demonstrate the procedure. It is concluded that the conditional, on length, linear grade distribution can be predicted in the same fashion for multi-phase systems. Accurate stereological conversion is the practical hurdle to be overcome for multi-phase systems, but it is already a reality for 3- phase systems."

Jan 1, 2003

By Lei Wang, Qi Zheng, Xiao-kui Che

"The wastewater emitted by gold chemical industry contained vast of different heavy metal ion, such as Zn, Cu and Ni etc. Among them Zn is the main ion in the waste water which causes the serious environment pollution. A method of preparing a kind of resin which is used for the removal of Zn by magnetic adsorbent was developed and was applied in practice. This adsorbent is a chitosan made of a kind of Fe3O4-chitosan modified by epichlorohydrin. The adsorption capacity of the absorbent and it was concluded that under the laboratory conditions, the maximum adsorbing capacity of this adsorbent could be 287.58 mg/g. The absorbent was also applied in the wastewater emitted by a gold industry in Shandong province. Its performance was tested and the result showed that the concentration of Zn ion in the wastewater was reduced from 0.58 mg/L to 0.0174 mg/L. What is more, the adsorption rate could be more than 97% when the dosage was 100L/m3 after adsorbing for 1h. KEYWORDS Selective, preparation, laboratory experiments, industry experiment, comparation INTRODUCTION Currently, most gold chemistry use cyanide to leach gold ore. Many different metals participate to this reaction besides the gold ion in this processing, so that the composition of the water is very complex. The waste water emitted by gold chemistry industry contains large amount of heavy metals. Definitely, if it was discharged without any treatment, the water would threaten the environment. The recuperation of any ion in the water would mitigate the pollution. Ion exchange resin, which is an effective material to do the water treatment with low cost, became widely applicated in this field [Yu-jiao Wang,2013]. Different kinds of resin were developed and the influence factors such as pH, adsorption properties and selectivity for different ions were investigated [CA Cruz et al,2018; PawanKumar et al.2016; Y Zhang, et al,2010; and ShengingSun, Aiqin Wang, 2006;]. The waste water mentioned in this article has a high Zn concentration, so a magic resin for Zn adsorption selectively we designed was used to manage this water. And the recovery of Zn could not only contribute to pollution abatement but also a best way to settle a dispute to the short of Zn resource. So the article mainly describes the preparation and the application of a kind of magnetic adsorbent used for the removal of Zn both in laboratory and industry. The aim of this article is to compare the effect of this resin in industry and laboratory?"

Jan 1, 2018

By Shugang Hu

According to XRD, DTA and SEM detections, the hydration products of blast furnace slag (BFS) based cementing material SL, SLG. were studied in different age periods. The XRD analysis of cementing material SL hydration products showed that the composition of hydration products were mainly amorphous substances, few crystalline substances. Characteristic peak of ettringite hadn?t been found in the spectral line of DTA, and it hadn?t been found in the figures of SEM, either, which was accordant with the conclusion that the cementing performance of SL mainly coming from gel of hydrated calcium silicate (CSH) and hydrated calcium aluminate. However, the main hydration products of SLG are Aft, CSH, and AFm, which are similar to Portland cement. All results suggest that BFS is a suitable base material for cementation. Keywords: blast furnace slag, backfilling cementing material, hydration products, cementing performance

Sep 1, 2012

By H. Ding

Calcium carbonate/Titanium dioxide composite, characterized by coating TiO2 on the surface of CaCO3 particles, is an important substitute for titanium dioxide. This paper studies preparation method of CaCO3/TiO2 ,composites based on mechano-chemical effects, measures its properties as a pigment, analyzes the binding form and interface reaction mechanism between CaCO3 and TiO2. Through single finely grinding of CaCO3, co-grinding of CaCO3 together with TiO2, and mecha-no-chemical effects produced in the course of grinding, CaCO3/TiO2 composites can be prepared successfully. Results indicate that grinding fineness of CaCO3, co-grinding time of CaCO3 and TiO2, the weight ratio of grinding media to mineral feeding, and the amount of TiO2 have much influence on the properties of CaCO3/TiO2 composites. CaCO3/TiO2 composites have the properties same as titanium dioxide pigment, oil adsorption and ultraviolet adsorption same as TiO2, and 90% of hiding power as that of TiO2. Wet grinding of CaCO3 causes the production of mechano-chemical effect and hydroxyl group, through which CaCO3 and TiO2 can be bonded together. Repulsion occurs between the particles of CaCO3 and the particles of TiO2, respectively, they are both in good dispersion. But attraction occurs between CaCO3 and TiO2. TiO2 particles are distributed evenly on the surface of CaCO3. Therefore, coating of TiO2 on the surface of CaCO3 particles and chemical bond between them make CaCO3/TiO2 compo-sites have pigment properties of Titanium.

Jan 1, 2014

By Z. F. Hu

Tourmaline has the characteristics of piezoelectricity, thermoelectricity, spontaneous polarization and far-off infrared radiations. Ultra-fine powders of tourmaline have extensive applications in the fields of electron, chemical and environment protection, as well as health protection. The preparation technology of ultra-fine tourmaline powder is discussed. The key equipment of a pilot plant for producing ultra-fine tourmaline powder with jet mill and stirred ball mill is described. Using this pilot plant facility it is possible to produce tourmaline powder with particle size smaller than 100 nm, and a continuous production process can be realized. The final powder product has many superior performance such as high whiteness and large specific surface area, and it?s a negative ions emission can reach the value of 7190 ions per cubic centimeter.

Jan 1, 2014

By Z. L. Huang

A new porous apatite product was prepared using phosphorite from Yichang China by a tem-plate-directed method in self-made reaction equipment under constant temperature and pressure. The product was characterized by XRD, FT-IR and SEM. The results showed that the product was a kind of micrometer porous sphere three-dimensionally structured by apatite nanoflakes, that the average thickness of nanoflakes was about 50 nm, that the average pore size was about 1.2 µm and that the particle average size was about 20 µm. Great amounts of Ca2+channel, high special surface area and regular spherical shape show the potential promising applications of this special porous apatite product in the fields of catalyst, medication, chemical engineering and environment engineering

Jan 1, 2014

By Fuqiang Zheng, Shuai Wang, Feng Chen, Yufeng Guo, Guanzhou Qiu, Tao Jiang

"The direct reduced iron powder and Ti-V-rich material was prepared from vanadium titanomagnetite concentrate by solid-state reduction-magnetic separation. The result indicated that under the studied conditions, adding KS can effectively improve the metallization rate of pellets. 2% KS was well mixed with vanadium titanomagnetite concentrate to make the pellets. The green pellet was preheated at 900 ? for 6 min. The preheated pellet was reduced at 1050 ? for 100 min, then crushed and ground to more than 80% was below 0.045 mm. The direct reduced iron powder and Ti-V-rich material were separated from the slurry by wet magnetic separation at 800Gs. The TFe content of magnetic material was 90.63%, and the Fe recovery rate reached 96.53%. The TiO2 and V2O5 contents of Ti-V-rich material were 28.40 % and 1.64 %, respectively. The TiO2 and V2O5 recovery rates were 69.05% and 96.82%, respectively. 1. Introduction The ilmenite and rutile are the main titanium resources which can be used in the present technical level and economic conditions[1,2]. However, with the rapid development of China’s economy, the market demand of titanium products is increasing sharply. The current supply of ilmenite and rutile cannot meet the needs of chemical industry[3]. China is rich in vanadium titanomagnetite concentrate which contains abundant titanium and vanadium resources. The TiO2 and V2O5 content of vanadium titanomagnetite concentrate are usually about 7% and 0.3%, respectively[4]. Because the TiO2 and V2O5 grades are low, it generally requires pre-concentrated to Ti-V-rich material before extracting the titanium and vanadium. Therefore, it is vital to find effective processes for pre-concentrating the titanium and vanadium in vanadium titanomagnetite concentrate. There are many methods[5-13] developed or under development to pre-concentrate Ti-V-rich material from vanadium titanomagnetite concentrate, including the blast furnace process, pre-reduction electric furnace process, to utilized vanadium titanomagnetite concentrate are direct reduction-electric furnace smelting, sodium salt roasting-direct reduction-electric furnace smelting and direct reduction-magnetic separation and so on. The blast furnace process and other methods cannot effectively utilize the titanium and vanadium resource due to the technical or environmental problems[9]. In this study, the vanadium titanomagnetite concentrate was obtained from Panxi region of China, the reserves of which account for 11.6% of vanadium and 35.17% of titanium all over the world[3]. The preparation of direct reduced iron powder and Ti-V-rich material based on reduction-magnetic separation is proposed. The process utilizes a new catalyst for titanium ore reduction in rotary kiln followed by magnetic separation. Using this novel technology, the titanium-vanadium and iron are successfully separated. Compared to the traditional reduction of Ti-bearing ore, the reduction temperature reduced to 1050 ?, leading to higher efficiency, lower energy consumption and investment, and broader applications."

Jan 1, 2018

By Juan Estrada, Mirtha Frómeta, Rubén Alcalá, Emilio Montejo, José Castellanos, Juan Berto, María Rivas

"The oxidized nickel ores from San Felipe deposit are composed mainly Smectites which gives to the pulps very unfavorable rheological .properties (cinematic viscosity and high shearing strength) for transportation processes (pumping), very low settling velocities and very low thickened pulps. These properties do not allow the preparation of high % solids, which affects the economic efficiency if a high pressure acid leach (HPAL) process is used. Pulps of close to 30% solids have very high BYS making pumping impossible. CIPIMM developed three technologies to solve these problems and to substantially increase the % solids in the pulps to be leached without a thickening step. These technologies are: • CIPIMM 2. At Preparation of pulps using additives. This method is based on the effect of some additives (inorganic salts) to improve the pulp’s properties. The use of this method allows increasing the % solids in the pulp up to 40% with good rheological properties • CIPIMM 2B. Preparation of pulps by thermal treatment of the ore previous to the preparation of the pulps. This method is based on the thermal destruction of the clays structure. Its use allows to obtain pulps with 50 - 60 % solids with excellent rheological characteristics. As a collateral effect, the Ni and Co grades increases by 10 - 15%. • CIPIMM 2C. Pulp preparation by chemical treatment. This method is based on the chemical transformation of clays, to obtain without thickening, pulps with 43- 45% solids and excellent rheological properties. The use of one of the three technologies depends on the chemical and mineralogical composition of the ores and the results of technical-economical evaluations to determine which one is the best alternative before running higher scale tests."

Jan 1, 2014

Domestic production of pyrite cinder reached 15.95 million tons in 2006. The pyrite cinder used in cement industry accounts for about 30% production. The remaining 70%, 11.17 million tons, was thrown away as waste, which brought serious environmental and resource problems. A new technology of composite pellet reduction-roasting and magnetic-separation (CPRM) has been developed to utilize pyrite cinder. Pyrite cinder sample, containing 45.56% Fe, 0.19% Cu and 1.45% S, was pelletized with addition of 5% composite agent in balling disc. Green balls after drying were reduced at 700~800 ? for 20min with 300kg/t pulverized coal injection in rotary kiln. After two stages of ball-grinding and four stages of magnetic separation, high grade magnetite concentrate with 66.23% Fe was produced, meanwhile impurities Cu and S was decreased to 0.048% and 0.053%, respectively. And iron recovery of 73.32%, desulphurization of 96.34% and decoppering degree of 74.73% were achieved. Key technique is that composite agent can accelerate reduction of Fe2O3 and transfer copper and sulphur into water-soluble inorganic salts, which can be removed during wet magnetic concentration. This new technology can be used to fully utilize pyrite cinder and produce high quality magnetite concentrates as feed for steel industry, which will help tackle the pollution problem of pyrite cinder and extend iron-bearing raw material sourcing for Chinese steel industry.

Jan 1, 2014

By F. L. Mentg

The utilization of acid leaching tailings was studied. It is obvious that the Fe in acid leaching tailings can be leached into solutions as Fe2+. In this paper, the influence of conditions, including the concentration of ferrous sulfate, pH, temperature and velocity of air flow was investigated. The optimum conditions for preparing seed crystal are as follows: the concentration of ferrous sulfate is 20 g/L; pH is 9.5~10; reaction temperature is 10~20?; velocity of air flow is 0.4m3/h. The optimum conditions for preparing iron oxide red are as follows: the concentration of ferrous sulfate is 5 g/L; reaction temperature is 80~85?; velocity of air flow is 0.13m3/h. At last, the product of iron oxide red could be prepared by ammonia method.

Jan 1, 2014

By M. Kargar Razi

According to the unique properties and many applications of nano gold powder, it was prepared from an acid leaching tail solution. The low value residual gold ions were existed in acid leaching tail solution in Mouteh gold mine in Iran with fellow heavy metals as pollutants (FeP2+P, Cu P2+P, and ZnP2+P). Preparation of nano gold particles is achieved by two steps. First, by addition of ammonia as separation step and second using suitable reagents for precipitation/extraction step. Conditions control includes pH, residence time, temperature, agitation, and molar ratio of reducing agents to reagents. The optimum results show that nano gold powder was prepared by temperature of 250 °C, urea to gold molar ratio of 3:1, and reduction time of 20 min. Also, heat treatment improves dispersion of nano sized gold particles. The properties of gold nano powders were evaluated by SEM, A.A, and UV- Vis spectroscopy methods. The size of prepared particles were about 80nm to 90nm.

Jan 1, 2014

By M. Kargar Razi

According to the unique properties and many applications of nano silver powder, it was prepared from acid leaching tail solution. The low value residual gold and silver ions were occurred with fellow heavy metals as pollutants (Fe2+, Cu 2+and Zn2+) in acid leaching tail solution in Mouteh gold mine in Iran. Preparation of nano silver particles was achieved in two steps: first, by addition of ammonia as separation step and second by using different reagents as precipitation and extraction steps. Different controlled parameters were including pH, residence time and temperature, mixing time, and reducing reagents to metals molar ratio. Acid leaching process was carried out with sulphuric and nitric acid via suitable reductants. In order to remove copper, zinc, and silver ions from solution, all of the conditions were controlled. The optimum conditions for preparation of nano silver powder with less than 90 nm were pH 10.5, hydrazine/methanol to silver molar ratio of 3 to 4, and reduction time of 5 min in 45 °C. The results were evaluated via SEM, A.A and UV- Vis spectroscopy analytical methods.

Jan 1, 2014

By Peter Ay, Matthias Schmidt, Christian Stollberg

"The aim of the study is the development of a seamless reprocessing procedure for plastics from automotive parts which are to be recycled (figure 1). Before automatic sorting can be performed, the materials first have to be identified by a near and middle infrared (NIR/MIR) system.Materials reprocessing basically includes research on size reduction, decoating, and roughening of the materials. Variants of the necessary technologies such as different shredders and mills and physico-chemical or mechanical decoating and roughening procedures together with the fundamental approaches underlying these methods are investigated and benchmarked. This allows the theoretical determination of the impact of each method not only on the overall process but also on the result achieved within the identification and sorting procedures."

Jan 1, 2003

By Y. X. Yang

Porous silica was obtained by acid leaching of chrysotile. The porous silica had been characterized by chemical analysis, powder X-ray diffraction (XRD), Fourier transform infrared spectros-copy (FT-IR), and N2 adsorption-desorption techniques. It is shown in this study that the porous silica retains the nanofibrous morphology of the original chrysotile, and produces a high specific surface area (SBET) of 391. 8 m2/g and total pore volume of 1. 05 mL/g. The increase in SBET and the total pore volume of the porous silica reflect the formation of micropores of 1.2~1.5nm and meso-pores of 3.2~3.8nm in diameter inside the porous structure. The hysteresis loop of N2 adsorption-desorption curve indicates mainly slit-shaped pores. The porous silica is amorphous, but its structure is regular to some extent. The structural unit of silica from chrysotile is a SiO4 tetrahedron and six-member silicon-oxygen rings with the tetrahedral positioned alternately up and down in the six-member rings.

Jan 1, 2014

By Xianjun Lyu, Junxiang Wang, Peng Wu, Minjie Lian

"In recent years, the efficient cementation of mine tailings is a new way to manage mine solid wastes. The traditional cement materials have a slow setting time, large dosage and poor cementation strength for fine aggregate such as mine tailings. Therefore, the preparation of new type cementitious materials for the cementation of fine tailings has great potential in the treatment of mine waste solids. The paper mainly focuses on exploring the critical factors affecting the cementing performance of granulated blast furnace slag and its performance in the cementation of fine aggregate. Results indicate that the fineness of slag has a significant effect on its cementitious activity and Portland cement clinker has a better stimulation effect on the cementitious properties of slag than lime. And, anhydrite has a better early stimulation effect on the cementitious properties of alkali-activated slag compared to semi-hydrated gypsum and dihydrate gypsum. According to a series of tests on the cementation of fine iron tailings, the optimal ratio of slag, Portland cement clinker and anhydrite is determined as 60:30:10. Compared with P.O 42.5 ordinary Portland cement, the new slag based cementitious material shows much better cementing performance on fine tailings sample. Under the dosage of 12%, the compressive strength of fine tailings mortar using slag-based cementitious material in 3 curing days is increased to 168% that of using P.O 42.5 ordinary Portland cement, while the compressive strength in 28 days curing period is increased to 194%."

Jan 1, 2018

By Y. F. Guo

Laboratory scale experiments were conducted to produce titanium-rich material from Panzhihua ilmenite. The results showed preoxidation with sodium salt additive especially for Na2B4O7 signif- icantly advance the reduction of iron in Panzhihua ilmenite. Acceleration mechanism of preoxidation with Na2B4O7 has been studied here. The maximum metallization of iron 92% can be obtained under conditions of preoxidation at 850? for 30 min and subsequent reduction at 1100? for 150 min. The rusting separation technique to reduced ilmenite has been further studied, obtaining titanium-rich product with TiO2 over 82% and the recovery of TiO2 above 97%.

Jan 1, 2014

By W. Z. Yin

It is investigated systemically in this paper that the granularity of the precursor, ZnC2O4?2H2O, is influenced by synthetic conditions. Instantaneously adding of precipitation agent is able to control the mean size of precursor ZnC2O4?2H2O under 300nm, which has great function to obtain well-dispersed ZnO nanoparticles in the next step, pyrolysis. The pyrolysis kinetics model of ZnC2O4?2H2O powder is obtained. Two steps take place during the pyrolysis. The first is dehydration, which the pyrolysis kinetic model is 2(1-a)2/3(chemical reaction), A=8.3×108s-1, E=(75.82±3.00) KJ/mol. The second is formation of ZnO, which the pyrolysis kinetic model is (1-a) (random nucleation and latter growth), A=8.45×1028s-1, E=(360.54±12.00)KJ/mol. ZnO nanoparticles obtained by pyrolysis take on self-growth behavior. It is resulted that for precursor ZnC2O4?2H2O pyrolysis time takes obvious influence on the partilces size under 420?, 500? and 600?. Finally, a new flow sheet for synthesis of ZnO nanoparticles is investigated, in which blendes is used as raw material and hydrometallurgy is introduced into it. The whole flow sheet has no industrial wastes, that is all byproducts can be used in the flow sheet recycled, resulted in the de-crease of productive cost and industrial wastes.

Jan 1, 2014

By Y. P. Lu

PET/kaolin nanocomposites were prepared with melt blending and the structure of the composites was characterized through IR techniques. The results showed that there is stable chemical bonding between PET and kaolin. In addition, the dispersion condition of nanokaolin was observed by means of SEM and TEM. As a result, the thickness of the dispersed nanokaolin particles in PET matrix is mainly from 20mm to 200nm, and the nanosized particles congregate to some extent in the samples. In addition, it was found the kaolin particles almost homogeneously dispersed in the PET matrix, without preferential orientation because of the shear effect due to melt blending. Furthermore, the mechanical properties of PET/kaolin nanocomposites are dependent on the modification efficiency of nanokaolin. With the poor efficiency, the nanokaolin particles tend to aggregate at a high content and have a bad interfacial compability between nanokaolin and PET matrix, which lead to stress concentration, so the mechanical property descends. Experiments of different contents of modified nanokalin indicated that the intensity of PET/kaolin nanocomposites decreased firstly, then increased, and then decreased, with the nanokaolin content of 4 to 5 percent, the rupture stress of the composites showed a maximum value, which was higher than that of pure PET. On one hand, nanokaolin decreases the function among PET macromolecules, which will decline the mechanical properties, on the other hand, the piece structure of kaolinite improves the intensity of the nanocomposite. When the nanokaolin content is low, the former has the dominant effect on mechanical property, while the latter will play a leading role with the content increasing. But if the nanokaolin content still increases, the agglomeration and stress concentration will be obvious.

Jan 1, 2014

By G. H. Li

Preparation strontium carbonate with celestite concentrate by flotation is studied by agglomeration-reduction roasting process. It is shown that, the drop strength of green pellet is greater than 4 times?(0.5m) -1 under the balling conditions of moisture of 9% and time of 18~20min. Lignin xanthate obviously improves the ballability of the celestite concentrate due to the increase of surface hydrophilicity, therefore, the balling rate is increased, as well as green ball strength. The drop strength of 7 times?(0.5m) -1 can be obtained when the lignin xanthate dosage is 0.5%~1%. Reduction roasting with anthracite shows that the SrSO4 conversion is 82%~83% for celestite concentrate pellet, under the optimal conditions of roasting temperature of 1100~1150? and time of 30min, and it is 10% higher than conversion of celestite lump under the same conditions. The strontium carbonate are prepared after roasted pellets are leached, purified and carbonated, and the SrCO3 content is higher than 97% , while the content of CaCO3 is less than 0.3%.

Jan 1, 2014