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By D. B. Dow

This report on methods employed for dehydrating oil-field emulsions, is the second of a series prepared as a result of a study of oil-field emulsions recently completed by the writer. The first paper2 dealt with the factors responsible for the formation of emulsions. A third paper will discuss the physical chemistry involved in the formation and resolution of such emulsions. In the early development of the oil fields of Pennsylvania, no emulsion troubles of any consequence were encountered, nor to any serious extent in the oil fields of other Eastern States: However, with the development of fields west of the Mississippi in Oklahoma, Kansas, Texas and California, where heavier oils of different characteristics were found, the problem of dealing with cut oil soon became of great importance.

Jan 1, 1925

By C. O. Anderson, W. M. Meyers

Since 1922, when a brief report3 on the production and utilization of garnet was issued by the Bureau of Mines, there have been a number of interest—in developments in the technology of that mineral. Greater activity has been displayed in mining, new mills have been erected, and more attention has been paid to improvements in milling so that a more efficient and economical recovery of garnet has been possible. These activities have resulted in larger production; therefore, attempts are being made to broaden the market for garnet abrasives, and to find new uses for the unusual combination of physical properties than this mineral possesses. The writers have recently completed a field study of the occurrence, methods of mining and milling of garnet, and the manufacture and utilization of abrasive garnet products. This preliminary report indicates the most important sources of garnet, the methods by which it is recovered, and the manner in which it is recovered, and the manner in which it is utilized.Chemical and Physical Properties.The term ""garnet"" is applied to a closely related group of minerals which crystallize in the caste forms and possess similar physical properties, although their chemical composition may exhibit greater variation. The chemical composition of the garnet group may be represented by the general formula 3R"" O.R""' 203.3S102, in which R represents the bivalent elements calcium, magnesium, in the manganese state and ferrous iron, R"" represents the trivalent elements, ferric iron, aluminum and chromium in the chromie state. An account of the amorphous substitution of the different bivalent and trivalent elements, specimens whose composition may be represented by a definite formula are rare, the composition of any given specimen generally exhibits treat complexity.

Jun 1, 1925

By D. B. Dow

This paper on the physical chemistry of oil-field emulsions is the last of a series of three prepared as a result of a study of oil-field emulsions. The first paper3 deals with the factors responsible for the formation of emulsions, find the second4 with methods now utilized for dehydrating oil-field emulsions. A more complete report of the whole investigation is in preparation. The laws governing the formation and resolution of oil-field emulsions fall in that branch of physical chemistry doling with colloids. Much work has been done by the physical chemist on colloids And emulsions, and, although most of this work was on commercial and pharmaceutical emulsions, yet the principles developed apply in a general gray to oil-field emulsions.

Jan 1, 1925

By A. W. Fahrenwald

The art of flotation has developed rapidly. Numerous technical staffs and individual investigators have, by their combined efforts, developed practicable methods of concentrating ores which ten or even five years ago were considered complex and impossible of commercial treatment. Also the work of those who have been engaged in pure research on the fundamentals of flotation has helped greatly to expedite the general development of the process. However, in spite of the highly successful practical operation of the flotation process, results are obtained and things happen that we are unable to explain completely, although much is known about the theory of the process. The rapid stride in flotation concentration, it is noteworthy to point out, is due to the freer exchange of facts and data by the staffs of the larger mining companies and the patent controlling corporations, and by investigators in general. Generally speaking, one may visit any mining plant and by presentation of proper credentials, be shown all that is going on or that is being done.

Jan 1, 1925

By J. E. Tiffany, J. J. McKitterick

"IntroductionThe Bureau of Mines is investigating the fundamental factors in breaking down coal at the face, which govern the production of lump coal in typical mines working, different coal beds. Tiffany and Nelson in 1923-21 conducted tests on methods of blasting and use of different explosives, in a mine working the Pittsburgh bed in Pennsylvania. They determined come of these factors quantitatively, and compared their results with those obtained when the regular mine practice was followed.Results of Previous InvestigationThe tests by Tiffany and Nelson showed that the use of the cartridge of smaller diameter than that used in mine practice, resulted in an increase of 5 per cent in the amount of lump coal passing over a 1-1/4-inch bar screen, with a reduction of 32 per cent by weight in amount of explosive required. On the other hand, they found that on reducing the weight of charge 20 per cent, and using the cartridge of larger diameter, the round would not throw down the coal satisfactorily.Experiments with ""snubbing"" showed a similar improvement in quantity of lump coal, end the coal that was blasted rolled forward into the working place. however, in recent tests at another mine where the coal Lad different physical characteristics, snubbing did not always result in the coal rolling forward, on account of clinging to the ribs, and was not found to be an advantage. Therein the writers of this paper recommend that tests be made before deciding upon the adoption of snubbing in a particular mine."

Aug 1, 1925

By Horace M. Lawrence, Edmund S. Leaver

"The sulphidizing filming of minerals in oxide ores as a preliminary treatment to aid their recovery by flotation is known practice. In this work the use of barium polysulphide does not appear to have been considered. A study of the properties of barium lead to the following comparative investigation of the sulphides and polysulphides of the alkaline and alkaline-earth metals. It is thought that barium polysulphide may prove to be a more satisfactory sulphidizing reagent than others now in use under conditions that favor the cheaper barium reagent.For the investigation two fairly typical oxidized ores of copper and lead were selected. The copper ore came from the Big Indian Mine in southeastern Utah, and assayed 3.8% Cu; the copper was present in a sandstone gangue mainly as the carbonates, malachite and azurite, with less than 0.2% as sulphides, or silicate. The lead ore is from the Tintic Standard mine in the Tintic district, Utah. It is typical of the oxidized lead-silver ores of that district; the lead is present in an oxidised form in a siliceous gangue, much: Uncolored by ferric oxide. The sample assayed 5.15% Pb and 11.3 oz. Ag.In addition to the results obtained in this investigation, there are included some results secured by Mr. J. B. Lain, consulting metallurgist of Reno, Nevada, on a sample of ore from the Chino Copper Co. The ore assayed about 1.7% Cu, of which about 0.25% was nonsuiphide."

Aug 1, 1925

By A. W. Fahrenwald

"The rate of progress in the last three years in the development of differential flotation has been rapid beyond the realization of most people. Differential flotation is no longer a ""delicate"" and unreliable process, but is now in wide use. Its ""safety"" is due to the wide use of chemicals which either depress or enhance floatability by definite modification of surfaces.The extent of the development and reliability of differential flotation methods any be emphasized by pointing out that there are now several customall-flotation"" plants in this country treating complex lead-zinc-iron ores from widely separated mines. While these ores differ in chemical composition and apparently in physical nature, the various ores treated in such a plant are passed through the same crushing and grinding equipment and through the same flotation machines and flow sheet with only slight changes, if any, in quantity and kind of chemicals and oils added.Some of the development in differential flotation is due to intelligent research on the part of well-trained chemists and metallurgists; much of It must be attributed to empirical testing.Much of the success in differential flotation is due to more care being given to constant conditions with regard to such factors as (1) fineness of grinding, (2) density of pulp entering flotation machines, (3) quantity and constancy of oils and chemicals added to the pulp, and (4) place of addition of reagents, and time of ""conditioning"" treatment of pulp with reagents."

Aug 1, 1925

By I. N. Beall

The present survey indicates 'that the average volatility of motor gasoline now being marketed throughout the country falls well within the limits of Federal Specifications. As would be expected, there is a slight decrease in volatility as compared with the gasoline marketed last wine:., but on the average the gasoline sold today is about the same as that sold last summer. During the past five years the Bureau of Mines has made semi-annual surveys of the gasoline marketed in the United States. To obtain a sample of each gasoline sold is obviously impracticable, but the cities in which samples have been collected have been so chosen as to be representative of the more important marketing territories. It is believed, therefore, that the samples obtained are indicative of the quality of gasoline marketed throughout the country.

Jan 1, 1925

By A. L. Murray

"Welfare endeavor in connection with both the metal and the coal mines of Utah has shown gratifying progress during recent years, and in most mining towns of the state, both the operators and their employees deserve much credit for the efforts put forth to better the living, working, educational and recreational conditions. Progress has been and is being made, but there are still a few important towns where purer water and better sewage disposal are pressing needs.In the older metal-mining towns that are incorporated and are independent of the mining properties operating in the vicinity, less opportunity is presented for the companies to exercise efforts looking toward improved welfare conditions than in company towns controlled by the mine operators.However, even in such towns the companies can do much to better welfare conditions, as shown by the progress in Bingham Canyon during the past several years. The Utah Copper Company has spent $800,000 since 1920, in the erection of modern brick cottages, apartment houses and the Germnell Memorial Club. The cottages and apartment houses have every convenience to be found in up-to-date city homes. The Gemmell Memorial Club erected and equipped at a cost of $175,000 was provided by the company for the benefit of the Utah Copper employees living in the canyon and has been made the recreational center for the camp. Another improvement is the $100,000 fireproof hotel built by the United States Mine of the United States Mining, Smelting and Refining; Co. in the Copperfield section of Bingham Canyon. This hotel will accommodate 105 men exclusive of hotel help and has all the conveniences of a city hotel."

Sep 1, 1925

By Ernest E. Berger

"INTRODUCTIONOne of the outstanding problems in the normetallic industries, and one which involves two of the greatest of these industries, cement and gypsum, is the reaction of Portland cement with calcium sulphate. To all Portland cement clinker there is added in the manufacturing process, a small amount of retarder, as a necessary ingredient of the finished product. This retards the initial set, increases the strength, and adds to the plasticity of the cement so it will have the desired working and setting qualities. The retarder commonly used is gypsum, (CaSOA.2HO), which is the hydrous form calcium sulphate. Calcium sulphate is also available as plaster of Paris (CaSO4 1/2 HC) and anhydrite (CaSO4). The purpose of this inquiry was to determine the form or mixture of forms best adapted for retarder. The problem is complicated by the fact that cement clinker is a complex mixture of calcium silicates and aluminates, and that clinker from different mills, making cement of approximately equal quality, differs considerably in chemical constitution. Thus the same retarder may give very different results with different types of clinker, especially in the percentage of retarder required for the same degree of retardation.It has been known for some time that a small percentage of plaster of Paris will greatly retard the time of set of Portland cement as well as increase its strength and plasticity, but whether gypsum and anhydrite will have a similar effect is as such disputed question. The offects of gypsum have received little consideration in laboratory research because, even though it will not retard a clinker when the two are mixed in the laboratory, as has been noted in some instances, the cement will have a normal set when the two arc mixed in the large tube mill at the plant, so that practically, gypsum seems to be equally as goou as plaster of Paris, and because of the great saving in cost it has been used almost exclusively."

Sep 1, 1925

"Requests are frequently received by the Information Service of the Bureau of Mines for published information on the coals of different foreign countries, as compared with coals mined in the United States. The analyses of various coals from several countries on the Pacific, which were submitted to the Fuels Division for certain tests between the years 1913 and 1916, may be of interest, and are shown below: Results of Analyses of Various Coals from China, New Zealand, Japan and Australia."

Sep 1, 1925

By Thomas Varley

Data on the consumption of reagents used in flotation during the years 1923 and 1924, in metallurgical plants in the Unites States, are presented in this paper. Two previous reports Lave been issued by the Bureau of Mines on consumption of oils and other reagents used to flotation - namely, "Statement of Flotation Oils," by O. C. Ralston, issued in 1913, and Serial No. 2203, "Consumption of Reagents Used in Flotation," by Thomas Varley, for the year 1919, issued in January, 1921.

Jan 1, 1925

By C. H. Kats, E. G. Meiter, J. J. Bloomfield

"INTRODUCTION.Street manholes for underground power and signal circuits, and for sewers vary in size from small openings that a workman can enter, to large central vaults. As the gas hazards in manholes are similar to those in mines, the mine safety committee of the Bureau of Mines was asked whether the miners' flame safety lamp is a practicable device for indicating inflammable gases in manholes.The coal miner detects firedamp (methane or CH4) with his flame safety lamp by observing the luminous can or the increased length of flame that appears when 1.5 per cent or more of the combustible gas is present. The lamp flame also warns him of lack of oxygen by going out when the oxygen becomes less than 16 to L7 per cent. A tentative rule regarding the proposed use of safety lamps at manholes has been suggested previously as follows: ""Testing for gas: Do not enter manholes until you have .assured yourself that the manholes are free from dangerous gases, by testing with an approved safety lamp, by ventilation, or by other adequate methods."" The Bureau's committee recommended that miners' flame safety lamps are not suitable,testing in manholes because hydrogen gas may be formed therein. The flame safety lamps approved by the Bureau of Mines for use in aseous mines are safe in presence of methane and while not tested against the members of the paraffin hydrocarbon series (CnH2n+2) higher than methane they been have been used therein; the lamps should not be used in hydrogen or acetylene they can initiate explosions in presence of these gases."

Oct 1, 1925

By W. W. Adams

luring the past two years the Bureau of ?,lines has been receiving from 100 to 150 coal mines in various States a report of each accident causing death, permanent total disability, permanent partial disability, or temporary disability lasting beyond the remainder of the day or shift on which the accident occurred. For each 100 accidents in these groups, there are perhaps from 35 to 45 accidents that do not disable the employee beyond the remainder of the day, and of these fraction-of-a-day accidents the Bureau has compiled no statistics. Information revealed by the reports is to the effect that falls of roof and coal in bituminous coal mines are responsible for 28 per cent of the temporary injuries to underground workers and 33 per cent of the days lost from all temporary injuries underground; they also indicate that falls caused 59 per cent of the deaths from all causes underground. Figures compiled by R. N. Hosler, of the Pennsylvania. Mine Rating Bureau, and covering accidents in bituminous; minis in that State, chow that 61 per cent of the deaths underground during the years 1917-1921 wore due to falls. Neither of these percentage figures includes deaths in major explosions; figures for all bituminous mines in the United States during the five years 1920-1024, inclusive of deaths in major explosions, show that 52 per cent of the deaths underground and in shafts were due to falls of roof and coal.

Jan 1, 1925

By Charles H. Shapiro

[In July, 1924, the Bureau of Mines, through its Petroleum Experiment Station, undertook a field study of methods used in oil-field shops for dressing and tempering fishtail bits. The purpose of this work was to suggest chances that would be helpful to the bit-dresser in turning out better treated, harder, and tougher bits, and thus cut down the excessive loss of time caused by too frequent changing of bits. It was the intention to eliminate as much as possible the guess work connected with dressing and tempering bits under the method of judging temperature by eye, by developing; practical methods of controlling temperature. If there were some possible means of accurate temperature control, then it would be an easy matter to bring all bits to the proper temperature for maximum hardness rued toughness, thus doing away with the source of most of the trouble experienced in the present method of bit tempering. Shortly after the Bureau of Mines began its study, a chop In the Stroud, Oklahoma, oil field announced method for tempering fishtail bits that Would increase the drilling footage of each bit treated. The method accurately regulates, by the use of a bath of molten salt, the temperature to which a bit is heated before being quenched to produce hardness. There is nothing new in using silt baths for the, heat treatment of steel, but this was the first attempt to introduce it into the oil fields for use in hardening bits, and for this purpose it proved to be admirably adapted. In tempering, by the old system it is not possible to measure the temperature of the heated bit by means of an electrical instrument for that purpose, whereas this is an easy matter with the now method. If heating steel to slightly above the critical point rind quenching suddenly will bring out its best properties, their here is a method of accurately bringing the steel to that point.]

Jan 1, 1925

By C. W., Davie

"DEFINITIONDiatomaceous earth consists almost entirely of the silicious remains of minute flowerless aquatic plants known as diatoms. The name diatomaceous earth, therefore, is to be preferred to others such as trade names, inappropriate terms, or names correctly applied to some other product. The following names should, therefore, not be used for diatomaceous earth,-- kieselguhr, infusorial earth, diatomite, celite, moler, bergnehl, English rottenstone, tripoli, tripolite, fossil earth, desmid earth, white peat, tellurine, randanite, ceyssatite, or any trade name.FORMATIONDiatoms live in practically all kinds of water, fresh or salt, hot or cold, still or running and under different conditions of depth and pressure. These minute plants assimilate inorganic salts from their environment and produce skeletons of silica much as mollusks secrete lime and form their Shalls. When the diatoms die they settle to the bottom together with anything else which may be present, such as sand, clay or volcanic ash. The organic matter gradually disappears leaving the silicious skeletons of the diatoms which, with impurities, make up the deposits of diatomaceous earth. These deposits which are still being foamed at the present time and which were produced throughout very different epochs, were more prolifically formed in the Tertiary, so that the thickest beds so far discovered are of that Age."

Nov 1, 1925

By A. C. Fieldner

The Bureau of Mires in its investigations of gas masks for use in mines and allied industries has studied and developed various types of masks for protection against noxious uses and furies that may be present in atmospheres encountered in mines, metallurgical works, chemical and other industries. As a result of these investigations, the Bureau issued a schedule5 of tests under which manufacturer who voluntarily submit masks for examination and test, are issued an approval certificate for masks that meet the Bureau's specifications. In the Bureau's schedule, masks arc classified by types of gases removed, as type A masks for protection against acid gases; B; organic vapor; C, ammonia; D, carbon monoxide; E, smoke, dust, and mist; F, special gases; combination types, and type N, for protection in air against all gases, vapors, and smokes. The purpose of this paper is to describe the physical and chemical tests that were conducted on a type N mask, the protective principles and construction of the essential elements of the canister and attachments, and the uses and limitations of this type of mask. The mask tested is known as the all-service mask, manufactured by the Mine Safety Appliances Co., Pittsburgh, Pa;, and was approved (approval No. 1403) by the Bureau on July 1, 1924, for protection from all classes of poisonous vapors, gases and smokes in air.

Jan 1, 1925

By Ludwig Schmidt

"IntroductionThe evaporation losses of gasoline in the refinery, can be reduced by proper methods of refinery construction and operation. When gasoline evaporates slowly, as when stored in tanks that are not vapor tight, the most volatile part evaporates first, so that the remaining liquid in not only less in volume, but is also lower in quality. In some,evaporation changes the characteristics of the product so much that it must be reblended to meet trade specifications.Refiners are, therefore, greatly interested in the various appliances and methods used to reduce these losses. In the past this interest has been directed largely to storage tanks, probably because evaporation from tanks is more readily observed than losses during other refinery operations. As tests by the Bureau of Mines on evaporation of gasoline from small storage tanks had indicated that the losses during the various stages of refining might be equal to or greater than those of standing storage, a survey was during the spring and early summer months of 1924 in a large number of refineries in the Mid-Continent field. In order to enable the refiner to select the results of those tests that conform most nearly to the conditions that he has to meet, tests were conducted at various stages of refining, as follows: (1) Randown tanks, (2) (agitators), (3) filling tank cars, (4) storage of refined products, and (3) miscellaneous handling. The results are presented in this paper."

Nov 1, 1925

By L. G. Marsh

The manufacture of lubricating oils from wax-bearing crude petroleums involves the removal and recovery of the paraffin wax contained in the lubricating distillates. During this process several intermediate products are formed, among them the mixture of waxes and oils known to the refiners as "foots oil." Because of its complex character, foots oil is little understood, and therefore methods of handling it in refineries are often inefficient. The Bureau of Mines is studying the manufacture of lubricating oils, and during the work has investigated the redistillation of foots oil. This report gives in brief the results of the investigation, and recommendations based upon it.

Jan 1, 1926

By R. D. Leitch

The pollution of streams by acid mine drainage has become of great importance in the past few years in certain regions of the United States. Large quantities of acids are used in a discharged from other industries than mining, notably in tube, sheet, tin-plate and era hell inn works. These are usually less important then coal mines as a source of acid drainage, because of their more limited distribution throughout the States most affected by acid waters and their relatively smaller numbers. Streams are naturally alkaline and are, therefore, able to take care of rather large quantities of acid wastes, but when such enormous quantities as are often found in mining districts enter the streams, the natural alkalinity is quickly overcome. When a neutral or almost neutral condition has been reached, the further addition of a relatively slight quantity of acids will cause a great difference in the quality of the water.

Jan 1, 1926